Matching Items (4)
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- All Subjects: Thermodynamics
- All Subjects: Planetary Science
- Creators: Christensen, Philip R.
Description
Water is a critical resource for future human missions, and is necessary for understanding the evolution of the Solar System. The Moon and Mars have water in various forms and are therefore high-priority targets in the search for accessible extraterrestrial water. Complementary remote sensing analyses coupled with laboratory and field studies are necessary to provide a scientific context for future lunar and Mars exploration. In this thesis, I use multiple techniques to investigate the presence of water-ice at the lunar poles and the properties of martian chloride minerals, whose evolution is intricately linked with liquid water.
Permanently shadowed regions (PSRs) at the lunar poles may contain substantial water ice, but radar signatures at PSRs could indicate water ice or large block populations. Mini-RF radar and Lunar Reconnaissance Orbiter Camera Narrow Angle Camera (LROC NAC) products were used to assess block abundances where radar signatures indicated potential ice deposits. While the majority of PSRs in this study indicated large block populations and a low likelihood of water ice, one crater – Rozhdestvenskiy N – showed indirect indications of water ice in its interior.
Chloride deposits indicate regions where the last substantial liquid water existed on Mars. Major ion abundances and expected precipitation sequences of terrestrial chloride brines could provide context for assessing the provenance of martian chloride deposits. Chloride minerals are most readily distinguished in the far-infrared (45+ μm), where their fundamental absorption features are strongest. Multiple chloride compositions and textures were characterized in far-infrared emission for the first time. Systematic variations in the spectra were observed; these variations will allow chloride mineralogy to be determined and large variations in texture to be constrained.
In the present day, recurring slope lineae (RSL) may indicate water flow, but fresh water is not stable on Mars. However, dissolved chloride could allow liquid water to flow transiently. Using Thermal Emission Imaging System (THEMIS) data, I determined that RSL are most likely not fed by chloride-rich brines on Mars. Substantial amounts of salt would be consumed to produce a surface water flow; therefore, these features are therefore thought to instead be surface darkening due to capillary wicking.
Permanently shadowed regions (PSRs) at the lunar poles may contain substantial water ice, but radar signatures at PSRs could indicate water ice or large block populations. Mini-RF radar and Lunar Reconnaissance Orbiter Camera Narrow Angle Camera (LROC NAC) products were used to assess block abundances where radar signatures indicated potential ice deposits. While the majority of PSRs in this study indicated large block populations and a low likelihood of water ice, one crater – Rozhdestvenskiy N – showed indirect indications of water ice in its interior.
Chloride deposits indicate regions where the last substantial liquid water existed on Mars. Major ion abundances and expected precipitation sequences of terrestrial chloride brines could provide context for assessing the provenance of martian chloride deposits. Chloride minerals are most readily distinguished in the far-infrared (45+ μm), where their fundamental absorption features are strongest. Multiple chloride compositions and textures were characterized in far-infrared emission for the first time. Systematic variations in the spectra were observed; these variations will allow chloride mineralogy to be determined and large variations in texture to be constrained.
In the present day, recurring slope lineae (RSL) may indicate water flow, but fresh water is not stable on Mars. However, dissolved chloride could allow liquid water to flow transiently. Using Thermal Emission Imaging System (THEMIS) data, I determined that RSL are most likely not fed by chloride-rich brines on Mars. Substantial amounts of salt would be consumed to produce a surface water flow; therefore, these features are therefore thought to instead be surface darkening due to capillary wicking.
ContributorsMitchell, Julie (Author) / Christensen, Philip R. (Thesis advisor) / Bell Iii, James F (Committee member) / Desch, Steven J (Committee member) / Hartnett, Hilairy E (Committee member) / Robinson, Mark S (Committee member) / Arizona State University (Publisher)
Created2017
Description
Planetary surface studies across a range of spatial scales are key to interpreting modern and ancient operative processes and to meeting strategic mission objectives for robotic planetary science exploration. At the meter-scale and below, planetary regolith conducts heat at a rate that depends on the physical properties of the regolith particles, such as particle size, sorting, composition, and shape. Radiometric temperature measurements thus provide the means to determine regolith properties and rock abundance from afar. However, heat conduction through a matrix of irregular particles is a complicated physical system that is strongly influenced by temperature and atmospheric gas pressure. A series of new regolith thermal conductivity experiments were conducted under realistic planetary surface pressure and temperature conditions. A new model is put forth to describe the radiative, solid, and gaseous conduction terms of regolith on Earth, Mars, and airless bodies. These results will be used to infer particle size distribution from temperature measurements of the primitive asteroid Bennu to aid in OSIRIS-REx sampling site selection. Moving up in scale, fluvial processes are extremely influential in shaping Earth's surface and likely played an influential role on ancient Mars. Amphitheater-headed canyons are found on both planets, but conditions necessary for their development have been debated for many years. A spatial analysis of canyon form distribution with respect to local stratigraphy at the Escalante River and on Tarantula Mesa, Utah, indicates that canyon distribution is most closely related to variations in local rock strata, rather than groundwater spring intensity or climate variations. This implies that amphitheater-headed canyons are not simple markers of groundwater seepage erosion or megaflooding. Finally, at the largest scale, volcanism has significantly altered the surface characteristics of Earth and Mars. A field campaign was conducted in Hawaii to investigate the December 1974 Kilauea lava flow, where it was found that lava coils formed in an analogous manner to those found in Athabasca Valles, Mars. The location and size of the coils may be used as indicators of local effusion rate, viscosity, and crustal thickness.
ContributorsRyan, Andrew J (Author) / Christensen, Philip R. (Thesis advisor) / Bell, James F. (Committee member) / Whipple, Kelin X (Committee member) / Ruff, Steven W (Committee member) / Asphaug, Erik I (Committee member) / Arizona State University (Publisher)
Created2018
Description
The seasonal deposition of CO2 on the polar caps is one of the most dynamic processes on Mars and is a dominant driver of the global climate. Remote sensing temperature and albedo data were used to estimate the subliming mass of CO2 ice on south polar gullies near Sisyphi Cavi. Results showed that column mass abundances range from 400 - 1000 kg.m2 in an area less than 60 km2 in late winter. Complete sublimation of the seasonal caps may occur later than estimated by large-scale studies and is geographically dependent. Seasonal ice depth estimates suggested variations of up to 1.5 m in depth or 75% in porosity at any one time. Interannual variations in these data appeared to correlate with dust activity in the southern hemisphere. Correlation coefficients were used to investigate the relationship between frost-free surface properties and the evolution of the seasonal ice in this region. Ice on high thermal inertia units was found to disappear before any other ice, likely caused by inhibited deposition during fall. Seasonal ice springtime albedo appeared to be predominantly controlled by orientation, with north-facing slopes undergoing brightening initially in spring, then subliming before south-facing slopes. Overall, the state of seasonal ice is far more complex than globally and regionally averaged studies can identify.
The discovery of cryovolcanic features on Charon and the presence of ammonia hydrates on the surfaces of other medium-sized Kuiper Belt Objects suggests that cryovolcanism may be important to their evolution. A two-dimensional, center-point finite difference, thermal hydraulic model was developed to explore the behavior of cryovolcanic conduits on midsized KBOs. Conduits on a Charon-surrogate were shown to maintain flow through over 200 km of crust and mantle down to radii of R = 0.20 m. Radii higher than this became turbulent due to high viscous dissipation and low thermal conductivity. This model was adapted to explore the emplacement of Kubrik Mons. Steady state flow was achieved with a conduit of radius R = 0.02 m for a source chamber at 2.3 km depth. Effusion rates computed from this estimated a 122 - 163 Myr upper limit formation timescale.
The discovery of cryovolcanic features on Charon and the presence of ammonia hydrates on the surfaces of other medium-sized Kuiper Belt Objects suggests that cryovolcanism may be important to their evolution. A two-dimensional, center-point finite difference, thermal hydraulic model was developed to explore the behavior of cryovolcanic conduits on midsized KBOs. Conduits on a Charon-surrogate were shown to maintain flow through over 200 km of crust and mantle down to radii of R = 0.20 m. Radii higher than this became turbulent due to high viscous dissipation and low thermal conductivity. This model was adapted to explore the emplacement of Kubrik Mons. Steady state flow was achieved with a conduit of radius R = 0.02 m for a source chamber at 2.3 km depth. Effusion rates computed from this estimated a 122 - 163 Myr upper limit formation timescale.
ContributorsMount, Christopher (Author) / Christensen, Philip R. (Thesis advisor) / Desch, Steven J (Committee member) / Bell, James F. (Committee member) / Clarke, Amanda B (Committee member) / Whipple, Kelin X (Committee member) / Arizona State University (Publisher)
Created2019
Description
Carbon allotropes are the basis for many exciting advancements in technology. While sp² and sp³ hybridizations are well understood, the sp¹ hybridized carbon has been elusive. However, with recent advances made using a pulsed laser ablation in liquid technique, sp¹ hybridized carbon allotropes have been created. The fabricated carbon chain is composed of sp¹ and sp³ hybridized bonds, but it also incorporates nanoparticles such as gold or possibly silver to stabilize the chain. The polyyne generated in this process is called pseudocarbyne due to its striking resemblance to the theoretical carbyne. The formation of these carbon chains is yet to be fully understood, but significant progress has been made in determining the temperature of the plasma in which the pseudocarbyne is formed. When a 532 nm pulsed laser with a pulsed energy of 250 mJ and pulse length of 10ns is used to ablate a gold target, a peak temperature of 13400 K is measured. When measured using Laser-Induced Breakdown spectroscopy (LIBS) the average temperature of the neutral carbon plasma over one second was 4590±172 K. This temperature strongly suggests that the current theoretical model used to describe the temperature at which pseudocarbyne generates is accurate.
ContributorsWala, Ryland Gerald (Co-author) / Wala, Ryland (Co-author) / Sayres, Scott (Thesis director) / Steimle, Timothy (Committee member) / Drucker, Jeffery (Committee member) / Historical, Philosophical & Religious Studies (Contributor) / Dean, W.P. Carey School of Business (Contributor) / Department of Physics (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2019-05