Matching Items (4)
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- All Subjects: Meteorites
- Creators: Anbar, Ariel D
- Creators: Sharp, Thomas G
- Status: Published
Description
The occurrence of exogenic, meteoritic materials on the surface of any world presents opportunities to explore a variety of significant problems in the planetary sciences. In the case of Mars, meteorites found on its surface may help to 1) constrain atmospheric conditions during their time of arrival; 2) provide insights into possible variabilities in meteoroid type sampling between Mars and Earth space environments; 3) aid in our understanding of soil, dust, and sedimentary rock chemistry; 4) assist with the calibration of crater-age dating techniques; and 5) provide witness samples for chemical and mechanical weathering processes. The presence of reduced metallic iron in approximately 88 percent of meteorite falls renders the majority of meteorites particularly sensitive to oxidation by H2O interaction. This makes them excellent markers for H2O occurrence. Several large meteorites have been discovered at Gusev Crater and Meridiani Planum by the Mars Exploration Rovers (MERs). Significant morphologic characteristics interpretable as weathering features in the Meridiani suite of iron meteorites include a 1) large pit lined with delicate iron protrusions suggestive of inclusion removal by corrosive interaction; 2) differentially eroded kamacite and taenite lamellae on three of the meteorites, providing relative timing through cross-cutting relationships with deposition of 3) an iron oxide-rich dark coating; and 4) regmaglypted surfaces testifying to regions of minimal surface modification; with other regions in the same meteorites exhibiting 5) large-scale, cavernous weathering. Iron meteorites found by Mini-TES at both Meridiani Planum and Gusev Crater have prompted laboratory experiments designed to explore elements of reflectivity, dust cover, and potential oxide coatings on their surfaces in the thermal infrared using analog samples. Results show that dust thickness on an iron substrate need be only one tenth as great as that on a silicate rock to obscure its infrared signal. In addition, a database of thermal emission spectra for 46 meteorites was prepared to aid in the on-going detection and interpretation of these valuable rocks on Mars using Mini-TES instruments on both MER spacecraft. Applications to the asteroidal sciences are also relevant and intended for this database.
ContributorsAshley, James Warren (Author) / Christensen, Philip R. (Thesis advisor) / Sharp, Thomas G (Committee member) / Shock, Everett L (Committee member) / Hervig, Richard L (Committee member) / Zolotov, Mikhail Y (Committee member) / Arizona State University (Publisher)
Created2011
Description
Remote sensing in visible to near-infrared wavelengths is an important tool for identifying and understanding compositional differences on planetary surfaces. Electronic transitions produce broad absorption bands that are often due to the presence of iron cations in crystalline mineral structures or amorphous phases. Mars’ iron-rich and variably oxidized surface provides an ideal environment for detecting spectral variations that can be related to differences in surface dust cover or the composition of the underlying bedrock. Several imaging cameras sent to Mars include the capability to selectively filter incoming light to discriminate between surface materials.
At the coarse spatial resolution provided by the wide-angle Mars Color Imager (MARCI) camera aboard the Mars Reconnaissance Orbiter (MRO), regional scale differences in reflectance at all wavelengths are dominated by the presence or absence of Fe3+-rich dust. The dust cover in many regions is highly variable, often with strong seasonal dependence although major storm events can redistribute dust in ways that significantly alter the albedo of large-scale regions outside of the normal annual cycle. Surface dust reservoirs represent an important part of the martian climate system and may play a critical role in the growth of regional dust storms to planet-wide scales. Detailed investigation of seasonal and secular changes permitted by repeated MARCI imaging coverage have allowed the surface dust coverage of the planet at large to be described and have revealed multiannual replenishing of regions historically associated with the growth of storms.
From the ground, rover-based multispectral imaging acquired by the Mastcam cameras allows compositional discrimination between bedrock units and float material encountered along the Curiosity rover’s traverse across crater floor and lower Mt. Sharp units. Mastcam spectra indicate differences in primary mineralogy, the presence of iron-bearing alteration phases, and variations in iron oxidation state, which occur at specific locations along the rover’s traverse. These changes represent differences in the primary depositional environment and the action of later alteration by fluids circulating through fractures in the bedrock. Loose float rocks sample materials brought into the crater by fluvial or other processes. Mastcam observations provide important constraints on the geologic history of the Gale Crater site.
At the coarse spatial resolution provided by the wide-angle Mars Color Imager (MARCI) camera aboard the Mars Reconnaissance Orbiter (MRO), regional scale differences in reflectance at all wavelengths are dominated by the presence or absence of Fe3+-rich dust. The dust cover in many regions is highly variable, often with strong seasonal dependence although major storm events can redistribute dust in ways that significantly alter the albedo of large-scale regions outside of the normal annual cycle. Surface dust reservoirs represent an important part of the martian climate system and may play a critical role in the growth of regional dust storms to planet-wide scales. Detailed investigation of seasonal and secular changes permitted by repeated MARCI imaging coverage have allowed the surface dust coverage of the planet at large to be described and have revealed multiannual replenishing of regions historically associated with the growth of storms.
From the ground, rover-based multispectral imaging acquired by the Mastcam cameras allows compositional discrimination between bedrock units and float material encountered along the Curiosity rover’s traverse across crater floor and lower Mt. Sharp units. Mastcam spectra indicate differences in primary mineralogy, the presence of iron-bearing alteration phases, and variations in iron oxidation state, which occur at specific locations along the rover’s traverse. These changes represent differences in the primary depositional environment and the action of later alteration by fluids circulating through fractures in the bedrock. Loose float rocks sample materials brought into the crater by fluvial or other processes. Mastcam observations provide important constraints on the geologic history of the Gale Crater site.
ContributorsWellington, Danika (Author) / Bell Iii, James F (Thesis advisor) / Christensen, Philip R. (Committee member) / Robinson, Mark S (Committee member) / Sharp, Thomas G (Committee member) / Till, Christy B. (Committee member) / Arizona State University (Publisher)
Created2018
Description
Meteorites and their components can be used to unravel the history of the early Solar System. Carbonaceous chondrites are meteorites that originated from undifferentiated parent bodies that formed within a few million years of the beginning of the Solar System. These meteorites contain calcium-aluminum-rich inclusions (CAIs), which are the oldest dated solids in the Solar System at ~4.567 billion years old and thus preserve a record of the earliest stage of Solar System formation. The isotopic compositions of CAIs and bulk carbonaceous chondrites can be used to identify the sources of material inherited by the protoplanetary disk, assess the degree of mixing in the disk, and evaluate sample origins and potential genetic relationships between parent bodies. In particular, mass-independent Cr and Ti isotopic compositions have proven to be especially useful for these purposes.
In this work, I first developed new methods for the chemical separation of Cr and Ti, improving the reliability of existing methods to ensure consistent yields and accurate isotopic measurements. I then measured the Cr and Ti isotopic compositions of CAIs from CV and CK chondrites to determine the extent of isotopic heterogeneity in the CAI-forming region and assess the role of CAIs in the preservation of planetary-scale isotopic anomalies. My results show that all measured CAIs originated from a common isotopic reservoir that incorporated material from at least three distinct nucleosynthetic sources and preserved limited isotopic heterogeneity. These results also suggest that planetary-scale isotopic anomalies cannot be attributed solely to the transport of CAIs from one part of the solar nebula to another. I finally measured the Cr and Ti isotopic compositions of bulk CM, CO, and ungrouped chondrites to evaluate the relationship between CM and CO chondrites, which have been suggested to originate from either distinct but related parent bodies or a common compositionally heterogeneous parent body. My results suggest that CM, CO, and related ungrouped chondrites originated from distinct parent bodies that formed from similar precursor materials in nearby formation regions. These results may have implications for asteroid samples returned by the OSIRIS-REx and Hayabusa2 missions.
In this work, I first developed new methods for the chemical separation of Cr and Ti, improving the reliability of existing methods to ensure consistent yields and accurate isotopic measurements. I then measured the Cr and Ti isotopic compositions of CAIs from CV and CK chondrites to determine the extent of isotopic heterogeneity in the CAI-forming region and assess the role of CAIs in the preservation of planetary-scale isotopic anomalies. My results show that all measured CAIs originated from a common isotopic reservoir that incorporated material from at least three distinct nucleosynthetic sources and preserved limited isotopic heterogeneity. These results also suggest that planetary-scale isotopic anomalies cannot be attributed solely to the transport of CAIs from one part of the solar nebula to another. I finally measured the Cr and Ti isotopic compositions of bulk CM, CO, and ungrouped chondrites to evaluate the relationship between CM and CO chondrites, which have been suggested to originate from either distinct but related parent bodies or a common compositionally heterogeneous parent body. My results suggest that CM, CO, and related ungrouped chondrites originated from distinct parent bodies that formed from similar precursor materials in nearby formation regions. These results may have implications for asteroid samples returned by the OSIRIS-REx and Hayabusa2 missions.
ContributorsTorrano, Zachary (Author) / Wadhwa, Meenakshi (Thesis advisor) / Anbar, Ariel D (Committee member) / Schrader, Devin L (Committee member) / Williams, David A. (Committee member) / Young, Patrick A (Committee member) / Arizona State University (Publisher)
Created2020
Description
Carbonaceous chondrites (CCs) present a unique opportunity for learning about the earliest organic chemistry that took place in our Solar System. The complex and diverse suite of meteoritic organic material is the result of multiple settings and physicochemical processes, including aqueous and thermal alteration. Though meteorites often inform origin-of-life discussions because they could have seeded early Earth with significant amounts of water and pre-biotic, organic material, their record of abiotic, aqueous, and organic geochemistry is of interest as well.
CC materials previously resided on asteroidal parent bodies, relic planetesimals of Solar System formation which never accreted enough material to develop long-lived, large-scale geological processes. These bodies were large enough, however, to experience some degree of heating due to the decay of radiogenic isotopes, and the meteorite record suggests the existence of 100-150 parent bodies which experienced varying degrees of thermal and aqueous alteration for the first several 10 Myr of Solar System history.
The first chapter of this dissertation reviews literature addressing aqueous alteration as an essential participant in parent body geochemistry, organic synthesis, or both (though papers which address both are rare). The second chapter is a published organic analysis of the soluble organic material of Bells, an unclassified type 2 chondrite. Analytical approaches to assess terrestrial contamination of meteorite samples are also reviewed in the first chapter to allow introduction in chapter 3 of kinetic modeling which rules out certain cases of contamination and constrains the timing of thermal and aqueous alteration. This is the first known application of isoleucine epimerization for either of these purposes. Chapter 4 is a kinetic study of D-allo-isoleucine epimerization to establish its behavior in systems with large, relative abundances of alloisoleucine to isoleucine. Previous epimerization studies for paleontological or geological purposes began with L-isoleucine, the only protein amino acid of the four isoleucine stereoisomers.
Kinetic model calculations using isoleucine stereoisomer abundances from 7 CR chondrites constrain the total duration of the amino acids' residence in the aqueous phase. The comparatively short timescales produced by the presented modeling elicit hypotheses for protection or transport of the amino acids within the CR parent body.
CC materials previously resided on asteroidal parent bodies, relic planetesimals of Solar System formation which never accreted enough material to develop long-lived, large-scale geological processes. These bodies were large enough, however, to experience some degree of heating due to the decay of radiogenic isotopes, and the meteorite record suggests the existence of 100-150 parent bodies which experienced varying degrees of thermal and aqueous alteration for the first several 10 Myr of Solar System history.
The first chapter of this dissertation reviews literature addressing aqueous alteration as an essential participant in parent body geochemistry, organic synthesis, or both (though papers which address both are rare). The second chapter is a published organic analysis of the soluble organic material of Bells, an unclassified type 2 chondrite. Analytical approaches to assess terrestrial contamination of meteorite samples are also reviewed in the first chapter to allow introduction in chapter 3 of kinetic modeling which rules out certain cases of contamination and constrains the timing of thermal and aqueous alteration. This is the first known application of isoleucine epimerization for either of these purposes. Chapter 4 is a kinetic study of D-allo-isoleucine epimerization to establish its behavior in systems with large, relative abundances of alloisoleucine to isoleucine. Previous epimerization studies for paleontological or geological purposes began with L-isoleucine, the only protein amino acid of the four isoleucine stereoisomers.
Kinetic model calculations using isoleucine stereoisomer abundances from 7 CR chondrites constrain the total duration of the amino acids' residence in the aqueous phase. The comparatively short timescales produced by the presented modeling elicit hypotheses for protection or transport of the amino acids within the CR parent body.
ContributorsMonroe, Adam Alexander (Author) / Pizzarello, Sandra (Thesis advisor) / Williams, Peter (Thesis advisor) / Anbar, Ariel D (Committee member) / Shock, Everett L (Committee member) / Arizona State University (Publisher)
Created2014