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The deterioration of drinking-water quality within distribution systems is a serious cause for concern. Extensive water-quality deterioration often results in violations against regulatory standards and has been linked to water-borne disease outbreaks. The causes for the deterioration of drinking water quality inside distribution systems are not yet fully

The deterioration of drinking-water quality within distribution systems is a serious cause for concern. Extensive water-quality deterioration often results in violations against regulatory standards and has been linked to water-borne disease outbreaks. The causes for the deterioration of drinking water quality inside distribution systems are not yet fully understood. Mathematical models are often used to analyze how different biological, chemical, and physical phenomena interact and cause water quality deterioration inside distribution systems. In this dissertation research I developed a mathematical model, the Expanded Comprehensive Disinfection and Water Quality (CDWQ-E) model, to track water quality changes in chloraminated water. I then applied CDWQ-E to forecast water quality deterioration trends and the ability of Naegleria fowleri (N.fowleri), a protozoan pathogen, to thrive within drinking-water distribution systems. When used to assess the efficacy of substrate limitation versus disinfection in controlling bacterial growth, CDWQ-E demonstrated that bacterial growth is more effectively controlled by lowering substrate loading into distribution systems than by adding residual disinfectants. High substrate concentrations supported extensive bacterial growth even in the presence of high levels of chloramine. Model results also showed that chloramine decay and oxidation of organic matter increase the pool of available ammonia, and thus have potential to advance nitrification within distribution systems. Without exception, trends predicted by CDWQ-E matched trends observed from experimental studies. When CDWQ-E was used to evaluate the ability N. fowleri to survive in finished drinking water, the model predicted that N. fowleri can survive for extended periods of time in distribution systems. Model results also showed that N. fowleri growth depends on the availability of high bacterial densities in the 105 CFU/mL range. Since HPC levels this high are rarely reported in bulk water, it is clear that in distribution systems biofilms are the prime reservoirs N. fowleri because of their high bacterial densities. Controlled laboratory experiments also showed that drinking water can be a source of N. fowleri, and the main reservoir appeared to be biofilms dominated by bacteria. When introduced to pipe-loops N. fowleri successfully attached to biofilms and survived for 5 months.
ContributorsBiyela, Precious Thabisile (Author) / Rittmann, Bruce E. (Thesis advisor) / Abbaszadegan, Morteza (Committee member) / Butler, Caitlyn (Committee member) / Arizona State University (Publisher)
Created2010
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Description
In the recent past, Iraq was considered relatively rich considering its water resources compared to its surroundings. Currently, the magnitude of water resource shortages in Iraq represents an important factor in the stability of the country and in protecting sustained economic development. The need for a practical, applicable, and sustainable

In the recent past, Iraq was considered relatively rich considering its water resources compared to its surroundings. Currently, the magnitude of water resource shortages in Iraq represents an important factor in the stability of the country and in protecting sustained economic development. The need for a practical, applicable, and sustainable river basin management for the Tigris and Euphrates Rivers in Iraq is essential. Applicable water resources allocation scenarios are important to minimize the potential future water crises in connection with water quality and quantity. The allocation of the available fresh water resources in addition to reclaimed water to different users in a sustainable manner is of the urgent necessities to maintain good water quantity and quality.

In this dissertation, predictive water allocation optimization models were developed which can be used to easily identify good alternatives for water management that can then be discussed, debated, adjusted, and simulated in greater detail. This study provides guidance for decision makers in Iraq for potential future conditions, where water supplies are reduced, and demonstrates how it is feasible to adopt an efficient water allocation strategy with flexibility in providing equitable water resource allocation considering alternative resource. Using reclaimed water will help in reducing the potential negative environmental impacts of treated or/and partially treated wastewater discharges while increasing the potential uses of reclaimed water for agriculture and other applications. Using reclaimed water for irrigation is logical and efficient to enhance the economy of farmers and the environment while providing a diversity of crops, especially since most of Iraq’s built or under construction wastewater treatment plants are located in or adjacent to agricultural lands. Adopting an optimization modelling approach can assist decision makers, ensuring their decisions will benefit the economy by incorporating global experiences to control water allocations in Iraq especially considering diminished water supplies.
ContributorsAhmed, Ahmed Abdulrazzaq (Author) / Mays, Larry W. (Thesis advisor) / Fox, Peter (Thesis advisor) / Mascaro, Giuseppe (Committee member) / Muenich, Rebecca (Committee member) / Arizona State University (Publisher)
Created2019
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Description
A model is presented for real-time, river-reservoir operation systems. It epitomizes forward-thinking and efficient approaches to reservoir operations during flooding events. The optimization/simulation includes five major components. The components are a mix of hydrologic and hydraulic modeling, short-term rainfall forecasting, and optimization and reservoir operation models.

A model is presented for real-time, river-reservoir operation systems. It epitomizes forward-thinking and efficient approaches to reservoir operations during flooding events. The optimization/simulation includes five major components. The components are a mix of hydrologic and hydraulic modeling, short-term rainfall forecasting, and optimization and reservoir operation models. The optimization/simulation model is designed for ultimate accessibility and efficiency. The optimization model uses the meta-heuristic approach, which has the capability to simultaneously search for multiple optimal solutions. The dynamics of the river are simulated by applying an unsteady flow-routing method. The rainfall-runoff simulation uses the National Weather Service NexRad gridded rainfall data, since it provides critical information regarding real storm events. The short-term rainfall-forecasting model utilizes a stochastic method. The reservoir-operation is simulated by a mass-balance approach. The optimization/simulation model offers more possible optimal solutions by using the Genetic Algorithm approach as opposed to traditional gradient methods that can only compute one optimal solution at a time. The optimization/simulation was developed for the 2010 flood event that occurred in the Cumberland River basin in Nashville, Tennessee. It revealed that the reservoir upstream of Nashville was more contained and that an optimal gate release schedule could have significantly decreased the floodwater levels in downtown Nashville. The model is for demonstrative purposes only but is perfectly suitable for real-world application.
ContributorsChe, Daniel C (Author) / Mays, Larry W. (Thesis advisor) / Fox, Peter (Committee member) / Wang, Zhihua (Committee member) / Lansey, Kevin (Committee member) / Wahlin, Brian (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Vegetative filter strips (VFS) are an effective methodology used for storm water management particularly for large urban parking lots. An optimization model for the design of vegetative filter strips that minimizes the amount of land required for stormwater management using the VFS is developed in this study. The

Vegetative filter strips (VFS) are an effective methodology used for storm water management particularly for large urban parking lots. An optimization model for the design of vegetative filter strips that minimizes the amount of land required for stormwater management using the VFS is developed in this study. The resulting optimization model is based upon the kinematic wave equation for overland sheet flow along with equations defining the cumulative infiltration and infiltration rate.

In addition to the stormwater management function, Vegetative filter strips (VFS) are effective mechanisms for control of sediment flow and soil erosion from agricultural and urban lands. Erosion is a major problem associated with areas subjected to high runoffs or steep slopes across the globe. In order to effect economy in the design of grass filter strips as a mechanism for sediment control & stormwater management, an optimization model is required that minimizes the land requirements for the VFS. The optimization model presented in this study includes an intricate system of equations including the equations defining the sheet flow on the paved and grassed area combined with the equations defining the sediment transport over the vegetative filter strip using a non-linear programming optimization model. In this study, the optimization model has been applied using a sensitivity analysis of parameters such as different soil types, rainfall characteristics etc., performed to validate the model
ContributorsKhatavkar, Puneet N (Author) / Mays, Larry W. (Thesis advisor) / Fox, Peter (Committee member) / Wang, Zhihua (Committee member) / Mascaro, Giuseppe (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Since its first report in 1976, many outbreaks linked to Legionella have been reported in the world. These outbreaks are a public health concern because of legionellosis, which is found in two forms, Pontiac fever and Legionnaires disease. Legionnaires disease is a type of pneumonia responsible for the majority of

Since its first report in 1976, many outbreaks linked to Legionella have been reported in the world. These outbreaks are a public health concern because of legionellosis, which is found in two forms, Pontiac fever and Legionnaires disease. Legionnaires disease is a type of pneumonia responsible for the majority of the illness in the reported outbreaks of legionellosis. This study consists of an extensive literature review and experimental work on the aerosolization and UV inactivation of E.coli and Legionella under laboratory conditions. The literature review summarizes Legionella general information, occurrence, environmental conditions for its survival, transmission to human, collection and detection methodologies and Legionella disinfection in air and during water treatment processes.

E. coli was used as an surrogate for Legionella in experimentation due to their similar bacterial properties such as size, gram-negative rod-shaped, un-encapsulated and non-spore-forming bacterial cells. The accessibility and non-pathogenicity of E. coli also served as factors for the substitution.

Three methods of bacterial aerosolization were examined, these included an electric spray gun, an air spray gun and a hand-held spray bottle. A set of experiments were performed to examine E. coli aerosolization and transport in the aerosolization chamber (an air tight box) placed in a Biological Safety Cabinet. Spiked sample was sprayed through the opening from one side of the aerosolization chamber using the selected aerosolization methods. The air sampler was placed at the other side to collect 100 L air sample from the aerosolization chamber. A Tryptic Soy Agar plate was placed inside the air sampler to collect and subsequently culture E. coli cells from air. Results showed that the air spray gun has the best capability of aerosolizing bacteria cells under all the conditions examined in this study compared to the other two spray methods. In this study, we provide a practical and efficient method of bacterial aerosolization technique for microbial dispersion in air. The suggested method can be used in future research for microbial dispersion and transmission studies.

A set of experiments were performed to examine UV inactivation of E. coli and Legionella cells in air. Spiked samples were sprayed through the opening from one side of the aerosolization chamber using the air spray gun. A UV-C germicidal lamp inside the Biological Safety Cabinet was turned on after each spray. The air samples were collected as previously described. The application of UV-C for the inactivation of bacterial cells resulted in removing aerosolized E. coli and Legionella cells in air. A 1 log reduction was achieved with 5 seconds UV exposure time while 10 seconds UV exposure resulted in a 2 log bacterial reduction for both bacteria. This study shows the applicability of UV inactivation of pathogenic bacterial cells in air by short UV exposure time. This method may be applicable for the inactivation of Legionella in air ducts by installing germicidal UV lamps for protecting susceptible populations in certain indoor settings such as nursing homes or other community rooms.
ContributorsYao, Wei (Author) / Abbaszadegan, Morteza (Thesis advisor) / Fox, Peter (Committee member) / Alum, Absar (Committee member) / Arizona State University (Publisher)
Created2015
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Description
The purpose of this study was to determine the applicability of fluorescent microspheres as a surrogate to measure the removal of Cryptosporidium oocysts through the coagulation, flocculation, sedimentation, and filtration steps of conventional water treatment. In order to maintain accuracy and applicability, a local water treatment facility was chosen as

The purpose of this study was to determine the applicability of fluorescent microspheres as a surrogate to measure the removal of Cryptosporidium oocysts through the coagulation, flocculation, sedimentation, and filtration steps of conventional water treatment. In order to maintain accuracy and applicability, a local water treatment facility was chosen as the system to model. The city of Chandler Arizona utilizes conventional treatment methodologies to remove pathogens from municipal drinking water and thus the water, coagulant, polymer, and doses concentrations were sourced directly from the plant. Jar testing was performed on four combinations of coagulant, polymer, and fluorescent microsphere to determine if the log removal was similar to that of Cryptosporidium oocysts.

Complications with the material properties of the microspheres arose during testing that ultimately yielded unfavorable but conclusive results. Log removal of microspheres did not increase with added coagulant in the predicted manner, though the beads were seen aggregating, the low density of the particles made the sedimentation step inefficient. This result can be explained by the low density of the microspheres as well as the potential presence of residual coagulant present in the system. Given the unfavorable properties of the beads, they do not appear to be a suitable candidate for the surrogacy of Cryptosporidium oocysts in conventional drinking water treatment. The beads in their current state are not an adequate surrogate; however, future testing has been outlined to modify the experiment in such a way that the microspheres should behave like oocysts in terms of physical transportation.
ContributorsLinks, Alexander Glenn (Author) / Abbaszadegan, Morteza (Thesis advisor) / Alum, Absar (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Bioretention basins are a common stormwater best management practice (BMP) used to mitigate the hydrologic consequences of urbanization. Dry wells, also known as vadose-zone wells, have been used extensively in bioretention basins in Maricopa County, Arizona to decrease total drain time and recharge groundwater. A mixed integer nonlinear programming (MINLP)

Bioretention basins are a common stormwater best management practice (BMP) used to mitigate the hydrologic consequences of urbanization. Dry wells, also known as vadose-zone wells, have been used extensively in bioretention basins in Maricopa County, Arizona to decrease total drain time and recharge groundwater. A mixed integer nonlinear programming (MINLP) model has been developed for the minimum cost design of bioretention basins with dry wells.

The model developed simultaneously determines the peak stormwater inflow from watershed parameters and optimizes the size of the basin and the number and depth of dry wells based on infiltration, evapotranspiration (ET), and dry well characteristics and cost inputs. The modified rational method is used for the design storm hydrograph, and the Green-Ampt method is used for infiltration. ET rates are calculated using the Penman Monteith method or the Hargreaves-Samani method. The dry well flow rate is determined using an equation developed for reverse auger-hole flow.

The first phase of development of the model is to expand a nonlinear programming (NLP) for the optimal design of infiltration basins for use with bioretention basins. Next a single dry well is added to the NLP bioretention basin optimization model. Finally the number of dry wells in the basin is modeled as an integer variable creating a MINLP problem. The NLP models and MINLP model are solved using the General Algebraic Modeling System (GAMS). Two example applications demonstrate the efficiency and practicality of the model.
ContributorsLacy, Mason (Author) / Mays, Larry W. (Thesis advisor) / Fox, Peter (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Specific inorganic and organic pollutants in water (As(V), Cr(VI), THMs, and hardness) cause health concerns or aesthetic problems. The goal of this dissertation is to demonstrate novel approaches to improve the performance of point of use and municipal activated carbon processes to provide safe and reliable water to the public

Specific inorganic and organic pollutants in water (As(V), Cr(VI), THMs, and hardness) cause health concerns or aesthetic problems. The goal of this dissertation is to demonstrate novel approaches to improve the performance of point of use and municipal activated carbon processes to provide safe and reliable water to the public at distributed centralized locations.

Template Assisted Crystallization system would adjust saturation index (SI) value of TAC treated water to zero when SI value of influent water was in the range at 0.08~0.3. However, the reduction in SI when SI values were higher (e.g. 0.7~1.3) was similar to the reduction at lower SI values which could be due to limitations in kinetics or mass transfer with the template on TAC media.

Pre-chlorination prior to municipal-scale granular activated carbon (GAC) treatment was evaluated to control THM formation in distribution systems. Pre-chlorination decreased UVA, shift the dissolved organic carbon (DOC) molecular weight distribution and pre-formed trihalomethanes (THM). GAC treatment of pre-chlorinated water achieved lower THM formation in distribution systems.

To add functionality in POU systems to remove As(V) and Cr(VI), activated carbon was nano-tized to fabricate nano-enabled carbon block (CB) by (1) impregnating iron or titanium metal oxides chemically or (2) attaching titanium based P25 through electrostatic attraction force. Nanoparticle loadings of 5 to 10 wt % with respect to activated carbon enables reduction of As(V) or Cr(VI) from levels of common occurrence to below regulatory levels across carbon block designs. Minimal impacts on As(V) and Cr(VI) sorption were observed up to a nanoparticle pre-treatment temperature of 200 C, which is the temperature for CB production. Through controlling pH at 4.5 during mixing of nanoparticles with pH IEP=6 and activated carbon with pH IEP=3, electrostatic attachment of nanoparticles to activated carbon could be achieved prior to fabricating carbon block. A mini carbon block test device was designed, fabricated, and validated to mimic performances of full-scale carbon block using less volumes of test water. As(V) removal tests showed Fe impregnated CB achieved the highest As(V) removal while P25 attached CB had the lowest among three nanoparticles loaded CBs.
ContributorsLee, Heuidae (Author) / Westerhoff, Paul (Thesis advisor) / Fox, Peter (Committee member) / Hristovski, Kiril (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Mexico City has an ongoing air pollution issue that negatively affects its citizens and surroundings with current structural disconnections preventing the city from improving its overall air quality. Thematic methodological analysis reveals current obstacles and barriers, as well as variables contributing to this persistent problem. A historical background reveals current

Mexico City has an ongoing air pollution issue that negatively affects its citizens and surroundings with current structural disconnections preventing the city from improving its overall air quality. Thematic methodological analysis reveals current obstacles and barriers, as well as variables contributing to this persistent problem. A historical background reveals current programs and policies implemented to improve Mexico’s City air quality. Mexico City’s current systems, infrastructure, and policies are inadequate and ineffective. There is a lack of appropriate regulation on other modes of transportation, and the current government system fails to identify how the class disparity in the city and lack of adequate education are contributing to this ongoing problem. Education and adequate public awareness can potentially aid the fight against air pollution in the Metropolitan City.
ContributorsGarcia, Lucero (Author) / Duarte, Marisa E. (Thesis advisor) / Arzubiaga, Angela (Committee member) / Richter, Jennifer (Committee member) / Arizona State University (Publisher)
Created2018