Matching Items (14)
Filtering by

Clear all filters

133653-Thumbnail Image.png
Description
In industrial applications, rotary drums are poorly understood and preform suboptimally when used to process particulates. In order to better understand how these drums work, a statistical experiment was designed to measure the effects of the fill level and rotation rate on the final temperature of the particle bed. A

In industrial applications, rotary drums are poorly understood and preform suboptimally when used to process particulates. In order to better understand how these drums work, a statistical experiment was designed to measure the effects of the fill level and rotation rate on the final temperature of the particle bed. A steel rotary drum was set up to be headed by three external heat guns, simulating the conditions under which standard rotary drums are operated. By measuring the bed temperature at steady state, and recording the combination of factors in each run, a regression analysis was run to determine the factor's effects. Fill level was seen to have a small positive effect, rotation rate was seen to have a small negative effect, and the interaction of the two was shown to have a large positive effect. This led the team to conclude that the flow profile of the bed may be the most important factor in heat transfer, and that further research should be done to isolate and study the effect of the flow profile.
ContributorsBeairsto, Cole James (Author) / Emady, Heather (Thesis director) / Adepu, Manogna (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
134643-Thumbnail Image.png
Description
In this paper, the effectiveness and practical applications of cooling a computer's CPU using mineral oil is investigated. A computer processor or CPU may be immersed along with other electronics in mineral oil and still be operational. The mineral oil acts as a dielectric and prevents shorts in the electronics

In this paper, the effectiveness and practical applications of cooling a computer's CPU using mineral oil is investigated. A computer processor or CPU may be immersed along with other electronics in mineral oil and still be operational. The mineral oil acts as a dielectric and prevents shorts in the electronics while also being thermally conductive and cooling the CPU. A simple comparison of a flat plate immersed in air versus mineral oil is considered using analytical natural convection correlations. The result of this comparison indicates that the plate cooled by natural convection in air would operate at 98.41[°C] while the plate cooled by mineral oil would operate at 32.20 [°C]. Next, CFD in ANSYS Fluent was used to conduct simulation with forced convection representing a CPU fan driving fluid flow to cool the CPU. A comparison is made between cooling done with air and mineral oil. The results of the CFD simulation results indicate that using mineral oil as a substitute to air as the cooling fluid reduced the CPU operating temperature by sixty degrees Celsius. The use of mineral oil as a cooling fluid for a consumer computer has valid thermal benefits, but the practical challenges of the method will likely prevent widespread adoption.
ContributorsTichacek, Louis Joseph (Author) / Huang, Huei-Ping (Thesis director) / Herrmann, Marcus (Committee member) / Middleton, James (Committee member) / Mechanical and Aerospace Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
Description
This honors thesis is focused on two separate catalysis projects conducted under the mentorship of Dr. Javier Pérez-Ramírez at ETH Zürich. The first project explored ethylene oxychlorination over supported europium oxychloride catalysts. The second project investigated alkyne semihydrogenation over nickel phosphide catalysts. This work is the subject of a publication

This honors thesis is focused on two separate catalysis projects conducted under the mentorship of Dr. Javier Pérez-Ramírez at ETH Zürich. The first project explored ethylene oxychlorination over supported europium oxychloride catalysts. The second project investigated alkyne semihydrogenation over nickel phosphide catalysts. This work is the subject of a publication of which I am a co-author, as cited below.

Project 1 Abstract: Ethylene Oxychlorination
The current two-step process for the industrial process of vinyl chloride production involves CuCl2 catalyzed ethylene oxychlorination to ethylene dichloride followed by thermal cracking of the latter to vinyl chloride. To date, no industrial application of a one-step process is available. To close this gap, this work evaluates a wide range of self-prepared supported CeO2 and EuOCl catalysts for one-step production of vinyl chloride from ethylene in a fixed-bed reactor at 623 773 K and 1 bar using feed ratios of C2H4:HCl:O2:Ar:He = 3:3 6:1.5 6:3:82 89.5. Among all studied systems, CeO2/ZrO2 and CeO2/Zeolite MS show the highest activity but suffer from severe combustion of ethylene, forming COx, while 20 wt.% EuOCl/γ-Al2O3 leads to the best vinyl chloride selectivity of 87% at 15.6% C2H4 conversion with complete suppression of CO2 formation and only 4% selectivity to CO conversion for over 100 h on stream. Characterization by XRD and EDX mapping reveals that much of the Eu is present in non-active phases such as Al2Eu or EuAl4, indicating that alternative synthesis methods could be employed to better utilize the metal. A linear relationship between conversion and metal loading is found for this catalyst, indicating that always part of the used Eu is available as EuOCl, while the rest forms inactive europium aluminate species. Zeolite-supported EuOCl slightly outperforms EuOCl/γ Al2O3 in terms of total yield, but is prone to significant coking and is unstable. Even though a lot of Eu seems locked in inactive species on EuOCl/γ Al2O3, these results indicate possible savings of nearly 16,000 USD per kg of catalyst compared to a bulk EuOCl catalyst. These very promising findings constitute a crucial step for process intensification of polyvinyl chloride production and exploring the potential of supported EuOCl catalysts in industrially-relevant reactions.

Project 2 Abstract: Alkyne Semihydrogenation
Despite strongly suffering from poor noble metal utilization and a highly toxic selectivity modifier (Pb), the archetypal catalyst applied for the three-phase alkyne semihydrogenation, the Pb-doped Pd/CaCO3 (Lindlar catalyst), is still being utilized at industrial level. Inspired by the very recent strategies involving the modification of Pd with p-block elements (i.e., S), this work extrapolates the concept by preparing crystalline metal phosphides with controlled stoichiometry. To develop an affordable and environmentally-friendly alternative to traditional hydrogenation catalysts, nickel, a metal belonging to the same group as Pd and capable of splitting molecular hydrogen has been selected. Herein, a simple two-step synthesis procedure involving nontoxic precursors was used to synthesize bulk nickel phosphides with different stoichiometries (Ni2P, Ni5P4, and Ni12P5) by controlling the P:Ni ratios. To uncover structural and surface features, this catalyst family is characterized with an array of methods including X-ray diffraction (XRD), 31P magic-angle nuclear magnetic resonance (MAS-NMR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). Bulk-sensitive techniques prove the successful preparation of pure phases while XPS analysis unravels the facile passivation occurring at the NixPy surface that persists even after reductive treatment. To assess the characteristic surface fingerprints of these materials, Ar sputtering was carried out at different penetration depths, reveling the presence of Ni+ and P-species. Continuous-flow three-phase hydrogenations of short-chain acetylenic compounds display that the oxidized layer covering the surface is reduced under reaction conditions, as evidenced by the induction period before reaching the steady state performance. To assess the impact of the phosphidation treatment on catalytic performance, the catalysts were benchmarked against a commercial Ni/SiO2-Al2O3 sample. While Ni/SiO2-Al2O3 presents very low selectivity to the alkene (the selectivity is about 10% at full conversion) attributed to the well-known tendency of naked nickel nanoparticles to form hydrides, the performance of nickel phosphides is highly selective and independent of P:Ni ratio. In line with previous findings on PdxS, kinetic tests indicate the occurrence of a dual-site mechanism where the alkyne and hydrogen do not compete for the same site.

This work is the subject of a publication of which I am a co-author, as cited below.

D. Albani; K. Karajovic; B. Tata; Q. Li; S. Mitchell; N. López; J. Pérez-Ramírez. Ensemble Design in Nickel Phosphide Catalysts for Alkyne Semi-Hydrogenation. ChemCatChem 2019. doi.org/10.1002/cctc.201801430
ContributorsTata, Bharath (Author) / Deng, Shuguang (Thesis director) / Muhich, Christopher (Committee member) / Chemical Engineering Program (Contributor, Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
134366-Thumbnail Image.png
Description
This paper presents an experimental investigation into the effects of altering electrode surface area roughness on thermogalvanic cell performance. A temperature difference between two electrodes was induced and brought to steady state to achieve a difference of around 50 °C, which was maintained with a DC power generated hot wire

This paper presents an experimental investigation into the effects of altering electrode surface area roughness on thermogalvanic cell performance. A temperature difference between two electrodes was induced and brought to steady state to achieve a difference of around 50 °C, which was maintained with a DC power generated hot wire and a pumped ice bath. The open-circuit voltage values at steady-state were measured by a programed multimeter and the temperatures were measured by a series of type K thermocouples. Electrode surface area roughness was altered using different grit values of sandpaper and measuring the values using a Zescope Optical Profilometer. Once three different surface area average values were achieved, 6 trials were performed with 2 trials per roughness value. The results were tabulated in Section 4 of this report.
It was predicted that increasing the surface area roughness would increase the number of electrons present in the reduction oxidation reaction and decrease the activation resistance of the thermogalvanic system. Decreasing the activation resistance, a component of total internal resistance, would therefore increase the power output of the cell by a small magnitude. The results showed that changing the surface area roughness of the Copper electrodes evidently had no effect on the outputs of the cell system. Additionally, the Seebeck coefficient was also unaffected by the presence of increased surface area roughness.
The work presented in the following paper is part of a continuing effort to better understand the performance of thermogalvanic cells and their heat to electrical energy transfer properties.
ContributorsLopez, Maggie Marie (Author) / Phelan, Patrick (Thesis director) / Miner, Mark (Committee member) / School of Sustainability (Contributor) / School of Music (Contributor) / Mechanical and Aerospace Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
133976-Thumbnail Image.png
Description
Rotary drums are commonly used for their high heat and mass transfer rates in the manufacture of pharmaceuticals, cement, food, and other particulate products. These processes are difficult to model because the particulate behavior is governed by the process conditions such as particle size, particle size distribution, shape, composition, and

Rotary drums are commonly used for their high heat and mass transfer rates in the manufacture of pharmaceuticals, cement, food, and other particulate products. These processes are difficult to model because the particulate behavior is governed by the process conditions such as particle size, particle size distribution, shape, composition, and operating parameters, such as fill level and rotation rate. More research on heat transfer in rotary drums will increase operating efficiency, leading to tremendous energy savings on a global scale. This study investigates the effects of drum fill level and rotation rate on the steady-state average particle bed temperature. 3 mm silica beads and a stainless steel rotary drum were used at fill levels ranging from 10 \u2014 25 % and rotation rates from 2 \u2014 10 rpm. Four heat guns were used to heat the system via conduction and convection, and an infrared camera was used to record temperature data. A three-level, two-factor, full-factorial design of experiments was employed to determine the effects of each factor on the steady-state average bed temperature. Low fill level and high rotation rate resulted in higher steady-state average bed temperatures. A quantitative model showed that rotation rate had a larger impact on the steady-state bed temperature than fill level.
ContributorsBoepple, Brandon Richard (Author) / Emady, Heather (Thesis director) / Adepu, Manogna (Committee member) / W.P. Carey School of Business (Contributor) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
148412-Thumbnail Image.png
Description

This work summarizes the development of a dynamic measurement platform in a cryostat to measure sample temperature response to space-like conditions and the creation a MATLAB theoretical model to predict sample temperature responses in the platform itself. An interesting variable-emittance sample called a Fabry-Perot emitter was studied for its thermal

This work summarizes the development of a dynamic measurement platform in a cryostat to measure sample temperature response to space-like conditions and the creation a MATLAB theoretical model to predict sample temperature responses in the platform itself. An interesting variable-emittance sample called a Fabry-Perot emitter was studied for its thermal homeostasis behavior using the two developments. Using the measurement platform, it was shown that there was no thermal homeostatic behavior demonstrated by the sample at steady state temperatures. Theoretical calculations show other ways to demonstrate the cooling homeostasis behavior through time-varying heat inputs. Factors within the system such as heat loss and thermal mass contributed to an inhibited sample performance in the platform. Future work will have to be conducted, not only to verify the findings of the initial experiments but also to improve the measurement platform and the theoretical model.

ContributorsBoman, Neal D (Author) / Wang, Liping (Thesis director) / Taylor, Syndey (Committee member) / Mechanical and Aerospace Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
148451-Thumbnail Image.png
Description

Rotary drums are tools used extensively in various prominent industries for their utility in heating and transporting particulate products. These processes are often inefficient and studies on heat transfer in rotary drums will reduce energy consumption as operating parameters are optimized. Research on this subject has been ongoing at ASU;

Rotary drums are tools used extensively in various prominent industries for their utility in heating and transporting particulate products. These processes are often inefficient and studies on heat transfer in rotary drums will reduce energy consumption as operating parameters are optimized. Research on this subject has been ongoing at ASU; however, the design of the rotary drum used in these studies is restrictive and experiments using radiation heat transfer have not been possible.<br/><br/>This study focuses on recounting the steps taken to upgrade the rotary drum setup and detailing the recommended procedure for experimental tests using radiant heat transfer upon completed construction of the new setup. To develop an improved rotary drum setup, flaws in the original design were analyzed and resolved. This process resulted in a redesigned drum heating system, an altered thinner drum, and a larger drum box. The recommended procedure for radiant heat transfer tests is focused on determining how particle size, drum fill level, and drum rotation rate impact the radiant heat transfer rate.

ContributorsMiller, Erik R (Author) / Emady, Heather (Thesis director) / Muhich, Christopher (Committee member) / Chemical Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
Description

This paper explores to mitigate the issue of Formula SAE brakes vaporizing by creating a computational model to determine when the fluid may boil given a velocity profile and brake geometry. The paper explores various parameters and assumptions and how they may lead to error determining when the brake fluid

This paper explores to mitigate the issue of Formula SAE brakes vaporizing by creating a computational model to determine when the fluid may boil given a velocity profile and brake geometry. The paper explores various parameters and assumptions and how they may lead to error determining when the brake fluid will vaporize. Common assumptions such as a constant convection coefficient are questioned throughout the paper and compared to methods requiring higher computational power. Throughout this model, a significant dependence on the heat partition factor is found on the final steady state temperature of the brake fluid is found, and a sensitivity analysis is performed to determine the effect of its variation.

ContributorsWesterhoff, Andrew (Author) / Kwon, Beomjin (Thesis director) / Milcarek, Ryan (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2023-05
Description

Rotary drums are used to manufacture pharmaceuticals, cement, food, and other particulate products because of their high heat and mass transfer rates. These processes are governed by particle parameters, such as particle size, particle distribution, and shape, and operating parameters, such as rotation rate and fill level. Enormous energy savings

Rotary drums are used to manufacture pharmaceuticals, cement, food, and other particulate products because of their high heat and mass transfer rates. These processes are governed by particle parameters, such as particle size, particle distribution, and shape, and operating parameters, such as rotation rate and fill level. Enormous energy savings are possible with further research in rotary drums due to potential increases in operating efficiency. This study investigates the drum rotation rate on particle bed temperature at temperatures above 500 °C to see the role that radiation heat transfer plays in this process. 2 mm silica beads and a stainless steel rotary drum were used at a fill level of 25% with rotation rates from 2-10 rpm. A new setup and procedure were developed using heating coils and an IR camera to reach high temperatures. The inner drum wall temperature exceeded the outer drum wall temperature because the steel transmitted more heat into the drum at higher temperatures. Although it was unclear whether the heat transfer rate was affected by the increasing rotation rate, the highest final average particle temperature was obtained at 5 rpm. The particle bed temperature distribution narrowed as the rotation rate increased because, at higher rotation rates, more particles are in contact with the drum wall than at lower rotation rates.

ContributorsTronstad, Joel (Author) / Emady, Heather (Thesis director) / Holloway, Julianne (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor) / Dean, W.P. Carey School of Business (Contributor)
Created2023-05
161085-Thumbnail Image.png
Description

Thermophotovoltaic energy conversion is seen as a viable option for efficiently converting heat to electricity. There are three key components to a thermophotovoltaic (TPV) system: a heat source, a heat emitter and a photovoltaic (PV) cell. A heat source heats up the emitter which causes the emitter to release thermal

Thermophotovoltaic energy conversion is seen as a viable option for efficiently converting heat to electricity. There are three key components to a thermophotovoltaic (TPV) system: a heat source, a heat emitter and a photovoltaic (PV) cell. A heat source heats up the emitter which causes the emitter to release thermal radiation. The photons are absorbed by a PV cell when they are acting above the bandgap energy. The PV cell then generates electricity from this thermal radiation. In theory, efficiency of a TPV system can be well above 50%. In order for TPV to reach large-scale adaptation, an efficiency at or above 20% is needed. In this project, a high-temperature heater capable of reaching 1000K was developed. The heater involved a copper block machined to hold two cartridge heaters, as well as two thermocouples. It has an accompanying copper lid that can be screwed tight to the main block, with an emitter in between. There is an aperture to allow radiation through the casing towards the PV cell. Preliminary thermal analysis showed that the heater provides uniform temperature distribution across the emitter, which is necessary for proper radiation. A mounting system was also designed to implement the heater into the overall TPV system. Current work is being done to lower the radiation loss from the heater and mounting system, as well as implementation of all auxiliary components to begin testing. The maximum temperature of the heater, radiation heat flux received by the cell, and overall power output and efficiency of the system will be tested.

ContributorsDeffigos, Nikolas (Author) / Wang, Liping (Thesis director) / Milcarek, Ryan (Committee member) / Ni, Qing (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2021-12