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Description
Concrete is the most widely used infrastructure material worldwide. Production of portland cement, the main binding component in concrete, has been shown to require significant energy and account for approximately 5-7% of global carbon dioxide production. The expected continued increased use of concrete over the coming decades indicates this is an ideal time to implement sustainable binder technologies. The current work aims to explore enhanced sustainability concretes, primarily in the context of limestone and flow. Aspects such as hydration kinetics, hydration product formation and pore structure add to the understanding of the strength development and potential durability characteristics of these binder systems. Two main strategies for enhancing this sustainability are explored in this work: (i) the use of high volume limestone in combination with other alternative cementitious materials to decrease the portland cement quantity in concrete and (ii) the use of geopolymers as the binder phase in concrete. The first phase of the work investigates the use of fine limestone as cement replacement from the perspective of hydration, strength development, and pore structure. The nature of the potential synergistic benefit of limestone and alumina will be explored. The second phase will focus on the rheological characterization of these materials in the fresh state, as well as a more general investigation of the rheological characterization of suspensions. The results of this work indicate several key ideas. (i) There is a potential synergistic benefit for strength, hydration, and pore structure by using alumina and in portland limestone cements, (ii) the limestone in these systems is shown to react to some extent, and fine limestone is shown to accelerate hydration, (iii) rheological characteristics of cementitious suspensions are complex, and strongly dependent on several key parameters including: the solid loading, interparticle forces, surface area of the particles present, particle size distribution of the particles, and rheological nature of the media in which the particles are suspended, and (iv) stress plateau method is proposed for the determination of rheological properties of concentrated suspensions, as it more accurately predicts apparent yield stress and is shown to correlate well with other viscoelastic properties of the suspensions.
ContributorsVance, Kirk (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Chawla, Nikhilesh (Committee member) / Marzke, Robert (Committee member) / Arizona State University (Publisher)
Created2014
Description
Increased priority on the minimization of environmental impacts of conventional construction materials in recent years has motivated increased use of waste materials or bi-products such as fly ash, blast furnace slag with a view to reduce or eliminate the manufacturing/consumption of ordinary portland cement (OPC) which accounts for approximately 5-7% of global carbon dioxide emission. The current study explores, for the first time, the possibility of carbonating waste metallic iron powder to develop carbon-negative sustainable binder systems for concrete. The fundamental premise of this work is that metallic iron will react with aqueous CO2 under controlled conditions to form complex iron carbonates which have binding capabilities. The compressive and flexural strengths of the chosen iron-based binder systems increase with carbonation duration and the specimens carbonated for 4 days exhibit mechanical properties that are comparable to those of companion ordinary portland cement systems. The optimal mixture proportion and carbonation regime for this non-conventional sustainable binder is established based on the study of carbonation efficiency of a series of mixtures using thermogravimetric analysis. The pore- and micro-structural features of this novel binding material are also evaluated. The fracture response of this novel binder is evaluated using strain energy release rate and measurement of fracture process zone using digital image correlation (DIC). The iron-based binder system exhibits significantly higher strain energy release rates when compared to those of the OPC systems in both the unreinforced and glass fiber reinforced states. The iron-based binder also exhibits higher amount of area of fracture process zone due to its ability to undergo inelastic deformation facilitated by unreacted metallic iron particle inclusions in the microstructure that helps crack bridging /deflection. The intrinsic nano-mechanical properties of carbonate reaction product are explored using statistical nanoindentation technique coupled with a stochastic deconvolution algorithm. Effect of exposure to high temperature (up to 800°C) is also studied. Iron-based binder shows significantly higher residual flexural strength after exposure to high temperatures. Results of this comprehensive study establish the viability of this binder type for concrete as an environment-friendly and economical alternative to OPC.
ContributorsDas, Sumanta (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, S.D. (Committee member) / Mobasher, Barzin (Committee member) / Marzke, Robert (Committee member) / Chawla, Nikhilesh (Committee member) / Stone, David (Committee member) / Arizona State University (Publisher)
Created2015
Description
Being a remarkably versatile and inexpensive building material, concrete has found tremendous use in development of modern infrastructure and is the most widely used material in the world. Extensive research in the field of concrete has led to the development of a wide array of concretes with applications ranging from building of skyscrapers to paving of highways. These varied applications require special cementitious composites which can satisfy the demand for enhanced functionalities such as high strength, high durability and improved thermal characteristics among others.
The current study focuses on the fundamental understanding of such functional composites, from their microstructural design to macro-scale application. More specifically, this study investigates three different categories of functional cementitious composites. First, it discusses the differences between cementitious systems containing interground and blended limestone with and without alumina. The interground systems are found to outperform the blended systems due to differential grinding of limestone. A novel approach to deduce the particle size distribution of limestone and cement in the interground systems is proposed. Secondly, the study delves into the realm of ultra-high performance concrete, a novel material which possesses extremely high compressive-, tensile- and flexural-strength and service life as compared to regular concrete. The study presents a novel first principles-based paradigm to design economical ultra-high performance concretes using locally available materials. In the final part, the study addresses the thermal benefits of a novel type of concrete containing phase change materials. A software package was designed to perform numerical simulations to analyze temperature profiles and thermal stresses in concrete structures containing PCMs.
The design of these materials is accompanied by material characterization of cementitious binders. This has been accomplished using techniques that involve measurement of heat evolution (isothermal calorimetry), determination and quantification of reaction products (thermo-gravimetric analysis, x-ray diffraction, micro-indentation, scanning electron microscopy, energy-dispersive x-ray spectroscopy) and evaluation of pore-size distribution (mercury intrusion porosimetry). In addition, macro-scale testing has been carried out to determine compression, flexure and durability response. Numerical simulations have been carried out to understand hydration of cementitious composites, determine optimum particle packing and determine the thermal performance of these composites.
The current study focuses on the fundamental understanding of such functional composites, from their microstructural design to macro-scale application. More specifically, this study investigates three different categories of functional cementitious composites. First, it discusses the differences between cementitious systems containing interground and blended limestone with and without alumina. The interground systems are found to outperform the blended systems due to differential grinding of limestone. A novel approach to deduce the particle size distribution of limestone and cement in the interground systems is proposed. Secondly, the study delves into the realm of ultra-high performance concrete, a novel material which possesses extremely high compressive-, tensile- and flexural-strength and service life as compared to regular concrete. The study presents a novel first principles-based paradigm to design economical ultra-high performance concretes using locally available materials. In the final part, the study addresses the thermal benefits of a novel type of concrete containing phase change materials. A software package was designed to perform numerical simulations to analyze temperature profiles and thermal stresses in concrete structures containing PCMs.
The design of these materials is accompanied by material characterization of cementitious binders. This has been accomplished using techniques that involve measurement of heat evolution (isothermal calorimetry), determination and quantification of reaction products (thermo-gravimetric analysis, x-ray diffraction, micro-indentation, scanning electron microscopy, energy-dispersive x-ray spectroscopy) and evaluation of pore-size distribution (mercury intrusion porosimetry). In addition, macro-scale testing has been carried out to determine compression, flexure and durability response. Numerical simulations have been carried out to understand hydration of cementitious composites, determine optimum particle packing and determine the thermal performance of these composites.
ContributorsArora, Aashay (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Chawla, Nikhilesh (Committee member) / Hoover, Christian G (Committee member) / Arizona State University (Publisher)
Created2018
Description
The loading provisions were compared between the ASCE 7-10 standard and ASCE 7-16 standard. Two different structural models were considered: an office building with a flat roof located in Tempe and a community center with a gable roof located in Flagstaff. The following load types were considered: dead, live, wind, and snow loads. The only major changes between the standards were found in the wind load calculations. The winds loads were reduced by approximately 22% for the office building in Tempe and 37% for the community center in Flagstaff. A structural design was completed for the frame of the Flagstaff community building. There was a 19% reduction in cost from the design using ASCE 7-10 provisions compared to the design utilizing ASCE 7-16 provisions, leading to a saving of $7,599.17. The reduction in loading, and subsequently more cost-effective design, is attributed to the reduction in basic wind speed for the region and consideration of the ground elevation factor. The introduction of the new ASCE 7-16 standard was met with criticism, especially over the increase in specific coefficients in the wind load and seismic load chapters. Proponents of ASCE 7-16 boast that the new chapter on tsunami loads, new maps for various environmental loads, and a new electronic hazard are some of the merits of the newest standard. Others still question whether the complexity of the provisions is necessary and call for further improvements for the wind and seismic provisions. While tension exists in the desire for a simple standard, ASCE 7-16 prioritizes in having its provisions provide economical and reliable results. More consideration could be devoted to developing a more convenient standard for users. Regardless, engineering professionals should be able to adapt alongside newly developed practices and newly discovered data.
ContributorsCajegas, Cyam Joshua Dato (Author) / Rajan, Subramaniam (Thesis director) / Neithalath, Narayanan (Committee member) / Civil, Environmental and Sustainable Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
Description
Glasses have many applications such as containers, substrates of displays, high strength fibers and portable electronic display panels. Their excellent mechanical properties such as high hardness, good forming ability and scratch resistance make glasses ideal for these applications. Many factors affect the selection of one glass over another for a given purpose such as cost, ingredients, scalability of manufacturing, etc. Typically, silicate based glasses are often selected because they satisfy most of the selection criteria. However, with the recent abundant use of these glasses in touch-based applications, understanding their abilities to dissipate energy due to surface contact loads has become increasingly desirable. The most common silicate glasses worldwide are glassy silica and soda lime. Calcium aluminosilicates are also gaining popularity due to their importance as substrates for display screens in electronic devices. The surface energy dissipation and strength of these glasses are based on several factors, but predominantly rely on ingredient composition and the so-called Indentation Size Effect (ISE), where the strength depends on the maximum surface force. Both the composition and ISE alter the strength and favored energy dissipation mechanisms of the glass. Unlocking the contribution of these mechanisms and elucidating their dependence on composition and force is the underlining goal of this thesis.Prior to cracking, silicate glasses can inelastically deform by shear and densification. However, the link between the mechanical properties, strength, glass structure and maximum force and the propensity by which either of these mechanisms are favored still remains unclear. In this study, the first aim is to elucidate the causes of the ISE and
i
explore the relationships between the ISE and the dissipation mechanisms, and identify what feature(s) of the glass can be used to infer their behavior. All glasses have shown a strong link between the ISE and shear flow and densification. Second, the link between composition and the dissipation mechanisms will be elucidated. This is accomplished by performing indentation tests coupled with an annealing method to independently quantify the amount of volume associated with each dissipation mechanism and elucidate relationships with ingredients and structure of the glasses. Some conclusions will then be presented that link all these behaviors together.
ContributorsKazembeyki, Maryam (Author) / Hoover, Christian G (Thesis advisor) / Rajan, Subramaniam (Committee member) / Neithalath, Narayanan (Committee member) / Chawla, Nikhilesh (Committee member) / Perreault, Francois (Committee member) / Arizona State University (Publisher)
Created2021
Description
Concrete develops strength rapidly after mixing and is highly influenced by temperature and curing process. The material characteristics and the rate of property development, along with the exposure conditions influences volume change mechanisms in concrete, and the cracking propensity of the mixtures. Furthermore, the structure geometry (due to restraint as well as the surface area-to-volume ratio) also influences shrinkage and cracking. Thus, goal of this research is to better understand and predict shrinkage cracking in concrete slab systems under different curing conditions. In this research, different concrete mixtures are evaluated on their propensity to shrink based on free shrinkage and restrained shrinkage tests.Furthermore, from the data obtained from restrained ring test, a casted slab is measured for shrinkage. Effects of different orientation of restraints are studied and compared to better understand the shrinking behavior of the concrete mixtures. The results show that the maximum shrinkage is near the edges of the slab and decreases towards the center. Shrinkage near the edges with no restraint is found out to be more than the shrinkage towards the edges with restraining effects.
ContributorsNimbalkar, Atharwa Samir (Author) / Neithalath, Narayanan (Thesis advisor) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam (Committee member) / Arizona State University (Publisher)
Created2023
Description
Alkali activated mine tailing-slag blends and mine tailing-cement blends containing mine tailings as the major binder constituent are evaluated for their setting time behavior,
reactivity properties, flow characteristics, and compressive strengths. Liquid sodium
silicate and sodium hydroxide are used as the activator solution. The effects of varying
alkali oxide-to-powder ratio (n value) and silicon oxide-to-alkali oxide ratio (Ms value) is
explored. The reactivity of all blends prepared in this study is studied using an isothermal
calorimeter. Mine tailing-cement blends show a higher initial heat release peak than mine
tailing-slag blends, whereas their cumulative heat release is comparable for higher n values
of 0.050 to 0.100. Compressive strength tests and rheological studies were done for the
refined blends selected based on setting time criterion. Setting times and compressive
strengths are found to depend significantly on the activator parameters and binder
compositions, allowing fine-tuning of the mix proportion parameters based on the intended
end applications. The compressive strength of the selected mine tailing-slag blends and
mine tailing-cement blends are in the range of 7-40 MPa and 4-11 MPa, respectively.
Higher compressive strength is generally achieved at lower Ms and higher n values for mine
tailing-slag blends, while a higher Ms yields better compressive strength in the case of mine
tailing-cement blends. Rheological studies indicate a decrease in yield stress and viscosity
with increase in the replacement ratio, while a higher activator concentration increase both.
Oscillatory shear studies were used to evaluate the storage modulus and loss modulus of
the mine tailing binders. The paste is seen to exhibit a more elastic behavior at n values of
0.05 and 0.075, however the viscous behavior is seen to dominate at higher n value of 0.1
at similar replacement ratios and Ms value. A higher Ms value is also seen to increase the
onset point of the drop in both the storage and loss modulus of the pastes. The studied also
investigated the potential use of mine tailing blends for coating applications. The pastes
with higher alkalinity showed a lesser crack percentage, with a 10% slag replacement ratio
having a better performance compared to 20% and 30% slag replacement ratios. Overall,
the study showed that the activation parameters and mine tailings replacement level have
a significant influence on the properties of both mine tailing-slag binders and mine tailing-cement binders, thereby allowing selection of suitable mix design for the desired end
application, allowing a sustainable approach to dispose the mine tailings waste
ContributorsRamasamy Jeyaprakash, Rijul Kanth (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2023
Description
Composites are replacing conventional materials in aerospace applications due to their light weight, non-corrosiveness, and high specific strength. This thesis aims to characterize the input data for IM7-8552 unidirectional composite to support MAT213, an orthotropic elasto-plastic damage material model and MAT_186, a mixed mode cohesive zone model used to model delamination. MAT_213 in conjunction with MAT_186 can be used to predict the behavior of composite under crush and impact loads including delamination. MAT_213 requires twelve sets of stress-strain curves, direction-dependent material constants, and flow rule coefficients as input. All the necessary inputs are obtained through the post-processing of a total of twelve distinct quasi-static and room temperature (QS-RT) experiments. MAT_186 is driven by a set of Mode I and Mode II fracture parameters and traction separation laws, a constitutive law that derives the relationship between stresses and relative displacements at integration points of cohesive elements. Obtaining cohesive law parameters experimentally is a tedious process as it requires close monitoring of the crack length during the test, which is a difficult task to achieve with accuracy even after using sophisticated equipment such as Digital Image Correlation (DIC). In this thesis, a numerical inverse analysis method to precisely predict these parameters by using finite element analysis with cohesive zone modeling and response surface methodology (RSM) is proposed. Three steps comprise RSM. The process in Step 1 involves calculating the root mean square error between the finite element and experimental load-displacement curves to produce the response surface. In step 2, the response surface is fitted with a second-order polynomial using the Levenberg-Marquardt algorithm. In step 3, an optimization problem is solved by minimizing the fitted function to find the optimum cohesive zone parameters. Finally, the obtained input for MAT_213 and MAT_186 material models is validated by performing a quasi-isotropic tension test simulation.
ContributorsRaihan, Mohammed (Author) / Rajan, Subramaniam (Thesis advisor) / Neithalath, Narayanan (Committee member) / Hoover, Christian (Committee member) / Yellavajjala, Ravi (Committee member) / Arizona State University (Publisher)
Created2023
Description
Ultra High Performance (UHP) cementitious binders are a class of cement-based materials with high strength and ductility, designed for use in precast bridge connections, bridge superstructures, high load-bearing structural members like columns, and in structural repair and strengthening. This dissertation aims to elucidate the chemo-mechanical relationships in complex UHP binders to facilitate better microstructure-based design of these materials and develop machine learning (ML) models to predict their scale-relevant properties from microstructural information.To establish the connection between micromechanical properties and constitutive materials, nanoindentation and scanning electron microscopy experiments are performed on several cementitious pastes. Following Bayesian statistical clustering, mixed reaction products with scattered nanomechanical properties are observed, attributable to the low degree of reaction of the constituent particles, enhanced particle packing, and very low water-to-binder ratio of UHP binders. Relating the phase chemistry to the micromechanical properties, the chemical intensity ratios of Ca/Si and Al/Si are found to be important parameters influencing the incorporation of Al into the C-S-H gel.
ML algorithms for classification of cementitious phases are found to require only the intensities of Ca, Si, and Al as inputs to generate accurate predictions for more homogeneous cement pastes. When applied to more complex UHP systems, the overlapping chemical intensities in the three dominant phases – Ultra High Stiffness (UHS), unreacted cementitious replacements, and clinker – led to ML models misidentifying these three phases. Similarly, a reduced amount of data available on the hard and stiff UHS phases prevents accurate ML regression predictions of the microstructural phase stiffness using only chemical information. The use of generic virtual two-phase microstructures coupled with finite element analysis is also adopted to train MLs to predict composite mechanical properties. This approach applied to three different representations of composite materials produces accurate predictions, thus providing an avenue for image-based microstructural characterization of multi-phase composites such UHP binders. This thesis provides insights into the microstructure of the complex, heterogeneous UHP binders and the utilization of big-data methods such as ML to predict their properties. These results are expected to provide means for rational, first-principles design of UHP mixtures.
ML algorithms for classification of cementitious phases are found to require only the intensities of Ca, Si, and Al as inputs to generate accurate predictions for more homogeneous cement pastes. When applied to more complex UHP systems, the overlapping chemical intensities in the three dominant phases – Ultra High Stiffness (UHS), unreacted cementitious replacements, and clinker – led to ML models misidentifying these three phases. Similarly, a reduced amount of data available on the hard and stiff UHS phases prevents accurate ML regression predictions of the microstructural phase stiffness using only chemical information. The use of generic virtual two-phase microstructures coupled with finite element analysis is also adopted to train MLs to predict composite mechanical properties. This approach applied to three different representations of composite materials produces accurate predictions, thus providing an avenue for image-based microstructural characterization of multi-phase composites such UHP binders. This thesis provides insights into the microstructure of the complex, heterogeneous UHP binders and the utilization of big-data methods such as ML to predict their properties. These results are expected to provide means for rational, first-principles design of UHP mixtures.
ContributorsFord, Emily Lucile (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Chawla, Nikhilesh (Committee member) / Hoover, Christian G. (Committee member) / Maneparambil, Kailas (Committee member) / Arizona State University (Publisher)
Created2020
Description
There has been a renewed interest to understand the degradation mechanism of concrete under radiation as many nuclear reactors are reaching their expiration date. Much of the information on the degradation mechanism of concrete under radiation comes from the experiments, which are carried out on very small specimens. With the advent of finite element analysis, a numerical predictive tool is desired that can predict the extent of damage in the nuclear concrete structure.
A mesoscale micro-structural framework is proposed in Multiphysics Object-Oriented Simulation Environment (MOOSE) finite element framework which represents the first step in this direction. As part of the framework, a coupled creep damage algorithm was developed and implemented in MOOSE. The algorithm considers creep through rheological models, while damage evolves exponentially as a function of elastic strain and creep strain. A characteristic length is introduced in the formulation such that the energy release rate associated with each element remains the same to avoid vanishing energy dissipation with mesh refinement. A creep damage parameter quantifies the effect of creep strain on the damage that was calibrated using three-point bending experiments with varying rates of loading.
The creep damage model was also validated with restrained ring shrinkage tests on cementitious materials containing compliant/stiff inclusions subjected to variable drying conditions. The simulation approach explicitly considers: (i) moisture diffusion driven differential shrinkage along the depth of the specimen (ii) viscoelastic response of aging cementitious materials (iii) isotropic damage model with Rankine′s failure initiation criterion, and (iv) random distribution of tensile strengths of individual finite elements.
The model was finally validated with experimental results on neutron-irradiated concrete. The simulation approach considers: (i) coupled hygro-thermal model to predict the temperature and humidity profile inside the specimen (ii) radiation-induced volumetric expansion of aggregates (RIVE) (iii) thermal, shrinkage and creep effects based on the temperature and humidity profile and (iv) isotropic damage model with Rankine’s criterion to determine failure initiation.
A mesoscale micro-structural framework is proposed in Multiphysics Object-Oriented Simulation Environment (MOOSE) finite element framework which represents the first step in this direction. As part of the framework, a coupled creep damage algorithm was developed and implemented in MOOSE. The algorithm considers creep through rheological models, while damage evolves exponentially as a function of elastic strain and creep strain. A characteristic length is introduced in the formulation such that the energy release rate associated with each element remains the same to avoid vanishing energy dissipation with mesh refinement. A creep damage parameter quantifies the effect of creep strain on the damage that was calibrated using three-point bending experiments with varying rates of loading.
The creep damage model was also validated with restrained ring shrinkage tests on cementitious materials containing compliant/stiff inclusions subjected to variable drying conditions. The simulation approach explicitly considers: (i) moisture diffusion driven differential shrinkage along the depth of the specimen (ii) viscoelastic response of aging cementitious materials (iii) isotropic damage model with Rankine′s failure initiation criterion, and (iv) random distribution of tensile strengths of individual finite elements.
The model was finally validated with experimental results on neutron-irradiated concrete. The simulation approach considers: (i) coupled hygro-thermal model to predict the temperature and humidity profile inside the specimen (ii) radiation-induced volumetric expansion of aggregates (RIVE) (iii) thermal, shrinkage and creep effects based on the temperature and humidity profile and (iv) isotropic damage model with Rankine’s criterion to determine failure initiation.
ContributorsSaklani, Naman (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramanian (Committee member) / Mobasher, Barzin (Committee member) / Hoover, Christian (Committee member) / Chawla, Nikhilesh (Committee member) / Arizona State University (Publisher)
Created2020