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- Creators: Barrett, The Honors College
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Description
The alkali activation of aluminosilicate materials as binder systems derived from industrial byproducts have been extensively studied due to the advantages they offer in terms enhanced material properties, while increasing sustainability by the reuse of industrial waste and byproducts and reducing the adverse impacts of OPC production. Fly ash and ground granulated blast furnace slag are commonly used for their content of soluble silica and aluminate species that can undergo dissolution, polymerization with the alkali, condensation on particle surfaces and solidification. The following topics are the focus of this thesis: (i) the use of microwave assisted thermal processing, in addition to heat-curing as a means of alkali activation and (ii) the relative effects of alkali cations (K or Na) in the activator (powder activators) on the mechanical properties and chemical structure of these systems. Unsuitable curing conditions instigate carbonation, which in turn lowers the pH of the system causing significant reductions in the rate of fly ash activation and mechanical strength development. This study explores the effects of sealing the samples during the curing process, which effectively traps the free water in the system, and allows for increased aluminosilicate activation. The use of microwave-curing in lieu of thermal-curing is also studied in order to reduce energy consumption and for its ability to provide fast volumetric heating. Potassium-based powder activators dry blended into the slag binder system is shown to be effective in obtaining very high compressive strengths under moist curing conditions (greater than 70 MPa), whereas sodium-based powder activation is much weaker (around 25 MPa). Compressive strength decreases when fly ash is introduced into the system. Isothermal calorimetry is used to evaluate the early hydration process, and to understand the reaction kinetics of the alkali powder activated systems. A qualitative evidence of the alkali-hydroxide concentration of the paste pore solution through the use of electrical conductivity measurements is also presented, with the results indicating the ion concentration of alkali is more prevalent in the pore solution of potassium-based systems. The use of advanced spectroscopic and thermal analysis techniques to distinguish the influence of studied parameters is also discussed.
ContributorsChowdhury, Ussala (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramanium D. (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2013
Description
Brain-computer interface technology establishes communication between the brain and a computer, allowing users to control devices, machines, or virtual objects using their thoughts. This study investigates optimal conditions to facilitate learning to operate this interface. It compares two biofeedback methods, which dictate the relationship between brain activity and the movement of a virtual ball in a target-hitting task. Preliminary results indicate that a method in which the position of the virtual object directly relates to the amplitude of brain signals is most conducive to success. In addition, this research explores learning in the context of neural signals during training with a BCI task. Specifically, it investigates whether subjects can adapt to parameters of the interface without guidance. This experiment prompts subjects to modulate brain signals spectrally, spatially, and temporally, as well differentially to discriminate between two different targets. However, subjects are not given knowledge regarding these desired changes, nor are they given instruction on how to move the virtual ball. Preliminary analysis of signal trends suggests that some successful participants are able to adapt brain wave activity in certain pre-specified locations and frequency bands over time in order to achieve control. Future studies will further explore these phenomena, and future BCI projects will be advised by these methods, which will give insight into the creation of more intuitive and reliable BCI technology.
ContributorsLancaster, Jenessa Mae (Co-author) / Appavu, Brian (Co-author) / Wahnoun, Remy (Co-author, Committee member) / Helms Tillery, Stephen (Thesis director) / Barrett, The Honors College (Contributor) / Harrington Bioengineering Program (Contributor) / Department of Psychology (Contributor)
Created2014-05
Description
It is the intent of this research to determine the feasibility of utilizing industrial byproducts in cementitious systems in lieu of Portland Cement to reduce global CO2 emissions. Class C and Class F Fly Ash (CFA and FFA, respectively) derived from industrial coal combustion were selected as the replacement materials for this study. Sodium sulfate and calcium oxide were used as activators. In Part 1 of this study, focus was placed on high volume replacement of OPC using sodium sulfate as the activator. Despite improvements in heat generation for both CFA and FFA systems in the presence of sulfate, sodium sulfate was found to have adverse effects on the compressive strength of CFA mortars. In the CFA mixes, strength improved significantly with sulfate addition, but began to decrease in strength around 14 days due to expansive ettringite formation. Conversely, the addition of sulfate led to improved strength for FFA mixes such that the 28 day strength was comparable to that of the CFA mixes with no observable strength loss. Maximum compressive strengths achieved for the high volume replacement mixes was around 40 MPa, which is considerably lower than the baseline OPC mix used for comparison. In Part 2 of the study, temperature dependency and calcium oxide addition were studied for sodium sulfate activated systems composed of 100% Class F fly ash. In the presence of sulfate, added calcium increased reactivity and compressive strength at early ages, particularly at elevated temperatures. It is believed that sulfate and calcium react with alumina from fly ash to form ettringite, while heat overcomes the activation energy barrier of fly ash. The greatest strengths were obtained for mixes containing the maximum allowed quantity of calcium oxide (5%) and sodium sulfate (3%), and were around 12 MPa. This is a very low compressive strength relative to OPC and would therefore be an inadequate substitute for OPC needs.
ContributorsTweedley, Shannon Elizabeth (Author) / Neithalath, Narayanan (Thesis director) / Mamlouk, Michael (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor) / School of Sustainable Engineering and the Built Environment (Contributor)
Created2014-05
Description
The preceding paper analyzes the effects of UV radiation in plastic reinforcement and its effects on the fracture properties of cement-based materials. Three point tests were performed on notched beams, which called for the consideration of the Type II Size Effect. A comparison of the ductility of beams with and without polyethylene plastic powder reinforcement was done through the calculation of the fracture parameters Gf and cf, which represent the initial fracture energy and the characteristic length respectively. Although there was an observed increase in ductile behavior and properties in beams with polyethylene reinforcement, there did not seem to be a significant effect caused by the UV radiation. The hydrophilicity of the polyethylene powder was successfully increased through UV radiation and validated through water retention tests, which showed that the UV-treated polyethylene was retaining more water than the non-treated polyethylene, yet there was no extra increase in ductility of the cement beams compared to using non-treated polyethylene. The Type II Size Effect analysis was performed and compared to the stress analysis results of the experiment. For future research, it is recommended that a higher volume of polyethylene per 1000 grams of cement powder be used, as well as increasing the strength of the UV chamber to achieve a larger increase in the hydrophilicity of the polyethylene. Also, perhaps using more precise equipment to cut the notches in the beams would be helpful in ensuring that all specimens are identical and there is no error in notch depth caused by inaccurate use of the hacksaw or radial saw. Further experiments will be conducted.
ContributorsMardambek, Karim (Author) / Hoover, Christian (Thesis director) / Kazembeyki, Maryam (Committee member) / Civil, Environmental and Sustainable Eng Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
As a student and then an Undergraduate Teaching Assistant (UGTA), I have had the opportunity to personally witness the learning process of both myself and approximately 75 additional incoming Civil Engineering students taking the Mechanics courses after me. While watching the student learning process as an UGTA, I realized that there were consistent points of confusion amongst the students that the teaching staff could not efficiently communicate with the electronic or physical classroom materials available. As a physical learner, I am able to learn more comprehensively if I have a physical model to manipulate, and often found myself in the position of wanting to be able to physically represent and manipulate the systems being studied in class.
ContributorsCamillucci, Allyson Nicole (Co-author, Co-author) / Hjelmstad, Keith (Thesis director) / Chatziefstratiou, Efthalia (Committee member) / Civil, Environmental and Sustainable Eng Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
Gathering the necessary information required to tackle traffic congestion problems is generally time consuming and challenging but is an important part of city planners’ work. The purpose of this paper is to describe the methodology used when analyzing potential solutions for the Arizona State Route 89A and Highway 179 roundabout in Sedona, Arizona; which is currently experiencing significant congestion. The oversaturated condition is typically applied to signalized intersections but its application to roundabouts requires further exploration for future management of similar transportation systems. The accompanying Quick Estimation and Simulation model (QESM) spreadsheet was calibrated using an iterative process to optimize its level of adaptability to various scenarios. This microsimulation modeling program can be used to predict the outcome of possible roadway improvements aimed at decreasing traffic congestion. The information provided in this paper helps users understand traffic system problems, as a primary to visual simulation programs.
ContributorsBrunetti, Isabel (Co-author) / Tran, Adam (Co-author) / Zhou, Xuesong (Thesis director) / Carreon, Adam (Committee member) / Civil, Environmental and Sustainable Eng Program (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
With a rapidly decreasing amount of resources for construction, wood and bamboo have been suggested as renewable materials for increased use in the future to attain sustainability. Through a literature review, bamboo and wood growth, manufacturing and structural attributes were compared and then scored in a weighted matrix to determine the option that shows the higher rate of sustainability. In regards to the growth phase, which includes water usage, land usage, growth time, bamboo and wood showed similar characteristics overall, with wood scoring 1.11% higher than bamboo. Manufacturing, which captures the extraction and milling processes, is experiencing use of wood at levels four times those of bamboo, as bamboo production has not reached the efficiency of wood within the United States. Structural use proved to display bamboo’s power, as it scored 30% higher than wood. Overall, bamboo received a score 15% greater than that of wood, identifying this fast growing plant as the comparatively more sustainable construction material.
ContributorsThies, Jett Martin (Author) / Ward, Kristen (Thesis director) / Halden, Rolf (Committee member) / Industrial, Systems & Operations Engineering Prgm (Contributor) / Civil, Environmental and Sustainable Eng Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
The following report followed three separate construction crews at a construction site at ASU and performed labor productivity analysis to quantitatively measure the efficiency of the workers performing specific tasks. These crews were tasked with electrical wiring, concrete pouring, and drywall sanding. Crew balance measured the down time of individual crew members compared to the overall time spent on a task, and the results of these observations were calculated, and suggested improvements given.
ContributorsScollick, Evelyn (Author) / Grau, David (Thesis director) / Lamanna, Anthony (Committee member) / School of Film, Dance and Theatre (Contributor) / Mechanical and Aerospace Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
The loading provisions were compared between the ASCE 7-10 standard and ASCE 7-16 standard. Two different structural models were considered: an office building with a flat roof located in Tempe and a community center with a gable roof located in Flagstaff. The following load types were considered: dead, live, wind, and snow loads. The only major changes between the standards were found in the wind load calculations. The winds loads were reduced by approximately 22% for the office building in Tempe and 37% for the community center in Flagstaff. A structural design was completed for the frame of the Flagstaff community building. There was a 19% reduction in cost from the design using ASCE 7-10 provisions compared to the design utilizing ASCE 7-16 provisions, leading to a saving of $7,599.17. The reduction in loading, and subsequently more cost-effective design, is attributed to the reduction in basic wind speed for the region and consideration of the ground elevation factor. The introduction of the new ASCE 7-16 standard was met with criticism, especially over the increase in specific coefficients in the wind load and seismic load chapters. Proponents of ASCE 7-16 boast that the new chapter on tsunami loads, new maps for various environmental loads, and a new electronic hazard are some of the merits of the newest standard. Others still question whether the complexity of the provisions is necessary and call for further improvements for the wind and seismic provisions. While tension exists in the desire for a simple standard, ASCE 7-16 prioritizes in having its provisions provide economical and reliable results. More consideration could be devoted to developing a more convenient standard for users. Regardless, engineering professionals should be able to adapt alongside newly developed practices and newly discovered data.
ContributorsCajegas, Cyam Joshua Dato (Author) / Rajan, Subramaniam (Thesis director) / Neithalath, Narayanan (Committee member) / Civil, Environmental and Sustainable Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
Description
Arizona's transportation infrastructure is in need of an update. The American Society of Civil Engineers (ASCE) State Infrastructure 2017 Report Card scores Arizona's roads at a D+ and Arizona's bridges at a B. These grades are indicative that the serviceability levels of the roads and bridges are less than adequate. These grades may seem tolerable in light of a national bridge C+ grade and a national road D grade, but the real problem lies in Arizona's existing funding gap that is in danger of exponentially increasing in the future. With an influx of vehicles on Arizona's roads and bridges, the cost of building, repairing, and maintaining them will grow and cause a problematic funding shortage. This report explores the current state of Arizona's roads and bridges as well as the policy and funding sources behind them, using statistics from the ASCE infrastructure report card and the Federal Highway Administration. Additionally, it discusses how regular, preventative maintenance for transportation infrastructure is the economically responsible choice for the state because it decreases delays and fuel expenses, prevents possible catastrophes, and increases human safety. To prioritize preventative transportation infrastructure maintenance, the common mentality that allows it to be sidelined for more newsworthy projects needs to be changed. Along with gaining preventative maintenance revenues through increasing vehicular taxes and fees, encouraging transportation policymakers and politicians to make economic decisions in favor of maintenance rather than waiting until failure is a reliable way to encourage regular, preventative maintenance.
ContributorsBurdett, Courtney (Author) / Hjelmstad, Keith (Thesis director) / Pendyala, Ram (Committee member) / Civil, Environmental and Sustainable Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05