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Description
Dry and steam NanoBonding™ are conceived and researched to bond Si-based surfaces, via nucleation and growth of a two-dimensional SiOxHy or hydrated SiOxHy interphase connecting surfaces at the nanoscale across macroscopic domains. The motivation is to create strong, long lasting, hermetically bonded sensors with their electronics for the development

Dry and steam NanoBonding™ are conceived and researched to bond Si-based surfaces, via nucleation and growth of a two-dimensional SiOxHy or hydrated SiOxHy interphase connecting surfaces at the nanoscale across macroscopic domains. The motivation is to create strong, long lasting, hermetically bonded sensors with their electronics for the development of an artificial pancreas and to bond solar cells to glass panels for robust photovoltaic technology. The first step in NanoBonding™ is to synthesize smooth surfaces with 20 nm wide atomic terraces via a precursor phase, ß-cSiO2 on Si(100) and oxygen-deficient SiOx on the silica using the Herbots-Atluri process and Entrepix’s spin etching. Smooth precursor phases act as geometric and chemical template to nucleate and grow macroscopic contacting domains where cross bridging occurs via arrays of molecular strands in the hydrated SiOxHy interphase. Steam pressurization is found to catalyze NanoBonding™ consistently, eliminating the need for direct mechanical compression that limits the size and shape of wafers to be bonded in turn, reducing the cost of processing. Total surface energy measurements via 3 Liquids Contact Angle Analysis (3L CAA) enables accurate quantitative analysis of the total surface energy and each of its components. 3L CAA at each step in the process shows that surface energy drops to 42.4 ± 0.6 mJ/m2 from 57.5 ± 1.4 mJ/m2 after the Herbots-Atluri clean of an “As Received” wafer. 3L CAA after steam pressurization Nanobonding™ shows almost complete elimination from 13.8 mJ/m2 ± 1.0 to 0.002 ±- 0.0002 mJ/m2 in the contribution of acceptors to the total free surface energy, and an increase from 0.2 ± .03 to 23.8± 1.6 mJ/m2 in the contribution of donors. This is consistent with an increase in hydroxylation of the ß-cSiO2 surface as a consistent precursor phase for cross-bridging. This research optimizes the use of glycerin, water, and α-bromo-naphtalene in the use of 3L CAA to effectively quantify the components of total free surface energy which helps to better understand the most consistent method for NanoBonding™.
ContributorsBennett-Kennett, Ross Buchanan (Author) / Culbertson, Robert (Thesis director) / Herbots, Nicole (Committee member) / Foy, Joseph (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / Department of Physics (Contributor) / School of Historical, Philosophical and Religious Studies (Contributor)
Created2013-05
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Description
In this project we are analyzing the diamond-titanium interface as it applies to diamond-based diode devices, including alpha particle, proton, and neutron detectors. This is done through the fabrication of an O-terminated B-doped diamond sample with a 20 Å Ti / 10 Å Pt overlayer which was then annealed and

In this project we are analyzing the diamond-titanium interface as it applies to diamond-based diode devices, including alpha particle, proton, and neutron detectors. This is done through the fabrication of an O-terminated B-doped diamond sample with a 20 Å Ti / 10 Å Pt overlayer which was then annealed and examined via X-ray photoelectron spectroscopy (XPS). It was discovered that after annealing the sample at temperatures ranging from 400 C - 900 C that TiC was not formed at any point during this experiment. Possible reasons for this include a lack of sufficient titanium in order to form TiC and over oxygenating the diamond surface before the metal was deposited.
ContributorsJohnson, Holly (Author) / Zaniewski, Anna (Thesis director) / Nemanich, Robert (Committee member) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
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Description
The preceding paper analyzes the effects of UV radiation in plastic reinforcement and its effects on the fracture properties of cement-based materials. Three point tests were performed on notched beams, which called for the consideration of the Type II Size Effect. A comparison of the ductility of beams with and

The preceding paper analyzes the effects of UV radiation in plastic reinforcement and its effects on the fracture properties of cement-based materials. Three point tests were performed on notched beams, which called for the consideration of the Type II Size Effect. A comparison of the ductility of beams with and without polyethylene plastic powder reinforcement was done through the calculation of the fracture parameters Gf and cf, which represent the initial fracture energy and the characteristic length respectively. Although there was an observed increase in ductile behavior and properties in beams with polyethylene reinforcement, there did not seem to be a significant effect caused by the UV radiation. The hydrophilicity of the polyethylene powder was successfully increased through UV radiation and validated through water retention tests, which showed that the UV-treated polyethylene was retaining more water than the non-treated polyethylene, yet there was no extra increase in ductility of the cement beams compared to using non-treated polyethylene. The Type II Size Effect analysis was performed and compared to the stress analysis results of the experiment. For future research, it is recommended that a higher volume of polyethylene per 1000 grams of cement powder be used, as well as increasing the strength of the UV chamber to achieve a larger increase in the hydrophilicity of the polyethylene. Also, perhaps using more precise equipment to cut the notches in the beams would be helpful in ensuring that all specimens are identical and there is no error in notch depth caused by inaccurate use of the hacksaw or radial saw. Further experiments will be conducted.
ContributorsMardambek, Karim (Author) / Hoover, Christian (Thesis director) / Kazembeyki, Maryam (Committee member) / Civil, Environmental and Sustainable Eng Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description

This thesis investigates the feasibility of using recycled ceramics as the aggregate in concrete, as an alternative to natural rock aggregates. The study evaluates the mechanical properties of concrete made with recycled ceramics and compares them with those of traditional concrete. The research involved laboratory experiments to determine compressive strength

This thesis investigates the feasibility of using recycled ceramics as the aggregate in concrete, as an alternative to natural rock aggregates. The study evaluates the mechanical properties of concrete made with recycled ceramics and compares them with those of traditional concrete. The research involved laboratory experiments to determine compressive strength and displacement. The results show that the concrete made with recycled ceramics exhibited higher compressive strength and lower maximum displacement than traditional concrete, which means it acted more brittle. However, when the recycled ceramics were used to replace only 50% of the rock aggregate, the compressive strength decreased while the maximum displacement stayed the same, though the study concludes that a larger sample size is needed for more reliable results. Based on the findings, the thesis concludes that while the use of recycled ceramics in concrete may not be suitable for structural concrete, it could still have potential as a sustainable building material in non-structural applications.

ContributorsLong, Mason (Author) / Hoover, Christian (Thesis director) / Pazhankave, Silpa (Committee member) / Barrett, The Honors College (Contributor) / Civil, Environmental and Sustainable Eng Program (Contributor)
Created2023-05
Description

In this project, we aim to fabricate PIN structure-like diodes for radiation detectors using Boron Nitride (BN). This fabrication is done by performing lithography and metal deposition processes on a Cubic Boron Nitride (cBN) of around 200 nm in thickness layer on top of a boron doped diamond substrate. The

In this project, we aim to fabricate PIN structure-like diodes for radiation detectors using Boron Nitride (BN). This fabrication is done by performing lithography and metal deposition processes on a Cubic Boron Nitride (cBN) of around 200 nm in thickness layer on top of a boron doped diamond substrate. The main goal is to create the most efficient and affordable alpha particle—and ideally neutron—detector in a radiation setting. Thus, making more accessible radiation detectors that can be more easily produced and disposed of, as well as minimizing the size of conventional detectors.

ContributorsGutierrez, Eric (Author) / Nemanich, Robert (Thesis director) / Zaniewski, Anna (Committee member) / Barrett, The Honors College (Contributor) / Department of Physics (Contributor)
Created2023-05