Matching Items (6)
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- All Subjects: Marriage
- All Subjects: Materials
- Creators: Department of Physics
- Creators: Yabiku, Scott
Description
Dry and steam NanoBonding™ are conceived and researched to bond Si-based surfaces, via nucleation and growth of a two-dimensional SiOxHy or hydrated SiOxHy interphase connecting surfaces at the nanoscale across macroscopic domains. The motivation is to create strong, long lasting, hermetically bonded sensors with their electronics for the development of an artificial pancreas and to bond solar cells to glass panels for robust photovoltaic technology. The first step in NanoBonding™ is to synthesize smooth surfaces with 20 nm wide atomic terraces via a precursor phase, ß-cSiO2 on Si(100) and oxygen-deficient SiOx on the silica using the Herbots-Atluri process and Entrepix’s spin etching. Smooth precursor phases act as geometric and chemical template to nucleate and grow macroscopic contacting domains where cross bridging occurs via arrays of molecular strands in the hydrated SiOxHy interphase. Steam pressurization is found to catalyze NanoBonding™ consistently, eliminating the need for direct mechanical compression that limits the size and shape of wafers to be bonded in turn, reducing the cost of processing. Total surface energy measurements via 3 Liquids Contact Angle Analysis (3L CAA) enables accurate quantitative analysis of the total surface energy and each of its components. 3L CAA at each step in the process shows that surface energy drops to 42.4 ± 0.6 mJ/m2 from 57.5 ± 1.4 mJ/m2 after the Herbots-Atluri clean of an “As Received” wafer. 3L CAA after steam pressurization Nanobonding™ shows almost complete elimination from 13.8 mJ/m2 ± 1.0 to 0.002 ±- 0.0002 mJ/m2 in the contribution of acceptors to the total free surface energy, and an increase from 0.2 ± .03 to 23.8± 1.6 mJ/m2 in the contribution of donors. This is consistent with an increase in hydroxylation of the ß-cSiO2 surface as a consistent precursor phase for cross-bridging. This research optimizes the use of glycerin, water, and α-bromo-naphtalene in the use of 3L CAA to effectively quantify the components of total free surface energy which helps to better understand the most consistent method for NanoBonding™.
ContributorsBennett-Kennett, Ross Buchanan (Author) / Culbertson, Robert (Thesis director) / Herbots, Nicole (Committee member) / Foy, Joseph (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / Department of Physics (Contributor) / School of Historical, Philosophical and Religious Studies (Contributor)
Created2013-05
Description
Racial and ethnic differences in marriage outcomes are well established in the previous literature. In addition, variation in the social structure in which individuals reside has an impact on the context in which mate selection and marriage occur. The purpose of this dissertation is to determine how these variations shape marriage outcomes for Non-Hispanic Whites, Non-Hispanic Blacks, Hispanics and Non-Hispanic Asians. Beyond racial and ethnic characteristics, this series of studies take into account temporal metropolitan characteristics. Study 1 uses U.S. Census and American Community Survey data to predict metropolitan marriage prevalence at three time points: 1990, 2000 and 2010. Study 2 predicts the odds that individuals across the four racial/ethnic groups have never married, taking into account structural characteristics including region of residence. Study 3 predicts the odds that currently married women are racially or ethnically intermarried, with emphasis on race/ethnicity and region of residence. The results suggest that metropolitan structural characteristics matter somewhat, but individuals' race/ethnicity is the strongest predictor of both the odds of having never married and intermarriage. There is also evidence that region serves as a moderator impacting the overall marriage outcomes of racial/ethnic minority groups to a greater extent in comparison to Non-Hispanic Whites.
ContributorsWalker, Laquitta M (Author) / Glick, Jennifer E. (Thesis advisor) / Yabiku, Scott (Committee member) / Diaz McConnell, Eileen (Committee member) / Arizona State University (Publisher)
Created2016
Description
In this paper, I first explain the legal theory which leads up to Obergefell v. Hodges, and then analyze Obergefell v. Hodges itself. My analysis leads me to conclude that the legal reasoning, or the argument used to come to the decision, is flawed for it relies too heavily upon public opinion and is a legislative action of the Supreme Court. Therefore, I offer three alternatives: each of which improve upon the legal reasoning in different ways. Furthermore, my analysis of these three arguments\u2014and particularly the Free Exercise Argument\u2014leads me to postulate that there is in fact a Freedom to Practice embedded in the penumbral, or unstated, rights of the United States Constitution. While the full extent of the implications of such a right must be explored in another paper, I establish the legal reasoning for the freedom by four routes, showing that although precedent has yet to materialize, there are several arguments for the freedom.
ContributorsMartin, Daniel Brockie (Author) / Kramer, Zachary (Thesis director) / Graff, Sarah (Committee member) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2015-12
Description
In this project, we aim to fabricate PIN structure-like diodes for radiation detectors using Boron Nitride (BN). This fabrication is done by performing lithography and metal deposition processes on a Cubic Boron Nitride (cBN) of around 200 nm in thickness layer on top of a boron doped diamond substrate. The main goal is to create the most efficient and affordable alpha particle—and ideally neutron—detector in a radiation setting. Thus, making more accessible radiation detectors that can be more easily produced and disposed of, as well as minimizing the size of conventional detectors.
ContributorsGutierrez, Eric (Author) / Nemanich, Robert (Thesis director) / Zaniewski, Anna (Committee member) / Barrett, The Honors College (Contributor) / Department of Physics (Contributor)
Created2023-05
Description
This dissertation explores changes in fertility and family formation in South Korea, a setting in which rapid demographic changes have taken place since the early twentieth century. Despite active debate and discussion among experts and policymakers, knowledge is still limited in regards to the country’s significant demographic changes. I take advantage of Korean census samples data from 1966 to 2010, which span birth cohorts from pre- and early-transitional stages to post-transitional stages, which comprise the entry stage of the second demographic transition. From a cohort perspective, I use diverse demographic methods to analyze three different aspects of fertility and family formation—fertility differentials, marriage delay, and fertility concentration.
The findings illustrate how fertility and marriage patterns have changed over generations and range from a politically tumultuous period, which includes World War II, liberation, and the Korean War, to an advanced economic period. By and large, the three studies suggest that until 1960, fertility and family formation converged as per social norms and leadership guidelines. Then, marriage and childbearing behaviors began to diversify and variation by social groups increased for cohorts born during and after the 1960s. The phrase “convergence towards diversity” captures the reversal of demographic trends within the country. Taken together, this dissertation advances our understanding of how fertility and family formation have changed in South Korea, which has been on an intense demographic journey from pre-transitional fertility through very low fertility, and currently headed toward another destination.
The findings illustrate how fertility and marriage patterns have changed over generations and range from a politically tumultuous period, which includes World War II, liberation, and the Korean War, to an advanced economic period. By and large, the three studies suggest that until 1960, fertility and family formation converged as per social norms and leadership guidelines. Then, marriage and childbearing behaviors began to diversify and variation by social groups increased for cohorts born during and after the 1960s. The phrase “convergence towards diversity” captures the reversal of demographic trends within the country. Taken together, this dissertation advances our understanding of how fertility and family formation have changed in South Korea, which has been on an intense demographic journey from pre-transitional fertility through very low fertility, and currently headed toward another destination.
ContributorsYoo, Sam Hyun (Author) / Sarah, Hayford (Thesis advisor) / Agadjanian, Victor (Committee member) / Yabiku, Scott (Committee member) / Arizona State University (Publisher)
Created2015
Description
In this project we are analyzing the diamond-titanium interface as it applies to diamond-based diode devices, including alpha particle, proton, and neutron detectors. This is done through the fabrication of an O-terminated B-doped diamond sample with a 20 Å Ti / 10 Å Pt overlayer which was then annealed and examined via X-ray photoelectron spectroscopy (XPS). It was discovered that after annealing the sample at temperatures ranging from 400 C - 900 C that TiC was not formed at any point during this experiment. Possible reasons for this include a lack of sufficient titanium in order to form TiC and over oxygenating the diamond surface before the metal was deposited.
ContributorsJohnson, Holly (Author) / Zaniewski, Anna (Thesis director) / Nemanich, Robert (Committee member) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05