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Previous studies are limited in scope and a more diverse range of mechanical characterization is required to understand both the advantages and limitations of these materials. One of the major challenges with testing these materials is that they are only able to be made in thicknesses on the order of micrometers so the testing methods are limited to small volume techniques. This work makes use of both microscale testing techniques from the literature as well as novel methodologies. Using these techniques we are able to gain insight into aspects of the material’s mechanical behavior such as the effects of layer orientation, flaw dependent fracture, tension-compression asymmetry, fracture toughness as a function of layer thickness, and shear behavior as a function of layer thickness.
In this study, an innovative composite membrane that integrates water-selective molecular sieve particles into a liquid-barrier chemically resistant polymer film is synthetized. This plan manipulates distinctive aspects of the two materials used to create the membranes: (1) the innate permeation and selectivity of the molecular sieves, and (2) the decay-resistant, versatile, and mechanical strength of the liquid-barrier polymer support matrix.
To synthesize the membrane, Linde Type A (LTA) zeolite particles are anchored to the porous substrate, producing a single layer of zeolite particles capable of transporting water through the membrane. Thereafter, coating the chemically resistant latex polymer filled the space between zeolites. Finally, excess polymer was etched from the surface to expose the zeolites to the feed solution. The completed membranes were tested in reverse osmosis mode with deionized water, sodium chloride, and rhodamine solutions to determine the suitability for water recovery.
The main distinguishing characteristics of the new membrane design compared with current composite membrane include: (1) the use of an impermeable polymer broadens the range of chemical resistant polymers that can be used as the polymer matrix; (2) the use of zeolite particles with specific pore size insures the high rejection of the neutral molecules since water is transported through the zeolite rather than the polymer; (3) the use of latex dispersions, environmentally friendly water based-solutions, as the polymer matrix shares the qualities of low volatile organic compound, low cost, and non- toxicity.
The objective of this study centered on two studies including the development of an automated pultrusion system for the manufacturing of TRC composites and ultimately the assessment of composites created with the pultrusion technique and their viability as a relevant structural construction material. Upon planning, fabrication, and continued use of an automated pultrusion system in Arizona State University’s Structures Lab, an initial, comparative study of polypropylene microfiber composites was conducted to assess fiber reinforced concrete composites, manufactured with Filament Winding Technique, and textile reinforced concrete composites, manufactured with Automated Pultrusion Technique, in tensile and flexural mechanical response at similar reinforcement dosages. A secondary study was then conducted to measure the mechanical behavior of carbon, polypropylene, and alkali-resistant glass TRC composites and explore the response of full scale TRC structural shapes, including angle and channel sections. Finally, a study was conducted on the connection type for large scale TRC composite structural sections in tension and compression testing.
The scope of this project is a combination of material science engineering and mechanical engineering. Overall, the main goal of this project is to develop a lightweight concrete that maintains its original strength profile. Initial research has shown that a plastic-concrete composite could create a more lightweight concrete than that made using the typical gravel aggregate for concrete, while still maintaining the physical strength that concrete is known for. This will be accomplished by varying the amount of plastic in the aggregate. If successful, this project would allow concrete to be used in applications it would typically not be suitable for.<br/>After testing the strength of the concrete specimens with varying fills of plastic aggregate it was determined that the control group experienced an average peak stress of 2089 psi, the 16.67% plastic group experienced an average peak stress of 2649 psi, the 33.3% plastic group experienced an average peak stress of 1852 psi, and the 50% plastic group experienced an average stress of 924.5 psi. The average time to reach the peak stress was found to be 12 minutes and 24 seconds in the control group, 15 minutes and 34 seconds in the 16.7% plastic group, 9 minutes and 45 seconds in the 33.3% plastic group, and 10 minutes and 58 seconds in the 50% plastic group. Taking the average of the normalized weights of the cylindrical samples it was determined that the control group weighed 14.773 oz/in, the 16.7% plastic group weighed 15 oz/in, the 33.3% plastic group weighed 14.573 oz/in, and the 50% plastic group weighed 12.959 oz/in. Based on these results it can be concluded that a small addition of plastic aggregate can be beneficial in creating a lighter, stronger concrete. The results show that a 16.7% fill ratio of plastic to rock aggregate can increase the failure time and the peak strength of a composite concrete. Overall, the experiment was successful in analyzing the effects of recycled plastic aggregate in composite concrete. <br/>Some possible future studies related to this subject material are adding aluminum to the concrete, having better molds, looking for the right consistency in each mixture, mixing for each mold individually, and performing other tests on the samples.