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Description
In nature, it is commonly observed that animals and birds perform movement-based thermoregulation activities to regulate their body temperatures. For example, flapping of elephant ears or plumage fluffing in birds. Taking inspiration from nature and to explore the possibilities of such heat transfer enhancements, augmentation of heat transfer rates induced

In nature, it is commonly observed that animals and birds perform movement-based thermoregulation activities to regulate their body temperatures. For example, flapping of elephant ears or plumage fluffing in birds. Taking inspiration from nature and to explore the possibilities of such heat transfer enhancements, augmentation of heat transfer rates induced by the vibration of solid and well as novel flexible pinned heatsinks were studied in this research project. Enhancement of natural convection has always been very important in improving the performance of the cooling mechanisms. In this research, flexible heatsinks were developed and they were characterized based on natural convection cooling with moderately vibrating conditions. The vibration of heated surfaces such as motor surfaces, condenser surfaces, robotic arms and exoskeletons led to the motivation of the development of heat sinks having flexible fins with an improved heat transfer capacity. The performance of an inflexible, solid copper pin fin heat sink was considered as the baseline, current industry standard for the thermal performance. It is expected to obtain maximum convective heat transfer at the resonance frequency of the flexible pin fins. Current experimental results with fixed input frequency and varying amplitudes indicate that the vibration provides a moderate improvement in convective heat transfer, however, the flexibility of fins had negligible effects.
ContributorsPrabhu, Saurabh (Author) / Rykaczewski, Konrad (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Solar energy has become one of the most popular renewable energy in human’s life because of its abundance and environment friendliness. To achieve high solar energy conversion efficiency, it usually requires surfaces to absorb selectivity within one spectral range of interest and reflect strongly over the rest of the spectrum.

Solar energy has become one of the most popular renewable energy in human’s life because of its abundance and environment friendliness. To achieve high solar energy conversion efficiency, it usually requires surfaces to absorb selectivity within one spectral range of interest and reflect strongly over the rest of the spectrum. An economic method is always desired to fabricate spectrally selective surfaces with improved energy conversion efficiency. Colloidal lithography is a recently emerged way of nanofabrication, which has advantages of low-cost and easy operation.

In this thesis, aluminum metasurface structures are proposed based on colloidal lithography method. High Frequency Structure Simulator is used to numerically study optical properties and design the aluminum metasurfaces with selective absorption. Simulation results show that proposed aluminum metasurface structure on aluminum oxide thin film and aluminum substrate has a major reflectance dip, whose wavelength is tunable within the near-infrared and visible spectrum with metasurface size. As the metasurface is opaque due to aluminum film, it indicates strong wavelength-selective optical absorption, which is due to the magnetic resonance between the top metasurface and bottom Al film within the aluminum oxide layer.

The proposed sample is fabricated based on colloidal lithography method. Monolayer polystyrene particles of 500 nm are successfully prepared and transferred onto silicon substrate. Scanning electron microscope is used to check the surface topography. Aluminum thin film with 20-nm or 50-nm thickness is then deposited on the sample. After monolayer particles are removed, optical properties of samples are measured by micro-scale optical reflectance and transmittance microscope. Measured and simulated reflectance of these samples do not have frequency selective properties and is not sensitive to defects. The next step is to fabricate the Al metasurface on Al_2 O_3 and Al films to experimentally demonstrate the selective absorption predicted from the numerical simulation.
ContributorsGuan, Chuyun (Author) / Wang, Liping (Thesis advisor) / Azeredo, Bruno (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2019
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Description
It is well known that radiative heat transfer rate can exceed that between two blackbodies by several orders of magnitude due to the coupling of evanescent waves. One promising application of near-field thermal radiation is thermophotovoltaic (TPV) devices, which convert thermal energy to electricity. Recently, different types of metamaterials with

It is well known that radiative heat transfer rate can exceed that between two blackbodies by several orders of magnitude due to the coupling of evanescent waves. One promising application of near-field thermal radiation is thermophotovoltaic (TPV) devices, which convert thermal energy to electricity. Recently, different types of metamaterials with excitations of surface plasmon polaritons (SPPs)/surface phonon polaritons (SPhPs), magnetic polaritons (MP), and hyperbolic modes (HM), have been studied to further improve near-field radiative heat flux and conversion efficiency. On the other hand, near-field experimental demonstration between planar surfaces has been limited due to the extreme challenge in the vacuum gap control as well as the parallelism.

The main objective of this work is to experimentally study the near-field radiative transfer and the excitation of resonance modes by designing nanostructured thin films separated by nanometer vacuum gaps. In particular, the near-field radiative heat transfer between two parallel plates of intrinsic silicon wafers coated with a thin film of aluminum nanostructure is investigated. In addition, theoretical studies about the effects of different physical mechanisms such as SPhP/SPP, MPs, and HM on near-field radiative transfer in various nanostructured metamaterials are conducted particularly for near-field TPV applications. Numerical simulations are performed by using multilayer transfer matrix method, rigorous coupled wave analysis, and finite difference time domain techniques incorporated with fluctuational electrodynamics. The understanding gained here will undoubtedly benefit the spectral control of near-field thermal radiation for energy-harvesting applications like thermophotovoltaic energy conversion and radiation-based thermal management.
ContributorsSabbaghi, Payam (Author) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Huang, Huei-Ping (Committee member) / Wang, Robert (Committee member) / Yu, Hongbin (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Droplet-structure interactions play a pivotal role in many engineering applications as droplet-based solutions are evolving. This work explores the physical understanding of these interactions through systematic research leading to improvements in thermal management via dropwise condensation (DWC), and breathable protective wearables against chemical aerosols for better thermoregulation.

In DWC, the heat

Droplet-structure interactions play a pivotal role in many engineering applications as droplet-based solutions are evolving. This work explores the physical understanding of these interactions through systematic research leading to improvements in thermal management via dropwise condensation (DWC), and breathable protective wearables against chemical aerosols for better thermoregulation.

In DWC, the heat transfer rate can be further increased by increasing the nucleation and by optimally ‘refreshing’ the surface via droplet shedding. Softening of surfaces favor the former while having an adverse effect on the latter. This optimization problem is addressed by investigating how mechanical properties of a substrate impact relevant droplet-surface interactions and DWC heat transfer rate. The results obtained by combining droplet induced surface deformation with finite element model show that softening of the substrates below a shear modulus of 500 kPa results in a significant reduction in the condensation heat transfer rate.

On the other hand, interactions between droplet and polymer leading to polymer swelling can be used to develop breathable wearables for use in chemically harsh environments. Chemical aerosols are hazardous and conventional protective measures include impermeable barriers which limit the thermoregulation. To solve this, a solution is proposed consisting of a superabsorbent polymer developed to selectively absorb these chemicals and closing the pores in the fabric. Starting from understanding and modeling the droplet induced swelling in elastomers, the extent and topological characteristic of swelling is shown to depend on the relative comparison of the polymer and aerosol geometries. Then, this modeling is extended to a customized polymer, through a simplified characterization paradigm. In that, a new method is proposed to measure the swelling parameters of the polymer-solvent pair and develop a validated model for swelling. Through this study, it is shown that for this polymer, the concentration-dependent diffusion coefficient can be measured through gravimetry and Poroelastic Relaxation Indentation, simplifying the characterization effort. Finally, this model is used to design composite fabric. Specifically, using model results, the SAP geometry, base fabric design, method of composition is optimized, and the effectiveness of the composite fabric highlighted in moderate-to-high concentrations over short durations.
ContributorsPhadnis, Akshay (Author) / Rykaczewski, Konrad (Thesis advisor) / Wang, Robert (Committee member) / Wang, Liping (Committee member) / Oswald, Jay (Committee member) / Burgin, Timothy (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Thermal Energy Storage (TES) is of great significance for many engineering applications as it allows surplus thermal energy to be stored and reused later, bridging the gap between requirement and energy use. Phase change materials (PCMs) are latent heat-based TES which have the ability to store and release heat through

Thermal Energy Storage (TES) is of great significance for many engineering applications as it allows surplus thermal energy to be stored and reused later, bridging the gap between requirement and energy use. Phase change materials (PCMs) are latent heat-based TES which have the ability to store and release heat through phase transition processes over a relatively narrow temperature range. PCMs have a wide range of operating temperatures and therefore can be used in various applications such as stand-alone heat storage in a renewable energy system, thermal storage in buildings, water heating systems, etc. In this dissertation, various PCMs are incorporated and investigated numerically and experimentally with different applications namely a thermochemical metal hydride (MH) storage system and thermal storage in buildings. In the second chapter, a new design consisting of an MH reactor encircled by a cylindrical sandwich bed packed with PCM is proposed. The role of the PCM is to store the heat released by the MH reactor during the hydrogenation process and reuse it later in the subsequent dehydrogenation process. In such a system, the exothermic and endothermic processes of the MH reactor can be utilized effectively by enhancing the thermal exchange between the MH reactor and the PCM bed. Similarly, in the third chapter, a novel design that integrates the MH reactor with cascaded PCM beds is proposed. In this design, two different types of PCMs with different melting temperatures and enthalpies are arranged in series to improve the heat transfer rate and consequently shorten the time duration of the hydrogenation and dehydrogenation processes. The performance of the new designs (in chapters 2 and 3) is investigated numerically and compared with the conventional designs in the literature. The results indicate that the new designs can significantly enhance the time duration of MH reaction (up to 87%). In the fourth chapter, organic coconut oil PCM (co-oil PCM) is explored experimentally and numerically for the first time as a thermal management tool in building applications. The results show that co-oil PCM can be a promising solution to improve the indoor thermal environment in semi-arid regions.
ContributorsAlqahtani, Talal (Author) / Phelan, Patrick E (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Mellouli, Sofiene (Committee member) / Wang, Robert (Committee member) / Mu, Bin (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Deformable heat exchangers could provide a multitude of previously untapped advantages ranging from adaptable performance via macroscale, dynamic shape change (akin to dilation/constriction seen in blood vessels) to enhanced heat transfer at thermal interfaces through microscale, surface deformations. So far, making deformable, ‘soft heat exchangers’ (SHXs) has been limited by

Deformable heat exchangers could provide a multitude of previously untapped advantages ranging from adaptable performance via macroscale, dynamic shape change (akin to dilation/constriction seen in blood vessels) to enhanced heat transfer at thermal interfaces through microscale, surface deformations. So far, making deformable, ‘soft heat exchangers’ (SHXs) has been limited by the low thermal conductivity of materials with suitable mechanical properties. The recent introduction of liquid-metal embedded elastomers by Bartlett et al1 has addressed this need. Specifically, by remaining soft and stretchable despite the addition of filler, these thermally conductive composites provide an ideal material for the new class of “soft thermal systems”, which is introduced in this work. Understanding such thermal systems will be a key element in enabling technology that require high levels of stretchability, such as thermoregulatory garments, soft electronics, wearable electronics, and high-powered robotics. Shape change inherent to SHX operation has the potential to violate many conventional assumptions used in HX design and thus requires the development of new theoretical approaches to predict performance. To create a basis for understanding these devices, this work highlights two sequential studies. First, the effects of transitioning to a surface deformable, SHX under steady state static conditions in the setting of a liquid cooling device for thermoregulation, electronics and robotics applications was explored. In this study, a thermomechanical model was built and validated to predict the thermal performance and a system wide analysis to optimize such devices was carried out. Second, from a more fundamental perspective, the effects of SHXs undergoing transient shape deformation during operation was explored. A phase shift phenomenon in cooling performance dependent on stretch rate, stretch extent and thermal diffusivity was discovered and explained. With the use of a time scale analysis, the extent of quasi-static assumption viability in modeling such systems was quantified and multiple shape modulation regime limits were defined. Finally, nuance considerations and future work of using liquid metal-silicone composites in SHXs were discussed.
ContributorsKotagama, Praveen (Author) / Rykaczewski, Konrad (Thesis advisor) / Wang, Robert (Committee member) / Phelan, Patrick (Committee member) / Herrmann, Marcus (Committee member) / Green, Matthew (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Solar energy as a limitless source of energy all around the globe has been difficult to harness. This is due to the low direct solar-electric conversion efficiency which has an upper limit set to the Shockley-Queisser limit. Solar thermophotovoltaics (STPV) is a much more efficient solar energy harvesting technology as

Solar energy as a limitless source of energy all around the globe has been difficult to harness. This is due to the low direct solar-electric conversion efficiency which has an upper limit set to the Shockley-Queisser limit. Solar thermophotovoltaics (STPV) is a much more efficient solar energy harvesting technology as it has the potential to overcome the Shockley-Queisser limit, by converting the broad-spectrum solar irradiation into narrowband infrared spectrum radiation matched to the PV cell. Despite the potential to surpass the Shockley-Queisser limit, very few experimental results have reported high system-level efficiency.

The objective of the thesis is to study the STPV conversion performance with selective metafilm absorber and emitter paired with a commercial GaSb cell at different solar concentrations. Absorber and Emitter metafilm thickness was optimized and fabricated. The optical properties of fabricated metafilms showed good agreement with the theoretically determined properties. The experimental setup was completed and validated by measuring the heat transfer rate across the test setup and comparing it with theoretical calculations. A novel method for maintaining the gap between the emitter and PV cell was developed using glass microspheres. Theoretical calculations show that the use of the glass of microspheres introduces negligible conduction loss across the gap compared to the radiation heat transfer, which is confirmed by experimental heat transfer measurement. This research work will help enhance the fundamental understanding and the development of the high-efficiency solar thermophotovoltaic system.
ContributorsNayal, Avinash (Author) / Wang, Liping (Thesis advisor) / Wang, Robert (Committee member) / Milcarek, Ryan (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Desorption processes are an important part of all processes which involve utilization of solid adsorbents such as adsorption cooling, sorption thermal energy storage, and drying and dehumidification processes and are inherently energy-intensive. Here, how those energy requirements can be reduced through the application of ultrasound for three widely used

Desorption processes are an important part of all processes which involve utilization of solid adsorbents such as adsorption cooling, sorption thermal energy storage, and drying and dehumidification processes and are inherently energy-intensive. Here, how those energy requirements can be reduced through the application of ultrasound for three widely used adsorbents namely zeolite 13X, activated alumina and silica gel is investigated. To determine and justify the effectiveness of incorporating ultrasound from an energy-savings point of view, an approach of constant overall input power of 20 and 25 W was adopted. To measure the extent of the effectiveness of using ultrasound, the ultrasonic-power-to-total power ratios of 0.2, 0.25, 0.4 and 0.5 were investigated and the results compared with those of no-ultrasound (heat only) at the same total power. Duplicate experiments were performed at three nominal frequencies of 28, 40 and 80 kHz to observe the influence of frequency on regeneration dynamics. Regarding moisture removal, application of ultrasound results in higher desorption rate compared to a non-ultrasound process. A nonlinear inverse proportionality was observed between the effectiveness of ultrasound and the frequency at which it is applied. Based on the variation of desorption dynamics with ultrasonic power and frequency, three mechanisms of reduced adsorbate adsorption potential, increased adsorbate surface energy and enhanced mass diffusion are proposed. Two analytical models that describe the desorption process were developed based on the experimental data from which novel efficiency metrics were proposed, which can be employed to justify incorporating ultrasound in regeneration and drying processes.
ContributorsDaghooghi Mobarakeh, Hooman (Author) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Wang, Robert (Committee member) / Calhoun, Ronald (Committee member) / Deng, Shuguang (Committee member) / Arizona State University (Publisher)
Created2021
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Description
Vanadium-dioxide-based devices show great switchability in their optical properties due to its dramatic thermochromic phase transition from insulator to metal, but generally have concerns due to its relatively high transition temperature at 68 °C. Doping the vanadium dioxide with tungsten has been shown to reduce its transition temperature at the

Vanadium-dioxide-based devices show great switchability in their optical properties due to its dramatic thermochromic phase transition from insulator to metal, but generally have concerns due to its relatively high transition temperature at 68 °C. Doping the vanadium dioxide with tungsten has been shown to reduce its transition temperature at the cost lower optical property differences between its insulating and metallic phases. A recipe is developed through parametric experimentation to fabricate tungsten-doped vanadium dioxide consisting of a novel dual target co-sputtering deposition, a furnace oxidation process, and a post-oxidation annealing process. The transmittance spectra of the resulting films are measured via Fourier-transform infrared spectroscopy at different temperatures to confirm the lowered transition temperature and analyze their thermal-optical hysteresis behavior through the transition temperature range. Afterwards, the optical properties of undoped sputtered vanadium films are modeled and effective medium theory is used to explain the effect of tungsten dopants on the observed transmittance decrease of doped vanadium dioxide. The optical modeling is used to predict the performance of tungsten-doped vanadium dioxide devices, in particular a Fabry-Perot infrared emitter and a nanophotonic infrared transmission filter. Both devices show great promise in their optical properties despite a slight performance decrease from the tungsten doping. These results serve to illustrate the excellent performance of the co-sputtered tungsten-doped vanadium dioxide films.
ContributorsChao, Jeremy (Author) / Wang, Liping (Thesis advisor) / Wang, Robert (Committee member) / Tongay, Sefaattin (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Dehumidifiers are ubiquitous and essential household appliances in many parts of the world. They are used extensively in tropical and sub-tropical environments to lower humidity in living spaces, where high ambient humidity can lead to numerous negative health effects from mild physical discomfort to more serious conditions such as mold

Dehumidifiers are ubiquitous and essential household appliances in many parts of the world. They are used extensively in tropical and sub-tropical environments to lower humidity in living spaces, where high ambient humidity can lead to numerous negative health effects from mild physical discomfort to more serious conditions such as mold build up in structures and dangerous illnesses in humans. Most common dehumidifiers are based on conventional mechanical refrigeration cycles, where the effects of condensation heat transfer play a critical role in their effectiveness. In these devices, humid ambient air flows over a cold evaporator, which lowers the temperature of the humid ambient air below its dew point temperature and therefore decreases its water content by causing liquid water condensation on the evaporator surface. The rate at which humidity can be extracted from the ambient air is governed in part by how quickly the evaporator can shed the condensed droplets. Recent advances in soft, stretchable, thermally enhanced (through the addition of liquid metals) silicone tubing offer the potential to use these stretchable tubes in place of conventional copper pipe for applications such as dehumidification. Copper is a common material choice for dehumidifier evaporator tubing owing to its ubiquity and its high thermal conductivity, but it has several thermal downsides. Specifically, copper tubes remain static and typically rely on gravity alone to remove water droplets when they reach a sufficient mass. Additionally, copper’s naturally hydrophilic surface promotes film-wise condensation, which is substantially less effective than dropwise condensation. In contrast to copper, thermally enhanced soft stretchable tubes have naturally hydrophobic surfaces that promote the more effective dropwise condensation mode and a soft surface that offers higher nucleation density. However, soft surfaces also increase droplet pinning, which inhibits their departure. This work experimentally explores the effects of periodic axial stretching and retraction of soft tubing internally cooled with water on droplet condensation dynamics on its exterior surface. Results are discussed in terms of overall system thermal performance and real-time condensation imaging. An overall null result is discovered, and recommendations for future experiments are made.
Contributorsnordstog, thomas (Author) / Rykaczewski, Konrad (Thesis advisor) / Wang, Robert (Committee member) / Devasenathipathy, Shankar (Committee member) / Arizona State University (Publisher)
Created2022