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Description
The energy crisis in the past decades has greatly boosted the search for alternatives to traditional fossil foils, and solar energy stands out as an important candidate due to its cleanness and abundance. However, the relatively low conversion efficiency and energy density strongly hinder the utilization of solar energy in

The energy crisis in the past decades has greatly boosted the search for alternatives to traditional fossil foils, and solar energy stands out as an important candidate due to its cleanness and abundance. However, the relatively low conversion efficiency and energy density strongly hinder the utilization of solar energy in wider applications. This thesis focuses on employing metamaterials and metafilms to enhance the conversion efficiency of solar thermal, solar thermophotovoltaic (STPV) and photovoltaic systems.

A selective metamaterial solar absorber is designed in this thesis to maximize the absorbed solar energy and minimize heat dissipation through thermal radiation. The theoretically designed metamaterial solar absorber exhibits absorptance higher than 95% in the solar spectrum but shows emittance less than 4% in the IR regime. This metamaterial solar absorber is further experimentally fabricated and optically characterized. Moreover, a metafilm selective absorber with stability up to 600oC is introduced, which exhibits solar absorptance higher than 90% and IR emittance less than 10%.

Solar thermophotovoltaic energy conversion enhanced by metamaterial absorbers and emitters is theoretically investigated in this thesis. The STPV system employing selective metamaterial absorber and emitter is investigated in this work, showing its conversion efficiency between 8% and 10% with concentration factor varying between 20 and 200. This conversion efficiency is remarkably enhanced compared with the conversion efficiency for STPV system employing black surfaces (<2.5%).

Moreover, plasmonic light trapping in ultra-thin solar cells employing concave grating nanostructures is discussed in this thesis. The plasmonic light trapping inside an ultrathin GaAs layer in the film-coupled metamaterial structure is numerically demonstrated. By exciting plasmonic resonances inside this structure, the short-circuit current density for the film-coupled metamaterial solar cell is three times the short-circuit current for a free-standing GaAs layer.

The dissertation is concluded by discussing about the future work on selective solar thermal absorbers, STPV/TPV systems and light trapping structures. Possibilities to design and fabricate solar thermal absorber with better thermal stability will be discussed, the experimental work of TPV system will be conducted, and the light trapping in organic and perovskite solar cells will be looked into.
ContributorsWang, Hao (Author) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Dai, Lenore (Committee member) / Rykaczewski, Konrad (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Current organic light emitting diodes (OLEDs) suffer from the low light extraction efficiency. In this thesis, novel OLED structures including photonic crystal, Fabry-Perot resonance cavity and hyperbolic metamaterials were numerically simulated and theoretically investigated. Finite-difference time-domain (FDTD) method was employed to numerically simulate the light extraction efficiency of various 3D

Current organic light emitting diodes (OLEDs) suffer from the low light extraction efficiency. In this thesis, novel OLED structures including photonic crystal, Fabry-Perot resonance cavity and hyperbolic metamaterials were numerically simulated and theoretically investigated. Finite-difference time-domain (FDTD) method was employed to numerically simulate the light extraction efficiency of various 3D OLED structures. With photonic crystal structures, a maximum of 30% extraction efficiency is achieved. A higher external quantum efficiency of 35% is derived after applying Fabry-Perot resonance cavity into OLEDs. Furthermore, different factors such as material properties, layer thicknesses and dipole polarizations and locations have been studied. Moreover, an upper limit for the light extraction efficiency of 80% is reached theoretically with perfect reflector and single dipole polarization and location. To elucidate the physical mechanism, transfer matrix method is introduced to calculate the spectral-hemispherical reflectance of the multilayer OLED structures. In addition, an attempt of using hyperbolic metamaterial in OLED has been made and resulted in 27% external quantum efficiency, due to the similar mechanism of wave interference as Fabry-Perot structure. The simulation and optimization methods and findings would facilitate the design of next generation, high-efficiency OLED devices.
ContributorsSu, Hang (Author) / Wang, Liping (Thesis advisor) / Li, Jian (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2016
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Description
An integrated experimental and numerical investigation for laser-generated optoacoustic wave propagation in structural materials is performed. First, a multi-physics simulation model is proposed to simulate the pulsed laser as a point heat source which hits the surface of an aluminum sheet. The pulsed laser source can generate a localized heating

An integrated experimental and numerical investigation for laser-generated optoacoustic wave propagation in structural materials is performed. First, a multi-physics simulation model is proposed to simulate the pulsed laser as a point heat source which hits the surface of an aluminum sheet. The pulsed laser source can generate a localized heating on the surface of the plate and induce an in-plane stress wave. ANSYS – a finite element analysis software – is used to build the 3D model and a coupled thermal-mechanical simulation is performed in which the heat flux is determined by an empirical laser-heat conversion relationship. The displacement and stress field-histories are obtained to get the time of arrival and wave propagation speed of the stress wave. The effect of an added point mass is investigated in detail to observe the local material perturbation and remote wave signals. Following this, the experimental investigation of optoacoustic wave is also performed. A new experimental setup and control is developed and assembled in-house. Various laser firing parameters are investigated experimentally and the optimal combination is used for the experimental testing. Matrix design for different testing conditions is also proposed to include the effect of wave path, sampling procedure, and local point mass on the optoacoustic wave propagation. The developed numerical simulation results are validated with experimental observations. It is shown that the proposed experimental setup can offer a potential fast scanning method for damage detection (local property change) for plate-like structural component.
ContributorsLiu, Chen (Author) / Liu, Yongming (Thesis advisor) / Wang, Liping (Committee member) / Jiao, Yang (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Origami and kirigami, the technique of generating three-dimensional (3D) structures from two-dimensional (2D) flat sheets, are now more and more involved in scientific and engineering fields. Therefore, the development of tools for their theoretical analysis becomes more and more important. Since much effort was paid on calculations based on pure

Origami and kirigami, the technique of generating three-dimensional (3D) structures from two-dimensional (2D) flat sheets, are now more and more involved in scientific and engineering fields. Therefore, the development of tools for their theoretical analysis becomes more and more important. Since much effort was paid on calculations based on pure mathematical consideration and only limited effort has been paid to include mechanical properties, the goal of my research is developing a method to analyze the mechanical behavior of origami and kirigami based structures. Mechanical characteristics, including nonlocal effect and fracture of the structures, as well as elasticity and plasticity of materials are studied. For calculation of relative simple structures and building of structures’ constitutive relations, analytical approaches were used. For more complex structures, finite element analysis (FEA), which is commonly applied as a numerical method for the analysis of solid structures, was utilized. The general study approach is not necessarily related to characteristic size of model. I believe the scale-independent method described here will pave a new way to understand the mechanical response of a variety of origami and kirigami based structures under given mechanical loading.
ContributorsLv, Cheng (Author) / Jiang, Hanqing (Thesis advisor) / Yu, Hongbin (Committee member) / Wang, Liping (Committee member) / Mignolet, Marc (Committee member) / Hildreth, Owen (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Solar photovoltaic (PV) industry is tipped to be one of the front-runners in the renewable industry. Typically, PV module manufacturers provide a linear or step warranty of 80% of original power over 25 years. This power loss during the field exposure is primarily attributed to the development of performance affecting

Solar photovoltaic (PV) industry is tipped to be one of the front-runners in the renewable industry. Typically, PV module manufacturers provide a linear or step warranty of 80% of original power over 25 years. This power loss during the field exposure is primarily attributed to the development of performance affecting defects in the PV modules. As many as 86 different defects can occur in a PV module. One of the major defects that can cause significant power loss is the interconnect metallization system (IMS) degradation which is the focus of this thesis. The IMS is composed of cell-interconnect (cell-ribbon interconnect) and string-interconnect (ribbon-ribbon interconnect). The cell interconnect is in turn composed of silver metallization (fingers and busbars) and solder bonds between silver busbar and copper ribbon. Weak solder bonding between copper ribbon and busbar of a cell results in increase of series resistance that in turn affects the fill factor causing a power drop. In this thesis work, the results obtained from various non-destructive and destructive experiments performed on modules exposed in three different climates (Arizona - Hot and Dry, Mexico - Warm and Humid, and California - Temperate) are presented. These experiments include light I-V measurements, dark I-V measurements, infrared imaging, extraction of test samples from the modules, peel strength measurements and four-point resistance measurements. The extraction of test samples was performed using a mechanical method and a chemical method. The merits and demerits of these two methods are presented. A drop of 10.33% in fill factor was observed for a 0.05Ω increase in the series resistance of the modules investigated in this work. Different combinations in a cell that can cause series resistance increase were considered and their effect on fill factor were observed using four-point probe experiments. Peel test experiments were conducted to correlate the effect of series resistance on the ribbon peel strength. Finally, climate specific thermal modelling was performed for 4 different sites over 20 years in order to calculate the accumulated thermal fatigue and also to evaluate its correlation, if any, with the increase of series resistance.
ContributorsTummala, Abhishiktha (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
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Description
In recent years, solar photovoltaic (PV) industry has seen lots of improvements in technology and of growth in market with crystalline silicon PV modules being the most widely used technology. Plant inspections are gaining much importance to identify and quantitatively determine the impacts of various visual defects on performance. There

In recent years, solar photovoltaic (PV) industry has seen lots of improvements in technology and of growth in market with crystalline silicon PV modules being the most widely used technology. Plant inspections are gaining much importance to identify and quantitatively determine the impacts of various visual defects on performance. There are about 86 different types of defects found in the PV modules installed in various climates and most of them can be visually observed. However, a quantitative determination of impact or risk of each of identified defect on performance is challenging. Thus, it is utmost important to quantify the risk for each of the visual defects without any human subjectivity. The best way to quantify the risk of each defect is to perform current-voltage measurements of the defective modules installed in the plant but it requires disruption of plant operation, expensive measuring equipment and intensive human resources. One of the most riskiest and dominant visual defects is encapsulant browning which affects the PV module performance in the form of current degradation. The present study deals with developing an automated image processing tool which can address the issues of human subjectivity on browning level impacting performance. The image processing tool developed in this work can be directly used to quantify the impact of browning on performance without intrusively disconnecting the modules from the plant. In this work, the quantified browning level impact on performance has also been experimentally validated through a correlation study using short-circuit current and reflectance/transmittance measurements of browned PV modules retrieved from aged plants/systems installed in diverse climatic conditions. The primary goal of the image processing tool developed in this work is to determine the performance impact of encapsulant browning without interrupting the plant operation for I-V measurements. The use of image processing tool provides a single numerical value, called browning index (BI), which can accurately quantify browning levels on modules and also correlate with the performance and reflectance/transmittance parameters of the modules.
ContributorsGudla, Sushanth (Author) / Govindasamy, Tamizhmani (Thesis advisor) / Patrick, Phelan E (Thesis advisor) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Soiling is one of the major environmental factors causing the negative performance of photovoltaic (PV) modules. Dust particles, air pollution particles, pollen, bird droppings and other industrial airborne particles are some natural sources that cause soiling. The thickness of soiling layer has a direct impact on the performance of PV

Soiling is one of the major environmental factors causing the negative performance of photovoltaic (PV) modules. Dust particles, air pollution particles, pollen, bird droppings and other industrial airborne particles are some natural sources that cause soiling. The thickness of soiling layer has a direct impact on the performance of PV modules. This phenomenon occurs over a period of time with many unpredictable environmental variables indicated above. This situation makes it difficult to calculate or predict the soiling effect on performance. The dust particles vary from one location to the other in terms of particle size, color and chemical composition. These properties influence the extent of performance (current) loss, spectral loss and adhesion of soil particles on the surface of the PV modules. To address this uncontrolled environmental issues, research institutes around the world have started designing indoor artificial soiling stations to deposit soil layers in various controlled environments using reference soil samples and/or soil samples collected from the surface of PV modules installed in the locations of interest. This thesis is part of a twin thesis. The first thesis (this thesis) authored by Shanmukha Mantha is related to the development of soiling stations and the second thesis authored by Darshan Choudhary is associated with the characterization of the soiled samples (glass coupons, one-cell PV coupons and multi-cell PV coupons). This thesis is associated with the development of three types of indoor artificial soiling deposition techniques replicating the outside environmental conditions to achieve required soil density, uniformity and other required properties. The three types of techniques are: gravity deposition method, dew deposition method, and humid deposition method. All the three techniques were applied on glass coupons, single-cell PV laminates containing monocrystalline silicon cells and multi-cell PV laminates containing polycrystalline silicon cells. The density and uniformity for each technique on all targets are determined. In this investigation, both reference soil sample (Arizona road dust, ISO 12103-1) and the soil samples collected from the surface of installed PV modules were used. All the three techniques are compared with each other to determine the best method for uniform deposition at varying thickness levels. The advantages, limitations and improvements made in each technique are discussed.
ContributorsMantha, Shanmukha (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Material extrusion based rapid prototyping systems have been used to produceprototypes for several years. They have been quite important in the additive manufacturing field, and have gained popularity in research, development and manufacturing in a wide field of applications. There has been a lot of interest in using these technologies

Material extrusion based rapid prototyping systems have been used to produceprototypes for several years. They have been quite important in the additive manufacturing field, and have gained popularity in research, development and manufacturing in a wide field of applications. There has been a lot of interest in using these technologies to produce end use parts, and Fused Deposition Modeling (FDM) has gained traction in leading the transition of rapid prototyping technologies to rapid manufacturing. But parts built with the FDM process exhibit property anisotropy. Many studies have been conducted into process optimization, material properties and even post processing of parts, but were unable to solve the strength anisotropy issue. To address this, an optical heating system has been proposed to achieve localized heating of the pre- deposition surface prior to material deposition over the heated region. This occurs in situ within the build process, and aims to increase the interface temperature to above glass transition (Tg), to trigger an increase in polymer chain diffusion, and in extension, increase the strength of the part. An increase in flexural strength by 95% at the layer interface has been observed when the optical heating method was implemented, thereby improving property isotropy of the FDM part. This approach can be designed to perform real time control of inter-filament and interlayer temperatures across the build volume of a part, and can be tuned to achieve required mechanical properties.
ContributorsKurapatti Ravi, Abinesh (Author) / Hao Hsu, Keng (Thesis advisor) / Hildreth, Owen (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Photovoltaic modules degrade in the field. This thesis aims to answer two questions: 1. Do photovoltaic modules degrade linearly or not? 2. Do soiled modules operate at lower temperatures than clean modules? Answers to these questions are provided in part 1 and part 2 of this thesis respectively.

Part 1:

Photovoltaic modules degrade in the field. This thesis aims to answer two questions: 1. Do photovoltaic modules degrade linearly or not? 2. Do soiled modules operate at lower temperatures than clean modules? Answers to these questions are provided in part 1 and part 2 of this thesis respectively.

Part 1: Linearity determination in degradation: The electricity output from PV power plants degrades every year. Generally, a system’s life is considered to last for 20-25 years and rate of degradation is commonly assumed as 1% per year. PV degradation can be found out using Performance Ratio (PR), Performance Index (PI) and raw kWh output. The rate of degradation is considered linear for simplicity of calculations. In this thesis, statistical methods are used to check whether systems in Arizona are degrading linearly or not. Time series modeling such as Winters’ method and ARIMA are used to model the data. Winters’ method and Seasonal ARIMA consider the seasonality component and perform well for small data sets of about 10 years. Rate of degradation is found out as linear for all the evaluated systems.

Part 2: Temperature analysis of clean and soiled modules: Soiling and temperature are important parameters in performance of PV modules. In this paper, an analysis is carried out on a soiling station located in Mesa, Arizona. The soiling station consists of 10 different c-Si coupons with tilt angles varying from 0° to 45° with the difference of 5°. These coupons are cut in half, one is cleaned periodically and the other is remained soiled naturally. The analysis involves data worth for 19 months. 6 dry spells in all four seasons within 19 months were analyzed. The temperature difference between a clean module and a soiled module (ΔT) is compared with the soiling loss factor (SLF). The analysis concludes stating in which season a soiled module is hotter or cooler than a clean module.
ContributorsPatankar, Adit (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2017
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Description
Durable, cost-effective, and environmentally friendly anti-icing methods are desired to reduce the icing hazard in many different industrial areas including transportation systems, power plants, power transmission, as well as offshore oil and gas production. In contrast to traditional passive anti-icing surfaces, this thesis work introduces an anti-icing coating that responds

Durable, cost-effective, and environmentally friendly anti-icing methods are desired to reduce the icing hazard in many different industrial areas including transportation systems, power plants, power transmission, as well as offshore oil and gas production. In contrast to traditional passive anti-icing surfaces, this thesis work introduces an anti-icing coating that responds to different icing conditions by releasing an antifreeze liquid. It consists of an outer porous superhydrophobic epidermis and a wick-like underlying dermis that is infused with the antifreeze liquid. This bi-layer coating prevents accumulation of frost, freezing fog, and freezing rain, while conventional anti-icing surfaces typically work only in one of these conditions. The bi-layer coating also delays condensation on the exterior surface at least ten times longer than identical system without antifreeze.

It is demonstrated that the significant delay in condensation onset is due to the integral humidity sink effect posed by the hygroscopic antifreeze liquid infused in the porous structure. This effect significantly alters the water vapor concentration field at the coating surface, which delays nucleation of drops and ice. It was demonstrated that with a proper design of the environmental chamber the size of the region of inhibited condensation and condensation frosting around an isolated pore, as well as periodically spaced pores, filled by propylene glycol can be quantitatively predicted from quasi-steady state water vapor concentration field. Theoretical analysis and experiments revealed that the inhibition of nucleation is governed by only two non-dimensional geometrical parameters: the pore size relative to the unit cell size and the ratio of the unit cell size to the thickness of the boundary layer. It is demonstrated that by switching the size of the pores from millimeters to nanometers, a dramatic depression of the nucleation onset temperature, as well as significantly greater delay in nucleation onset can be achieved.
ContributorsSun, Xiaoda (Author) / Rykaczewski, Konrad (Thesis advisor) / Lin, Jerry (Committee member) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Herrmann, Marcus (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2017