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Future robotic and human missions to the Moon and Mars will need in situ capabilities to characterize the mineralogy of rocks and soils within a microtextural context. Such spatially-correlated information is considered crucial for correct petrogenetic interpretations and will be key observations for assessing the potential for past habitability on

Future robotic and human missions to the Moon and Mars will need in situ capabilities to characterize the mineralogy of rocks and soils within a microtextural context. Such spatially-correlated information is considered crucial for correct petrogenetic interpretations and will be key observations for assessing the potential for past habitability on Mars. These data will also enable the selection of the highest value samples for further analysis and potential caching for return to Earth. The Multispectral Microscopic Imager (MMI), similar to a geologist's hand lens, advances the capabilities of current microimagers by providing multispectral, microscale reflectance images of geological samples, where each image pixel is comprised of a 21-band spectrum ranging from 463 to 1735 nm. To better understand the capabilities of the MMI in future surface missions to the Moon and Mars, geological samples comprising a range of Mars-relevant analog environments as well as 18 lunar rocks and four soils, from the Apollo collection were analyzed with the MMI. Results indicate that the MMI images resolve the fine-scale microtextural features of samples, and provide important information to help constrain mineral composition. Spectral end-member mapping revealed the distribution of Fe-bearing minerals (silicates and oxides), along with the presence of hydrated minerals. In the case of the lunar samples, the MMI observations also revealed the presence of opaques, glasses, and in some cases, the effects of space weathering in samples. MMI-based petrogenetic interpretations compare favorably with laboratory observations (including VNIR spectroscopy, XRD, and thin section petrography) and previously published analyses in the literature (for the lunar samples). The MMI was also deployed as part of the 2010 ILSO-ISRU field test on the slopes of Mauna Kea, Hawaii and inside the GeoLab as part of the 2011 Desert RATS field test at the Black Point Lava Flow in northern Arizona to better assess the performance of the MMI under realistic field conditions (including daylight illumination) and mission constraints to support human exploration. The MMI successfully imaged rocks and soils in outcrops and samples under field conditions and mission operation scenarios, revealing the value of the MMI to support future rover and astronaut exploration of planetary surfaces.
ContributorsNúñez Sánchez, Jorge Iván (Author) / Farmer, Jack D. (Thesis advisor) / Christensen, Philip R. (Committee member) / Garcia-Pichel, Ferran (Committee member) / Robinson, Mark S. (Committee member) / Sellar, R. Glenn (Committee member) / Williams, Lynda B. (Committee member) / Arizona State University (Publisher)
Created2012
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Description
A wide range of types of activity in mid-latitude Martian gullies has been observed over the last decade (Malin et al., 2006; Harrison et al., 2009, 2015; Diniega et al., 2010; Dundas et al., 2010, 2012, 2015, 2017) with some activity constrained temporally to occur in the coldest times of

A wide range of types of activity in mid-latitude Martian gullies has been observed over the last decade (Malin et al., 2006; Harrison et al., 2009, 2015; Diniega et al., 2010; Dundas et al., 2010, 2012, 2015, 2017) with some activity constrained temporally to occur in the coldest times of year (winter and spring; Harrison et al., 2009; Diniega et al., 2010; Dundas et al., 2010, 2012, 2015, 2017), suggesting that surficial frosts that form seasonally and diurnally might play a key role in this present-day activity. Frost formation is highly dependent on two key factors: (1) surface temperature and (2) the atmospheric partial pressure of the condensable gas (Kieffer, 1968). The Martian atmosphere is primarily composed of CO2and CO2 frost formation is not diffusion-limited (unlike H2O). Hence, for temperatures less than the local frost point of CO2, (~ 148 K at a surface pressure of 610 Pa) frost is always present (Piqueux et al., 2016). Typically, these frosts are dominated volumetrically by CO2, although small amounts of H2O frosts are also present, and typically precede CO2 frost deposition (due to water’s higher condensation temperature (Schorghofer and Edgett, 2006)). Here we use the Thermal Emission Imaging System (THEMIS) and the Thermal Emission Spectrometer (TES) onboard Mars Odyssey and Mars Global Surveyor, respectively, to explore the global spatial and temporal variation of temperatures conducive to CO2 and H2O frost formation on Mars, and assess their distribution with gully landforms. CO2 frost temperatures are observed at all latitudes and are strongly correlated with dusty, low thermal inertia regions near the equator. Modeling results suggest that frost formation is restricted to the surface due to near-surface radiative effects. About 49 % of all gullies lie within THEMIS frost framelets. In terms of active gullies, 54 % of active gullies lie within THEMIS framelets, with 14.3% in the north and 54% in the south.
Relatively small amounts of H2O frost (~ 10–100 μm) are also likely to form diurnally and seasonally. The global H2O frost point distribution follows water vapor column abundance closely, with a weak correlation with local surface pressure. There is a strong hemispherical dependence on the frost point temperature—with the northern hemisphere having a higher frost point (in general) than the southern hemisphere—likely due to elevation differences. Unlike the distribution of CO2 frost temperatures, there is little to no correlation with surface thermophysical properties (thermal inertia, albedo, etc.). Modeling suggests H2O frosts can briefly attain melting point temperatures for a few hours if present under thin layers of dust, and can perhaps play a role in present-day equatorial mass-wasting events (eg. McEwen et al., 2018).
Based on seasonal constraints on gully activity timing, preliminary field studies, frost presence from visible imagery, spectral data and thermal data (this work), it is likely that most present-day activity can be explained by frosts (primarily CO2, and possibly H2O). We predict that the conditions necessary for significant present-day activity include formation of sufficient amounts of frost (> ~20 cm/year) within loose, unconsolidated sediments (I < ~ 350) on available slopes. However, whether or not present-day gully activity is representative of gully formation as a whole is still open to debate, and the details on CO2 frost-induced gully formation mechanisms remain unresolved.
ContributorsKhuller, Aditya Rai (Author) / Christensen, Philip (Thesis director) / Harrison, Tanya (Committee member) / Diniega, Serina (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
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Description
This research focuses on a geologic controversy regarding the stratigraphic position of the Hermit Formation outside of the Grand Canyon, specifically in Sedona, Arizona. The goal of this research is to provide additional constraints on this dispute by pinpointing the transition to the Hermit Formation in Sedona, if possible. To

This research focuses on a geologic controversy regarding the stratigraphic position of the Hermit Formation outside of the Grand Canyon, specifically in Sedona, Arizona. The goal of this research is to provide additional constraints on this dispute by pinpointing the transition to the Hermit Formation in Sedona, if possible. To accomplish this, we use field observations and detrital zircon dating techniques to compare data we collected in Sedona with data previously published for the Grand Canyon. Fossil evidence in Sedona and near Payson, Arizona is also used to aid correlation. Starting from the Grand Canyon, the Hermit Formation pinches out to the southeast and, hypothetically obstructed by the Sedona Arch, does not reach Sedona. Detrital zircon data show similar age distributions between the Grand Canyon and Sedona rock units, but the results are not strong enough to confidently correlate units between these two localities. The data collected for this study suggest that if the Hermit Formation is present in Sedona, it is limited to higher up in the section as opposed to occupying the middle portion of the section as is currently interpreted. To determine with greater accuracy whether the Hermit Formation does exist higher in the section of Sedona, more detrital zircons should be collected and analyzed from the part of the section that yielded a relative increase in young zircons aged 200-600 Ma.
ContributorsFinger, Mikayla (Co-author) / Spitzer, Patrick (Co-author) / Reynolds, Stephen (Thesis director) / Semken, Steven (Committee member) / DeVecchio, Duane (Committee member) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
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Description
For the geoscience community to continue to grow, students need to be attracted to the field. Here we examine the Incorporated Research Institutions for Seismology (IRIS) Research Experience for Undergraduates (REU) program to understand how the participants' experiences' affects their interest in geoscience and educational and career goals. Eleven interns

For the geoscience community to continue to grow, students need to be attracted to the field. Here we examine the Incorporated Research Institutions for Seismology (IRIS) Research Experience for Undergraduates (REU) program to understand how the participants' experiences' affects their interest in geoscience and educational and career goals. Eleven interns over two years (2013-2014) were interviewed prior to the start of their internship, after their internship, and after presenting their research at the American Geophysical Union annual meeting. This internship program is of particular interest because many of the interns come into the REU with non-geoscience or geophysics backgrounds (e.g., physics, mathematics, chemistry, engineering). Both a priori and emergent codes are used to convert interview transcripts into quantitative data, which is analyzed alongside demographic information to understand how the REU influences their decisions. Increases in self-efficacy and exposure to multiple facets of geoscience research are expressed as primary factors that help shape their future educational and career goals. Other factors such as networking opportunities and connections during the REU also can play a role in their decision. Overall, REU participants who identified as geosciences majors solidified their decisions to pursue a career in geosciences, while participants who identified as non-geosciences majors were inclined to change majors, pursue geosciences in graduate school, or explore other job opportunities in the geosciences.
ContributorsGossard, Trey Marshall (Author) / Semken, Steven (Thesis director) / Garnero, Edward (Committee member) / Reynolds, Stephen (Committee member) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
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Description
Blue Mound State Park, located in the state of Wisconsin (USA), is host to a topographic anomaly known as Blue Mound. This mound is the western of the two mounds that make up the park, and it marks the highest elevation in southern Wisconsin. Unlike its eastern sibling, Blue Mound

Blue Mound State Park, located in the state of Wisconsin (USA), is host to a topographic anomaly known as Blue Mound. This mound is the western of the two mounds that make up the park, and it marks the highest elevation in southern Wisconsin. Unlike its eastern sibling, Blue Mound possesses an unusual chert cap that may have protected it from erosion, thus preserving its stratigraphic integrity. Although Blue Mound's unique chert armor was noted in 1927 by the Wisconsin Geological and Natural History Survey, no published work has satisfactorily explained its origin. As little was known about the formation of cherts until the mid-to-late 1900s, the Blue Mound cap was classified merely as a Silurian dolostone into which chert had somehow become integrated (Steidtmann). However, the published observations of the Blue Mound chert do not necessarily match with the classification granted by the Wisconsin Geological and Natural History Survey, nor were any convincing interpretations offered regarding the presence of the chert. Since 1927, significant progress in the field of sedimentology has been achieved. There now exists knowledge that may fill the gaps between observation and interpretation in the Blue Mound survey. The observations in the 1927 bulletin correspond with modern notions of a paleokarst chert breccia, which forms a chert rubble or residuum. A chert breccia is formed when existing clasts, or pieces, of chert become cemented together by further chert deposition (Kolodny, Chaussidon and Katz). This can form large boulders of chert rubble that resist erosion. Accumulation of chert rubble has been documented to form along old weathering surfaces as an insoluble residue in environments similar to Blue Mound (Kolodny, Chaussidon and Katz). The purpose of this investigation was to verify the observations within the 1927 survey of the Blue Mound chert, and determine through field observations and sample study if the Blue Mound chert fits the model of a paleokarst chert breccia.
ContributorsGalarowicz, Calley (Author) / Knauth, Paul (Thesis director) / Semken, Steven (Committee member) / Martin, Thomas (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2013-05
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Description

Papago Park in Tempe, Arizona (USA) is host to several buttes composed of landslide breccias. The focus of this thesis is a butte called “Contact Hill,” which is composed of metarhyolitic debris flows, granitic debris flows, and Barnes Butte Breccia. The Barnes Butte Breccia can be broken down into several

Papago Park in Tempe, Arizona (USA) is host to several buttes composed of landslide breccias. The focus of this thesis is a butte called “Contact Hill,” which is composed of metarhyolitic debris flows, granitic debris flows, and Barnes Butte Breccia. The Barnes Butte Breccia can be broken down into several different compositional categories that can be dated based on their relative ages. The depositional timeline of these rocks is explored through their mineral and physical properties. The rhyolitic debris flow is massively bedded and dips at 26° to the southeast. The granitic debris flow is not bedded and exhibits a mixture of granite clasts of different grain sizes. In thin section analysis, five mineral types were identified: opaque inclusions, white quartz, anhedral and subhedral biotite, yellow stained K-feldspar, and gray plagioclase. It is hypothesized that regional stretching and compression of the crust, accompanied with magmatism, helped bring the metarhyolite and granite to the surface. Domino-like fault blocks caused large brecciation, and collapse of a nearby quartzite and granite mountain helped create the Barnes Butte Breccia: a combination of quartzite, metarhyolite, and granite clasts. Evidence of Papago Park’s ancient terrestrial history is seen in metarhyolite clasts containing sand grains. These geologic events, in addition to erosion, are responsible for Papago Park’s unique appearance today.

ContributorsScheller, Jessica Rose (Author) / Reynolds, Stephen (Thesis director) / Johnson, Julia (Committee member) / School of Earth and Space Exploration (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Description
Hydraulic fracturing, or fracking, has become a common practice in United States oil fields for enhancing their productivity. Among the concerns regarding fracking, however, is the possibility that it could trigger shallow earthquakes. The brine that results from fracking is injected into the subsurface for disposal. This brine causes a

Hydraulic fracturing, or fracking, has become a common practice in United States oil fields for enhancing their productivity. Among the concerns regarding fracking, however, is the possibility that it could trigger shallow earthquakes. The brine that results from fracking is injected into the subsurface for disposal. This brine causes a pore pressure gradient that is commonly believed to trigger failure along critically stressed subsurface faults. In Timpson, a small city in eastern Texas, earthquakes have become much more common since two injection wells were installed in 2007. 16 events of M_W > 2 have been detected since 2008 and are believed to be associated with failure along a subsurface fault. Applying interferometric synthetic aperture radar, we analyzed 3 sets of SAR images from the Advanced Land Observing Satellite (ALOS) from May 2007 to December 2010. Using these data sets, XX interferograms were generated. From these interferograms, it was possible to determine the spatial and temporal evolution of the crustal deformation in the line-of-sight of the satellite. The results show strong evidence of uplift in the region adjacent to the injection wells. While previous studies have established a strong connection between fluid injection and increased seismicity, this is to our knowledge the first observed case of crustal deformation that has been observed as a result of hydraulic fracturing fluid disposal.
Created2014-05
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Description
The ability to find evidence of life on early Earth and other planets is constrained by the current understanding of biosignatures and our ability to differentiate fossils from abiotic mimics. When organisms transition from the living realm to the fossil record, their morphological and chemical characteristics are modified, usually resulting

The ability to find evidence of life on early Earth and other planets is constrained by the current understanding of biosignatures and our ability to differentiate fossils from abiotic mimics. When organisms transition from the living realm to the fossil record, their morphological and chemical characteristics are modified, usually resulting in the loss of information. These modifications can happen during early and late diagenesis and differ depending on local geochemical properties. These post-depositional modifications need to be understood to better interpret the fossil record. Siliceous hot spring deposits (sinters) are of particular interest for biosignature research as they are early Earth analog environments and targets for investigating the presence of fossil life on Mars. As silica-supersaturated fluids flow from the vent to the distal apron, they precipitate non-crystalline opal-A that fossilizes microbial communities at a range in scales (μm-cm). Therefore, many studies have documented the ties between the active microbial communities and the morphological and chemical biosignatures in hot springs. However, far less attention has been placed on understanding preservation in systems with complex mineralogy or how post-depositional alteration affects the retention of biosignatures. Without this context, it can be challenging to recognize biosignatures in ancient rocks. This dissertation research aims to refine our current understanding of biosignature preservation and retention in sinters. Biosignatures of interest include organic matter, microfossils, and biofabrics. The complex nature of hot springs requires a comprehensive understanding of biosignature preservation that is representative of variable chemistries and post-depositional alterations. For this reason, this dissertation research chapters are field site-based. Chapter 2 investigates biosignature preservation in an unusual spring with mixed opal-A-calcite mineralogy at Lýsuhóll, Iceland. Chapter 3 tracks how silica diagenesis modifies microfossil morphology and associated organic matter at Puchuldiza, Chile. Chapter 4 studies the effects of acid fumarolic overprinting on biosignatures in Gunnuhver, Iceland. To accomplish this, traditional geologic methods (mapping, petrography, X-ray diffraction, bulk elemental analyses) were combined with high-spatial-resolution elemental mapping to better understand diagenetic effects in these systems. Preservation models were developed to predict the types and styles of biosignatures that can be present depending on the depositional and geochemical context. Recommendations are also made for the types of deposits that are most likely to preserve biosignatures.
ContributorsJuarez Rivera, Marisol (Author) / Farmer, Jack D (Thesis advisor) / Hartnett, Hilairy E (Committee member) / Shock, Everett (Committee member) / Garcia-Pichel, Ferran (Committee member) / Trembath-Reichert, Elizabeth (Committee member) / Arizona State University (Publisher)
Created2021
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Description
Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better

Cinder cones are common volcanic structures that occur in fields, and on the flanks of shield volcanoes, stratovolcanoes, and calderas. Because they are common structures, they have a significant possibility of impacting humans and human environments. As such, there is a need to analyze cinder cones to get a better understanding of their eruptions and associated hazards. I will approach this analysis by focusing on volcanic bombs and ballistics, which are large clots of lava that are launched from the volcanic vent, follow ballistic trajectories, and can travel meters to a few kilometers from their source (e.g. Fagents and Wilson 1993; Waitt et al. 1995).
Tecolote Volcano in the Pinacate Volcanic Field in Mexico contains multiple vents within a horseshoe-shaped crater that have all produced various ejecta (Zawacki et al. 2019). The objectives of this research are to map ballistic distribution to understand the relationship between the source vent or vents and the bombs and ballistics that litter the region around Tecolote, and interpret the eruption conditions that ejected those bombs by using their distributions, morphologies, and fine-scale textures.
The findings of this work are that these bombs are apparently from the last stages of the eruption, succeeding the final lava flows. The interiors and exteriors of the bombs display different cooling rates which can are indicated by the fabric found within. Using this, certain characteristics of the bombs during eruption were extrapolated. The ‘cow pie’ bombs were determined to be the least viscous or contained a higher gas content at the time of eruption. Whereas the ribbon/rope bombs were determined to be the most viscous or contained a lesser gas content. Looking at the Southern Bomb Field site, it is dominated by large bombs that were during flight were molded into aerodynamic shapes. The Eastern Rim site is dominated by smaller bombs that appeared to be more liquid during the eruption. This difference in the two sites is a probable indication of at least two different eruptive events of different degrees of explosivity. Overall, aerodynamic bombs are more common and extend to greater distances from the presumed vent (up to 800 m), while very fluidal bombs are uncommon beyond 500 meters. Fluidal bombs (‘cow pie’, ‘ribbon’, ‘rope/spindle’) show a clear trend in decreasing size with distance from vent, whereas the size-distance trend is less dramatic for the aerodynamic bombs.
ContributorsWest, Jacob Alexander (Co-author) / West, Jacob (Co-author) / Clarke, Amanda (Thesis director) / Arrowsmith, Ramon (Committee member) / Roggensack, Kurt (Committee member) / School of Earth and Space Exploration (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
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Description
With the development and successful landing of the NASA Perseverance rover, there has been growing interest in identifying how evidence of ancient life may be preserved and recognized in the geologic record. Environments that enable fossilization of biological remains are termed, “taphonomic windows”, wherein signatures of past life may be

With the development and successful landing of the NASA Perseverance rover, there has been growing interest in identifying how evidence of ancient life may be preserved and recognized in the geologic record. Environments that enable fossilization of biological remains are termed, “taphonomic windows”, wherein signatures of past life may be detected. In this dissertation, I have sought to identify taphonomic windows in planetary-analog environments with an eye towards the exploration of Mars. In the first chapter, I describe how evidence of past microbial life may be preserved within serpentinizing systems. Owing to energetic rock-water reactions, these systems are known to host lithotrophic and organotrophic microbial communities. By investigating drill cores from the Samail Ophiolite in Oman, I report morphological and associated chemical biosignatures preserved in these systems as a result of subsurface carbonation. As serpentinites are known to occur on Mars and potentially other planetary bodies, these deposits potentially represent high-priority targets in the exploration for past microbial life. Next, I investigated samples from Atacama Desert, Chile, to understand how evidence of life may be preserved in ancient sediments formed originally in evaporative playa lakes. Here, I describe organic geochemical and morphological evidence of life preserved within sulfate-dominated evaporite rocks from the Jurassic-Cretaceous Tonel Formation and Oligocene San Pedro Formation. Because evaporative lakes are considered to have been potentially widespread on Mars, these deposits may represent additional key targets to search for evidence of past life. In the final chapter, I describe the fossilization potential of surficial carbonates by investigating Crystal Geyser, an active cold spring environment. Here, carbonate minerals precipitate rapidly in the presence of photosynthetic microbial mat communities. I describe how potential biosignatures are initially captured by mineralization, including cell-like structures and microdigitate stromatolites. However, these morphological signatures quickly degrade owing to diagenetic dissolution and recrystallization reactions, as well as textural coarsening that homogenizes the carbonate fabric. Overall, my dissertation underscores the complexity of microbial fossilization and highlights chemically-precipitating environments that may serve as high-priority targets for astrobiological exploration.
ContributorsZaloumis, Jonathan (Author) / Farmer, Jack D (Thesis advisor) / Garcia-Pichel, Ferran (Committee member) / Trembath-Reichert, Elizabeth (Committee member) / Ruff, Steven W (Committee member) / Shock, Everett L (Committee member) / Arizona State University (Publisher)
Created2021