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Being a remarkably versatile and inexpensive building material, concrete has found tremendous use in development of modern infrastructure and is the most widely used material in the world. Extensive research in the field of concrete has led to the development of a wide array of concretes with applications ranging from

Being a remarkably versatile and inexpensive building material, concrete has found tremendous use in development of modern infrastructure and is the most widely used material in the world. Extensive research in the field of concrete has led to the development of a wide array of concretes with applications ranging from building of skyscrapers to paving of highways. These varied applications require special cementitious composites which can satisfy the demand for enhanced functionalities such as high strength, high durability and improved thermal characteristics among others.

The current study focuses on the fundamental understanding of such functional composites, from their microstructural design to macro-scale application. More specifically, this study investigates three different categories of functional cementitious composites. First, it discusses the differences between cementitious systems containing interground and blended limestone with and without alumina. The interground systems are found to outperform the blended systems due to differential grinding of limestone. A novel approach to deduce the particle size distribution of limestone and cement in the interground systems is proposed. Secondly, the study delves into the realm of ultra-high performance concrete, a novel material which possesses extremely high compressive-, tensile- and flexural-strength and service life as compared to regular concrete. The study presents a novel first principles-based paradigm to design economical ultra-high performance concretes using locally available materials. In the final part, the study addresses the thermal benefits of a novel type of concrete containing phase change materials. A software package was designed to perform numerical simulations to analyze temperature profiles and thermal stresses in concrete structures containing PCMs.

The design of these materials is accompanied by material characterization of cementitious binders. This has been accomplished using techniques that involve measurement of heat evolution (isothermal calorimetry), determination and quantification of reaction products (thermo-gravimetric analysis, x-ray diffraction, micro-indentation, scanning electron microscopy, energy-dispersive x-ray spectroscopy) and evaluation of pore-size distribution (mercury intrusion porosimetry). In addition, macro-scale testing has been carried out to determine compression, flexure and durability response. Numerical simulations have been carried out to understand hydration of cementitious composites, determine optimum particle packing and determine the thermal performance of these composites.
ContributorsArora, Aashay (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Chawla, Nikhilesh (Committee member) / Hoover, Christian G (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Phase change materials (PCMs) are combined sensible-and-latent thermal energy storage materials that can be used to store and dissipate energy in the form of heat. PCMs incorporated into wall-element systems have been well-studied with respect to energy efficiency of building envelopes. New applications of PCMs in infrastructural concrete, e.g., for

Phase change materials (PCMs) are combined sensible-and-latent thermal energy storage materials that can be used to store and dissipate energy in the form of heat. PCMs incorporated into wall-element systems have been well-studied with respect to energy efficiency of building envelopes. New applications of PCMs in infrastructural concrete, e.g., for mitigating early-age cracking and freeze-and-thaw induced damage, have also been proposed. Hence, the focus of this dissertation is to develop a detailed understanding of the physic-chemical and thermo-mechanical characteristics of cementitious systems and novel coating systems for wall-elements containing PCM. The initial phase of this work assesses the influence of interface properties and inter-inclusion interactions between microencapsulated PCM, macroencapsulated PCM, and the cementitious matrix. The fact that these inclusions within the composites are by themselves heterogeneous, and contain multiple components necessitate careful application of models to predict the thermal properties. The next phase observes the influence of PCM inclusions on the fracture and fatigue behavior of PCM-cementitious composites. The compliant nature of the inclusion creates less variability in the fatigue life for these composites subjected to cyclic loading. The incorporation of small amounts of PCM is found to slightly improve the fracture properties compared to PCM free cementitious composites. Inelastic deformations at the crack-tip in the direction of crack opening are influenced by the microscale PCM inclusions. After initial laboratory characterization of the microstructure and evaluation of the thermo-mechanical performance of these systems, field scale applicability and performance were evaluated. Wireless temperature and strain sensors for smart monitoring were embedded within a conventional portland cement concrete pavement (PCCP) and a thermal control smart concrete pavement (TCSCP) containing PCM. The TCSCP exhibited enhanced thermal performance over multiple heating and cooling cycles. PCCP showed significant shrinkage behavior as a result of compressive strains in the reinforcement that were twice that of the TCSCP. For building applications, novel PCM-composites coatings were developed to improve and extend the thermal efficiency. These coatings demonstrated a delay in temperature by up to four hours and were found to be more cost-effective than traditional building insulating materials.

The results of this work prove the feasibility of PCMs as a temperature-regulating technology. Not only do PCMs reduce and control the temperature within cementitious systems without affecting the rate of early property development but they can also be used as an auto-adaptive technology capable of improving the thermal performance of building envelopes.
ContributorsAguayo, Matthew Joseph (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Underwood, Benjamin (Committee member) / Liu, Yongming (Committee member) / Arizona State University (Publisher)
Created2018
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Description
This report analyzed the dynamic response of a long, linear elastic concrete bridge subject to spatially varying ground displacements as well as consistent ground displacements. Specifically, the study investigated the bridge’s response to consistent ground displacements at all supports (U-NW), ground displacements with wave passage effects and no soil profile

This report analyzed the dynamic response of a long, linear elastic concrete bridge subject to spatially varying ground displacements as well as consistent ground displacements. Specifically, the study investigated the bridge’s response to consistent ground displacements at all supports (U-NW), ground displacements with wave passage effects and no soil profile variability (U-WP), and ground displacements with both wave passage effects and soil profile variability (V-WP). Time-history ground displacements were taken from recordings of the Loma Prieta, Duzce, and Chuetsu earthquakes. The two horizontal components of each earthquake time-history displacement record were applied to the bridge supports in the transverse and longitudinal directions. It was found that considering wave passage effects without soil profile variability, as compared with consistent ground displacements, significantly reduced the peak total energy of the system, as well as decreasing the maximum relative longitudinal displacements. The maximum relative transverse displacements were not significantly changed in the same case. It was also found that including both wave passage effects and soil profile variability (V-WP) generally resulted in larger maximum transverse relative displacements, across all earthquake time-histories tested. Similarly, it was found that using consistent ground displacements (U-NW) generally resulted in larger maximum longitudinal relative displacements, as well as larger peak total energy values.
ContributorsSeawright, Jordan Michael (Author) / Hjelmstad, Keith (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Kavazanjian, Edward (Committee member) / Arizona State University (Publisher)
Created2019
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Description
The motivation of this work is based on development of new construction products with strain hardening cementitious composites (SHCC) geared towards sustainable residential applications. The proposed research has three main objectives: automation of existing manufacturing systems for SHCC laminates; multi-level characterization of mechanical properties of fiber, matrix, interface and composites

The motivation of this work is based on development of new construction products with strain hardening cementitious composites (SHCC) geared towards sustainable residential applications. The proposed research has three main objectives: automation of existing manufacturing systems for SHCC laminates; multi-level characterization of mechanical properties of fiber, matrix, interface and composites phases using servo-hydraulic and digital image correlation techniques. Structural behavior of these systems were predicted using ductility based design procedures using classical laminate theory and structural mechanics. SHCC sections are made up of thin sections of matrix with Portland cement based binder and fine aggregates impregnating continuous one-dimensional fibers in individual or bundle form or two/three dimensional woven, bonded or knitted textiles. Traditional fiber reinforced concrete (FRC) use random dispersed chopped fibers in the matrix at a low volume fractions, typically 1-2% to avoid to avoid fiber agglomeration and balling. In conventional FRC, fracture localization occurs immediately after the first crack, resulting in only minor improvement in toughness and tensile strength. However in SHCC systems, distribution of cracking throughout the specimen is facilitated by the fiber bridging mechanism. Influence of material properties of yarn, composition, geometry and weave patterns of textile in the behavior of laminated SHCC skin composites were investigated. Contribution of the cementitious matrix in the early age and long-term performance of laminated composites was studied with supplementary cementitious materials such as fly ash, silica fume, and wollastonite. A closed form model with classical laminate theory and ply discount method, coupled with a damage evolution model was utilized to simulate the non-linear tensile response of these composite materials. A constitutive material model developed earlier in the group was utilized to characterize and correlate the behavior of these structural composites under uniaxial tension and flexural loading responses. Development and use of analytical models enables optimal design for application of these materials in structural applications. Another area of immediate focus is the development of new construction products from SHCC laminates such as angles, channels, hat sections, closed sections with optimized cross sections. Sandwich composites with stress skin-cellular core concept were also developed to utilize strength and ductility of fabric reinforced skin in addition to thickness, ductility, and thermal benefits of cellular core materials. The proposed structurally efficient and durable sections promise to compete with wood and light gage steel based sections for lightweight construction and panel application
ContributorsDey, Vikram (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Neithalath, Narayanan (Committee member) / Underwood, Benjamin (Committee member) / Liu, Yongming (Committee member) / Arizona State University (Publisher)
Created2016
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Description
The need for sustainability in construction has encouraged scientists to develop novel environmentally friendly materials. The use of supplementary cementitious materials was one such initiative which aided in enhancing the fresh and hardened concrete properties. This thesis aims to explore the understanding of the early age rheological properties of such

The need for sustainability in construction has encouraged scientists to develop novel environmentally friendly materials. The use of supplementary cementitious materials was one such initiative which aided in enhancing the fresh and hardened concrete properties. This thesis aims to explore the understanding of the early age rheological properties of such cementitious systems.

The first phase of the work investigates the influence of supplementary cementitious materials (SCM) in combination with ordinary Portland cement (OPC) on the rheological properties of fresh paste with and without the effect of superplasticizers. Yield stress, plastic viscosity and storage modulus are the rheological parameters which were evaluated for all the design mixtures to fundamentally understand the synergistic effects of the SCM. A time-dependent study was conducted on these blends to explore the structure formation at various time intervals which explains the effect of hydration in conjecture to its physical stiffening. The second phase focuses on the rheological characterization of novel iron powder based binder system.

The results of this work indicate that the rheological characteristics of cementitious suspensions are complex, and strongly dependent on several key parameters including: the solid loading, inter-particle forces, shape of the particle, particle size distribution of the particles, and rheological nature of the media in which the particles are suspended. Chemical composition and reactivity of the material play an important role in the time-dependent rheological study.

A stress plateau method is utilized for the determination of rheological properties of concentrated suspensions, as it better predicts the apparent yield stress and is shown to correlate well with other viscoelastic properties of the suspensions. Plastic viscosity is obtained by calculating the slope of the stress-strain rate curve of ramp down values of shear rates. In oscillatory stress measurements the plateau obtained within the linear visco-elastic region was considered to be the value for storage modulus.

Between the different types of fly ash, class F fly ash indicated a reduction in the rheological parameters as opposed to class C fly ash that is attributable to the enhanced ettringite formation in the latter. Use of superplasticizer led to a huge influence on yield stress and storage modulus of the paste due to the steric hindrance effect.

In the study of iron based binder systems, metakaolin had comparatively higher influence than fly ash on the rheology due to its tendency to agglomerate as opposed to the ball bearing effect observed in the latter. Iron increment above 60% resulted in a decrease in all the parameters of rheology discussed in this thesis. In the OPC-iron binder, the iron behaved as reinforcements yielding higher yield stress and plastic viscosity.
ContributorsInbasekaran, Aditya (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Composite materials are widely used in various structural applications, including within the automotive and aerospace industries. Unidirectional composite layups have replaced other materials such as metals due to composites’ high strength-to-weight ratio and durability. Finite-element (FE) models are actively being developed to model response of composite systems subjected to a

Composite materials are widely used in various structural applications, including within the automotive and aerospace industries. Unidirectional composite layups have replaced other materials such as metals due to composites’ high strength-to-weight ratio and durability. Finite-element (FE) models are actively being developed to model response of composite systems subjected to a variety of loads including impact loads. These FE models rely on an array of measured material properties as input for accuracy. This work focuses on an orthotropic plasticity constitutive model that has three components – deformation, damage and failure. The model relies on the material properties of the composite such as Young’s modulus, Poisson’s ratio, stress-strain curves in the principal and off-axis material directions, etc. This thesis focuses on two areas important to the development of the FE model – tabbing of the test specimens and data processing of the tests used to generate the required stress-strain curves. A comparative study has been performed on three candidate adhesives using double lap-shear testing to determine their effectiveness in composite specimen tabbing. These tests determined the 3M DP460 epoxy performs best in shear. The Loctite Superglue with 80% the ultimate stress of the 3M DP460 epoxy is acceptable when test specimens have to be ready for testing within a few hours. JB KwikWeld is not suitable for tabbing. In addition, the Experimental Data Processing (EDP) program has been improved for use in post-processing raw data from composites test. EDP has improved to allow for complete processing with the implementation of new weighted least squares smoothing options, curve averaging techniques, and new functionality for data manipulation.
ContributorsSchmidt, Nathan William (Author) / Rajan, Subramaniam D. (Thesis advisor) / Neithalath, Narayanan (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Tall building developments are spreading across the globe at an ever-increasing rate (www.ctbuh.org). In 1982, the number of ‘tall buildings’ in North America was merely 1,701. This number rose to 26,053, in 2006. The global number of buildings, 200m or more in height, has risen from 286 to 602 in

Tall building developments are spreading across the globe at an ever-increasing rate (www.ctbuh.org). In 1982, the number of ‘tall buildings’ in North America was merely 1,701. This number rose to 26,053, in 2006. The global number of buildings, 200m or more in height, has risen from 286 to 602 in the last decade alone. This dissertation concentrates on design optimization of such, about-to-be modular, structures by implementing AISC 2010 design requirements. Along with a discussion on and classification of lateral load resisting systems, a few design optimization cases are also being studied. The design optimization results of full scale three dimensional buildings subject to multiple design criteria including stress, serviceability and dynamic response are discussed. The tool being used for optimization is GS-USA Frame3D© (henceforth referred to as Frame3D). Types of analyses being verified against a strong baseline of Abaqus 6.11-1, are stress analysis, modal analysis and buckling analysis.

The provisions in AISC 2010 allows us to bypass the limit state of flexural buckling in compression checks with a satisfactory buckling analysis. This grants us relief from the long and tedious effective length factor computations. Besides all the AISC design checks, an empirical equation to check beams with high shear and flexure is also being enforced.

In this study, we present the details of a tool that can be useful in design optimization - finite element modeling, translating AISC 2010 design code requirements into components of the FE and design optimization models. A comparative study of designs based on AISC 2010 and fixed allowable stresses, (regardless of the shape of cross section) is also being carried out.
ContributorsUnde, Yogesh (Author) / Rajan, Subramaniam D. (Thesis advisor) / Neithalath, Narayanan (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2016
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Description
As more and more stadia structures nowadays are being built by making use of new high strength building materials which tend to be lighter than the "old" ones, composite systems and also the fact that engineers, contractors and clients want their structures as optimized as possible, in terms of minimal

As more and more stadia structures nowadays are being built by making use of new high strength building materials which tend to be lighter than the "old" ones, composite systems and also the fact that engineers, contractors and clients want their structures as optimized as possible, in terms of minimal materials used, there is an inevitable side effect that comes with this. The result is that structures are more flexible, and thus they become susceptible to undergone vibration problems due to the action of dynamic loading. Pop/rock concerts, exhibitions, boxing matches, and so forth are staged to supplement the football/sport seasons. Consequently, stadia structures must resist not only static loading, but also dynamic loading, such as the human induced loads from various activities of the spectators which include, standing, jumping, stamping, clapping and dancing, particularly in response to touchdowns (in football matches) or musical beats (during concerts). Active and passive models of humans are studied to see how they influence the response in TCF Bank Stadium for different ranges in excitation frequencies, by performing dynamic analyses and comparing the results with the ones obtained from static analysis. Parameter estimation and system identification in mechanical sciences and structural engineering have become increasingly important areas of research in the last three decades. Many nondestructive testing methods are based on the concepts of system identification and parameter estimation. In this document, two parameter estimation algorithms are studied, namely the Equation Error Estimator and the Output Error Estimator, through the simulation of modal data obtained from a computer structural analysis program and comparisons of their results are presented so that future researchers are better informed about the two and therefore can decide which one would give the best results for their application.
ContributorsAldaco Lopez, Manuel (Author) / Hjelmstad, Keith D. (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Fafitis, Apostolos (Committee member) / Arizona State University (Publisher)
Created2014
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Description
The demand for portland cement concrete is expected to increase over time. There is a need to develop a more sustainable cementitious systems in order to reduce the negative environmental impacts associated with ordinary portland cement (OPC) production. An attempt is made to investigate sustainable binder solutions through the use

The demand for portland cement concrete is expected to increase over time. There is a need to develop a more sustainable cementitious systems in order to reduce the negative environmental impacts associated with ordinary portland cement (OPC) production. An attempt is made to investigate sustainable binder solutions through the use of alternative cementitious materials at high levels of volume replacement. Limestone, an abundant material is used as a filler in low water-to-powder concretes where a substantial fraction of the portland cement remains unhydrated. At high volume OPC replacement, 20% and 35%, the combination of limestone and an alumina source has been shown to improve mechanical and durability performance. At 20% OPC replacement levels the migration coefficient which is an indication of chloride penetration in concrete is lower than the OPC control mixture at 28 and 56 days of hydration. The use of limestone with a similar particle size distribution to that of the OPC is used in each of these blended systems. A 20% binary limestone blend provide similar strength to an OPC mortar at all ages and comparable transport properties to that of the OPC concrete. Fly ash and metakaolin are the two alumina sources for the ternary blended mixes with concrete. The metakaolin shows the highest increase in the amount of hydration products formed out of all the mixes, including calcium-silicate-hydrate and carboaluminate phases in combination with limestone powder. At both levels of replacement the metakaolin blends show a substantially lower migration coefficient which is contributed to the smaller pore sizes found in the metakaolin blends. The fracture response of these systems show that at all replacement levels the ductility of the systems increase indicated by the large critical crack tip opening displacement. The fracture toughness is the highest for the blend containing metakaolin indicative of the smaller pore sizes allowing more dissipation of energy. An attempt is made to relate all mechanical and durability parameters to the reaction products and pore-structure developing at later ages.
ContributorsAguayo, Matthew (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Buildings and other structures, all components and cladding thereof, shall be designed and constructed to resist the wind loads are required in all wind codes. Simple quasi-static treatment of wind loads, which is universally applied to design of low to medium-rise structures, can be either overly conservative or erroneous under-estimated

Buildings and other structures, all components and cladding thereof, shall be designed and constructed to resist the wind loads are required in all wind codes. Simple quasi-static treatment of wind loads, which is universally applied to design of low to medium-rise structures, can be either overly conservative or erroneous under-estimated for design of high-rise structures. Dynamic response, vortex, wind directionality, and shedding from other structures are all complicated key factors suppose to be considered in design. Meanwhile, wind tunnel testing is expansive, difficult and sometimes inaccurate even if it is a widely used method in simulation of aerodynamic response. Computational Fluid dynamics (CFD), historically, were two-dimensional (2D) method using conformal transformations of the flow about a cylinder to the flow about an airfoil were developed in the 1930s. A number of three-dimensional (3D) codes were developed, leading to numerous commercial packages, which is more accessible and economical for wind load analysis.
ContributorsZhu, Xitong (Author) / Hjelmstad, Keith D. (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Fafitis, Apostolos (Committee member) / Arizona State University (Publisher)
Created2014