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The photovoltaic (PV) modules are primarily characterized for their performance with respect to incident irradiance and operating temperature. This work deals with data collection and automation of data processing for the performance and thermal characterizations of PV modules. This is a two-part thesis: The primary part (part-1) deals with the

The photovoltaic (PV) modules are primarily characterized for their performance with respect to incident irradiance and operating temperature. This work deals with data collection and automation of data processing for the performance and thermal characterizations of PV modules. This is a two-part thesis: The primary part (part-1) deals with the software automation to generate performance matrix as per IEC 61853-1 standard using MPPT (maximum power point tracking) data at the module or system level; the secondary part (part-2) deals with the software automation to predict temperature of rooftop PV modules using the thermal model coefficients generated in the previous studies of the Photovoltaic Reliability Laboratory (PRL). Part 1: The IEC 61853-1 standard published in January 2011 specifies the generation of a target performance matrix of photovoltaic (PV) modules at various temperatures and irradiance levels. In a conventional method, this target matrix is generated using all the data points of several measured I-V curves and the translation procedures defined in IEC 60891 standard. In the proposed method, the target matrix is generated using only three commonly field measured parameters: Module temperature, Incident irradiance and MPPT (Maximum Peak Power Tracking) value. These parameters are loaded into the programmed Excel file and with a click of a button, IEC 61853-1 specified Pmppt matrix is displayed on the screen in about thirty seconds. Part 2: In a previous study at PRL, an extensive thermal model to predict operating temperature of rooftop PV modules was developed with a large number of empirical monthly coefficients for ambient temperature, irradiance and wind speed. Considering that there is large number of coefficients for each air gap of rooftop modules, it became necessary to automate the entire data processing to predict the temperature of rooftop PV modules at different air gaps. This part of the work was dedicated to automatically predict the temperature of rooftop modules at different air gaps for any month in a year just using only four input parameters: Month, Irradiance, Ambient temperature and Wind speed.
ContributorsKoka, Kartheek (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Macia, Narciso F. (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Potential induced degradation (PID) due to high system voltages is one of the major degradation mechanisms in photovoltaic (PV) modules, adversely affecting their performance due to the combined effects of the following factors: system voltage, superstrate/glass surface conductivity, encapsulant conductivity, silicon nitride anti-reflection coating property and interface property (glass/encapsulant; encapsulant/cell;

Potential induced degradation (PID) due to high system voltages is one of the major degradation mechanisms in photovoltaic (PV) modules, adversely affecting their performance due to the combined effects of the following factors: system voltage, superstrate/glass surface conductivity, encapsulant conductivity, silicon nitride anti-reflection coating property and interface property (glass/encapsulant; encapsulant/cell; encapsulant/backsheet). Previous studies carried out at ASU's Photovoltaic Reliability Laboratory (ASU-PRL) showed that only negative voltage bias (positive grounded systems) adversely affects the performance of commonly available crystalline silicon modules. In previous studies, the surface conductivity of the glass surface was obtained using either conductive carbon layer extending from the glass surface to the frame or humidity inside an environmental chamber. This thesis investigates the influence of glass surface conductivity disruption on PV modules. In this study, conductive carbon was applied only on the module's glass surface without extending to the frame and the surface conductivity was disrupted (no carbon layer) at 2cm distance from the periphery of frame inner edges. This study was carried out under dry heat at two different temperatures (60 °C and 85 °C) and three different negative bias voltages (-300V, -400V, and -600V). To replicate closeness to the field conditions, half of the selected modules were pre-stressed under damp heat for 1000 hours (DH 1000) and the remaining half under 200 hours of thermal cycling (TC 200). When the surface continuity was disrupted by maintaining a 2 cm gap from the frame to the edge of the conductive layer, as demonstrated in this study, the degradation was found to be absent or negligibly small even after 35 hours of negative bias at elevated temperatures. This preliminary study appears to indicate that the modules could become immune to PID losses if the continuity of the glass surface conductivity is disrupted at the inside boundary of the frame. The surface conductivity of the glass, due to water layer formation in a humid condition, close to the frame could be disrupted just by applying a water repelling (hydrophobic) but high transmittance surface coating (such as Teflon) or modifying the frame/glass edges with water repellent properties.
ContributorsTatapudi, Sai Ravi Vasista (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Photovoltaic (PV) modules are typically rated at three test conditions: STC (standard test conditions), NOCT (nominal operating cell temperature) and Low E (low irradiance). The current thesis deals with the power rating of PV modules at twenty-three test conditions as per the recent International Electrotechnical Commission (IEC) standard of IEC

Photovoltaic (PV) modules are typically rated at three test conditions: STC (standard test conditions), NOCT (nominal operating cell temperature) and Low E (low irradiance). The current thesis deals with the power rating of PV modules at twenty-three test conditions as per the recent International Electrotechnical Commission (IEC) standard of IEC 61853 – 1. In the current research, an automation software tool developed by a previous researcher of ASU – PRL (ASU Photovoltaic Reliability Laboratory) is validated at various stages. Also in the current research, the power rating of PV modules for four different manufacturers is carried out according to IEC 61853 – 1 standard using a new outdoor test method. The new outdoor method described in this thesis is very different from the one reported by a previous researcher of ASU – PRL. The new method was designed to reduce the labor hours in collecting the current-voltage ( I – V) curves at various temperatures and irradiance levels. The power matrices for all the four manufacturers were generated using the I – V data generated at different temperatures and irradiance levels and the translation procedures described in IEC 60891 standard. All the measurements were carried out on both clear and cloudy days using an automated 2 – axis tracker located at ASU – PRL, Mesa, Arizona. The modules were left on the 2 – axis tracker for 12 continuous days and the data was continuously and automatically collected for every two minutes from 6 am to 6 pm. In order to obtain the I – V data at wide range of temperatures and irradiance levels, four identical (or nearly identical) modules were simultaneously installed on the 2 – axis tracker with and without thermal insulators on the back of the modules and with and without mesh screens on the front of the modules. Several issues related to the automation software were uncovered and the required improvement in the software has been suggested. The power matrices for four manufacturers have been successfully generated using the new outdoor test method developed in this work. The data generated in this work has been extensively analyzed for accuracy and for performance efficiency comparison at various temperatures and irradiance levels.
ContributorsVemula, Meena Gupta (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Macia, Narcio F. (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Power rating photovoltaic modules at six irradiance and four temperature matrix levels of IEC 61853-1 draft standard is one of the most important requirements to accurately predict energy production of photovoltaic modules at different climatic conditions. Two studies were carried out in this investigation: a measurement repeatability study and a

Power rating photovoltaic modules at six irradiance and four temperature matrix levels of IEC 61853-1 draft standard is one of the most important requirements to accurately predict energy production of photovoltaic modules at different climatic conditions. Two studies were carried out in this investigation: a measurement repeatability study and a translation procedure validation study. The repeatability study was carried out to define a testing methodology that allows generating repeatable power rating results under outdoor conditions. The validation study was carried out to validate the accuracy of the four translation procedures: the first three procedures are from the IEC 60891 standard and the fourth procedure is reported by NREL. These translation procedures are needed to translate the measured data from the actual test conditions to the reporting rating conditions required by the IEC 61853-1 draft standard. All the measurements were carried out outdoors on clear days using a manual, 2-axis tracker, located in Mesa/Tempe, Arizona. Four module technologies were investigated: crystalline silicon, amorphous silicon, cadmium telluride, and copper indium gallium selenide. The modules were cooled and then allowed to naturally warm up to obtain current-voltage data at different temperatures. Several black mesh screens with a wide range of transmittance were used for varying irradiance levels. From the measurements repeatability study, it was determined that: (i) a certain minimum distance (2 inches) should be maintained between module surface and the screen surface; (ii) the reference cell should be kept outside the screen (calibrated screen) as opposed to inside the screen (uncalibrated screen); and (iii) the air mass should not exceed 2.5. From the translation procedure validation study, it was determined that the accuracy of the translation procedure depends on the irradiance and temperature range of translation. The difference between measured and translatet power at maximum power point (Pmax) is determined to be less than 3% for all the technologies, all the irradiance/ temperature ranges investigated and all the procedures except Procedure 2 of IEC 60891 standard. For the Procedure 2, the difference was found to fall between 3% and 17% depending on the irradiance range used for the translation. The difference of 17% is very large and unacceptable. This work recommends reinvestigating the cause for this large difference for Procedure 2. Finally, a complete power rating matrix for each of the four module technologies has been successfully generated as per IEC 61853-1 draft standard.
ContributorsPaghasian, Karen (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Madakannan, Arunachalandar (Committee member) / Macia, Narciso F. (Committee member) / Arizona State University (Publisher)
Created2010
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Description
Photovoltaic (PV) modules appear to have three classifications of failure: Infant mortality, normal-life failure, and end-of-life failure. Little is known of the end-of-life failures experienced by PV modules due to their inherent longevity. Accelerated Life Testing (ALT) has been at the crux of this lifespan prediction; however, without naturally failing

Photovoltaic (PV) modules appear to have three classifications of failure: Infant mortality, normal-life failure, and end-of-life failure. Little is known of the end-of-life failures experienced by PV modules due to their inherent longevity. Accelerated Life Testing (ALT) has been at the crux of this lifespan prediction; however, without naturally failing modules an accurate acceleration factor cannot be determined for use in ALT. By observing modules that have been aged in the field, a comparison can be made with modules undergoing accelerated testing. In this study an investigation on about 1900 aged (10-17 years) grid-tied PV modules installed in the desert climatic condition of Arizona was undertaken. The investigation was comprised of a check sheet that documented any visual defects and their severity, infrared (IR) scanning, and current-voltage (I-V) curve measurements. After data was collected on modules, an analysis was performed to classify the failure modes and to determine the annual performance degradation rates.
ContributorsSuleske, Adam Alfred (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Macia, Narciso (Committee member) / Arizona State University (Publisher)
Created2010
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Description
Bifacial photovoltaic modules are a relatively new development in the photovoltaic industry which allows for the collection and conversion of light on both sides of photovoltaic modules to usable electricity. Additional energy yield from bifacial photovoltaic modules, despite a slight increase in cost due to manufacturing processes of the bifacial

Bifacial photovoltaic modules are a relatively new development in the photovoltaic industry which allows for the collection and conversion of light on both sides of photovoltaic modules to usable electricity. Additional energy yield from bifacial photovoltaic modules, despite a slight increase in cost due to manufacturing processes of the bifacial cells, has the potential to significantly decrease the LCOE of photovoltaic installation. The performance of bifacial modules is dependent on three major factors: incident irradiation on the front side of the module, reflected irradiation on the back side of the module, and the module's bifaciality. Bifaciality is an inherent property of the photovoltaic cells and is determined by the performance of the front and rear side of the module when tested at STC. The reflected light on the back side of the module, however, is determined by several different factors including the incident ground irradiance, shading from the modules and racking system, height of the module installation, and ground albedo. Typical ground surfaces have a low albedo, which means that the magnitude of reflected light is a low percentage of the incident irradiance. Non-uniformity of back-side irradiance can also reduce the power generation due to cell-to-cell mismatch losses. This study investigates the use of controlled back-side reflectors to improve the irradiance on the back side of loosely packed 48-cell bifacial modules and compares this performance to the performance of 48 and 60-cell bifacial modules which rely on the uncontrolled reflection off nearby ground surfaces. Different construction geometries and reflective coating materials were tested to determine optimal construction to improve the reflectivity and uniformity of reflection. Results of this study show a significant improvement of 10-14% total energy production from modules with reflectors when compared to the 48-cell module with an uncontrolled ground reflection.
ContributorsBowersox, David Andrew (Author) / Tamizhmani, Govindasamy (Thesis director) / Srinivasan, Devarajan (Committee member) / School for Engineering of Matter, Transport and Energy (Contributor) / Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
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Description
Solar photovoltaic (PV) generation has seen significant growth in 2021, with an increase of around 22% and exceeding 1000 TWh. However, this has also led to reliability and durability issues, particularly potential induced degradation (PID), which can reduce module output by up to 30%. This study uses cell- and module-level

Solar photovoltaic (PV) generation has seen significant growth in 2021, with an increase of around 22% and exceeding 1000 TWh. However, this has also led to reliability and durability issues, particularly potential induced degradation (PID), which can reduce module output by up to 30%. This study uses cell- and module-level analysis to investigate the impact of superstrate, encapsulant, and substrate on PID.The influence of different substrates and encapsulants is studied using one-cell modules, showing that substrates with poor water-blocking properties can worsen PID, and encapsulants with lower volumetric resistance can conduct easily under damp conditions, enabling PID mechanisms (results show maximum degradation of 9%). Applying an anti-soiling coating on the front glass (superstrate) reduces PID by nearly 53%. Typical superstrates have sodium which accelerates the PID process, and therefore, using such coatings can lessen the PID problem. At the module level, the study examines the influence of weakened interface adhesion strengths in traditional Glass-Backsheet (GB) and emerging Glass-Glass (GG) (primarily bifacial modules) constructions. The findings show nearly 64% more power degradation in GG modules than in GB. Moreover, the current methods for detecting PID use new modules, which can give inaccurate information instead of DH-stressed modules for PID testing, as done in this work. A comprehensive PID susceptibility analysis for multiple fresh bifacial constructions shows significant degradation from 20 to 50% in various constructions. The presence of glass as the substrate exacerbates the PID problem due to more ionic activity available from the two glass sides. Recovery experiments are also conducted to understand the extent of the PID issue. Overall, this study identifies, studies, and explains the impact of superstrate, substrate, and encapsulant on the underlying PID mechanisms. Various pre- and post-stress characterization tests, including light and dark current-voltage (I-V) tests, electroluminescence (EL) imaging, infrared (IR) imaging, and UV fluorescence (UVF) imaging, are used to evaluate the findings. This study is significant as it provides insights into the PID issues in solar PV systems, which can help improve their performance and reliability.
ContributorsMahmood, Farrukh ibne (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Oh, Jaewon (Committee member) / Rajadas, John (Committee member) / Arizona State University (Publisher)
Created2023
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Description
This study introduces a new outdoor accelerated testing method called “Field Accelerated Stress Testing (FAST)” for photovoltaic (PV) modules performed at two different climatic sites in Arizona (hot-dry) and Florida (hot-humid). FAST is a combined accelerated test methodology that simultaneously accounts for all the field-specific stresses and accelerates only key

This study introduces a new outdoor accelerated testing method called “Field Accelerated Stress Testing (FAST)” for photovoltaic (PV) modules performed at two different climatic sites in Arizona (hot-dry) and Florida (hot-humid). FAST is a combined accelerated test methodology that simultaneously accounts for all the field-specific stresses and accelerates only key stresses, such as temperature, to forecast the failure modes by 2- 7 times in advance depending on the activation energy of the degradation mechanism (i.e., 10th year reliability issues can potentially be predicted in the 2nd year itself for an acceleration factor of 5). In this outdoor combined accelerated stress study, the temperatures of test modules were increased (by 16-19℃ compared to control modules) using thermal insulations on the back of the modules. All other conditions (ambient temperature, humidity, natural sunlight, wind speed, wind direction, and tilt angle) were left constant for both test modules (with back thermal insulation) and control modules (without thermal insulation). In this study, a total of sixteen 4-cell modules with two different construction types (glass/glass [GG] and glass/backsheet [GB]) and two different encapsulant types (ethylene vinyl acetate [EVA] and polyolefin elastomer [POE]), were investigated at both sites with eight modules at each site (four insulated and four non-insulated modules at each site). All the modules were extensively characterized before installation in the field and after field exposure over two years. The methods used for characterizing the devices included I-V (current-voltage curves), EL (electroluminescence), UVF (ultraviolet fluorescence), and reflectance. The key findings of this study are: i) the GG modules tend to operate at a higher temperature (1-3℃) than the GB modules at both sites of Arizona and Florida (a lower lifetime is expected for GG modules compared to GB modules); ii) the GG modules tend to experience a higher level of encapsulant discoloration and grid finger degradation than the GB modules at both sites (a higher level of the degradation rate is expected in GG modules compared to GB modules); and, iii) the EVA-based modules tend to have a higher level of discoloration and finger degradation compared to the POE-based modules at both sites.
ContributorsThayumanavan, Rishi Gokul (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Calhoun, Ronald (Committee member) / Arizona State University (Publisher)
Created2023
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Description
The volume of end-of-life photovoltaic (PV) modules is increasing as the global PV market increases, and the global PV waste streams are expected to reach 250,000 metric tons by the end of 2020. If the recycling processes are not in place, there would be 60 million tons of end-of-life PV

The volume of end-of-life photovoltaic (PV) modules is increasing as the global PV market increases, and the global PV waste streams are expected to reach 250,000 metric tons by the end of 2020. If the recycling processes are not in place, there would be 60 million tons of end-of-life PV modules lying in the landfills by 2050, that may not become a not-so-sustainable way of sourcing energy since all PV modules could contain certain amount of toxic substances. Currently in the United States, PV modules are categorized as general waste and can be disposed in landfills. However, potential leaching of toxic chemicals and materials, if any, from broken end-of-life modules may pose health or environmental risks. There is no standard procedure to remove samples from PV modules for chemical toxicity testing in the Toxicity Characteristic Leaching Procedure (TCLP) laboratories as per EPA 1311 standard. The main objective of this thesis is to develop an unbiased sampling approach for the TCLP testing of PV modules. The TCLP testing was concentrated only for the laminate part of the modules, as they are already existing recycling technologies for the frame and junction box components of PV modules. Four different sample removal methods have been applied to the laminates of five different module manufacturers: coring approach, cell-cut approach, strip-cut approach, and hybrid approach. These removed samples were sent to two different TCLP laboratories, and TCLP results were tested for repeatability within a lab and reproducibility between the labs. The pros and cons of each sample removal method have been explored and the influence of sample removal methods on the variability of TCLP results has been discussed. To reduce the variability of TCLP results to an acceptable level, additional improvements in the coring approach, the best of the four tested options, are still needed.
ContributorsLeslie, Joswin (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Kuitche, Joseph (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Ethylene vinyl acetate (EVA) is the most commonly used encapsulant in photovoltaic modules. However, EVA degrades over time and causes performance losses in PV system. Therefore, EVA degradation is a matter of concern from a durability point of view.

This work compares EVA encapsulant degradation in glass/backsheet and glass/glass field-aged

Ethylene vinyl acetate (EVA) is the most commonly used encapsulant in photovoltaic modules. However, EVA degrades over time and causes performance losses in PV system. Therefore, EVA degradation is a matter of concern from a durability point of view.

This work compares EVA encapsulant degradation in glass/backsheet and glass/glass field-aged PV modules. EVA was extracted from three field-aged modules (two glass/backsheet and one glass/glass modules) from three different manufacturers from various regions (cell edges, cell centers, and non-cell region) from each module based on their visual and UV Fluorescence images. Characterization techniques such as I-V measurements, Colorimetry, Different Scanning Calorimetry, Thermogravimetric Analysis, Raman spectroscopy, and Fourier Transform Infrared Spectroscopy were performed on EVA samples.

The intensity of EVA discoloration was quantified using colorimetric measurements. Module performance parameters like Isc and Pmax degradation rates were calculated from I-V measurements. Properties such as degree of crystallinity, vinyl acetate content and degree of crosslinking were calculated from DSC, TGA, and Raman measurements, respectively. Polyenes responsible for EVA browning were identified in FTIR spectra.

The results from the characterization techniques confirmed that when EVA undergoes degradation, crosslinking in EVA increases beyond 90% causing a decrease in the degree of crystallinity and an increase in vinyl acetate content of EVA. Presence of polyenes in FTIR spectra of degraded EVA confirmed the occurrence of Norrish II reaction. However, photobleaching occurred in glass/backsheet modules due to the breathable backsheet whereas no photobleaching occurred in glass/glass modules because they were hermetically sealed. Hence, the yellowness index along with the Isc and Pmax degradation rates of EVA in glass/glass module is higher than that in glass/backsheet modules.

The results implied that more acetic acid was produced in the non-cell region due to its double layer of EVA compared to the front EVA from cell region. But, since glass/glass module is hermetically sealed, acetic acid gets entrapped inside the module further accelerating EVA degradation whereas it diffuses out through backsheet in glass/backsheet modules. Hence, it can be said that EVA might be a good encapsulant for glass/backsheet modules, but the same cannot be said for glass/glass modules.
ContributorsPatel, Aesha Parimalbhai (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Green, Matthew (Committee member) / Mu, Bin (Committee member) / Arizona State University (Publisher)
Created2018