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- All Subjects: Particulate matter
- All Subjects: Geophysics
- Creators: Clarke, Amanda
- Creators: Fraser, Matthew
To investigate the impacts of an energy efficiency retrofit on IAQ, indoor and outdoor air quality sampling was carried out at Sunnyslope Manor, a city-subsidized senior living apartment complex. Measured indoor formaldehyde levels before the building retrofit exceeded reference exposure limits, but in the long term follow-up sampling, indoor formaldehyde decreased for the entire study population by a statistically significant margin. Indoor PM levels were dominated by fine particles and showed a statistically significant decrease in the long term follow-up sampling within certain resident subpopulations (i.e. residents who reported smoking and residents who had lived longer at the apartment complex). Additionally, indoor glyoxal and methylglyoxal exceeded outdoor concentrations, with methylglyoxal being more prevalent pre-retrofit than glyoxal, suggesting different chemical pathways are involved. Indoor concentrations reported are larger than previous studies. TSNAs, specifically N'-nitrosonornicotine (NNN), 4-(methyl-nitrosamino)-4-(3-pyridyl)-butanal (NNA) and 4-(methylnitrosoamino)-1-(3-pyridyl)-1-butanone (NNK) were evaluated post-retrofit at Sunnyslope Manor. Of the units tested, 86% of the smoking units and 46% of the non-smoking units had traces of at least one of the nitrosamines.
Successful forecasting of the timing, style, and intensity of a volcanic eruption is made possible by improved understanding of the volcano life cycle as well as building quantitative models incorporating the processes that govern rock melting, melt ascending, magma storage, eruption initiation, and interaction between magma and surrounding host rocks at different spatial extent and time scale. One key part of such models is the shallow magma chamber, which is generally directly linked to volcano’s eruptive behaviors. However, its actual shape, size, and temporal evolution are often not entirely known. To address this issue, I use space-based geodetic data with high spatiotemporal resolution to measure surface deformation at Kilauea volcano. The obtained maps of InSAR (Interferometric Synthetic Aperture Radar) deformation time series are exploited with two novel modeling schemes to investigate Kilauea’s shallow magmatic system. Both models can explain the same observation, leading to a new compartment model of magma chamber. Such models significantly advance the understanding of the physical processes associated with Kilauea’s summit plumbing system with potential applications for volcanoes around the world.
The unprecedented increase in the number of earthquakes in the Central and Eastern United States since 2008 is attributed to massive deep subsurface injection of saltwater. The elevated chance of moderate-large damaging earthquakes stemming from increased seismicity rate causes broad societal concerns among industry, regulators, and the public. Thus, quantifying the time-dependent seismic hazard associated with the fluid injection is of great importance. To this end, I investigate the large-scale seismic, hydrogeologic, and injection data in northern Texas for period of 2007-2015 and in northern-central Oklahoma for period of 1995-2017. An effective induced earthquake forecasting model is developed, considering a complex relationship between injection operations and consequent seismicity. I find that the timing and magnitude of regional induced earthquakes are fully controlled by the process of fluid diffusion in a poroelastic medium and thus can be successfully forecasted. The obtained time-dependent seismic hazard model is spatiotemporally heterogeneous and decreasing injection rates does not immediately reduce the probability of an earthquake. The presented framework can be used for operational induced earthquake forecasting. Information about the associated fundamental processes, inducing conditions, and probabilistic seismic hazards has broad benefits to the society.
A 1: 1,000,000 scale geologic map of Ascraeus Mons was produced using ArcGIS and will be submitted to the USGS for review and publication. Mapping revealed 26 units total, broken into three separate categories: Flank units, Apron and Scarp units, and Plains units. Units were defined by geomorphological characteristics such as: surface texture, albedo, size, location, and source. Defining units in this manner allowed for contact relationships to be observed, creating a relative age date for each unit to understand the evolution and history of this large shield volcano.
Ascraeus Mons began with effusive, less viscous style of eruptions and transitioned to less effusive, more viscous eruptions building up the main shield. This was followed by eruptions onto the plains from the two main rift aprons on AM. Apron eruptions continued, while flank eruptions ceased, surrounding and embaying the flanks of AM. Eruptions from the rifts wane and build up the large aprons and low shield fields. Glaciers modified the base of the west flank and deposited the Aureole material. Followed by localized recent eruptions on the flanks, in the calderas, and small vent fields. Currently AM is modified by aeolian and tectonic processes. While the overall story of Ascraeus Mons does not change significantly, higher resolution imagery allowed for a better understanding of magma evolution and lava characteristics across the main shield. This study helps identify martian magma production rates and how not only Ascraeus Mons evolved, but also the Tharsis province and other volcanic regions of Mars.
To investigate the impacts of an energy efficiency retrofit, indoor air quality and resident health were evaluated at a low‐income senior housing apartment complex in Phoenix, Arizona, before and after a green energy building renovation. Indoor and outdoor air quality sampling was carried out simultaneously with a questionnaire to characterize personal habits and general health of residents. Measured indoor formaldehyde levels before the building retrofit routinely exceeded reference exposure limits, but in the long‐term follow‐up sampling, indoor formaldehyde decreased for the entire study population by a statistically significant margin. Indoor PM levels were dominated by fine particles and showed a statistically significant decrease in the long‐term follow‐up sampling within certain resident subpopulations (i.e. residents who report smoking and residents who had lived longer at the apartment complex).
Quantifying halogen presence and speciation in particulate matter is crucial given the role atmospheric particulates play in transport and cycling. While some halogens (fluorine and chlorine) are often included in aerosol studies, iodine and bromine have rarely been examined, especially outside of a marine environment. Focus on this environment is, in part, due to the existence of biogenic marine sources for both halogens. However, examining iodine and bromine in an urban environment has the potential to provide key insights into the transport and processing of these species in the atmosphere. As Tempe is set within a desert environment, bromine concentration is expected to be relatively high due to its presence in Earth’s crust, while iodine is expected to exist in higher concentrations near the coast. To detect presence and concentration, ICP-MS analysis was performed on samples taken in Tempe, AZ as well as sites in Bakersfield, CA and Davis, CA, which yielded preliminary results in line with these expectations. A secondary set of samples were taken in Tempe, AZ during dust storms, haboobs, and winter holidays. CIC was used to determine the organic fraction. In doing so, this study aims to identify species present in an urban environment as well as potential transportation pathways.
This work first compares carbon isotope measurements (δ13C) of particulate matter and fog from locations across the globe to assess how different primary aerosol sources are reflected in the atmosphere. Three field campaigns are then discussed that highlight different aspects of PM formation, composition, and processing. In Tempe, AZ, seasonal and size-dependent differences in the δ13C of total carbon and n-alkanes in PM were studied. δ13C was influenced by seasonal trends, including inversion, transport, population density, and photochemical activity. Variations in δ13C among particle size fractions were caused by sources that generate particles in different size modes.
An analysis of PM from urban and suburban sites in northeastern France shows how both fog and rain can cause measurable changes in the δ13C of PM. The δ13C of PM was consistent over time when no weather events occurred, but particles were isotopically depleted by up to 1.1‰ in the presence of fog due to preferential scavenging of larger isotopically enriched particles. Finally, the δ13C of the dissolved organic carbon in fog collected on the coast of Southern California is discussed. Here, temporal depletion of the δ13C of fog by up to 1.2‰ demonstrates its use in observing the scavenging and deposition of organic PM.
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In arid environments like Phoenix, many professional and residential outdoor spaces are cooled by the use of misting systems. These systems spray a fine mist of water droplets that cool down the surrounding air through the endothermic evaporation process. When the water droplets evaporate, they leave behind dissolved material that is present in the water, generating ambient particulate matter (PM). Thus, misting systems are a point source of PM. Currently there is no information on their impact on air quality in close proximity to these systems, or on the chemical composition of the particulate matter generated by the evaporating mist.
In this project, PM concentrations are found to increase on average by a factor of 8 from ambient levels in the vicinity of a residential misting system in controlled experiments. PM concentrations in public places that use misting systems are also investigated. The PM10 concentrations in public places ranged from 0.102 ± 0.010 mg m-3 to 1.47 ± 0.15 mg m-3, and PM2.5 ranged from 0.095 ± 0.010 mg m-3 to 0.99 ± 0.10 mg m-3. Air quality index (AQI) values based on these concentrations indicate that these levels of PM range from unhealthy to hazardous in most cases. PM concentrations tend to decrease after remaining relatively constant with increasing distance from misting systems. Chemical data reveal that chloride and magnesium ions may be used as tracers of aerosolized water from misting systems. The average chloride concentration was 71 µg m-3 in misting samples and below the detection limit for Cl- (< 8.2 µg m-3) in ambient samples. The average magnesium concentration was 11.7 µg m-3 in misting samples and 0.23 µg m-3 in ambient samples.