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Description
Dry and steam NanoBonding™ are conceived and researched to bond Si-based surfaces, via nucleation and growth of a two-dimensional SiOxHy or hydrated SiOxHy interphase connecting surfaces at the nanoscale across macroscopic domains. The motivation is to create strong, long lasting, hermetically bonded sensors with their electronics for the development of an artificial pancreas and to bond solar cells to glass panels for robust photovoltaic technology. The first step in NanoBonding™ is to synthesize smooth surfaces with 20 nm wide atomic terraces via a precursor phase, ß-cSiO2 on Si(100) and oxygen-deficient SiOx on the silica using the Herbots-Atluri process and Entrepix’s spin etching. Smooth precursor phases act as geometric and chemical template to nucleate and grow macroscopic contacting domains where cross bridging occurs via arrays of molecular strands in the hydrated SiOxHy interphase. Steam pressurization is found to catalyze NanoBonding™ consistently, eliminating the need for direct mechanical compression that limits the size and shape of wafers to be bonded in turn, reducing the cost of processing. Total surface energy measurements via 3 Liquids Contact Angle Analysis (3L CAA) enables accurate quantitative analysis of the total surface energy and each of its components. 3L CAA at each step in the process shows that surface energy drops to 42.4 ± 0.6 mJ/m2 from 57.5 ± 1.4 mJ/m2 after the Herbots-Atluri clean of an “As Received” wafer. 3L CAA after steam pressurization Nanobonding™ shows almost complete elimination from 13.8 mJ/m2 ± 1.0 to 0.002 ±- 0.0002 mJ/m2 in the contribution of acceptors to the total free surface energy, and an increase from 0.2 ± .03 to 23.8± 1.6 mJ/m2 in the contribution of donors. This is consistent with an increase in hydroxylation of the ß-cSiO2 surface as a consistent precursor phase for cross-bridging. This research optimizes the use of glycerin, water, and α-bromo-naphtalene in the use of 3L CAA to effectively quantify the components of total free surface energy which helps to better understand the most consistent method for NanoBonding™.
ContributorsBennett-Kennett, Ross Buchanan (Author) / Culbertson, Robert (Thesis director) / Herbots, Nicole (Committee member) / Foy, Joseph (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / Department of Physics (Contributor) / School of Historical, Philosophical and Religious Studies (Contributor)
Created2013-05
Description
We designed and constructed a cryostat setup for MKID detectors. The goal for the cryostat is to have four stages: 40K, 4K, 1K and 250mK. Prior to the start of my thesis, the cryostat was reaching 70K and 9K on the first and second stages respectively. During the first semester of my thesis I worked on getting the second stage to reach below 4K such that it would be cold enough to add a sorption fridge to reach 250mK. Various parts were machined for the cryostat and some tweaks were made to existing pieces. The largest changes were we thinned our stainless steel supports from 2mm to 10mil and we added roughly 6-10 layers of multi-layer insulation to the first and second stages. Our result was that we now reach temperatures of 36K and 2.6K on the first and second stages respectively. Next we added the sorption fridge to the 4K stage by having the 4K stage remachined to allow the sorption fridge to be mounted to the stage. Then I designed a final, two stage, setup for the 1K and 250mK stages that has maximum capabilities of housing a six inch wafer for testing. The design was sent to a machinist, but the parts were unfinished by the end of my thesis, so the parts and stage were not tested. Once the cryostat was fully tested and proven to reach the necessary temperatures, preliminary testing was done on a Microwave Kinetic Inductance Detector (MKID) provided by Stanford. Data was collected on the resonance and quality factor as they shifted with final stage temperature (5K to 285mK) and with input power (60dB to 15dB). The data was analyzed and the results agreed within expectations, as the resonant frequency and quality factor shifted down with increased temperature on the MKID. Finally, a noise characterization setup was designed to test the noise of devices, but was not fully implemented.
ContributorsAbers, Paul (Author) / Mauskopf, Phil (Thesis director) / Groppi, Chris (Committee member) / Department of Physics (Contributor) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
Description
In this project, we aim to fabricate PIN structure-like diodes for radiation detectors using Boron Nitride (BN). This fabrication is done by performing lithography and metal deposition processes on a Cubic Boron Nitride (cBN) of around 200 nm in thickness layer on top of a boron doped diamond substrate. The main goal is to create the most efficient and affordable alpha particle—and ideally neutron—detector in a radiation setting. Thus, making more accessible radiation detectors that can be more easily produced and disposed of, as well as minimizing the size of conventional detectors.
ContributorsGutierrez, Eric (Author) / Nemanich, Robert (Thesis director) / Zaniewski, Anna (Committee member) / Barrett, The Honors College (Contributor) / Department of Physics (Contributor)
Created2023-05
Description
In this project we are analyzing the diamond-titanium interface as it applies to diamond-based diode devices, including alpha particle, proton, and neutron detectors. This is done through the fabrication of an O-terminated B-doped diamond sample with a 20 Å Ti / 10 Å Pt overlayer which was then annealed and examined via X-ray photoelectron spectroscopy (XPS). It was discovered that after annealing the sample at temperatures ranging from 400 C - 900 C that TiC was not formed at any point during this experiment. Possible reasons for this include a lack of sufficient titanium in order to form TiC and over oxygenating the diamond surface before the metal was deposited.
ContributorsJohnson, Holly (Author) / Zaniewski, Anna (Thesis director) / Nemanich, Robert (Committee member) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
The Compact X-ray Light Source is an x-ray source at ASU that allows scientists to study the structures and dynamics of matter on an atomic scale. The radio frequency system that provides the power to accelerate electrons in the Compact X-ray Light Source must operate with a high degree of precision. This thesis measures the precision with which that system performs.
ContributorsBabic, Gregory (Author) / Graves, William (Thesis director) / Kitchen, Jennifer (Committee member) / Holl, Mark (Committee member) / Barrett, The Honors College (Contributor) / Electrical Engineering Program (Contributor) / Department of Physics (Contributor)
Created2022-05