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A well-insulated dark conventional rooftop can be hotter than any other urban surface, including pavements. Since rooftops cover around 20 – 25% of most urban areas, their role in the urban heat island effect is significant. In general, buildings exchange heat with the surroundings in three ways: heat release from

A well-insulated dark conventional rooftop can be hotter than any other urban surface, including pavements. Since rooftops cover around 20 – 25% of most urban areas, their role in the urban heat island effect is significant. In general, buildings exchange heat with the surroundings in three ways: heat release from the cooling/heating system, air exchange associated with exfiltration and relief air, and heat transfer between the building envelope and surroundings. Several recent studies show that the building envelope generates more heat release into the environment than any other building component.Current advancements in material science have enabled the development of materials and coatings with very high solar reflectance and thermal emissivity, and that can alter their radiative properties based on surface temperature. This dissertation is an effort to quantify the impact of recent developments in such technologies on urban air. The current study addresses three specific unresolved topics: 1) the relative importance of rooftop solar reflectance and thermal emissivity, 2) the role of rooftop radiative properties in different climates, and 3) the impact of temperature-adaptive exterior materials/coatings on building energy savings and urban cooling. The findings from this study show that the use of rooftop materials with solar reflectance above 0.9 maintain the surface temperature below ambient air temperature most of the time, even when the materials have conventional thermal emissivity (0.9). This research has demonstrated that for hot cities, rooftops with high solar reflectance and thermal emittance maximize building energy savings and always cool the surrounding air. For moderate climate regions, high solar reflectance and low thermal emittance result in the greatest building energy cost savings. This combination of radiative properties cools the air during the daytime and warms it at night. Finally, this research found that temperature-adaptive materials could play a significant role in reducing utility costs for poorly insulated buildings, but that they heat the surrounding air in the winter, irrespective of the rooftop insulation. Through the detailed analysis of building façade radiative properties, this dissertation offers climate-specific design guidance that can be used to simultaneously optimize energy costs while minimizing adverse warming of the surrounding environment.
ContributorsPrem Anand Jayaprabha, Jyothis Anand (Author) / Sailor, David (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Huang, Huei-Ping (Committee member) / Wang, Liping (Committee member) / Yeom, Dongwoo Jason (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Over the past few years, research into the use of doped diamond in electronics has seen an exponential growth. In the course of finding ways to reduce the contact resistivity, nanocarbon materials have been an interesting focus. In this work, the transfer length method (TLM) was used to investigate Ohmic

Over the past few years, research into the use of doped diamond in electronics has seen an exponential growth. In the course of finding ways to reduce the contact resistivity, nanocarbon materials have been an interesting focus. In this work, the transfer length method (TLM) was used to investigate Ohmic contact properties using the tri-layer stack Ti/Pt/Au on nitrogen-doped n-type conducting nano-carbon (nanoC) layers grown on (100) diamond substrates. The nanocarbon material was characterized using Secondary Ion Mass Spectrometry (SIMS), Scanning electron Microscopy (SEM) X-ray diffraction (XRD), Raman scattering and Hall effect measurements to probe the materials characteristics. Room temperature electrical measurements were taken, and samples were annealed to observe changes in electrical conductivity. Low specific contact resistivity values of 8 x 10^-5 Ωcm^2 were achieved, which was almost two orders of magnitude lower than previously reported values. The results were attributed to the increased nitrogen incorporation, and the presence of electrically active defects which leads to an increase in conduction in the nanocarbon. Further a study of light phosphorus doped layers using similar methods with Ti/Pt/Au contacts again yielded a low contact resistivity of about 9.88 x 10^-2 Ωcm^2 which is an interesting prospect among lightly doped diamond films for applications in devices such as transistors. In addition, for the first time, hafnium was substituted for Ti in the contact stack (Hf/Pt/Au) and studied on nitrogen doped nanocarbon films, which resulted in low contact resistivity values on the order of 10^-2 Ωcm^2. The implications of the results were discussed, and recommendations for improving the experimental process was outlined. Lastly, a method for the selective area growth of nanocarbon was developed and studied and the results provided an insight into how different characterizations can be used to confirm the presence of the nanocrystalline diamond material, the limitations due to the film thickness was explored and ideas for future work was proposed.
ContributorsAmonoo, Evangeline Abena (Author) / Thornton, Trevor (Thesis advisor) / Alford, Terry L (Thesis advisor) / Anwar, Shahriar (Committee member) / Theodore, David (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Scaling of the Metal-Oxide-Semiconductor Field Effect Transistor (MOSFET) towards shorter channel lengths, has lead to an increasing importance of quantum effects on the device performance. Until now, a semi-classical model based on Monte Carlo method for instance, has been sufficient to address these issues in silicon, and arrive at a

Scaling of the Metal-Oxide-Semiconductor Field Effect Transistor (MOSFET) towards shorter channel lengths, has lead to an increasing importance of quantum effects on the device performance. Until now, a semi-classical model based on Monte Carlo method for instance, has been sufficient to address these issues in silicon, and arrive at a reasonably good fit to experimental mobility data. But as the semiconductor world moves towards 10nm technology, many of the basic assumptions in this method, namely the very fundamental Fermi’s golden rule come into question. The derivation of the Fermi’s golden rule assumes that the scattering is infrequent (therefore the long time limit) and the collision duration time is zero. This thesis overcomes some of the limitations of the above approach by successfully developing a quantum mechanical simulator that can model the low-field inversion layer mobility in silicon MOS capacitors and other inversion layers as well. It solves for the scattering induced collisional broadening of the states by accounting for the various scattering mechanisms present in silicon through the non-equilibrium based near-equilibrium Green’s Functions approach, which shall be referred to as near-equilibrium Green’s Function (nEGF) in this work. It adopts a two-loop approach, where the outer loop solves for the self-consistency between the potential and the subband sheet charge density by solving the Poisson and the Schrödinger equations self-consistently. The inner loop solves for the nEGF (renormalization of the spectrum and the broadening of the states), self-consistently using the self-consistent Born approximation, which is then used to compute the mobility using the Green-Kubo Formalism.
ContributorsJayaram Thulasingam, Gokula Kannan (Author) / Vasileska, Dragica (Thesis advisor) / Ferry, David (Committee member) / Goodnick, Stephen (Committee member) / Allee, David (Committee member) / Arizona State University (Publisher)
Created2017
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Description
An efficient thermal solver is available in the CMC that allows modeling self-heating in the electrical simulations, which treats phonons as flux and solves the energy balance equation to quantify thermal effects. Using this solver, thermal simulations were performed on GaN-HEMTs in order to test effect of gate architectures on

An efficient thermal solver is available in the CMC that allows modeling self-heating in the electrical simulations, which treats phonons as flux and solves the energy balance equation to quantify thermal effects. Using this solver, thermal simulations were performed on GaN-HEMTs in order to test effect of gate architectures on the DC and RF performance of the device. A Π- gate geometry is found to suppress 19.75% more hot electrons corresponding to a DC power of 2.493 W/mm for Vgs = -0.6V (max transconductance) with respect to the initial T-gate. For the DC performance, the output current, Ids is nearly same for each device configuration over the entire bias range. For the RF performance, the current gain was evaluated over a frequency range 20 GHz to 120 GHz in each device for both thermal (including self-heating) and isothermal (without self-heating). The evaluated cutoff frequency is around 7% lower for the thermal case than the isothermal case. The simulated cutoff frequency closely follows the experimental cutoff frequency. The work was extended to the study of ultra-wide bandgap material (Diamond), where isotope effect causes major deterioration in thermal conductivity. In this case, bulk phonons are modeled as semiclassical particles solving the nonlinear Peierls - Boltzmann transport equation with a stochastic approach. Simulations were performed for 0.001% (ultra-pure), 0.1% and 1.07% isotope concentration (13C) of diamond, showing good agreement with the experimental values. Further investigation was performed on the effect of isotope on the dynamics of individual phonon branches, thermal conductivity and the mean free path, to identify the dominant phonon branch. Acoustic phonons are found to be the principal contributors to thermal conductivity across all isotope concentrations with transverse acoustic (TA2) branch is the dominant branch with a contribution of 40% at room temperature and 37% at 500K. Mean free path computations show the lower bound of device dimensions in order to obtain maximum thermal conductivity. At 300K, the lowest mean free path (which is attributed to Longitudinal Optical phonon) reduces from 24nm to 8 nm for isotope concentration of 0.001% and 1.07% respectively. Similarly, the maximum mean free path (which is attributed to Longitudinal Acoustic phonon) reduces from 4 µm to 3.1 µm, respectively, for the same isotope concentrations. Furthermore, PETSc (Portable, Extensible Toolkit for Scientific Computation) developed by Argonne National Lab, was included in the existing Cellular Monte Carlo device simulator as a Poisson solver to further extend the capability of the simulator. The validity of the solver was tested performing 2D and 3D simulations and the results were compared with the well-established multigrid Poisson solver.
ContributorsAcharjee, Joy (Author) / Saraniti, Marco (Thesis advisor) / Goodnick, Stephen (Committee member) / Thornton, Trevor (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2024
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Description
Integrating advanced materials with innovative manufacturing techniques has propelled the field of additive manufacturing into new frontiers. This study explores the rapid 3D printing of reduced graphene oxide/polymer composites using Micro-Continuous Liquid Interface Production (μCLIP), a cutting-edge technology known for its speed and precision. A printable ink is formulated with

Integrating advanced materials with innovative manufacturing techniques has propelled the field of additive manufacturing into new frontiers. This study explores the rapid 3D printing of reduced graphene oxide/polymer composites using Micro-Continuous Liquid Interface Production (μCLIP), a cutting-edge technology known for its speed and precision. A printable ink is formulated with reduced graphene oxide for μCLIP-based 3D printing. The research focuses on optimizing μCLIP parameters to fabricate reduced graphene composites efficiently. The study encompasses material synthesis, ink formulation and explores the resulting material's structural and electrical properties. The marriage of graphene's unique attributes with the rapid prototyping capabilities of μCLIP opens new avenues for scalable and rapid production in applications such as energy storage, sensors, and lightweight structural components. This work contributes to the evolving landscape of advanced materials and additive manufacturing, offering insights into the synthesis, characterization, and potential applications of 3D printed reduced graphene oxide/polymercomposites.
ContributorsRavishankar, Chayaank Bangalore (Author) / Chen, Xiangfan (Thesis advisor) / Bhate, Dhruv (Committee member) / Azeredo, Bruno (Committee member) / Arizona State University (Publisher)
Created2024
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Description
Recent advancements in communication standards, such as 5G demand transmitter hardware to support high data rates with high energy efficiency. With the revolution of communication standards, modulation schemes have become more complex and require high peak-to-average (PAPR) signals. In wireless transceiver hardware, the power amplifier (PA) consumes most of the

Recent advancements in communication standards, such as 5G demand transmitter hardware to support high data rates with high energy efficiency. With the revolution of communication standards, modulation schemes have become more complex and require high peak-to-average (PAPR) signals. In wireless transceiver hardware, the power amplifier (PA) consumes most of the transceiver’s DC power and is typically the bottleneck for transmitter linearity. Therefore, the transmitter’s performance directly depends on the PA. To support high PAPR signals, the PA must operate efficiently at its saturated and backoff output power. Maintaining high efficiency at both peak and backoff output power is challenging. One effective technique for addressing this problem is load modulation. Some of the prominent load-modulated PA architectures are outphasing PAs, load-modulated balanced amplifiers (LMBA), envelope elimination and restoration (EER), envelope tracking (ET), Doherty power amplifiers (DPA), and polar transmitters. Amongst them, the DPA is the most popular for infrastructure applications due to its simpler architecture compared to other techniques and linearizability with digital pre-distortion (DPD). Another crucial characteristic of progressing communication standards is wide signal bandwidths. High-efficiency power amplifiers like class J/F/F-1 and load-modulated PAs like the DPA exhibit narrowband performance because the amplifiers require precise output impedance terminations. Therefore, it is equally essential to develop adaptable PA solutions to process radio frequency (RF) signals with wide bandwidths. To support modern and future cellular infrastructure, RF PAs need to be innovated to increase the backoff power efficiency by two times or more and support ten times or more wider bandwidths than current state-of-the-art PAs. This work presents five RF PA analyses and implementations to support future wireless communications transmitter hardware. Chapter 2 presents an optimized output-matching network analysis and design to achieve extended output power backoff of the DPA. Chapters 3 and 4 unveil two bandwidth enhancement techniques for the DPA while maintaining extended output power backoff. Chapter 5 exhibits a dual-band hybrid mode PA design targeted for wideband applications. Chapter 6 presents a built-in self-test circuit integrated into a PA for output impedance monitoring. This can alleviate the PA performance degradation due to the variation in the PA's output load over frequency, process, and aging. All RF PAs in this dissertation are implemented using Gallium Nitride (GaN)-based high electron mobility transistors (HEMT), and the realized designs validate the proposed PAs' theories/architectures.
ContributorsRoychowdhury, Debatrayee (Author) / Kitchen, Jennifer (Thesis advisor) / Bakkaloglu, Bertan (Committee member) / Ozev, Sule (Committee member) / Aberle, James (Committee member) / Arizona State University (Publisher)
Created2024
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Description
When solving analysis, estimation, and control problems for Partial Differential Equations (PDEs) via computational methods, one must resolve three main challenges: (a) the lack of a universal parametric representation of PDEs; (b) handling unbounded differential operators that appear as parameters; and (c), enforcing auxiliary constraints such as Boundary conditions and

When solving analysis, estimation, and control problems for Partial Differential Equations (PDEs) via computational methods, one must resolve three main challenges: (a) the lack of a universal parametric representation of PDEs; (b) handling unbounded differential operators that appear as parameters; and (c), enforcing auxiliary constraints such as Boundary conditions and continuity conditions. To address these challenges, an alternative representation of PDEs called the `Partial Integral Equation' (PIE) representation is proposed in this work. Primarily, the PIE representation alleviates the problem of the lack of a universal parametrization of PDEs since PIEs have, at most, $12$ Partial Integral (PI) operators as parameters. Naturally, this also resolves the challenges in handling unbounded operators because PI operators are bounded linear operators. Furthermore, for admissible PDEs, the PIE representation is unique and has no auxiliary constraints --- resolving the last of the $3$ main challenges. The PIE representation for a PDE is obtained by finding a unique unitary map from the states of the PIE to the states of the PDE. This map shows a PDE and its associated PIE have equivalent system properties, including well-posedness, internal stability, and I/O behavior. Furthermore, this unique map also allows us to construct a well-defined dual representation that can be used to solve optimal control problems for a PDE. Using the equivalent PIE representation of a PDE, mathematical and computational tools are developed to solve standard problems in Control theory for PDEs. In particular, problems such as a test for internal stability, Input-to-Output (I/O) $L_2$-gain, $\hinf$-optimal state observer design, and $\hinf$-optimal full state-feedback controller design are solved using convex-optimization and Lyapunov methods for linear PDEs in one spatial dimension. Once the PIE associated with a PDE is obtained, Lyapunov functions (or storage functions) are parametrized by positive PI operators to obtain a solvable convex formulation of the above-stated control problems. Lastly, the methods proposed here are applied to various PDE systems to demonstrate the application.
ContributorsShivakumar, Sachin (Author) / Peet, Matthew (Thesis advisor) / Nedich, Angelia (Committee member) / Marvi, Hamidreza (Committee member) / Platte, Rodrigo (Committee member) / Berman, Spring (Committee member) / Arizona State University (Publisher)
Created2024
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Description
Alzheimer's disease (AD) and Alzheimer's Related Dementias (ADRD) is projected to affect 50 million people globally in the coming decades. Clinical research suggests that Mild Cognitive Impairment (MCI), a precursor to dementia, offers a critical window for lifestyle interventions to delay or prevent the progression of AD/ADRD. Previous research indicates

Alzheimer's disease (AD) and Alzheimer's Related Dementias (ADRD) is projected to affect 50 million people globally in the coming decades. Clinical research suggests that Mild Cognitive Impairment (MCI), a precursor to dementia, offers a critical window for lifestyle interventions to delay or prevent the progression of AD/ADRD. Previous research indicates that lifestyle changes, including increased physical exercise, reduced caloric intake, and mentally stimulating exercises, can reduce the risk of MCI. Early detection of MCI is challenging due to subtle and often unnoticed cognitive decline, traditionally monitored through infrequent clinical tests. As part of this research, the Smart Driving System was proposed, a novel, unobtrusive, and economical technology to detect early stages of neurodegenerative diseases. This system, leveraging a multi-modal biosensing array (MMS) and AI algorithms, assesses daily driving behavior, offering insights into a driver's cognitive function. The ultimate goal is to develop the Smart Driving Device and App, integrating it into vehicles, and validating its effectiveness in detecting MCI through comprehensive pilot studies. The Smart Driving System represents a breakthrough in AD/ADRD management, promising significant improvements in early detection and offering a scalable, cost-effective solution for monitoring cognitive health in real-world settings.
ContributorsSerhan, Peter (Author) / Forzani, Erica (Thesis advisor) / Wu, Teresa (Committee member) / Hihath, Joshua (Committee member) / Arizona State University (Publisher)
Created2024
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Description
The measurement of the radiation and convection that the human body experiences are important for ensuring safety in extreme heat conditions. The radiation from the surroundings on the human body is most often measured using globe or cylindrical radiometers. The large errors stemming from differences in internal and exterior temperatures

The measurement of the radiation and convection that the human body experiences are important for ensuring safety in extreme heat conditions. The radiation from the surroundings on the human body is most often measured using globe or cylindrical radiometers. The large errors stemming from differences in internal and exterior temperatures and indirect estimation of convection can be resolved by simultaneously using three cylindrical radiometers (1 cm diameter, 9 cm height) with varying surface properties and internal heating. With three surface balances, the three unknowns (heat transfer coefficient, shortwave, and longwave radiation) can be solved for directly. As compared to integral radiation measurement technique, however, the bottom mounting using a wooden-dowel of the three-cylinder radiometers resulted in underestimated the total absorbed radiation. This first part of this thesis focuses on reducing the size of the three-cylinder radiometers and an alternative mounting that resolves the prior issues. In particular, the heat transfer coefficient in laminar wind tunnel with wind speed of 0.25 to 5 m/s is measured for six polished, heated cylinders with diameter of 1 cm and height of 1.5 to 9 cm mounted using a wooden dowel. For cylinders with height of 6 cm and above, the heat transfer coefficients are independent of the height and agree with the Hilpert correlation for infinitely long cylinder. Subsequently, a side-mounting for heated 6 cm tall cylinder with top and bottom metallic caps is developed and tested within the wind tunnel. The heat transfer coefficient is shown to be independent of the flow-side mounting and in agreement with the Hilpert correlation. The second part of this thesis explores feasibility of employing the three-cylinder concept to measuring all air-flow parameters relevant to human convection including mean wind speed, turbulence intensity and length scale. Heated cylinders with same surface properties but varying diameters are fabricated. Uniformity of their exterior temperature, which is fundamental to the three-cylinder anemometer concept, is tested during operation using infrared camera. To provide a lab-based method to measure convection from the cylinders in turbulent flow, several designs of turbulence-generating fractal grids are laser-cut and introduced into the wind tunnel.
ContributorsGupta, Mahima (Author) / Rykaczewski, Konrad (Thesis advisor) / Pathikonda, Gokul (Thesis advisor) / Middel, Ariane (Committee member) / Arizona State University (Publisher)
Created2024