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Discovering Puerto Rican art song: a research project on four art song works by Héctor Campos Parsi
Finally, I leverage these large biochemical datasets, in conjunction with planetary observations and computational tools, to provide a methodological foundation for the quantitative assessment of biology’s viability amongst other geospheres. Investigating a case study of alkaliphilic prokaryotes in the context of Enceladus, I find that the chemical compounds observed on Enceladus thus far would be insufficient to allow even these extremophiles to produce the compounds necessary to sustain a viable metabolism. The environmental precursors required by these organisms provides a reference for the compounds which should be prioritized for detection in future planetary exploration missions. The results of this framework have further consequences in the context of planetary protection, and hint that forward contamination may prove infeasible without meticulous intent. Taken together these results point to a deeper level of organization in biochemical networks than what has been understood so far, and suggests the existence of common organizing principles operating across different levels of biology and planetary chemistry.
(MSR) mission, Mars 2020, will be NASA's next step towards this goal, carrying an instrument suite that can identify samples containing potential biosignatures. Those samples will be later returned to Earth for detailed analysis. This dissertation is intended to inform strategies for fossil biosignature detection in Mars analog samples targeted for their high biosignature preservation potential (BPP) using in situ rover-based instruments. In chapter 2, I assessed the diagenesis and BPP of one relevant analog habitable Martian environment: a playa evaporite sequence within the Verde Formation, Arizona. Coupling outcrop-scale observations with laboratory analyses, results revealed four diagenetic pathways, each with distinct impacts on BPP. When MSR occurs, the sample mass returned will be restricted, highlighting the importance of developing instruments that can select the most promising samples for MSR. Raman spectroscopy is one favored technique for this purpose. Three Raman instruments will be sent onboard two upcoming Mars rover missions for the first time. In chapters 3-4, I investigated the challenges of Raman to identify samples for MSR. I examined two Raman systems, each optimized in a different way to mitigate a major problem commonly suffered by Raman instruments: background fluorescence. In Chapter 3, I focused on visible laser excitation wavelength (532 nm) gated (or time-resolved Raman, TRR) spectroscopy. Results showed occasional improvement over conventional Raman for mitigating fluorescence in samples. It was hypothesized that results were wavelength-dependent and that greater fluorescence reduction was possible with UV laser excitation. In Chapter 4, I tested this hypothesis with a time-resolved UV (266 nm) gated Raman and UV fluorescence spectroscopy capability. I acquired Raman and fluorescence data sets on samples and showed that the UV system enabled identifications of minerals and biosignatures in samples with high confidence. The results obtained in this dissertation may inform approaches for MSR by: (1) refining models for biosignature preservation in habitable Mars environments; (2) improving sample selection and caching strategies, which may increase the success of Earth-based biogenicity studies; and (3) informing the development of Raman instruments for upcoming rover-based missions.
Assembly theory as a way of defining the biotic/abiotic boundary has been established for molecules, but not yet for crystal structures. This is an assembly algorithm that calculates the complexity of biotic and abiotic minerals in order to constrain the quantitative fundamentals of "life". The calculation utilizes the Hermann-Mauguin space group symmetry and Wyckoff sites of mineral unit cells to calculate the path-building complexity of a crystal structure. 5,644 minerals from the American Mineralogist COD database were run through the algorithm. The five structures with the highest information complexity were a mix of biotic and abiotic minerals, indicating that further calculations on larger datasets would be pertinent. Furthermore, an expansion of the definition of mineral to include biotically synthesized solids would further research efforts aimed at using minerals as possible biomarkers.
During the Dawn mission, bright spots were discovered on the surface of the dwarf planet Ceres, which were determined to be evaporite deposits of sodium carbonate, ammonium carbonate, and hydrohalite. These deposits are significant because they indicate the presence of subsurface water and potential geologic activity on Ceres. These evaporites form from the brine-water mixture in the deep Ceres reservoir, which likely possesses the conditions ideal for forming complex organics. Here, we report the results of a suite of laboratory techniques (CHN Elemental Analyzer, Secondary Ion Mass Spectrometry, Fourier-Transform Infrared Spectroscopy, Gas Chromatography, and Brunauer-Emmett-Teller Analysis) for quantifying the likelihood of primordial carbon survival and distribution in analog materials found on Ceres, particularly in salt evaporates. We are specifically looking at if the amino acid glycine can be preserved in sodium chloride crystals. Our results conclude that if the Ceres brine reservoir is saturated with organics, and with the lower limits that we have for our instrumentation thus far, these techniques should be more than sufficient to measure glycine content should we ever receive samples from Ceres.
In order to gauge the true habitability potential of a given planetary system, it is extremely important to characterize the host-star's mass, specific chemical composition, and thus the timescale over which the star will evolve. It is also necessary to assess the likelihood that a planet found in the "instantaneous" habitable zone has actually had sufficient time to become "detectably" habitable. This catalog provides accurate stellar evolution predictions for a large collection of theoretical host-stars; the models are of particular utility in that they represent the real variation in stellar parameters that have been observed in nearby stars.