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This report will review the mechanical and microstructural properties of the refractory element rhenium (Re) deposited using Laser Additive Manufacturing (LAM). With useable structural strength over 2200 °C, existing applications up to 2760 °C, very high strength, ductility and chemical resistance, interest in Re is understandable. This study includes data

This report will review the mechanical and microstructural properties of the refractory element rhenium (Re) deposited using Laser Additive Manufacturing (LAM). With useable structural strength over 2200 °C, existing applications up to 2760 °C, very high strength, ductility and chemical resistance, interest in Re is understandable. This study includes data about tensile properties including tensile data up to 1925 °C, fracture modes, fatigue and microstructure including deformation systems and potential applications of that information. The bulk mechanical test data will be correlated with nanoindentation and crystallographic examination. LAM properties are compared to the existing properties found in the literature for other manufacturing processes. The literature indicates that Re has three significant slip systems but also twins as part of its deformation mechanisms. While it follows the hcp metal characteristics for deformation, it has interesting and valuable extremes such as high work hardening, potentially high strength, excellent wear resistance and superior elevated temperature strength. These characteristics are discussed in detail.
ContributorsAdams, Robbie (Author) / Chawla, Nikhilesh (Thesis advisor) / Adams, James (Committee member) / Krause, Stephen (Committee member) / Arizona State University (Publisher)
Created2012
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Description
In this research, the effect of the crystal structure of the parent phase on the morphology of nanoporous gold is explored. Specifically, Cu-Au alloys are studied. For this experiment, Cu0.75Au0.25 is heat treated to achieve an ordered phase Cu3Au and a disordered random solid solution, face centered cubic, Cu0.75Au0.25 phase,

In this research, the effect of the crystal structure of the parent phase on the morphology of nanoporous gold is explored. Specifically, Cu-Au alloys are studied. For this experiment, Cu0.75Au0.25 is heat treated to achieve an ordered phase Cu3Au and a disordered random solid solution, face centered cubic, Cu0.75Au0.25 phase, which are then dealloyed to form nanoporous gold (NPG). Using a morphology digital image analysis software called AQUAMI, SEM images of the NPG morphology were characterized to collect data on the ligament length, ligament diameter, porosity size, etc. of the samples. It was determined that the NPG formed from the ordered parent phase had an average ligament diameter that was 10 nm larger than the NPG formed from the disordered parent phase. This may be due to the ordered crystal structure allowing for faster gold diffusion and coarsening resulting in an increased average ligament size. Further future work is needed in order to obtain further evidence to support this hypothesis.
ContributorsTse, Ariana Yusof (Author) / Sieradzki, Karl (Thesis director) / Wang, Qing Hua (Committee member) / Materials Science and Engineering Program (Contributor) / Walter Cronkite School of Journalism & Mass Comm (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
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This paper discusses the possibility of utilizing 2D molybdenum disulfide (MoS2) as a nanozyme to detect dopamine colorimetric assays, first by detecting color change in liquid solutions due to oxidation and then second on paper-based assays. MoS2 samples dispersed in methylcellulose (MC) solution were prepared using liquid-phase exfoliation through sonication.

This paper discusses the possibility of utilizing 2D molybdenum disulfide (MoS2) as a nanozyme to detect dopamine colorimetric assays, first by detecting color change in liquid solutions due to oxidation and then second on paper-based assays. MoS2 samples dispersed in methylcellulose (MC) solution were prepared using liquid-phase exfoliation through sonication. The dopamine (DOPA) and hydrogen peroxide (H¬¬2O2) solutions were prepared separately in specific concentrations. The solutions were mixed in a well plate and colorimetric results were analyzed by a plate reader, revealing a quantitative relationship between dopamine concentration and absorbance. Subsequent testing was conducted using paper assays, where combined solutions of DOPA and H2O2 were dropped onto paper with printed wax wells that contained dried MoS2. An analysis of the color change was conducted using a smartphone application called Color Grab to detect the red, green, and blue (RGB) values. Plotting the RGB results across the dopamine concentrations revealed a positively correlated relationship between the two factors, suggesting that a predictive model could be developed to predict dopamine concentrations based on measured colorimetric values.
ContributorsNalla, Akshay (Co-author, Co-author) / Wang, Qing Hua (Thesis director) / Green, Alexander (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / Materials Science and Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
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Description
Suction stabilized floats have been implemented into a variety of applications such as supporting wind turbines in off-shore wind farms and for stabilizing cargo ships. This thesis proposes an alternative use for the technology in creating a system of suction stabilized floats equipped with real time location modules to hel

Suction stabilized floats have been implemented into a variety of applications such as supporting wind turbines in off-shore wind farms and for stabilizing cargo ships. This thesis proposes an alternative use for the technology in creating a system of suction stabilized floats equipped with real time location modules to help first responders establish a localized coordinate system to assist in rescues. The floats create a stabilized platform for each anchor module due to the inverse slack tank effect established by the inner water chamber. The design of the float has also been proven to be stable in most cases of amplitudes and frequencies ranging from 0 to 100 except for when the frequency ranges from 23 to 60 Hz for almost all values of the amplitude. The modules in the system form a coordinate grid based off the anchors that can track the location of a tag module within the range of the system using ultra-wideband communications. This method of location identification allows responders to use the system in GPS denied environments. The system can be accessed through an Android app with Bluetooth communications in close ranges or through internet of things (IoT) using a module as a listener, a Raspberry Pi and an internet source. The system has proven to identify the location of the tag in moderate ranges with an approximate accuracy of the tag location being 15 cm.
ContributorsDye, Michaela (Author) / Redkar, Sangram (Thesis advisor) / Sugar, Thomas (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2020
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Description
There has been a decrease in the fertility rate over the years due to today’s younger generation facing more pressure in the workplace and their personal lives. With an aging population, more and more older people with limited mobility will require nursing care for their daily activities. There are several

There has been a decrease in the fertility rate over the years due to today’s younger generation facing more pressure in the workplace and their personal lives. With an aging population, more and more older people with limited mobility will require nursing care for their daily activities. There are several applications for wearable sensor networks presented in this paper. The study will also present a motion capture system using inertial measurement units (IMUs) and a pressure-sensing insole with a control system for gait assistance using wearable sensors. This presentation will provide details on the implementation and calibration of the pressure-sensitive insole, the IMU-based motion capture system, as well as the hip exoskeleton robot. Furthermore, the estimation of the Ground Reaction Force (GRF) from the insole design and implementation of the motion tracking using quaternion will be discussed in this document.
ContributorsLi, Xunguang (Author) / Redkar, Sangram (Thesis advisor) / Sugar, Thomas (Committee member) / Subramanian, Susheelkumar (Committee member) / Arizona State University (Publisher)
Created2022
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Description
This work endeavors to lay a solid foundation for the exploration and the considerations of exoskeletons, exosuits, and medical devices concerning proprioceptive feedback. This investigation is situated at the nexus of engineering, neuroscience, and rehabilitation medicine, striving to cultivate a holistic understanding of how mechanical augmentation, interfaced synergistically with human

This work endeavors to lay a solid foundation for the exploration and the considerations of exoskeletons, exosuits, and medical devices concerning proprioceptive feedback. This investigation is situated at the nexus of engineering, neuroscience, and rehabilitation medicine, striving to cultivate a holistic understanding of how mechanical augmentation, interfaced synergistically with human proprioception, can foster enhanced mobility and safety. This is especially pertinent for individuals with compromised motor functions.British Neurologist Oliver Wolf Sacks in 1985 published “The Man who Mistook His Wife for a Hat” a series of his most memorable neurological case describing the brain's strangest pathways. One of these cases is “The Disembodied Lady”, Christina a 27-year-old woman that lost entirely the sense of proprioception due to polyneuropathy. This caused her to not be able to control her body, and she declares that “I feel the wind on my arms and face, and then I know, faintly, I have arms and a face. It’s not the real thing, but it’s something—it lifts this horrible, dead veil for a while. ” Finally, she was able to control her body using vision alone. Dr. Sacks introduced, for the first time, the importance of proprioception, as the sense of position of body parts relative to other parts of the body, to western culture. This document’s mission is to identify unexplored concepts in the literature regarding exoskeletons, wearables and assistive technology and a user’s proprioception, embodiment and utilization when wearing devices. Dr. Philipp Beckerle suggests the need to research the connections between wearable hardware and human sense of proprioception. He also emphasizes the need for functional assessment protocols for wearables devices and the role of embodiment. He criticizes the current commercially available upper-limb prostheses since they only restore limited functions and therefore impede embodiment. This document’s goal is to identify operative solutions through the adaptation of existing technologies and to use effective solutions to improve the quality of life of people suffering from pathologies or traumatic injuries.
ContributorsVignola, Claudio (Author) / Sugar, Thomas (Thesis advisor) / Redkar, Sangram (Committee member) / McDaniels, Troy (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Fine control of standing postural balance is essential for completing various tasks in daily activities, which might be compromised when interacting with dynamically challenging environments (e.g., moving ground). Among various biofeedback to improve postural balance control, vibrotactile feedback has an advantage of providing supplementary information about balance control without disturbing

Fine control of standing postural balance is essential for completing various tasks in daily activities, which might be compromised when interacting with dynamically challenging environments (e.g., moving ground). Among various biofeedback to improve postural balance control, vibrotactile feedback has an advantage of providing supplementary information about balance control without disturbing other core functions (e.g., seeing and hearing). This paper investigated the effectiveness of a waist vibrotactile feedback device to improve postural control during standing balance on a dynamically moving ground simulated by a robotic balance platform. Four vibration motors of the waist device applied vibration feedback in the anterior-posterior and medio-lateral direction based on the 2-dimensional sway angle, measured by an inertia measurement unit. Experimental results with 15 healthy participants demonstrated that the waist vibrotactile feedback is effective in improving postural control, evidenced by improvements in center-of-mass and center-of-pressure stability measures. In addition, this study confirmed the effectiveness of the waist vibrotactile feedback in improving standing balance control even under muscle fatigue induced by lower body exercise. The study further confirmed that the waist feedback is more effective in people with lower baseline balance performance in both normal and fatigue conditions.
ContributorsJo, Kwanghee (Author) / Lee, Hyunglae (Thesis advisor) / Sugar, Thomas (Committee member) / Peterson, Daniel (Committee member) / Arizona State University (Publisher)
Created2022
Description

Cornhole, traditionally seen as tailgate entertainment, has rapidly risen in popularity since the launching of the American Cornhole League in 2016. However, it lacks robust quality control over large tournaments, since many of the matches are scored and refereed by the players themselves. In the past, there have been issues

Cornhole, traditionally seen as tailgate entertainment, has rapidly risen in popularity since the launching of the American Cornhole League in 2016. However, it lacks robust quality control over large tournaments, since many of the matches are scored and refereed by the players themselves. In the past, there have been issues where entire competition brackets have had to be scrapped and replayed because scores were not handled correctly. The sport is in need of a supplementary scoring solution that can provide quality control and accuracy over large matches where there aren’t enough referees present to score games. Drawing from the ACL regulations as well as personal experience and testimony from ACL Pro players, a list of requirements was generated for a potential automatic scoring system. Then, a market analysis of existing scoring solutions was done, and it found that there are no solutions on the market that can automatically score a cornhole game. Using the problem requirements and previous attempts to solve the scoring problem, a list of concepts was generated and evaluated against each other to determine which scoring system design should be developed. After determining that the chosen concept was the best way to approach the problem, the problem requirements and cornhole rules were further refined into a set of physical assumptions and constraints about the game itself. This informed the choice, structure, and implementation of the algorithms that score the bags. The prototype concept was tested on their own, and areas of improvement were found. Lastly, based on the results of the tests and what was learned from the engineering process, a roadmap was set out for the future development of the automatic scoring system into a full, market-ready product.

ContributorsGillespie, Reagan (Author) / Sugar, Thomas (Thesis director) / Li, Baoxin (Committee member) / Barrett, The Honors College (Contributor) / Engineering Programs (Contributor) / Dean, W.P. Carey School of Business (Contributor)
Created2023-05
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Description
With the extensive technological progress made in the areas of drives, sensors and processing, exoskeletons and other wearable devices have become more feasible. However, the stringent requirements in regards to size and weight continue to exert a strong influence on the system-wide design of these devices and present many obstacles

With the extensive technological progress made in the areas of drives, sensors and processing, exoskeletons and other wearable devices have become more feasible. However, the stringent requirements in regards to size and weight continue to exert a strong influence on the system-wide design of these devices and present many obstacles to a successful solution. On the other hand, while the area of controls has seen a significant amount of progress, there also remains a large potential for improvements. This dissertation approaches the design and control of wearable devices from a systems perspective and provides a framework to successfully overcome the often-encountered obstacles with optimal solutions. The electronics, drive and control system design for the HeSA hip exoskeleton project and APEx hip exoskeleton project are presented as examples of how this framework is used to design wearable devices. In the area of control algorithms, a real-time implementation of the Fast Fourier Transform (FFT) is presented as an alternative approach to extracting amplitude and frequency information of a time varying signal. In comparison to the peak search method (PSM), the FFT allows extracting basic gait signal information at a faster rate because time windows can be chosen to be less than the fundamental gait frequency. The FFT is implemented on a 16-bit processor and the results show the real-time detection of amplitude and frequency coefficients at an update rate of 50Hz. Finally, a novel neural networks based approach to detecting human gait activities is presented. Existing neural networks often require vast amounts of data along with significant computer resources. Using Neural Ordinary Differential Equations (Neural ODEs) it is possible to distinguish between seven different daily activities using a significantly smaller data set, lower system resources and a time window of only 0.1 seconds.
ContributorsBoehler, Alexander (Author) / Sugar, Thomas (Thesis advisor) / Redkar, Sangram (Committee member) / Hollander, Kevin (Committee member) / Arizona State University (Publisher)
Created2021
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Organic materials have emerged as an attractive component of electronics over the past few decades, particularly in the development of efficient and stable organic light-emitting diodes (OLEDs) and organic neuromorphic devices. The electrical, chemical, physical, and optical studies of organic materials and their corresponding devices have been conducted for efficient

Organic materials have emerged as an attractive component of electronics over the past few decades, particularly in the development of efficient and stable organic light-emitting diodes (OLEDs) and organic neuromorphic devices. The electrical, chemical, physical, and optical studies of organic materials and their corresponding devices have been conducted for efficient and stable electronics. The development of efficient and stable deep blue OLED devices remains a challenge that has obstructed the progress of large-scale OLED commercialization. One approach was taken to achieve a deep blue emitter through a color tuning strategy. A new complex, PtNONS56-dtb, was designed and synthesized by controlling the energy gap between T1 and T2 energy states to achieve narrowed and blueshifted emission spectra. This emitter material showed an emission spectrum at 460 nm with a FWHM of 59 nm at room temperature in PMMA, and the PtNONS56-dtb-based device exhibited a peak EQE of 8.5% with CIE coordinates of (0.14, 0.27). A newly developed host and electron blocking materials were demonstrated to achieve efficient and stable OLED devices. The indolocarbazole-based materials were designed to have good hole mobility and high triplet energy. BCN34 as an electron blocking material achieved the estimated LT80 of 12509 h at 1000 cd m-2 with a peak EQE of 30.3% in devices employing Pd3O3 emitter. Additionally, a device with bi-layer emissive layer structure, using BCN34 and CBP as host materials doped with PtN3N emitter, achieved a peak EQE of 16.5% with the LT97 of 351 h at 1000 cd m-2. A new neuromorphic device using Ru(bpy)3(PF6)2 as an active layer was designed to emulate the short-term characteristics of a biological synapse. This memristive device showed a similar operational mechanism with biological synapse through the movement of ions and electronic charges. Furthermore, the performance of the device showed tunability by adding salt. Ultimately, the device with 2% LiClO4 salt shows similar timescales to short-term plasticity characteristics of biological synapses.
ContributorsShin, Samuel (Author) / Li, Jian (Thesis advisor) / Adams, James (Committee member) / Alford, Terry (Committee member) / Arizona State University (Publisher)
Created2021