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Description

Nighttime visibility of pavement markings is provided by glass beads embedded into the striping surface. The glass beads take light from the vehicle headlamps and reflect it back to the driver. This phenomenon is known as retroreflection. Literature suggests that the amount of the bead embedded into the striping surface

Nighttime visibility of pavement markings is provided by glass beads embedded into the striping surface. The glass beads take light from the vehicle headlamps and reflect it back to the driver. This phenomenon is known as retroreflection. Literature suggests that the amount of the bead embedded into the striping surface has a profound impact on the intensity of the retroreflected light. In order to gain insight into how the glass beads provide retroreflection, an experiment was carried out to produce paint stripes with glass beads and measure the retroreflection. Samples were created at various application rates and embedment depths, in an attempt to verify the optimal embedment and observe the effect of application rate on retroreflection. The experiment was conducted using large, airport quality beads and small, road quality beads. Image analysis was used to calculate the degree to which beads were embedded and in an attempt to quantify bead distribution on the stripe surface. The results from the large beads showed that retroreflection was maximized when the beads were embedded approximately seventy percent by bead volume. The results also showed that as the application rate increased, the retroreflection increased, up to a point and then decreased. A model was developed to estimate the retroreflectivity given the amount of beads, bead spacing, and distribution of bead embedment. Results from the small beads were less conclusive, but did demonstrate that the larger beads are better at providing retroreflection. Avenues for future work in this area were identified as the experiment was conducted.

ContributorsStevens, Ryan David (Author) / Underwood, Shane (Thesis advisor) / Kaloush, Kamil (Committee member) / Mamlouk, Michael S. (Committee member) / Arizona State University (Publisher)
Created2014
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Description

The activity-based approach to travel demand analysis and modeling, which has been developed over the past 30 years, has received tremendous success in transportation planning and policy analysis issues, capturing the multi-way joint relationships among socio-demographic, economic, land use characteristics, activity participation, and travel behavior. The development of synthesizing population

The activity-based approach to travel demand analysis and modeling, which has been developed over the past 30 years, has received tremendous success in transportation planning and policy analysis issues, capturing the multi-way joint relationships among socio-demographic, economic, land use characteristics, activity participation, and travel behavior. The development of synthesizing population with an array of socio-demographic and socio-economic attributes has drawn remarkable attention due to privacy and cost constraints in collecting and disclosing full scale data. Although, there has been enormous progress in producing synthetic population, there has been less progress in the development of population evolution modeling arena to forecast future year population. The objective of this dissertation is to develop a well-structured full-fledged demographic evolution modeling system, capturing migration dynamics and evolution of person level attributes, introducing the concept of new household formations and apprehending the dynamics of household level long-term choices over time. A comprehensive study has been conducted on demography, sociology, anthropology, economics and transportation engineering area to better understand the dynamics of evolutionary activities over time and their impacts in travel behavior. This dissertation describes the methodology and the conceptual framework, and the development of model components. Demographic, socio-economic, and land use data from American Community Survey, National Household Travel Survey, Census PUMS, United States Time Series Economic Dynamic data and United States Center for Disease Control and Prevention have been used in this research. The entire modeling system has been implemented and coded using programming language to develop the population evolution module named `PopEvol' into a computer simulation environment. The module then has been demonstrated for a portion of Maricopa County area in Arizona to predict the milestone year population to check the accuracy of forecasting. The module has also been used to evolve the base year population for next 15 years and the evolutionary trend has been investigated.

ContributorsPaul, Sanjay (Author) / Pendyala, Ram M. (Thesis advisor) / Kaloush, Kamil (Committee member) / Ahn, Soyoung (Committee member) / Arizona State University (Publisher)
Created2014
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Description
With the increased penetration of solar PV, it has become considerable for the system planners and operators to recognize the impact of PV plant on the power system stability and reliable operation of grid. This enforced the development of adequate PV system models for grid planning and interconnection studies. Western

With the increased penetration of solar PV, it has become considerable for the system planners and operators to recognize the impact of PV plant on the power system stability and reliable operation of grid. This enforced the development of adequate PV system models for grid planning and interconnection studies. Western Electricity Coordinating Council (WECC) Renewable Energy Modeling Task Force has developed generator/converter, electrical controller and plant controller modules to represent positive sequence solar PV plant model for grid interconnection studies. This work performs the validation of these PV plant models against the field measured data. Sheer purpose of this validation effort is to authenticate model accuracy and their capability to represent dynamics of a solar PV plant. Both steady state and dynamic models of PV plant are discussed in this work. An algorithm to fine tune and determine the electrical controller and plant controller module gains is developed. Controller gains as obtained from proposed algorithm is used in PV plant dynamic simulation model. Model is simulated for a capacitor bank switching event and simulated plant response is then compared with field measured data. Validation results demonstrate that, the proposed algorithm is performing well to determine controller gains within the region of interest. Also, it concluded that developed PV plant models are adequate enough to capture PV plant dynamics.
ContributorsSoni, Sachin (Author) / Karady, George G. (Thesis advisor) / Undrill, John (Committee member) / Vittal, Vijay (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Monitoring of air pollutants is critical for many applications and studies. In

order to access air pollutants with high spatial and temporal resolutions, it is

necessary

Monitoring of air pollutants is critical for many applications and studies. In

order to access air pollutants with high spatial and temporal resolutions, it is

necessary to develop an affordable, small size and weight, low power, high

sensitivity and selectivity, and wireless enable device that can provide real time

monitoring of air pollutants. Three different kind of such devices are presented, they

are targeting environmental pollutants such as volatile organic components (VOCs),

nitrogen dioxide (NO2) and ozone. These devices employ innovative detection

methods, such as quartz crystal tuning fork coated with molecularly imprinted

polymer and chemical reaction induced color change colorimetric sensing. These

portable devices are validated using the gold standards in the laboratory, and their

functionality and capability are proved during the field tests, make them great tools

for various air quality monitoring applications.
ContributorsChen, Cheng, Ph.D (Author) / Tao, Nongjian (Thesis advisor) / Kiaei, Sayfe (Committee member) / Zhang, Yanchao (Committee member) / Tsow, Tsing (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Organic light emitting diodes (OLEDs) are a promising approach for display and solid state lighting applications. However, further work is needed in establishing the availability of efficient and stable materials for OLEDs with high external quantum efficiency's (EQE) and high operational lifetimes. Recently, significant improvements in the internal quantum efficiency

Organic light emitting diodes (OLEDs) are a promising approach for display and solid state lighting applications. However, further work is needed in establishing the availability of efficient and stable materials for OLEDs with high external quantum efficiency's (EQE) and high operational lifetimes. Recently, significant improvements in the internal quantum efficiency or ratio of generated photons to injected electrons have been achieved with the advent of phosphorescent complexes with the ability to harvest both singlet and triplet excitons. Since then, a variety of phosphorescent complexes containing heavy metal centers including Os, Ni, Ir, Pd, and Pt have been developed. Thus far, the majority of the work in the field has focused on iridium based complexes. Platinum based complexes, however, have received considerably less attention despite demonstrating efficiency's equal to or better than their iridium analogs. In this study, a series of OLEDs implementing newly developed platinum based complexes were demonstrated with efficiency's or operational lifetimes equal to or better than their iridium analogs for select cases.

In addition to demonstrating excellent device performance in OLEDs, platinum based complexes exhibit unique photophysical properties including the ability to form excimer emission capable of generating broad white light emission from a single emitter and the ability to form narrow band emission from a rigid, tetradentate molecular structure for select cases. These unique photophysical properties were exploited and their optical and electrical properties in a device setting were elucidated.

Utilizing the unique properties of a tridentate Pt complex, Pt-16, a highly efficient white device employing a single emissive layer exhibited a peak EQE of over 20% and high color quality with a CRI of 80 and color coordinates CIE(x=0.33, y=0.33). Furthermore, by employing a rigid, tetradentate platinum complex, PtN1N, with a narrow band emission into a microcavity organic light emitting diode (MOLED), significant enhancement in the external quantum efficiency was achieved. The optimized MOLED structure achieved a light out-coupling enhancement of 1.35 compared to the non-cavity structure with a peak EQE of 34.2%. In addition to demonstrating a high light out-coupling enhancement, the microcavity effect of a narrow band emitter in a MOLED was elucidated.
ContributorsEcton, Jeremy David (Author) / Li, Jian (Thesis advisor) / Adams, James (Committee member) / Alford, Terry (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Owner organizations in the architecture, engineering, and construction (AEC) industry are presented with a wide variety of project delivery approaches. Implementation of these approaches, while enticing due to their potential to save money, reduce schedule delays, or improve quality, is extremely difficult to accomplish and requires a concerted change management

Owner organizations in the architecture, engineering, and construction (AEC) industry are presented with a wide variety of project delivery approaches. Implementation of these approaches, while enticing due to their potential to save money, reduce schedule delays, or improve quality, is extremely difficult to accomplish and requires a concerted change management effort. Research in the field of organizational behavior cautions that perhaps more than half of all organizational change efforts fail to accomplish their intended objectives. This study utilizes an action research approach to analyze change message delivery within owner organizations, model owner project team readiness and adoption of change, and identify the most frequently encountered types of resistance from lead project members. The analysis methodology included Spearman's rank order correlation, variable selection testing via three methods of hierarchical linear regression, relative weight analysis, and one-way ANOVA. Key findings from this study include recommendations for communicating the change message within owner organizations, empirical validation of critical predictors for change readiness and change adoption among project teams, and identification of the most frequently encountered resistive behaviors within change implementation in the AEC industry. A key contribution of this research is the recommendation of change management strategies for use by change practitioners.
ContributorsLines, Brian (Author) / Sullivan, Kenneth (Thesis advisor) / Wiezel, Avi (Committee member) / Badger, William (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Today's energy market is facing large-scale changes that will affect all market players. Near the top of that list is the rapid deployment of residential solar photovoltaic (PV) systems. Yet that growing trend will be influenced multiple competing interests between various stakeholders, namely the utility, consumers and technology provides. This

Today's energy market is facing large-scale changes that will affect all market players. Near the top of that list is the rapid deployment of residential solar photovoltaic (PV) systems. Yet that growing trend will be influenced multiple competing interests between various stakeholders, namely the utility, consumers and technology provides. This study provides a series of analyses--utility-side, consumer-side, and combined analyses--to understand and evaluate the effect of increases in residential solar PV market

penetration. Three urban regions have been selected as study locations--Chicago, Phoenix, Seattle--with simulated load data and solar insolation data at each locality. Various time-of-use pricing schedules are investigated, and the effect of net metering is evaluated to determine the optimal capacity of solar PV and battery storage in a typical residential home. The net residential load profile is scaled to assess system-wide technical and economic figures of merit for the utility with an emphasis on intraday load profiles, ramp rates and electricity sales with increasing solar PV penetration. The combined analysis evaluates the least-cost solar PV system for the consumer and models the associated system-wide effects on the electric grid. Utility revenue was found to drop by 1.2% for every percent PV penetration increase, net metering on a monthly or annual basis improved the cost-effectiveness of solar PV but not battery storage, the removal of net metering policy and usage of an improved the cost-effectiveness of battery storage and increases in solar PV penetration reduced the system load factor. As expected, Phoenix had the most favorable economic scenario for residential solar PV, primarily due to high solar insolation. The study location--solar insolation and load profile--was also found to affect the time of

year at which the largest net negative system load was realized.
ContributorsArnold, Michael (Author) / Johnson, Nathan G (Thesis advisor) / Rogers, Bradley (Committee member) / Ruddell, Benjamin (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Natural rubber and rubber products can be produced from the guayule plant (Parthenium argentatum Gray), which is a low input perennial shrub native to Mexico and the American Southwest. Guayule rubber has the potential to replace Hevea (Hevea brasiliensis) rubber, the most common natural rubber, and synthetic rubber, which is

Natural rubber and rubber products can be produced from the guayule plant (Parthenium argentatum Gray), which is a low input perennial shrub native to Mexico and the American Southwest. Guayule rubber has the potential to replace Hevea (Hevea brasiliensis) rubber, the most common natural rubber, and synthetic rubber, which is derived from petroleum, in a wide variety of products, including automobile tires. Rubbers make up approximately 47% of the analyzed conventional passenger tire's weight, with 31% from synthetic rubber and 16% from natural Hevea rubber. Replacing the current rubber sources used for the tire industry with guayule rubber could help reduce dependency on imported rubber in addition to reducing greenhouse gas emissions. Moreover, residues from guayule rubber are being researched as a bioenergy feedstock to further improve the environmental footprint of guayule rubber products. This study used life cycle assessment (LCA), a useful tool to determine environmental impacts from a product or process, to quantify and compare environmental impacts of the raw material extraction, transportation and manufacturing of a conventional and a guayule rubber based passenger tire. The impact results of this comparative LCA identified the major environmental impacts and contributing process and informed how the impacts from the tire production can be reduced through utilization of natural rubber co-products as electricity off-sets and reducing guayule rubber's environmental impacts through agricultural and transportation modifications. Results showed that tire raw material extraction contributed the majority of impacts in all categories, where the production of guayule rubber for guayule tires, and the production of synthetic rubber for conventional tires, were the main contributors. Guayule rubber impacts occurred mainly from electricity consumption for agricultural irrigation, while synthetic rubber is a petroleum-based material resulting in high impacts. Transportation impacts had little significance compared to other stages in the life cycle, except for smog impacts, which occurred mainly from truck transport for guayule tires, and transoceanic transport for conventional tires. Tire manufacturing impacts occurred mainly from electricity use in the facilities and were reduced with the use of guayule rubber in guayule tires.
ContributorsRasutis, Daina (Author) / Landis, Amy E. (Thesis advisor) / Colvin, Howard (Committee member) / Seager, Thomas P. (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Research in design, emotion, and product experience has focused on establishing a connection between the aesthetic qualities of products and emotions. Studies in product expression have demonstrated relevant patterns between aesthetics and spatial reasoning. In design research, fully understanding latent qualities of consumers assists in developing an immersive product experience

Research in design, emotion, and product experience has focused on establishing a connection between the aesthetic qualities of products and emotions. Studies in product expression have demonstrated relevant patterns between aesthetics and spatial reasoning. In design research, fully understanding latent qualities of consumers assists in developing an immersive product experience which in turn can engender a lasting product relationship. This study evaluates how people interpret the emotionality of form in order to establish a veritable method for interpreting emotional variables in 3D objects.

This research assesses the emotional perception of aesthetic values in 2D and 3D teapots. A teapot image collection and taxonomy was constructed with 101 images of teapots across four centuries. Eighty-four participants completed a card sorting task of twenty randomly distributed teapot images (taken from the total 101 image collection) into Plutchik's eight emotion categories. Individual pieces of the teapots were coded according to the base, handle, lid, or spout that was presented in the image. The coded pieces from the card-sorting task were arranged per frequency in the overall set. Through the use of response data from the card sorting task, a network of the images was developed in Pathfinder. The content of these results were compared to images of models gathered during an interview with an interactive co-creation method referred to as Magnetic Modeling. Magnetic Modeling is a methodological tool that allowed participants to manipulate individualized pieces of 3D printed teapots into proposed emotional labels.

The findings of this research establish prototypical associations in aesthetic traits and teapot piece combinations for each emotion category. Participant responses were categorized into 4 personas representing the types of perceptual bias in the studies' participants. A discussion and comparison of the methods for academic and theoretical practice is provided.
ContributorsHorner, Candace (Author) / Takamura, John (Thesis advisor) / McDermott, Lauren (Committee member) / Branaghan, Russel; (Committee member) / Arizona State University (Publisher)
Created2014
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Description
The main objective of this study is to investigate the behaviour and applications of strain hardening cement composites (SHCC). Application of SHCC for use in slabs of common configurations was studied and design procedures are prepared by employing yield line theory and integrating it with simplified tri-linear model developed in

The main objective of this study is to investigate the behaviour and applications of strain hardening cement composites (SHCC). Application of SHCC for use in slabs of common configurations was studied and design procedures are prepared by employing yield line theory and integrating it with simplified tri-linear model developed in Arizona State University by Dr. Barzin Mobasher and Dr. Chote Soranakom. Intrinsic material property of moment-curvature response for SHCC was used to derive the relationship between applied load and deflection in a two-step process involving the limit state analysis and kinematically admissible displacements. For application of SHCC in structures such as shear walls, tensile and shear properties are necessary for design. Lot of research has already been done to study the tensile properties and therefore shear property study was undertaken to prepare a design guide. Shear response of textile reinforced concrete was investigated based on picture frame shear test method. The effects of orientation, volume of cement paste per layer, planar cross-section and volume fraction of textiles were investigated. Pultrusion was used for the production of textile reinforced concrete. It is an automated set-up with low equipment cost which provides uniform production and smooth final surface of the TRC. A 3-D optical non-contacting deformation measurement technique of digital image correlation (DIC) was used to conduct the image analysis on the shear samples by means of tracking the displacement field through comparison between the reference image and deformed images. DIC successfully obtained full-field strain distribution, displacement and strain versus time responses, demonstrated the bonding mechanism from perspective of strain field, and gave a relation between shear angle and shear strain.
ContributorsAswani, Karan (Author) / Mobasher, Barzin (Thesis advisor) / Dharmarajan, Subramaniam (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2014