Matching Items (23)
Filtering by
- All Subjects: engineering
- Creators: Tamizhmani, Govindasamy
Description
The primary goal of this thesis work is to determine the activation energy for encapsulant browning reaction of photovoltaic (PV) modules using outdoor field degradation data and indoor accelerated degradation data. For the outdoor field data, six PV modules fielded in Arizona (hot climate) over 21 years and four PV modules fielded in New York (cold climate) over 18 years have been analyzed. All the ten modules were manufactured by the same manufacturer with glass/EVA/cell/EVA/back sheet construction. The activation energy for the encapsulant browning is calculated using the degradation rates of short-circuit current (Isc, the response parameter), weather data (temperature, humidity, and UV, the stress parameters) and different empirical rate models such as Arrhenius, Peck, Klinger and modified Peck models. For the indoor accelerated data, three sets of mini-modules with the same construction/manufacturer as that of the outdoor fielded modules were subjected indoor accelerated weathering stress and the test data were analyzed. The indoor accelerated test was carried out in a weathering chamber at the chamber temperature of 20°C, chamber relative humidity of 65%, and irradiance of 1 W/m2 at 340nm using a xenon arc lamp. Typically, to obtain activation energy, the test samples are stressed at two (or more) temperatures in two (or more) chambers. However, in this work, it has been attempted to do the acceleration testing of eight mini-modules at multiple temperatures using a single chamber. Multiple temperatures in a single chamber were obtained using thermal insulators on the back of the mini-modules. Depending on the thickness of the thermal insulators with constant solar gain from the xenon lamp, different temperatures on the test samples were achieved using a single weathering chamber. The Isc loss and temperature of the mini-modules were continuously monitored using a data logger. Also, the mini-modules were taken out every two weeks and various characterization tests such as IV, QE, UV fluorescence and reflectance were carried out. Activation energy from the indoor accelerated tests was calculated using the short circuit current degradation rate and operating temperatures of the mini-modules. The activation energy for the encapsulant browning obtained from the outdoor field data and the indoor accelerated data are compared and analyzed in this work.
ContributorsVeerendra Kumar, Deepak Jain (Author) / Tamizhmani, Govindasamy (Committee member) / Srinivasan, Devarajan (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2016
Description
As the photovoltaic (PV) power plants age in the field, the PV modules degrade and generate visible and invisible defects. A defect and statistical degradation rate analysis of photovoltaic (PV) power plants is presented in two-part thesis. The first part of the thesis deals with the defect analysis and the second part of the thesis deals with the statistical degradation rate analysis. In the first part, a detailed analysis on the performance or financial risk related to each defect found in multiple PV power plants across various climatic regions of the USA is presented by assigning a risk priority number (RPN). The RPN for all the defects in each PV plant is determined based on two databases: degradation rate database; defect rate database. In this analysis it is determined that the RPN for each plant is dictated by the technology type (crystalline silicon or thin-film), climate and age. The PV modules aging between 3 and 19 years in four different climates of hot-dry, hot-humid, cold-dry and temperate are investigated in this study.
In the second part, a statistical degradation analysis is performed to determine if the degradation rates are linear or not in the power plants exposed in a hot-dry climate for the crystalline silicon technologies. This linearity degradation analysis is performed using the data obtained through two methods: current-voltage method; metered kWh method. For the current-voltage method, the annual power degradation data of hundreds of individual modules in six crystalline silicon power plants of different ages is used. For the metered kWh method, a residual plot analysis using Winters’ statistical method is performed for two crystalline silicon plants of different ages. The metered kWh data typically consists of the signal and noise components. Smoothers remove the noise component from the data by taking the average of the current and the previous observations. Once this is done, a residual plot analysis of the error component is performed to determine the noise was successfully separated from the data by proving the noise is random.
In the second part, a statistical degradation analysis is performed to determine if the degradation rates are linear or not in the power plants exposed in a hot-dry climate for the crystalline silicon technologies. This linearity degradation analysis is performed using the data obtained through two methods: current-voltage method; metered kWh method. For the current-voltage method, the annual power degradation data of hundreds of individual modules in six crystalline silicon power plants of different ages is used. For the metered kWh method, a residual plot analysis using Winters’ statistical method is performed for two crystalline silicon plants of different ages. The metered kWh data typically consists of the signal and noise components. Smoothers remove the noise component from the data by taking the average of the current and the previous observations. Once this is done, a residual plot analysis of the error component is performed to determine the noise was successfully separated from the data by proving the noise is random.
ContributorsSundarajan, Prasanna (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Srinivasan, Devarajan (Committee member) / Arizona State University (Publisher)
Created2016
Description
This is a two-part thesis. Part 1 presents the seasonal and tilt angle dependence of soiling loss factor of photovoltaic (PV) modules over two years for Mesa, Arizona (a desert climatic condition). Part 2 presents the development of an indoor artificial soil deposition chamber replicating natural dew cycle. Several environmental factors affect the performance of PV systems including soiling. Soiling on PV modules results in a decrease of sunlight reaching the solar cell, thereby reducing the current and power output. Dust particles, air pollution particles, pollen, bird droppings and other industrial airborne particles are some natural sources that cause soiling. The dust particles vary from one location to the other in terms of particle size, color, and chemical composition. The thickness and properties of the soil layer determine the optical path of light through the soil/glass interface. Soil accumulation on the glass surface is also influenced by environmental factors such as dew, wind speeds and rainfall. Studies have shown that soil deposition is closely related to tilt angle and exposure period before a rain event. The first part of this thesis analyzes the reduction in irradiance transmitted to a solar cell through the air/soil/glass in comparison to a clean cell (air/glass interface). A time series representation is used to compare seasonal soiling loss factors for two consecutive years (2014-2016). The effect of tilt angle and rain events on these losses are extensively analyzed. Since soiling is a significant field issue, there is a growing need to address the problem, and several companies have come up with solutions such as anti-soiling coatings, automated cleaning systems etc. To test and validate the effectiveness of these anti-soiling coating technologies, various research institutes around the world are working on the design and development of artificial indoor soiling chambers to replicate the natural process in the field. The second part of this thesis work deals with the design and development of an indoor artificial soiling chamber that replicates natural soil deposition process in the field.
ContributorsVirkar, Shalaim (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Kuitche, Joseph (Committee member) / Arizona State University (Publisher)
Created2017
Description
Solar photovoltaic (PV) deployment has grown at unprecedented rates since the early 2000s. As the global PV market increases, so will the volume of decommissioned PV panels. Growing PV panel waste presents a new environmental challenge, but also unprecedented opportunities to create value and pursue new economic avenues. Currently, in the United States, there are no regulations for governing the recycling of solar panels and the recycling process varies by the manufacturer. To bring in PV specific recycling regulations, whether the PV panels are toxic to the landfills, is to be determined. Per existing EPA regulations, PV panels are categorized as general waste and are subjected to a toxicity characterization leaching procedure (TCLP) to determine if it contains any toxic metals that can possibly leach into the landfill. In this thesis, a standardized procedure is developed for extracting samples from an end of life PV module. A literature review of the existing regulations in Europe and other countries is done. The sample extraction procedure is tested on a crystalline Si module to validate the method. The extracted samples are sent to an independent TCLP testing lab and the results are obtained. Image processing technique developed at ASU PRL is used to detect the particle size in a broken module and the size of samples sent is confirmed to follow the regulation.
ContributorsKrishnamurthy, Raghav (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Kuitche, Joseph (Committee member) / Arizona State University (Publisher)
Created2017
Description
Performance of photovoltaic (PV) modules decrease as the operating temperatures increase. In hot climatic conditions, the operating temperature can reach as high as 85°C for the rooftop modules. Considering a typical power drop of 0.5%/°C for crystalline silicon modules, a performance decrease of approximately 30% could be expected during peak summer seasons due to the difference between module rated temperature of 25°C and operating temperature of 85°C. Therefore, it is critical to accurately predict the temperature of the modules so the performance can be accurately predicted. The module operating temperature is based not only on the ambient and irradiance conditions but is also based on the thermal properties of module packaging materials. One of the key packaging materials that would influence the module operating temperature is the substrate, polymer backsheet or glass. In this study, the thermal influence of three different polymer backsheet substrates and one glass substrate has been investigated through five tasks:
1. Determination and modeling of substrate or module temperature of coupons using four different substrates (three backsheet materials and one glass material).
2. Determination and modeling of cell temperature of coupons using four different substrates (three backsheet materials and one glass material)
3. Determination of temperature difference between cell and individual substrates for coupons of all four substrates
4. Determination of NOCT (nominal operating cell temperature) of coupons using all four substrate materials
5. Comparison of operating temperature difference between backsheet substrate coupons.
All these five tasks have been executed using the specially constructed one-cell coupons with identical cells but with four different substrates. For redundancy, two coupons per substrate were constructed and investigated. This study has attempted to model the effect of thermal conductivity of backsheet material on the cell and backsheet temperatures.
1. Determination and modeling of substrate or module temperature of coupons using four different substrates (three backsheet materials and one glass material).
2. Determination and modeling of cell temperature of coupons using four different substrates (three backsheet materials and one glass material)
3. Determination of temperature difference between cell and individual substrates for coupons of all four substrates
4. Determination of NOCT (nominal operating cell temperature) of coupons using all four substrate materials
5. Comparison of operating temperature difference between backsheet substrate coupons.
All these five tasks have been executed using the specially constructed one-cell coupons with identical cells but with four different substrates. For redundancy, two coupons per substrate were constructed and investigated. This study has attempted to model the effect of thermal conductivity of backsheet material on the cell and backsheet temperatures.
ContributorsNatarajan Rammohan, Balamurali (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Kuitche, Joseph (Committee member) / Arizona State University (Publisher)
Created2017
Description
The American Diabetes Association reports that diabetes costs $322 billion annually and affects 29.1 million Americans. The high out-of-pocket cost of managing diabetes can lead to noncompliance causing serious and expensive complications. There is a large market potential for a more cost-effective alternative to the current market standard of screen-printed self-monitoring blood glucose (SMBG) strips. Additive manufacturing, specifically 3D printing, is a developing field that is growing in popularity and functionality. 3D printers are now being used in a variety of applications from consumer goods to medical devices. Healthcare delivery will change as the availability of 3D printers expands into patient homes, which will create alternative and more cost-effective methods of monitoring and managing diseases, such as diabetes. 3D printing technology could transform this expensive industry. A 3D printed sensor was designed to have similar dimensions and features to the SMBG strips to comply with current manufacturing standards. To make the sensor electrically active, various conductive filaments were tested and the conductive graphene filament was determined to be the best material for the sensor. Experiments were conducted to determine the optimal print settings for printing this filament onto a mylar substrate, the industry standard. The reagents used include a mixture of a ferricyanide redox mediator and flavin adenine dinucleotide dependent glucose dehydrogenase. With these materials, each sensor only costs $0.40 to print and use. Before testing the 3D printed sensor, a suitable design, voltage range, and redox probe concentration were determined. Experiments demonstrated that this novel 3D printed sensor can accurately correlate current output to glucose concentration. It was verified that the sensor can accurately detect glucose levels from 25 mg/dL to 400 mg/dL, with an R2 correlation value as high as 0.97, which was critical as it covered hypoglycemic to hyperglycemic levels. This demonstrated that a 3D-printed sensor was created that had characteristics that are suitable for clinical use. This will allow diabetics to print their own test strips at home at a much lower cost compared to SMBG strips, which will reduce noncompliance due to the high cost of testing. In the future, this technology could be applied to additional biomarkers to measure and monitor other diseases.
ContributorsAdams, Anngela (Author) / LaBelle, Jeffrey (Thesis advisor) / Pizziconi, Vincent (Committee member) / Abbas, James (Committee member) / Arizona State University (Publisher)
Created2017
Description
Building applied photovoltaics (BAPV) is a major application sector for photovoltaics (PV). Due to the negative temperature coefficient of power output, the performance of a PV module decreases as the temperature of the module increases. In hot climatic conditions, such as the summer in Arizona, the operating temperature of a BAPV module can reach as high as 90°C. Considering a typical 0.5%/°C power drop for crystalline silicon (c-Si) modules, a performance decrease of approximately 30% would be expected during peak summer temperatures due to the difference between rated temperature (25°C) and operating temperature (~90°C) of the modules. Also, in a worst-case scenario, such as partial shading of the PV cells of air gap-free BAPV modules, some of the components could attain temperatures that would be high enough to compromise the safety and functionality requirements of the module and its components. Based on the temperature and weather data collected over a year in Arizona, a mathematical thermal model has been developed and presented in this paper to predict module temperature for five different air gaps (0", 1", 2", 3", and 4"). For comparison, modules with a thermally-insulated (R30) back were evaluated to determine the worst-case scenario. This thesis also provides key technical details related to the specially-built, simulated rooftop structure; the mounting configuration of the PV modules on the rooftop structure; the LabVIEW program that was developed for data acquisition and the MATLAB program for developing the thermal models. In order to address the safety issue, temperature test results (obtained in accordance with IEC 61730-2 and UL 1703 safety standards) are presented and analyzed for nine different components of a PV module, i.e., the front glass, substrate/backsheet (polymer), PV cell, j-box ambient, j-box surface, positive terminal, backsheet inside j-box, field wiring, and diode. The temperature test results obtained for about 140 crystalline silicon modules from a large number of manufacturers who tested modules between 2006 and 2009 at ASU/TÜV-PTL were analyzed and presented in this paper under three test conditions, i.e., short-circuit, open-circuit, and short-circuit and shaded. Also, the nominal operating cell temperatures (NOCTs) of the BAPV modules and insulated-back PV modules are presented in this paper for use by BAPV module designers and installers.
ContributorsOh, Jaewon (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley R (Committee member) / Macia, Narciso F. (Committee member) / Arizona State University (Publisher)
Created2010
Description
Solar photovoltaic (PV) generation has seen significant growth in 2021, with an increase of around 22% and exceeding 1000 TWh. However, this has also led to reliability and durability issues, particularly potential induced degradation (PID), which can reduce module output by up to 30%. This study uses cell- and module-level analysis to investigate the impact of superstrate, encapsulant, and substrate on PID.The influence of different substrates and encapsulants is studied using one-cell modules, showing that substrates with poor water-blocking properties can worsen PID, and encapsulants with lower volumetric resistance can conduct easily under damp conditions, enabling PID mechanisms (results show maximum degradation of 9%). Applying an anti-soiling coating on the front glass (superstrate) reduces PID by nearly 53%. Typical superstrates have sodium which accelerates the PID process, and therefore, using such coatings can lessen the PID problem.
At the module level, the study examines the influence of weakened interface adhesion strengths in traditional Glass-Backsheet (GB) and emerging Glass-Glass (GG) (primarily bifacial modules) constructions. The findings show nearly 64% more power degradation in GG modules than in GB. Moreover, the current methods for detecting PID use new modules, which can give inaccurate information instead of DH-stressed modules for PID testing, as done in this work.
A comprehensive PID susceptibility analysis for multiple fresh bifacial constructions shows significant degradation from 20 to 50% in various constructions. The presence of glass as the substrate exacerbates the PID problem due to more ionic activity available from the two glass sides. Recovery experiments are also conducted to understand the extent of the PID issue.
Overall, this study identifies, studies, and explains the impact of superstrate, substrate, and encapsulant on the underlying PID mechanisms. Various pre- and post-stress characterization tests, including light and dark current-voltage (I-V) tests, electroluminescence (EL) imaging, infrared (IR) imaging, and UV fluorescence (UVF) imaging, are used to evaluate the findings. This study is significant as it provides insights into the PID issues in solar PV systems, which can help improve their performance and reliability.
ContributorsMahmood, Farrukh ibne (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Oh, Jaewon (Committee member) / Rajadas, John (Committee member) / Arizona State University (Publisher)
Created2023
Description
This study introduces a new outdoor accelerated testing method called “Field Accelerated Stress Testing (FAST)” for photovoltaic (PV) modules performed at two
different climatic sites in Arizona (hot-dry) and Florida (hot-humid). FAST is a combined
accelerated test methodology that simultaneously accounts for all the field-specific stresses
and accelerates only key stresses, such as temperature, to forecast the failure modes by 2-
7 times in advance depending on the activation energy of the degradation mechanism (i.e.,
10th year reliability issues can potentially be predicted in the 2nd year itself for an
acceleration factor of 5). In this outdoor combined accelerated stress study, the
temperatures of test modules were increased (by 16-19℃ compared to control modules)
using thermal insulations on the back of the modules. All other conditions (ambient
temperature, humidity, natural sunlight, wind speed, wind direction, and tilt angle) were
left constant for both test modules (with back thermal insulation) and control modules
(without thermal insulation). In this study, a total of sixteen 4-cell modules with two different construction types (glass/glass [GG] and glass/backsheet [GB]) and two different encapsulant types (ethylene
vinyl acetate [EVA] and polyolefin elastomer [POE]), were investigated at both sites with
eight modules at each site (four insulated and four non-insulated modules at each site). All
the modules were extensively characterized before installation in the field and after field
exposure over two years. The methods used for characterizing the devices included I-V
(current-voltage curves), EL (electroluminescence), UVF (ultraviolet fluorescence), and
reflectance. The key findings of this study are: i) the GG modules tend to operate at a higher temperature (1-3℃) than the GB modules at both sites of Arizona and Florida (a lower
lifetime is expected for GG modules compared to GB modules); ii) the GG modules tend
to experience a higher level of encapsulant discoloration and grid finger degradation than
the GB modules at both sites (a higher level of the degradation rate is expected in GG
modules compared to GB modules); and, iii) the EVA-based modules tend to have a higher
level of discoloration and finger degradation compared to the POE-based modules at both
sites.
ContributorsThayumanavan, Rishi Gokul (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Calhoun, Ronald (Committee member) / Arizona State University (Publisher)
Created2023
Description
The goal of any solar photovoltaic (PV) system is to generate maximum energy throughout its lifetime. The parameters that can affect PV module power output include: solar irradiance, temperature, soil accumulation, shading, encapsulant browning, encapsulant delamination, series resistance increase due to solder bond degradation and corrosion and shunt resistance decrease due to potential induced degradation, etc. Several PV modules together in series makes up a string, and in a power plant there are a number of these strings in parallel which can be referred to as an array. Ideally, PV modules in a string should be identically matched to attain maximum power output from the entire string. Any underperforming module or mismatch among modules within a string can reduce the power output. The goal of this project is to quickly identify and quantitatively determine the underperforming module(s) in an operating string without the use of an I-V curve tracer, irradiance sensor or temperature sensor. This goal was achieved by utilizing Radiovoltmeters (RVM). In this project, it is demonstrated that the voltages at maximum power point (Vmax) of all the individual modules in a string can be simultaneously and quantitatively obtained using RVMs at a single irradiance, single module operating temperature, single spectrum and single angle of incidence. By combining these individual module voltages (Vmax) with the string current (Imax) using a Hall sensor, the power output of individual modules can be obtained, quickly and quantitatively.
ContributorsTahghighi, Arash (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Srinivasan, Devarajan (Committee member) / Arizona State University (Publisher)
Created2019