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High-entropy alloys possessing mechanical, chemical, and electrical properties that far exceed those of conventional alloys have the potential to make a significant impact on many areas of engineering. Identifying element combinations and configurations to form these alloys, however, is a difficult, time-consuming, computationally intensive task. Machine learning has revolutionized many different fields due to its ability to generalize well to different problems and produce computationally efficient, accurate predictions regarding the system of interest. In this thesis, we demonstrate the effectiveness of machine learning models applied to toy cases representative of simplified physics that are relevant to high-entropy alloy simulation. We show these models are effective at learning nonlinear dynamics for single and multi-particle cases and that more work is needed to accurately represent complex cases in which the system dynamics are chaotic. This thesis serves as a demonstration of the potential benefits of machine learning applied to high-entropy alloy simulations to generate fast, accurate predictions of nonlinear dynamics.
Protein and gene circuit level synthetic bioengineering can require years to develop a single target. Phage assisted continuous evolution (PACE) is a powerful new tool for rapidly engineering new genes and proteins, but the method requires an automated cell culture system, making it inaccessible to non industrial research programs. Complex protein functions, like specific binding, require similarly dynamic PACE selection that can be alternatively induced or suppressed, with heat labile chemicals like tetracycline. Selection conditions must be controlled continuously over days, with adjustments made every few minutes. To make PACE experiments accessible to the broader community, we designed dedicated cell culture hardware and integrated optogenetically controlled plasmids. The low cost and open source platform allows a user to conduct PACE with continuous monitoring and precise control of evolution using light.
Performance evaluation and characterization of lithium-ion cells under simulated PHEVs' drive cycles
In PHEVs, batteries operate under charge sustaining and charge depleting mode based on torque requirement and state of charge. In the current article, 26650 lithium-ion cells were cycled extensively at 25 and 50 oC under charge sustaining mode to monitor capacity and cell impedance values followed by analyzing the Lithium iron phosphate (LiFePO4) cathode material by X-ray diffraction analysis (XRD). High frequency resistance measured by electrochemical impedance spectroscopy was found to increase significantly under high temperature cycling, leading to power fading. No phase change in LiFePO4 cathode material is observed after 330 cycles at elevated temperature under charge sustaining mode from the XRD analysis. However, there was significant change in crystallite size of the cathode active material after charge/discharge cycling with charge sustaining mode. Additionally, 18650 lithium-ion cells were tested under charge depleting mode to monitor capacity values.
The objective of this research is to allocate tolerance values to ensure that the assemblability conditions are satisfied. Assemblability refers to “the ability to assemble/fit a set of parts in specified configuration given a nominal geometry and its corresponding tolerances”. Assemblability is determined by the clearances between the mating features. These clearances are affected by accumulation of tolerances in tolerance loops and hence, the tolerance loops are extracted first. Once tolerance loops have been identified initial tolerance values are allocated to the contributors in these loops. It is highly unlikely that the initial allocation would satisfice assemblability requirements. Overlapping loops have to be simultaneously satisfied progressively. Hence, tolerances will need to be re-allocated iteratively. This is done with the help of tolerance analysis module.
The tolerance allocation and analysis module receives the constraint graph which contains all basic dimensions and mating constraints from the generated schema. The tolerance loops are detected by traversing the constraint graph. The initial allocation distributes the tolerance budget computed from clearance available in the loop, among its contributors in proportion to the associated nominal dimensions. The analysis module subjects the loops to 3D parametric variation analysis and estimates the variation parameters for the clearances. The re-allocation module uses hill climbing heuristics derived from the distribution parameters to select a loop. Re-allocation Of the tolerance values is done using sensitivities and the weights associated with the contributors in the stack.
Several test cases have been run with this software and the desired user input acceptance rates are achieved. Three test cases are presented and output of each module is discussed.