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Description
Tire blowout often occurs during driving, which can suddenly disturb vehicle motions and seriously threaten road safety. Currently, there is still a lack of effective methods to mitigate tire blowout risks in everyday traffic, even for automated vehicles. To fundamentally study and systematically resolve the tire blowout issue for automated

Tire blowout often occurs during driving, which can suddenly disturb vehicle motions and seriously threaten road safety. Currently, there is still a lack of effective methods to mitigate tire blowout risks in everyday traffic, even for automated vehicles. To fundamentally study and systematically resolve the tire blowout issue for automated vehicles, a collaborative project between General Motors (GM) and Arizona State University (ASU) has been conducted since 2018. In this dissertation, three main contributions of this project will be presented. First, to explore vehicle dynamics with tire blowout impacts and establish an effective simulation platform for close-loop control performance evaluation, high-fidelity tire blowout models are thoroughly developed by explicitly considering important vehicle parameters and variables. Second, since human cooperation is required to control Level 2/3 partially automated vehicles (PAVs), novel shared steering control schemes are specifically proposed for tire blowout to ensure safe vehicle stabilization via cooperative driving. Third, for Level 4/5 highly automated vehicles (HAVs) without human control, the development of control-oriented vehicle models, controllability study, and automatic control designs are performed based on impulsive differential systems (IDS) theories. Co-simulations Matlab/Simulink® and CarSim® are conducted to validate performances of all models and control designs proposed in this dissertation. Moreover, a scaled test vehicle at ASU and a full-size test vehicle at GM are well instrumented for data collection and control implementation. Various tire blowout experiments for different scenarios are conducted for more rigorous validations. Consequently, the proposed high-fidelity tire blowout models can correctly and more accurately describe vehicle motions upon tire blowout. The developed shared steering control schemes for PAVs and automatic control designs for HAVs can effectively stabilize a vehicle to maintain path following performance in the driving lane after tire blowout. In addition to new research findings and developments in this dissertation, a pending patent for tire blowout detection is also generated in the tire blowout project. The obtained research results have attracted interest from automotive manufacturers and could have a significant impact on driving safety enhancement for automated vehicles upon tire blowout.
ContributorsLi, Ao (Author) / Chen, Yan (Thesis advisor) / Berman, Spring (Committee member) / Kannan, Arunachala Mada (Committee member) / Liu, Yongming (Committee member) / Lin, Wen-Chiao (Committee member) / Marvi, Hamidreza (Committee member) / Arizona State University (Publisher)
Created2023
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Description
In this dissertation, the nanofabrication process is characterized for fabrication of nanostructure on surface of silicon and gallium phosphide using silica nanosphere lithography (SNL) and metal assisted chemical etching (MACE) process. The SNL process allows fast process time and well defined silica nanosphere monolayer by spin-coating process after mixing N,N-dimethyl-formamide

In this dissertation, the nanofabrication process is characterized for fabrication of nanostructure on surface of silicon and gallium phosphide using silica nanosphere lithography (SNL) and metal assisted chemical etching (MACE) process. The SNL process allows fast process time and well defined silica nanosphere monolayer by spin-coating process after mixing N,N-dimethyl-formamide (DMF) solvent. The MACE process achieves the high aspect ratio structure fabrication using the reaction between metal and wet chemical. The nanostructures are fabricated on Si surface for enhanced light management, but, without proper surface passivation those gains hardly impact the performance of the solar cell. The surface passivation of nanostructures is challenging, not only due to larger surface areas and aspect ratios, but also has a direct result of the nanofabrication processes. In this research, the surface passivation of silicon nanostructures is improved by modifying the silica nanosphere lithography (SNL) and the metal assisted chemical etching (MACE) processes, frequently used to fabricate nanostructures. The implementation of a protective silicon oxide layer is proposed prior to the lithography process to mitigate the impact of the plasma etching during the SNL. Additionally, several adhesion layers are studied, chromium (Cr), nickel (Ni) and titanium (Ti) with gold (Au), used in the MACE process. The metal contamination is one of main damage and Ti makes the mitigation of metal contamination. Finally, a new chemical etching step is introduced, using potassium hydroxide at room temperature, to smooth the surface of the nanostructures after the MACE process. This chemical treatment allows to improve passivation by surface area control and removing surface defects. In this research, I demonstrate the Aluminum Oxide (Al2O3) passivation on nanostructure using atomic layer deposition (ALD) process. 10nm of Al2O3 layer makes effective passivation on nanostructure with optimized post annealing in forming gas (N2/H2) environment. However, 10nm thickness is not suitable for hetero structure because of carrier transportation. For carrier transportation, ultrathin Al2O3 (≤ 1nm) layer is used for passivation, but effective passivation is not achieved because of insufficient hydrogen contents. This issue is solved to use additional ultrathin SiO2 (1nm) below Al2O3 layer and hydrogenation from doped a-Si:H. Moreover, the nanostructure is creased on gallium phosphide (GaP) by SNL and MACE process. The fabrication process is modified by control of metal layer and MACE solution.
ContributorsKim, Sangpyeong (Author) / Honsberg, Christiana (Thesis advisor) / Bowden, Stuart (Committee member) / Goryll, Michael (Committee member) / Augusto, Andre (Committee member) / Arizona State University (Publisher)
Created2021
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Description
Colloidal nanocrystals (NCs) are promising candidates for a wide range of applications (electronics, optoelectronics, photovoltaics, thermoelectrics, etc.). Mechanical and thermal transport property play very important roles in all of these applications. On one hand, mechanical robustness and high thermal conductivity are desired in electronics, optoelectronics, and photovoltaics. This improves thermomechanical

Colloidal nanocrystals (NCs) are promising candidates for a wide range of applications (electronics, optoelectronics, photovoltaics, thermoelectrics, etc.). Mechanical and thermal transport property play very important roles in all of these applications. On one hand, mechanical robustness and high thermal conductivity are desired in electronics, optoelectronics, and photovoltaics. This improves thermomechanical stability and minimizes the temperature rise during the device operation. On the other hand, low thermal conductivity is desired for higher thermoelectric figure of merit (ZT). This dissertation demonstrates that ligand structure and nanocrystal ordering are the primary determining factors for thermal transport and mechanical properties in colloidal nanocrystal assemblies. To eliminate the mechanics and thermal transport barrier, I first propose a ligand crosslinking method to improve the thermal transport across the ligand-ligand interface and thus increasing the overall thermal conductivity of NC assemblies. Young’s modulus of nanocrystal solids also increases simultaneously upon ligand crosslinking. My thermal transport measurements show that the thermal conductivity of the iron oxide NC solids increases by a factor of 2-3 upon ligand crosslinking. Further, I demonstrate that, though with same composition, long-range ordered nanocrystal superlattices possess higher mechanical and thermal transport properties than disordered nanocrystal thin films. Experimental measurements along with theoretical modeling indicate that stronger ligand-ligand interaction in NC superlattice accounts for the improved mechanics and thermal transport. This suggests that NC/ligand arranging order also plays important roles in determining mechanics and thermal transport properties of NC assemblies. Lastly, I show that inorganic ligand functionalization could lead to tremendous mechanical enhancement (a factor of ~60) in NC solids. After ligand exchange and drying, the short inorganic Sn2S64- ligands dissociate into a few atomic layers of amorphous SnS2 at room temperature and interconnects the neighboring NCs. I observe a reverse Hall-Petch relation as the size of NC decreases. Both atomistic simulations and analytical phase mixture modeling identify the grain boundaries and their activities as the mechanic bottleneck.
ContributorsWang, Zhongyong (Author) / Wang, Robert RW (Thesis advisor) / Wang, Liping LW (Committee member) / Newman, Nathan NN (Committee member) / Arizona State University (Publisher)
Created2021
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Description
The world faces significant environmental and social challenges due to high economic development, population growth, industrialization, rapid urbanization, and unsustainable consumption. Global communities are taking the necessary measures to confront these international challenges and applying sustainable development principles across all sectors. Construction is a critical driving instrument of economic activity,

The world faces significant environmental and social challenges due to high economic development, population growth, industrialization, rapid urbanization, and unsustainable consumption. Global communities are taking the necessary measures to confront these international challenges and applying sustainable development principles across all sectors. Construction is a critical driving instrument of economic activity, and to achieve sustainable development, it is vital to transform conventional construction into a more sustainable model. The research investigated sustainable construction perceptions in Kuwait, a rapidly growing country with a high volume of construction activities. Kuwait has ambitious plans to transition into a more sustainable economic development model, and the construction industry needs to align with these plans. This research aims to identify the characteristics of sustainable construction applications in the Kuwaiti construction market, such as awareness, current perceptions, drivers and barriers, and the construction regulations' impact. The research utilized a qualitative approach to answer research questions and deliver research objectives by conducting eleven Semi-structured interviews with experienced professionals in the Kuwaiti construction market to collect rich data that reflects insights and understandings of the Kuwaiti construction industry. The Thematic analysis of the data resulted in six themes and one sub-theme that presented reflections, insights, and perspectives on sustainable construction perceptions in the Kuwaiti construction market. The research findings reflected poor sustainable construction awareness and poor environmental and social application in the construction industry, the determinant role of construction regulations in promoting sustainable construction. and barriers and drivers to sustainable construction applications. The research concluded with answers to research questions, delivery of research objectives, and an explanation of sustainable construction perceptions in the Kuwaiti construction market.
Contributorsalsalem, mohammad salem (Author) / Duran, Melanie (Thesis advisor) / Chong, Oswald (Committee member) / Sullivan, Kenneth (Committee member) / Grau, David (Committee member) / Arizona State University (Publisher)
Created2023
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Description
A well-insulated dark conventional rooftop can be hotter than any other urban surface, including pavements. Since rooftops cover around 20 – 25% of most urban areas, their role in the urban heat island effect is significant. In general, buildings exchange heat with the surroundings in three ways: heat release from

A well-insulated dark conventional rooftop can be hotter than any other urban surface, including pavements. Since rooftops cover around 20 – 25% of most urban areas, their role in the urban heat island effect is significant. In general, buildings exchange heat with the surroundings in three ways: heat release from the cooling/heating system, air exchange associated with exfiltration and relief air, and heat transfer between the building envelope and surroundings. Several recent studies show that the building envelope generates more heat release into the environment than any other building component.Current advancements in material science have enabled the development of materials and coatings with very high solar reflectance and thermal emissivity, and that can alter their radiative properties based on surface temperature. This dissertation is an effort to quantify the impact of recent developments in such technologies on urban air. The current study addresses three specific unresolved topics: 1) the relative importance of rooftop solar reflectance and thermal emissivity, 2) the role of rooftop radiative properties in different climates, and 3) the impact of temperature-adaptive exterior materials/coatings on building energy savings and urban cooling. The findings from this study show that the use of rooftop materials with solar reflectance above 0.9 maintain the surface temperature below ambient air temperature most of the time, even when the materials have conventional thermal emissivity (0.9). This research has demonstrated that for hot cities, rooftops with high solar reflectance and thermal emittance maximize building energy savings and always cool the surrounding air. For moderate climate regions, high solar reflectance and low thermal emittance result in the greatest building energy cost savings. This combination of radiative properties cools the air during the daytime and warms it at night. Finally, this research found that temperature-adaptive materials could play a significant role in reducing utility costs for poorly insulated buildings, but that they heat the surrounding air in the winter, irrespective of the rooftop insulation. Through the detailed analysis of building façade radiative properties, this dissertation offers climate-specific design guidance that can be used to simultaneously optimize energy costs while minimizing adverse warming of the surrounding environment.
ContributorsPrem Anand Jayaprabha, Jyothis Anand (Author) / Sailor, David (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Huang, Huei-Ping (Committee member) / Wang, Liping (Committee member) / Yeom, Dongwoo Jason (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Delamination of solar module interfaces often occurs in field-tested solar modules after decades of service due to environmental stressors such as humidity. In the presence of water, the interfaces between the encapsulant and the cell, glass, and backsheet all experience losses of adhesion, exposing the module to accelerated degradation. Understanding

Delamination of solar module interfaces often occurs in field-tested solar modules after decades of service due to environmental stressors such as humidity. In the presence of water, the interfaces between the encapsulant and the cell, glass, and backsheet all experience losses of adhesion, exposing the module to accelerated degradation. Understanding the relation between interfacial adhesion and water content inside photovoltaic modules can help mitigate detrimental power losses. Water content measurements via water reflectometry detection combined with 180° peel tests were used to study adhesion of module materials exposed to damp heat and dry heat conditions. The effect of temperature, cumulative water dose, and water content on interfacial adhesion between ethylene vinyl acetate and (1) glass, (2) front of the cell, and (3) backsheet was studied. Temperature and time decreased adhesion at all these interfaces. Water content in the sample during the measurement showed significant decreases in adhesion for the Backsheet/Ethylene vinyl acetate interface. Water dose showed little effect for the Glass/ Ethylene vinyl acetate and Backsheet/ Ethylene vinyl acetate interfaces, but there was significant adhesion loss with water dose at the front cell busbar/encapsulant interface. Initial tensile test results to monitor the effects of the mechanical properties ethylene vinyl acetate and backsheet showed water content increasing the strength of ethylene vinyl acetate during plastic deformation but no change in the strength of the backsheet properties. This mechanical property change is likely inducing variation along the peel interface to possibly convolute the adhesion measurements conducted or to explain the variation seen for the water saturated and dried peel test sample types.
ContributorsTheut, Nicholas (Author) / Bertoni, Mariana (Thesis advisor) / Holman, Zachary (Committee member) / Chan, Candace (Committee member) / Arizona State University (Publisher)
Created2020
Description
Ulaanbaatar, Mongolia is one of the world’s coldest capital cities with roughly 1.5 million residents. About fifty percent of the city’s residents are off the electrical grid and millions continue to live nomadic lifestyles, raising livestock for food. Problematically, residents often turn to raw coal - Mongolia’s largest export -

Ulaanbaatar, Mongolia is one of the world’s coldest capital cities with roughly 1.5 million residents. About fifty percent of the city’s residents are off the electrical grid and millions continue to live nomadic lifestyles, raising livestock for food. Problematically, residents often turn to raw coal - Mongolia’s largest export - as a means to cook food and stay warm. Project Koyash is a philanthropic engineering initiative that was founded in the Arizona State University Program Engineering Projects in Community Service (EPICS) to combat the air quality crisis plaguing the ger districts of Ulaanbaatar. Koyash has already deployed 13 fully functional and autonomous units consisting of a solar powered air filtration system in Ulaanbaatar. Koyash innovated a solution of solar panels, air filters, batteries, inverters, PCB Arduinos, and other necessary components for providing crucial humanitarian services. The team is working to send more units and develop a local supply chain for the systems. This thesis project explores the development of Koyash, assesses the human health implications of air pollution, and reflects on the entire process.
ContributorsYavari, Bryan (Author) / Hartwell, Leland (Thesis director) / Schoepf, Jared (Thesis director) / Diddle, Julianna (Committee member) / Barrett, The Honors College (Contributor) / Department of Psychology (Contributor) / School of Life Sciences (Contributor)
Created2024-05
Description
Our Idea: As a team of engineers, two in the engineering field and one in computer science and software development, we wanted to find a way to put these skills to use in our company. As we did not have a revolutionary idea to build our own product, we wanted to base our

Our Idea: As a team of engineers, two in the engineering field and one in computer science and software development, we wanted to find a way to put these skills to use in our company. As we did not have a revolutionary idea to build our own product, we wanted to base our company on the assumption that people have great ideas and lack the ability to execute on these ideas. Our mission is to enable these people and companies to make their ideas a reality, and allow them to go to market with a clean and user friendly product. We are using our skills and experience in hardware and device prototyping and testing, as well as software design and development to make this happen. Implementation: To this point, we have been working with a client building a human diagnostic and enhancement AI device. We have been consulting on mostly the design and creation of their first proof of concept, working on hardware and sensor interaction as well as developing the software allowing their platform to come to life. We have been working closely with the leaders of the company, who have the ideas and business knowledge, while we focus on the technology side. As for the scalability and market potential of our business, we believe that the potential market is not the limiting factor. Instead, the limiting factor to the growth of our business is the time we have to devote. We are currently only working with one client, and not looking to expand into new clients. We believe this would require the addition of new team members, but instead we are happy with the progress we are making at the moment. We believe we are not only building equity in business we believe in, but also building a product that could help the safety and wellness of our users.
ContributorsMiller, Kyle (Author) / Engerholm, Liam (Co-author) / Schildgen, Nathan (Co-author) / Byrne, Jared (Thesis director) / Lee, Christopher (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2024-05
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Description
Integrating advanced materials with innovative manufacturing techniques has propelled the field of additive manufacturing into new frontiers. This study explores the rapid 3D printing of reduced graphene oxide/polymer composites using Micro-Continuous Liquid Interface Production (μCLIP), a cutting-edge technology known for its speed and precision. A printable ink is formulated with

Integrating advanced materials with innovative manufacturing techniques has propelled the field of additive manufacturing into new frontiers. This study explores the rapid 3D printing of reduced graphene oxide/polymer composites using Micro-Continuous Liquid Interface Production (μCLIP), a cutting-edge technology known for its speed and precision. A printable ink is formulated with reduced graphene oxide for μCLIP-based 3D printing. The research focuses on optimizing μCLIP parameters to fabricate reduced graphene composites efficiently. The study encompasses material synthesis, ink formulation and explores the resulting material's structural and electrical properties. The marriage of graphene's unique attributes with the rapid prototyping capabilities of μCLIP opens new avenues for scalable and rapid production in applications such as energy storage, sensors, and lightweight structural components. This work contributes to the evolving landscape of advanced materials and additive manufacturing, offering insights into the synthesis, characterization, and potential applications of 3D printed reduced graphene oxide/polymercomposites.
ContributorsRavishankar, Chayaank Bangalore (Author) / Chen, Xiangfan (Thesis advisor) / Bhate, Dhruv (Committee member) / Azeredo, Bruno (Committee member) / Arizona State University (Publisher)
Created2024
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Description
When solving analysis, estimation, and control problems for Partial Differential Equations (PDEs) via computational methods, one must resolve three main challenges: (a) the lack of a universal parametric representation of PDEs; (b) handling unbounded differential operators that appear as parameters; and (c), enforcing auxiliary constraints such as Boundary conditions and

When solving analysis, estimation, and control problems for Partial Differential Equations (PDEs) via computational methods, one must resolve three main challenges: (a) the lack of a universal parametric representation of PDEs; (b) handling unbounded differential operators that appear as parameters; and (c), enforcing auxiliary constraints such as Boundary conditions and continuity conditions. To address these challenges, an alternative representation of PDEs called the `Partial Integral Equation' (PIE) representation is proposed in this work. Primarily, the PIE representation alleviates the problem of the lack of a universal parametrization of PDEs since PIEs have, at most, $12$ Partial Integral (PI) operators as parameters. Naturally, this also resolves the challenges in handling unbounded operators because PI operators are bounded linear operators. Furthermore, for admissible PDEs, the PIE representation is unique and has no auxiliary constraints --- resolving the last of the $3$ main challenges. The PIE representation for a PDE is obtained by finding a unique unitary map from the states of the PIE to the states of the PDE. This map shows a PDE and its associated PIE have equivalent system properties, including well-posedness, internal stability, and I/O behavior. Furthermore, this unique map also allows us to construct a well-defined dual representation that can be used to solve optimal control problems for a PDE. Using the equivalent PIE representation of a PDE, mathematical and computational tools are developed to solve standard problems in Control theory for PDEs. In particular, problems such as a test for internal stability, Input-to-Output (I/O) $L_2$-gain, $\hinf$-optimal state observer design, and $\hinf$-optimal full state-feedback controller design are solved using convex-optimization and Lyapunov methods for linear PDEs in one spatial dimension. Once the PIE associated with a PDE is obtained, Lyapunov functions (or storage functions) are parametrized by positive PI operators to obtain a solvable convex formulation of the above-stated control problems. Lastly, the methods proposed here are applied to various PDE systems to demonstrate the application.
ContributorsShivakumar, Sachin (Author) / Peet, Matthew (Thesis advisor) / Nedich, Angelia (Committee member) / Marvi, Hamidreza (Committee member) / Platte, Rodrigo (Committee member) / Berman, Spring (Committee member) / Arizona State University (Publisher)
Created2024