Matching Items (62)
Description

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar plans

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar plans to initially begin by developing the foundational technological patent for our perovskite-based single-junction solar cells. Sun Stop Solar plans to initially begin by first having a patent set up, then licensing our patent to a manufacturer, and slowly building towards manufacturing our own solar modules.

ContributorsMatyushov, Ivan (Author) / Aboudi, Joseph (Co-author) / Hofer, David (Co-author) / Byrne, Jared (Thesis director) / Lawson, Brennan (Committee member) / Cartwright, Bryce (Committee member) / Adarsh, Siddharth (Committee member) / Higashino, Katsuko (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor)
Created2023-05
Description

This paper outlines the issue of end-of-life management in small scale solar systems deployed generally in Sub-Saharan Africa, known as PAYGos (Pay-as-you-go). Research and interviews were conducted in order to determine the current state of the industry and plans in terms of waste management. Considering the current capabilities and technology

This paper outlines the issue of end-of-life management in small scale solar systems deployed generally in Sub-Saharan Africa, known as PAYGos (Pay-as-you-go). Research and interviews were conducted in order to determine the current state of the industry and plans in terms of waste management. Considering the current capabilities and technology of PV recycling, the future of the industry was analyzed. It is important to provide the highest quality of service to the customer and minimize issues with environmental hazards. Therefore, it is recommended here that PAYGo companies create contracts with recycling companies before the issue of solar waste increases drastically.

ContributorsDiehl, Phoebe (Author) / Kelman, Jonathan (Thesis director) / Moore, Thomas (Committee member) / Barrett, The Honors College (Contributor) / School of Molecular Sciences (Contributor)
Created2023-05
Description

With the rise of global warming and the growing energy crisis, scientists have pivoted from typical resources to look for new materials and technologies that can aid in advancing renewable energy efforts. Perovskite materials hold the potential for making high-efficiency, low-cost solar cells through solution processing of Earth abundant materials;

With the rise of global warming and the growing energy crisis, scientists have pivoted from typical resources to look for new materials and technologies that can aid in advancing renewable energy efforts. Perovskite materials hold the potential for making high-efficiency, low-cost solar cells through solution processing of Earth abundant materials; however, scalability and manufacturability remain a challenge. In order to transition from small scale processing in inert environments via spin coating to higher throughput processing in ambient conditions via blade coating, the fundamentals of perovskite crystallization must be understood. Classical nucleation theory, the LaMer relation, and nonclassical crystallization considerations are discussed to provide a mechanism by which gellan gum, a nontoxic biopolymer from the food industry, has enabled quality halide perovskite thin films. Specifically, this research aims to study the effects of gellan gum in improving perovskite manufacturability by controlling crystallization through indirect alteration of evaporation and supersaturation rates by modifying fluid dynamics and the free energy associated with nucleation and growth. Simply, gellan gum controls crystallization to enable the fabrication of promising scalable PVSK devices in open air.

ContributorsCartledge, Carsen (Author) / Rolston, Nicholas (Thesis director) / Yu, Zhengshan (Committee member) / Barrett, The Honors College (Contributor) / Materials Science and Engineering Program (Contributor) / School of International Letters and Cultures (Contributor) / School of Art (Contributor)
Created2023-05
Description

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will focus on first developing the patent, licensing the technology to a manufacturer, and slowly garnering funds to launch our own manufacturing eventually. Sun Stop Solar is offering a domestic, affordable, and sustainable solution for the current solar market.

ContributorsAboudi, Joseph (Author) / Hofer, David (Co-author) / Matyushov, Ivan (Co-author) / Byrne, Jared (Thesis director) / Higashino, Katsuko (Committee member) / Barrett, The Honors College (Contributor) / Department of Finance (Contributor)
Created2023-05
Description
Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will focus on first developing the patent, licensing the technology to a manufacturer, and slowly garnering funds to launch our own manufacturing eventually. Sun Stop Solar is offering a domestic, affordable, and sustainable solution for the current solar market.
ContributorsAboudi, Joseph (Author) / Hofer, David (Co-author) / Matyushov, Ivan (Co-author) / Byrne, Jared (Thesis director) / Higashino, Katsuko (Committee member) / Barrett, The Honors College (Contributor) / Department of Finance (Contributor)
Created2023-05
Description
Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will focus on first developing the patent, licensing the technology to a manufacturer, and slowly garnering funds to launch our own manufacturing eventually. Sun Stop Solar is offering a domestic, affordable, and sustainable solution for the current solar market.
ContributorsAboudi, Joseph (Author) / Hofer, David (Co-author) / Matyushov, Ivan (Co-author) / Byrne, Jared (Thesis director) / Higashino, Katsuko (Committee member) / Barrett, The Honors College (Contributor) / Department of Finance (Contributor)
Created2023-05
Description

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will

Sun Stop Solar, is a solar module development and manufacturing company that utilizes a unique class of materials, perovskites, as the solar cells’ absorption layer. Perovskites are a unique class of compounds with some perovskites being able to absorb photons and excite electrons to create current. Sun Stop Solar will focus on first developing the patent, licensing the technology to a manufacturer, and slowly garnering funds to launch our own manufacturing eventually. Sun Stop Solar is offering a domestic, affordable, and sustainable solution for the current solar market.

ContributorsHofer, David (Author) / Matyushov, Ivan (Co-author) / Aboudi, Joseph (Co-author) / Byrne, Jared (Thesis director) / Lawson, Brennan (Committee member) / Higashino, Katsuko (Committee member) / Barrett, The Honors College (Contributor) / Department of Supply Chain Management (Contributor) / Department of Economics (Contributor)
Created2023-05
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Description
Solar energy is a disruptive technology within the electricity industry, and rooftop solar is particularly disruptive as it changes the relationship between the industry and its customers as the latter generate their own power, sell power to the grid, and reduce their dependence on the industry as the sole source

Solar energy is a disruptive technology within the electricity industry, and rooftop solar is particularly disruptive as it changes the relationship between the industry and its customers as the latter generate their own power, sell power to the grid, and reduce their dependence on the industry as the sole source provider of electric power. Hundreds of thousands of people in the western United States have made the decision to adopt residential rooftop solar photovoltaic technologies (solar PV) for their homes, with some areas of western cities now having 50% or more of homes with solar installed. This dissertation seeks to understand how rooftop solar energy is altering the fabric of urban life, drawing on three distinct lenses and a mixed suite of methods to examine how homeowners, electric utilities, financial lenders, regulators, solar installers, realtors, and professional trade organizations have responded to the opportunities and challenges presented by rooftop solar energy. First, using a novel solar installation data set, it systematically examines the temporal, geographic, and socio-economic dynamics of the adoption of rooftop solar technologies across the Phoenix metropolitan area over the decade of the 2010s. This study examines the broad social, economic, and urban environmental contexts within which solar adoption has occurred and how these have impacted differential rates of solar uptake. Second, using survey and real estate data from the Phoenix metropolitan area, it explores how solar energy has begun to shape important social and market dynamics, illuminating how decision-making in real estate transactions, including by buyers, sellers, agents, lenders, and appraisers is shifting to accommodate houses with installed solar systems. Lastly, the study explores patterns of rooftop solar adoption across major electric utilities and what those can tell us about the extent to which corporate social responsibility and sustainability reporting have affected the practices of investor-owned electric utilities (IOU) within the western US.
ContributorsO'Leary, Jason (Author) / Fisher, Erik (Thesis advisor) / Miller, Clark (Thesis advisor) / Dirks, Gary (Committee member) / Arizona State University (Publisher)
Created2021
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Description
The metallization and interconnection of Si photovoltaic (PV) devices are among some of the most critically important aspects to ensure the PV cells and modules are cost-effective, highly-efficient, and robust through environmental stresses. The aim of this work is to contribute to the development of these innovations to move them

The metallization and interconnection of Si photovoltaic (PV) devices are among some of the most critically important aspects to ensure the PV cells and modules are cost-effective, highly-efficient, and robust through environmental stresses. The aim of this work is to contribute to the development of these innovations to move them closer to commercialization.Shingled PV modules and laser-welded foil-interconnected modules present an alternative to traditional soldered ribbons that can improve module power densities in a cost-effective manner. These two interconnection methods present new technical challenges for the PV industry. This work presents x-ray imaging methods to aid in the process-optimization of the application and curing of the adhesive material used in shingled modules. Further, detailed characterization of laser welds, their adhesion, and their effect on module performances is conducted. A strong correlation is found between the laser-weld adhesion and the modules’ durability through thermocycling. A minimum laser weld adhesion of 0.8 mJ is recommended to ensure a robust interconnection is formed. Detailed characterization and modelling are demonstrated on a 21% efficient double-sided tunnel-oxide passivating contact (DS-TOPCon) cell. This technology uses a novel approach that uses the front-metal grid to etch-away the parasitically-absorbing poly-Si material everywhere except for underneath the grid fingers. The modelling yielded a match to the experimental device within 0.06% absolute of its efficiency. This DS-TOPCon device could be improved to a 23.45%-efficient device by improving the optical performance, n-type contact resistivity, and grid finger aspect ratio. Finally, a modelling approach is explored for simulating Si thermophotovoltaic (TPV) devices. Experimentally fabricated diffused-junction devices are used to validate the optical and electrical aspects of the model. A peak TPV efficiency of 6.8% is predicted for the fabricated devices, but a pathway to 32.5% is explained by reducing the parasitic absorption of the contacts and reducing the wafer thickness. Additionally, the DS-TOPCon technology shows the potential for a 33.7% efficient TPV device.
ContributorsHartweg, Barry (Author) / Holman, Zachary (Thesis advisor) / Chan, Candace (Committee member) / Bertoni, Mariana (Committee member) / Yu, Zhengshan (Committee member) / Arizona State University (Publisher)
Created2023
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Description
An ongoing effort in the photovoltaic (PV) industry is to reduce the major manufacturing cost components of solar cells, the great majority of which are based on crystalline silicon (c-Si). This includes the substitution of screenprinted silver (Ag) cell contacts with alternative copper (Cu)-based contacts, usually applied with plating. Plated

An ongoing effort in the photovoltaic (PV) industry is to reduce the major manufacturing cost components of solar cells, the great majority of which are based on crystalline silicon (c-Si). This includes the substitution of screenprinted silver (Ag) cell contacts with alternative copper (Cu)-based contacts, usually applied with plating. Plated Cu contact schemes have been under study for many years with only minor traction in industrial production. One of the more commonly-cited barriers to the adoption of Cu-based contacts for photovoltaics is long-term reliability, as Cu is a significant contaminant in c-Si, forming precipitates that degrade performance via degradation of diode character and reduction of minority carrier lifetime. Cu contamination from contacts might cause degradation during field deployment if Cu is able to ingress into c-Si. Furthermore, Cu contamination is also known to cause a form of light-induced degradation (LID) which further degrades carrier lifetime when cells are exposed to light.

Prior literature on Cu-contact reliability tended to focus on accelerated testing at the cell and wafer level that may not be entirely replicative of real-world environmental stresses in PV modules. This thesis is aimed at advancing the understanding of Cu-contact reliability from the perspective of quasi-commercial modules under more realistic stresses. In this thesis, c-Si solar cells with Cu-plated contacts are fabricated, made into PV modules, and subjected to environmental stress in an attempt to induce hypothesized failure modes and understand any new vulnerabilities that Cu contacts might introduce. In particular, damp heat stress is applied to conventional, p-type c-Si modules and high efficiency, n-type c-Si heterojunction modules. I present evidence of Cu-induced diode degradation that also depends on PV module materials, as well as degradation unrelated to Cu, and in either case suggest engineering solutions to the observed degradation. In a forensic search for degradation mechanisms, I present novel evidence of Cu outdiffusion from contact layers and encapsulant-driven contact corrosion as potential key factors. Finally, outdoor exposures to light uncover peculiarities in Cu-plated samples, but do not point to especially serious vulnerabilities.
ContributorsKaras, Joseph (Author) / Bowden, Stuart (Thesis advisor) / Alford, Terry (Thesis advisor) / Tamizhmani, Govindasamy (Committee member) / Michaelson, Lynne (Committee member) / Arizona State University (Publisher)
Created2020