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ABSTRACT As the use of photovoltaic (PV) modules in large power plants continues to increase globally, more studies on degradation, reliability, failure modes, and mechanisms of field aged modules are needed to predict module life expectancy based on accelerated lifetime testing of PV modules. In this work, a 26+ year

ABSTRACT As the use of photovoltaic (PV) modules in large power plants continues to increase globally, more studies on degradation, reliability, failure modes, and mechanisms of field aged modules are needed to predict module life expectancy based on accelerated lifetime testing of PV modules. In this work, a 26+ year old PV power plant in Phoenix, Arizona has been evaluated for performance, reliability, and durability. The PV power plant, called Solar One, is owned and operated by John F. Long's homeowners association. It is a 200 kWdc, standard test conditions (STC) rated power plant comprised of 4000 PV modules or frameless laminates, in 100 panel groups (rated at 175 kWac). The power plant is made of two center-tapped bipolar arrays, the north array and the south array. Due to a limited time frame to execute this large project, this work was performed by two masters students (Jonathan Belmont and Kolapo Olakonu) and the test results are presented in two masters theses. This thesis presents the results obtained on the south array and the other thesis presents the results obtained on the north array. Each of these two arrays is made of four sub arrays, the east sub arrays (positive and negative polarities) and the west sub arrays (positive and negative polarities), making up eight sub arrays. The evaluation and analyses of the power plant included in this thesis consists of: visual inspection, electrical performance measurements, and infrared thermography. A possible presence of potential induced degradation (PID) due to potential difference between ground and strings was also investigated. Some installation practices were also studied and found to contribute to the power loss observed in this investigation. The power output measured in 2011 for all eight sub arrays at STC is approximately 76 kWdc and represents a power loss of 62% (from 200 kW to 76 kW) over 26+ years. The 2011 measured power output for the four south sub arrays at STC is 39 kWdc and represents a power loss of 61% (from 100 kW to 39 kW) over 26+ years. Encapsulation browning and non-cell interconnect ribbon breakages were determined to be the primary causes for the power loss.
ContributorsOlakonu, Kolapo (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2012
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Description
To increase the deployment of photovoltaic (PV) systems, a higher level of performance for PV modules should be sought. Soiling, or dust accumulation on the PV modules, is one of the conditions that negatively affect the performance of the PV modules by reducing the light incident onto the surface of

To increase the deployment of photovoltaic (PV) systems, a higher level of performance for PV modules should be sought. Soiling, or dust accumulation on the PV modules, is one of the conditions that negatively affect the performance of the PV modules by reducing the light incident onto the surface of the PV module. This thesis presents two studies that focus on investigating the soiling effect on the performance of the PV modules installed in Metro Phoenix area.

The first study was conducted to investigate the optimum cleaning frequency for cleaning PV modules installed in Mesa, AZ. By monitoring the soiling loss of PV modules mounted on a mock rooftop at ASU-PRL, a detailed soiling modeling was obtained. Same setup was also used for other soiling-related investigations like studying the effect of soiling density on angle of incidence (AOI) dependence, the climatological relevance (CR) to soiling, and spatial variation of the soiling loss. During the first dry season (May to June), the daily soiling rate was found as -0.061% for 20o tilted modules. Based on the obtained soiling rate, cleaning PV modules, when the soiling is just due to dust on 20o tilted residential arrays, was found economically not justifiable.

The second study focuses on evaluating the soiling loss in different locations of Metro Phoenix area of Arizona. The main goal behind the second study was to validate the daily soiling rate obtained from the mock rooftop setup in the first part of this thesis. By collaborating with local solar panel cleaning companies, soiling data for six residential systems in 5 different cities in and around Phoenix was collected, processed, and analyzed. The range of daily soiling rate in the Phoenix area was found as -0.057% to -0.085% for 13-28o tilted arrays. The soiling rate found in the first part of the thesis (-0.061%) for 20o tilted array, was validated since it falls within the range obtained from the second part of the thesis.
ContributorsNaeem, Mohammad Hussain (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Srinivasan, Devarajan (Committee member) / Arizona State University (Publisher)
Created2014
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Description
A primary motivation of research in photovoltaic technology is to obtain higher efficiency photovoltaic devices at reduced cost of production so that solar electricity can be cost competitive. The majority of photovoltaic technologies are based on p-n junction, with efficiency potential being much lower than the thermodynamic limits of individual

A primary motivation of research in photovoltaic technology is to obtain higher efficiency photovoltaic devices at reduced cost of production so that solar electricity can be cost competitive. The majority of photovoltaic technologies are based on p-n junction, with efficiency potential being much lower than the thermodynamic limits of individual technologies and thereby providing substantial scope for further improvements in efficiency. The thesis explores photovoltaic devices using new physical processes that rely on thin layers and are capable of attaining the thermodynamic limit of photovoltaic technology. Silicon heterostructure is one of the candidate technologies in which thin films induce a minority carrier collecting junction in silicon and the devices can achieve efficiency close to the thermodynamic limits of silicon technology. The thesis proposes and experimentally establishes a new theory explaining the operation of silicon heterostructure solar cells. The theory will assist in identifying the optimum properties of thin film materials for silicon heterostructure and help in design and characterization of the devices, along with aiding in developing new devices based on this technology. The efficiency potential of silicon heterostructure is constrained by the thermodynamic limit (31%) of single junction solar cell and is considerably lower than the limit of photovoltaic conversion (~ 80 %). A further improvement in photovoltaic conversion efficiency is possible by implementing a multiple quasi-fermi level system (MQFL). A MQFL allows the absorption of sub band gap photons with current being extracted at a higher band-gap, thereby allowing to overcome the efficiency limit of single junction devices. A MQFL can be realized either by thin epitaxial layers of alternating higher and lower band gap material with nearly lattice matched (quantum well) or highly lattice mismatched (quantum dot) structure. The thesis identifies the material combination for quantum well structure and calculates the absorption coefficient of a MQFl based on quantum well. GaAsSb (barrier)/InAs(dot) was identified as a candidate material for MQFL using quantum dot. The thesis explains the growth mechanism of GaAsSb and the optimization of GaAsSb and GaAs heterointerface.
ContributorsGhosha, Kuṇāla (Author) / Bowden, Stuart (Thesis advisor) / Honsberg, Christiana (Thesis advisor) / Vasileska, Dragica (Committee member) / Goodnick, Stephen (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Photovoltaic (PV) modules undergo performance degradation depending on climatic conditions, applications, and system configurations. The performance degradation prediction of PV modules is primarily based on Accelerated Life Testing (ALT) procedures. In order to further strengthen the ALT process, additional investigation of the power degradation of field aged PV modules in

Photovoltaic (PV) modules undergo performance degradation depending on climatic conditions, applications, and system configurations. The performance degradation prediction of PV modules is primarily based on Accelerated Life Testing (ALT) procedures. In order to further strengthen the ALT process, additional investigation of the power degradation of field aged PV modules in various configurations is required. A detailed investigation of 1,900 field aged (12-18 years) PV modules deployed in a power plant application was conducted for this study. Analysis was based on the current-voltage (I-V) measurement of all the 1,900 modules individually. I-V curve data of individual modules formed the basis for calculating the performance degradation of the modules. The percentage performance degradation and rates of degradation were compared to an earlier study done at the same plant. The current research was primarily focused on identifying the extent of potential induced degradation (PID) of individual modules with reference to the negative ground potential. To investigate this, the arrangement and connection of the individual modules/strings was examined in detail. The study also examined the extent of underperformance of every series string due to performance mismatch of individual modules in that string. The power loss due to individual module degradation and module mismatch at string level was then compared to the rated value.
ContributorsJaspreet Singh (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Photovoltaic (PV) modules are typically rated at three test conditions: STC (standard test conditions), NOCT (nominal operating cell temperature) and Low E (low irradiance). The current thesis deals with the power rating of PV modules at twenty-three test conditions as per the recent International Electrotechnical Commission (IEC) standard of IEC

Photovoltaic (PV) modules are typically rated at three test conditions: STC (standard test conditions), NOCT (nominal operating cell temperature) and Low E (low irradiance). The current thesis deals with the power rating of PV modules at twenty-three test conditions as per the recent International Electrotechnical Commission (IEC) standard of IEC 61853 – 1. In the current research, an automation software tool developed by a previous researcher of ASU – PRL (ASU Photovoltaic Reliability Laboratory) is validated at various stages. Also in the current research, the power rating of PV modules for four different manufacturers is carried out according to IEC 61853 – 1 standard using a new outdoor test method. The new outdoor method described in this thesis is very different from the one reported by a previous researcher of ASU – PRL. The new method was designed to reduce the labor hours in collecting the current-voltage ( I – V) curves at various temperatures and irradiance levels. The power matrices for all the four manufacturers were generated using the I – V data generated at different temperatures and irradiance levels and the translation procedures described in IEC 60891 standard. All the measurements were carried out on both clear and cloudy days using an automated 2 – axis tracker located at ASU – PRL, Mesa, Arizona. The modules were left on the 2 – axis tracker for 12 continuous days and the data was continuously and automatically collected for every two minutes from 6 am to 6 pm. In order to obtain the I – V data at wide range of temperatures and irradiance levels, four identical (or nearly identical) modules were simultaneously installed on the 2 – axis tracker with and without thermal insulators on the back of the modules and with and without mesh screens on the front of the modules. Several issues related to the automation software were uncovered and the required improvement in the software has been suggested. The power matrices for four manufacturers have been successfully generated using the new outdoor test method developed in this work. The data generated in this work has been extensively analyzed for accuracy and for performance efficiency comparison at various temperatures and irradiance levels.
ContributorsVemula, Meena Gupta (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Macia, Narcio F. (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2012
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Description
This dissertation addresses challenges pertaining to multi-junction (MJ) solar cells from material development to device design and characterization. Firstly, among the various methods to improve the energy conversion efficiency of MJ solar cells using, a novel approach proposed recently is to use II-VI (MgZnCd)(SeTe) and III-V (AlGaIn)(AsSb) semiconductors lattice-matched on

This dissertation addresses challenges pertaining to multi-junction (MJ) solar cells from material development to device design and characterization. Firstly, among the various methods to improve the energy conversion efficiency of MJ solar cells using, a novel approach proposed recently is to use II-VI (MgZnCd)(SeTe) and III-V (AlGaIn)(AsSb) semiconductors lattice-matched on GaSb or InAs substrates for current-matched subcells with minimal defect densities. CdSe/CdTe superlattices are proposed as a potential candidate for a subcell in the MJ solar cell designs using this material system, and therefore the material properties of the superlattices are studied. The high structural qualities of the superlattices are obtained from high resolution X-ray diffraction measurements and cross-sectional transmission electron microscopy images. The effective bandgap energies of the superlattices obtained from the photoluminescence (PL) measurements vary with the layer thicknesses, and are smaller than the bandgap energies of either the constituent material. Furthermore, The PL peak position measured at the steady state exhibits a blue shift that increases with the excess carrier concentration. These results confirm a strong type-II band edge alignment between CdSe and CdTe. The valence band offset between unstrained CdSe and CdTe is determined as 0.63 eV±0.06 eV by fitting the measured PL peak positions using the Kronig-Penney model. The blue shift in PL peak position is found to be primarily caused by the band bending effect based on self-consistent solutions of the Schrödinger and Poisson equations. Secondly, the design of the contact grid layout is studied to maximize the power output and energy conversion efficiency for concentrator solar cells. Because the conventional minimum power loss method used for the contact design is not accurate in determining the series resistance loss, a method of using a distributed series resistance model to maximize the power output is proposed for the contact design. It is found that the junction recombination loss in addition to the series resistance loss and shadowing loss can significantly affect the contact layout. The optimal finger spacing and maximum efficiency calculated by the two methods are close, and the differences are dependent on the series resistance and saturation currents of solar cells. Lastly, the accurate measurements of external quantum efficiency (EQE) are important for the design and development of MJ solar cells. However, the electrical and optical couplings between the subcells have caused EQE measurement artifacts. In order to interpret the measurement artifacts, DC and small signal models are built for the bias condition and the scan of chopped monochromatic light in the EQE measurements. Characterization methods are developed for the device parameters used in the models. The EQE measurement artifacts are found to be caused by the shunt and luminescence coupling effects, and can be minimized using proper voltage and light biases. Novel measurement methods using a pulse voltage bias or a pulse light bias are invented to eliminate the EQE measurement artifacts. These measurement methods are nondestructive and easy to implement. The pulse voltage bias or pulse light bias is superimposed on the conventional DC voltage and light biases, in order to control the operating points of the subcells and counterbalance the effects of shunt and luminescence coupling. The methods are demonstrated for the first time to effectively eliminate the measurement artifacts.
ContributorsLi, Jingjing (Author) / Zhang, Yong-Hang (Thesis advisor) / Tao, Meng (Committee member) / Schroder, Dieter (Committee member) / Vasileska, Dragica (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Testing was conducted for a solar assisted water heater and conventional all electric water heater for the purpose of investigating the advantages of utilizing solar energy to heat up water. The testing conducted simulated a four person household living in the Phoenix, Arizona region. With sensors and a weather station,

Testing was conducted for a solar assisted water heater and conventional all electric water heater for the purpose of investigating the advantages of utilizing solar energy to heat up water. The testing conducted simulated a four person household living in the Phoenix, Arizona region. With sensors and a weather station, data was gathered and analyzed for the water heaters. Performance patterns were observed that correlated to ambient conditions and functionality of the solar assisted water heater. This helped better understand how the solar water heater functioned and how it may continue to function. The testing for the solar assisted water heater was replicated with the all-electric water heater. One to one analyzes was conducted for comparison. The efficiency and advantages were displayed by the solar assisted water heater having a 61% efficiency. Performance parameters were calculated for the solar assisted water heater and it showed how accurate certified standards are. The results showed 8% difference in performance, but differed in energy savings. This further displayed the effects of uncontrollable ambient conditions and the effects of different testing conditions.
ContributorsMartínez, Luis, active 1995 (Author) / Rajadas, John (Thesis advisor) / Kannan, Arunachala (Committee member) / Rogers, Bradley (Committee member) / Arizona State University (Publisher)
Created2016
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Description
It has been a long-standing goal to epitaxially integrate III-V alloys with Si substrates which can enable low-cost microelectronic and optoelectronic systems. Among the III-V alloys, gallium phosphide (GaP) is a strong candidate, especially for solar cells applications. Gallium phosphide with small lattice mismatch (~0.4%) to Si enables coherent/pseudomorphic epitaxial

It has been a long-standing goal to epitaxially integrate III-V alloys with Si substrates which can enable low-cost microelectronic and optoelectronic systems. Among the III-V alloys, gallium phosphide (GaP) is a strong candidate, especially for solar cells applications. Gallium phosphide with small lattice mismatch (~0.4%) to Si enables coherent/pseudomorphic epitaxial growth with little crystalline defect creation. The band offset between Si and GaP suggests that GaP can function as an electron-selective contact, and it has been theoretically shown that GaP/Si integrated solar cells have the potential to overcome the limitations of common a-Si based heterojunction (SHJ) solar cells.

Despite the promising potential of GaP/Si heterojunction solar cells, there are two main obstacles to realize high performance photovoltaic devices from this structure. First, the growth of the polar material (GaP) on the non-polar material (Si) is a challenge in how to suppress the formation of structural defects, such as anti-phase domains (APD). Further, it is widely observed that the minority-carrier lifetime of the Si substrates is significantly decreased during epitaxially growth of GaP on Si.

In this dissertation, two different GaP growth methods were compared and analyzed, including migration-enhanced epitaxy (MEE) and traditional molecular beam epitaxy (MBE). High quality GaP can be realized on precisely oriented (001) Si substrates by MBE growth, and the investigation of structural defect creation in the GaP/Si epitaxial structures was conducted using high resolution X-ray diffraction (HRXRD) and high resolution transmission electron microscopy (HRTEM).

The mechanisms responsible for lifetime degradation were further investigated, and it was found that external fast diffusors are the origin for the degradation. Two practical approaches including the use of both a SiNx diffusion barrier layer and P-diffused layers, to suppress the Si minority-carrier lifetime degradation during GaP epitaxial growth on Si by MBE were proposed. To achieve high performance of GaP/Si solar cells, different GaP/Si structures were designed, fabricated and compared, including GaP as a hetero-emitter, GaP as a heterojunction on the rear side, inserting passivation membrane layers at the GaP/Si interface, and GaP/wet-oxide functioning as a passivation contact. A designed of a-Si free carrier-selective contact MoOx/Si/GaP solar cells demonstrated 14.1% power conversion efficiency.
ContributorsZhang, Chaomin (Author) / Honsberg, Christiana (Thesis advisor) / King, Richard (Thesis advisor) / Goodnick, Stephen (Committee member) / Faleev, Nikolai (Committee member) / Bowden, Stuart (Committee member) / Arizona State University (Publisher)
Created2017
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Description
Thermal modeling and investigation into heat extraction methods for building-applied photovoltaic (BAPV) systems have become important for the industry in order to predict energy production and lower the cost per kilowatt-hour (kWh) of generating electricity from these types of systems. High operating temperatures have a direct impact on the performance

Thermal modeling and investigation into heat extraction methods for building-applied photovoltaic (BAPV) systems have become important for the industry in order to predict energy production and lower the cost per kilowatt-hour (kWh) of generating electricity from these types of systems. High operating temperatures have a direct impact on the performance of BAPV systems and can reduce power output by as much as 10 to 20%. The traditional method of minimizing the operating temperature of BAPV modules has been to include a suitable air gap for ventilation between the rooftop and the modules. There has been research done at Arizona State University (ASU) which investigates the optimum air gap spacing on sufficiently spaced (2-6 inch vertical; 2-inch lateral) modules of four columns. However, the thermal modeling of a large continuous array (with multiple modules of the same type and size and at the same air gap) had yet to be done at ASU prior to this project. In addition to the air gap effect analysis, the industry is exploring different ways of extracting the heat from PV modules including hybrid photovoltaic-thermal systems (PV/T). The goal of this project was to develop a thermal model for a small residential BAPV array consisting of 12 identical polycrystalline silicon modules at an air gap of 2.5 inches from the rooftop. The thermal model coefficients are empirically derived from a simulated field test setup at ASU and are presented in this thesis. Additionally, this project investigates the effects of cooling the array with a 40-Watt exhaust fan. The fan had negligible effect on power output or efficiency for this 2.5-inch air gap array, but provided slightly lower temperatures and better temperature uniformity across the array.
ContributorsHrica, Jonathan Kyler (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Rogers, Bradley (Committee member) / Macia, Narciso (Committee member) / Arizona State University (Publisher)
Created2010
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Description
Wire connected solar cells are a promising new technology that can increase the efficiency and reduce the cost of solar modules. The use of wire rather than ribbon bus bars can lead to reduced shading, better light trapping, and reduced material costs, all while eliminating the need for soldering. This

Wire connected solar cells are a promising new technology that can increase the efficiency and reduce the cost of solar modules. The use of wire rather than ribbon bus bars can lead to reduced shading, better light trapping, and reduced material costs, all while eliminating the need for soldering. This research first analyzes the optimal wire gauge to reduce cracking and improve efficiency. Wire sizes between 20 AWG and 28 AWG were tested, with the optimal size being between 24 AWG and 26 AWG for the ethylene vinyl acetate (EVA) layer used in the module. A polyethylene sheet was then added between the wires and EVA layer to prevent the EVA from running underneath the wires during lamination, ultimately allowing for a more uniform contact and only a slight reduction in quantum efficiency. Then, a comparison between tinned copper wires and indium coated copper wires is shown. A mini-module efficiency of 20.0% has been achieved using tinned copper wires, while indium coated copper wires have produced a mini-module efficiency of 21.2%. Thus, tinned copper wires can be a viable alternative to indium coated copper wires, depending on the needs of the customers and the current price of indium. The module design throughout the research utilizes a planar assembly method, which improves the ease of manufacturing for wire interconnection technology. A two-cell base component is constructed and shown, with the intended future application of making large wire connected modules. Finally, wire applications in both single-cell and four-cell flexible modules are explored, with an efficiency of 18.65% achieved on a single-cell, flexible, heterojunction solar module using wire interconnections. A fully flexible four-cell string is developed, and future recommendations for related research are included.
ContributorsTyler, Kevin Daniel (Author) / Bowden, Stuart (Thesis director) / Herasimenka, Stanislau (Committee member) / Electrical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2015-12