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- All Subjects: Particulate matter
- All Subjects: remote sensing
- Creators: Clarke, Amanda
Description
Americans spend upwards of 90% of their time indoors, hence indoor air quality (IAQ) and the impact of IAQ on human health is a major public health concern. IAQ can be negatively impacted by outdoor pollution infiltrating indoors, the emission of indoor pollutants, indoor atmospheric chemistry and poor ventilation. Energy saving measures like retrofits to seal the building envelope to prevent the leakage of heated or cooled air will impact IAQ. However, existing studies have been inconclusive as to whether increased energy efficiency is leading to detrimental IAQ. In this work, field campaigns were conducted in apartment homes in Phoenix, Arizona to evaluate IAQ as it relates to particulate matter (PM), carbonyls, and tobacco specific nitrosamines (TSNA).
To investigate the impacts of an energy efficiency retrofit on IAQ, indoor and outdoor air quality sampling was carried out at Sunnyslope Manor, a city-subsidized senior living apartment complex. Measured indoor formaldehyde levels before the building retrofit exceeded reference exposure limits, but in the long term follow-up sampling, indoor formaldehyde decreased for the entire study population by a statistically significant margin. Indoor PM levels were dominated by fine particles and showed a statistically significant decrease in the long term follow-up sampling within certain resident subpopulations (i.e. residents who reported smoking and residents who had lived longer at the apartment complex). Additionally, indoor glyoxal and methylglyoxal exceeded outdoor concentrations, with methylglyoxal being more prevalent pre-retrofit than glyoxal, suggesting different chemical pathways are involved. Indoor concentrations reported are larger than previous studies. TSNAs, specifically N'-nitrosonornicotine (NNN), 4-(methyl-nitrosamino)-4-(3-pyridyl)-butanal (NNA) and 4-(methylnitrosoamino)-1-(3-pyridyl)-1-butanone (NNK) were evaluated post-retrofit at Sunnyslope Manor. Of the units tested, 86% of the smoking units and 46% of the non-smoking units had traces of at least one of the nitrosamines.
To investigate the impacts of an energy efficiency retrofit on IAQ, indoor and outdoor air quality sampling was carried out at Sunnyslope Manor, a city-subsidized senior living apartment complex. Measured indoor formaldehyde levels before the building retrofit exceeded reference exposure limits, but in the long term follow-up sampling, indoor formaldehyde decreased for the entire study population by a statistically significant margin. Indoor PM levels were dominated by fine particles and showed a statistically significant decrease in the long term follow-up sampling within certain resident subpopulations (i.e. residents who reported smoking and residents who had lived longer at the apartment complex). Additionally, indoor glyoxal and methylglyoxal exceeded outdoor concentrations, with methylglyoxal being more prevalent pre-retrofit than glyoxal, suggesting different chemical pathways are involved. Indoor concentrations reported are larger than previous studies. TSNAs, specifically N'-nitrosonornicotine (NNN), 4-(methyl-nitrosamino)-4-(3-pyridyl)-butanal (NNA) and 4-(methylnitrosoamino)-1-(3-pyridyl)-1-butanone (NNK) were evaluated post-retrofit at Sunnyslope Manor. Of the units tested, 86% of the smoking units and 46% of the non-smoking units had traces of at least one of the nitrosamines.
ContributorsFrey, Sarah E (Author) / Herckes, Pierre (Thesis advisor) / Fraser, Matthew P (Thesis advisor) / Destaillats, Hugo (Committee member) / Chizmeshya, Andrew (Committee member) / Arizona State University (Publisher)
Created2014
Description
The dynamic Earth involves feedbacks between the solid crust and both natural and anthropogenic fluid flows. Fluid-rock interactions drive many Earth phenomena, including volcanic unrest, seismic activities, and hydrological responses. Mitigating the hazards associated with these activities requires fundamental understanding of the underlying physical processes. Therefore, geophysical monitoring in combination with modeling provides valuable tools, suitable for hazard mitigation and risk management efforts. Magmatic activities and induced seismicity linked to fluid injection are two natural and anthropogenic processes discussed in this dissertation.
Successful forecasting of the timing, style, and intensity of a volcanic eruption is made possible by improved understanding of the volcano life cycle as well as building quantitative models incorporating the processes that govern rock melting, melt ascending, magma storage, eruption initiation, and interaction between magma and surrounding host rocks at different spatial extent and time scale. One key part of such models is the shallow magma chamber, which is generally directly linked to volcano’s eruptive behaviors. However, its actual shape, size, and temporal evolution are often not entirely known. To address this issue, I use space-based geodetic data with high spatiotemporal resolution to measure surface deformation at Kilauea volcano. The obtained maps of InSAR (Interferometric Synthetic Aperture Radar) deformation time series are exploited with two novel modeling schemes to investigate Kilauea’s shallow magmatic system. Both models can explain the same observation, leading to a new compartment model of magma chamber. Such models significantly advance the understanding of the physical processes associated with Kilauea’s summit plumbing system with potential applications for volcanoes around the world.
The unprecedented increase in the number of earthquakes in the Central and Eastern United States since 2008 is attributed to massive deep subsurface injection of saltwater. The elevated chance of moderate-large damaging earthquakes stemming from increased seismicity rate causes broad societal concerns among industry, regulators, and the public. Thus, quantifying the time-dependent seismic hazard associated with the fluid injection is of great importance. To this end, I investigate the large-scale seismic, hydrogeologic, and injection data in northern Texas for period of 2007-2015 and in northern-central Oklahoma for period of 1995-2017. An effective induced earthquake forecasting model is developed, considering a complex relationship between injection operations and consequent seismicity. I find that the timing and magnitude of regional induced earthquakes are fully controlled by the process of fluid diffusion in a poroelastic medium and thus can be successfully forecasted. The obtained time-dependent seismic hazard model is spatiotemporally heterogeneous and decreasing injection rates does not immediately reduce the probability of an earthquake. The presented framework can be used for operational induced earthquake forecasting. Information about the associated fundamental processes, inducing conditions, and probabilistic seismic hazards has broad benefits to the society.
Successful forecasting of the timing, style, and intensity of a volcanic eruption is made possible by improved understanding of the volcano life cycle as well as building quantitative models incorporating the processes that govern rock melting, melt ascending, magma storage, eruption initiation, and interaction between magma and surrounding host rocks at different spatial extent and time scale. One key part of such models is the shallow magma chamber, which is generally directly linked to volcano’s eruptive behaviors. However, its actual shape, size, and temporal evolution are often not entirely known. To address this issue, I use space-based geodetic data with high spatiotemporal resolution to measure surface deformation at Kilauea volcano. The obtained maps of InSAR (Interferometric Synthetic Aperture Radar) deformation time series are exploited with two novel modeling schemes to investigate Kilauea’s shallow magmatic system. Both models can explain the same observation, leading to a new compartment model of magma chamber. Such models significantly advance the understanding of the physical processes associated with Kilauea’s summit plumbing system with potential applications for volcanoes around the world.
The unprecedented increase in the number of earthquakes in the Central and Eastern United States since 2008 is attributed to massive deep subsurface injection of saltwater. The elevated chance of moderate-large damaging earthquakes stemming from increased seismicity rate causes broad societal concerns among industry, regulators, and the public. Thus, quantifying the time-dependent seismic hazard associated with the fluid injection is of great importance. To this end, I investigate the large-scale seismic, hydrogeologic, and injection data in northern Texas for period of 2007-2015 and in northern-central Oklahoma for period of 1995-2017. An effective induced earthquake forecasting model is developed, considering a complex relationship between injection operations and consequent seismicity. I find that the timing and magnitude of regional induced earthquakes are fully controlled by the process of fluid diffusion in a poroelastic medium and thus can be successfully forecasted. The obtained time-dependent seismic hazard model is spatiotemporally heterogeneous and decreasing injection rates does not immediately reduce the probability of an earthquake. The presented framework can be used for operational induced earthquake forecasting. Information about the associated fundamental processes, inducing conditions, and probabilistic seismic hazards has broad benefits to the society.
ContributorsZhai, Guang (Author) / Shirzaei, Manoochehr (Thesis advisor) / Garnero, Edward (Committee member) / Clarke, Amanda (Committee member) / Tyburczy, James (Committee member) / Li, Mingming (Committee member) / Arizona State University (Publisher)
Created2018
Description
Understanding and predicting climate changes at the urban scale have been an important yet challenging problem in environmental engineering. The lack of reliable long-term observations at the urban scale makes it difficult to even assess past climate changes. Numerical modeling plays an important role in filling the gap of observation and predicting future changes. Numerical studies on the climatic effect of desert urbanization have focused on basic meteorological fields such as temperature and wind. For desert cities, urban expansion can lead to substantial changes in the local production of wind-blown dust, which have implications for air quality and public health. This study expands the existing framework of numerical simulation for desert urbanization to include the computation of dust generation related to urban land-use changes. This is accomplished by connecting a suite of numerical models, including a meso-scale meteorological model, a land-surface model, an urban canopy model, and a turbulence model, to produce the key parameters that control the surface fluxes of wind-blown dust. Those models generate the near-surface turbulence intensity, soil moisture, and land-surface properties, which are used to determine the dust fluxes from a set of laboratory-based empirical formulas. This framework is applied to a series of simulations for the desert city of Erbil across a period of rapid urbanization. The changes in surface dust fluxes associated with urbanization are quantified. An analysis of the model output further reveals the dependence of surface dust fluxes on local meteorological conditions. Future applications of the models to environmental prediction are discussed.
ContributorsTahir, Sherzad Tahseen (Author) / Huang, Huei-Ping (Thesis advisor) / Phelan, Patrick (Committee member) / Herrmann, Marcus (Committee member) / Chen, Kangping (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2019
Description
Among volcanic gases, sulfur dioxide (SO2) is by far the most commonly measured. More than a monitoring proxy for volcanic degassing, SO2 has the potential to alter climate patterns. Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day, spanning years to decades. SO2 emissions at those volcanoes are poorly constrained, in large part because the current satellite monitoring techniques are unable to detect or quantify plumes of low concentration in the troposphere. Eruption plumes also often show high concentrations of ash and/or aerosols, which further inhibit the detection methods. In this work I focus on quantifying volcanic gas emissions at persistently active explosive volcanoes and their variations over short timescales (minutes to hours), in order to document their contribution to natural SO2 flux as well as investigate the physical processes that control their behavior.
In order to make these measurements, I first develop and assemble a UV ground-based instrument, and validate it against an independently measured source of SO2 at a coal-burning power plant in Arizona. I establish a measurement protocol and demonstrate that the instrument measures SO2 fluxes with < 20 % error. Using the same protocol, I establish a record of the degassing patterns at Semeru volcano (Indonesia), a volcano that has been producing cycles of repeated explosions with periods of minutes to hours for the past several decades. Semeru produces an average of 21-71 tons of SO2 per day, amounting to a yearly output of 8-26 Mt.
Using the Semeru data, along with a 1-D transient numerical model of magma ascent, I test the validity of a model in which a viscous plug at the top of the conduit produces cycles of eruption and gas release. I find that it can be a valid hypothesis to explain the observed patterns of degassing at Semeru. Periodic behavior in such a system occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it.
In order to make these measurements, I first develop and assemble a UV ground-based instrument, and validate it against an independently measured source of SO2 at a coal-burning power plant in Arizona. I establish a measurement protocol and demonstrate that the instrument measures SO2 fluxes with < 20 % error. Using the same protocol, I establish a record of the degassing patterns at Semeru volcano (Indonesia), a volcano that has been producing cycles of repeated explosions with periods of minutes to hours for the past several decades. Semeru produces an average of 21-71 tons of SO2 per day, amounting to a yearly output of 8-26 Mt.
Using the Semeru data, along with a 1-D transient numerical model of magma ascent, I test the validity of a model in which a viscous plug at the top of the conduit produces cycles of eruption and gas release. I find that it can be a valid hypothesis to explain the observed patterns of degassing at Semeru. Periodic behavior in such a system occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it.
ContributorsSmekens, Jean-François (Author) / Clarke, Amanda (Thesis advisor) / Christensen, Philip R. (Philip Russel) (Committee member) / Williams, Stanley (Committee member) / Burton, Michael (Committee member) / Fink, Jonathan (Committee member) / Moore, Gordon (Committee member) / Arizona State University (Publisher)
Created2015
Description
On Mars, sedimentary deposits reveal a complex history of water- and wind-related geologic processes. Central mounds – kilometer-scale stacks of sediment located within craters – occur across Mars, but the specific processes responsible for mound formation and subsequent modification are still uncertain. A survey of central mounds within large craters was conducted. Mound locations, mound offsets within their host craters, and relative mound heights were used to address various mound formation hypotheses. The results suggest that mound sediments once filled their host craters and were later eroded into the features observed today. Mounds offsets from the center of their host crater imply that wind caused the erosion of central mounds. An in depth study of a single central mound (Mt. Sharp within Gale crater) was also conducted. Thermal Emission Imaging System Visible Imaging Subsystem (THEMIS-VIS) mosaics in grayscale and false color were used to characterize the morphology and color variations in and around Gale crater. One result of this study is that dunes within Gale crater vary in false color composites from blue to purple, and that these color differences may be due to changes in dust cover, grain size, and/or composition. To further investigate dune fields on Mars, albedo variations at eight dune fields were studied based on the hypothesis that a dune’s ripple migration rate is correlated to its albedo. This study concluded that a dune’s minimum albedo does not have a simple correlation with its ripple migration rate. Instead, dust devils remove dust on slow-moving and immobile dunes, whereas saltating sand caused by strong winds removes dust on faster-moving dunes.
On the Moon, explosive volcanic deposits within Oppenheimer crater that were emplaced ballistically were investigated. Lunar Reconnaissance Orbiter (LRO) Diviner Radiometer mid-infrared data, LRO Camera images, and Chandrayaan-1 orbiter Moon Mineralogy Mapper near-infrared spectra were used to test the hypothesis that the pyroclastic deposits in Oppenheimer crater were emplaced via Vulcanian activity by constraining their composition and mineralogy. The mineralogy and iron-content of the pyroclastic deposits vary significantly (including examples of potentially very high iron compositions), which indicates variability in eruption style. These results suggest that localized lunar pyroclastic deposits may have a more complex origin and mode of emplacement than previously thought.
On the Moon, explosive volcanic deposits within Oppenheimer crater that were emplaced ballistically were investigated. Lunar Reconnaissance Orbiter (LRO) Diviner Radiometer mid-infrared data, LRO Camera images, and Chandrayaan-1 orbiter Moon Mineralogy Mapper near-infrared spectra were used to test the hypothesis that the pyroclastic deposits in Oppenheimer crater were emplaced via Vulcanian activity by constraining their composition and mineralogy. The mineralogy and iron-content of the pyroclastic deposits vary significantly (including examples of potentially very high iron compositions), which indicates variability in eruption style. These results suggest that localized lunar pyroclastic deposits may have a more complex origin and mode of emplacement than previously thought.
ContributorsBennett, Kristen Alicia (Author) / Bell, James F. (Thesis advisor) / Christensen, Phillip (Committee member) / Clarke, Amanda (Committee member) / Robinson, Mark (Committee member) / Whipple, Kelin (Committee member) / Arizona State University (Publisher)
Created2016
Description
To investigate the impacts of an energy efficiency retrofit, indoor air quality and resident health were evaluated at a low‐income senior housing apartment complex in Phoenix, Arizona, before and after a green energy building renovation. Indoor and outdoor air quality sampling was carried out simultaneously with a questionnaire to characterize personal habits and general health of residents. Measured indoor formaldehyde levels before the building retrofit routinely exceeded reference exposure limits, but in the long‐term follow‐up sampling, indoor formaldehyde decreased for the entire study population by a statistically significant margin. Indoor PM levels were dominated by fine particles and showed a statistically significant decrease in the long‐term follow‐up sampling within certain resident subpopulations (i.e. residents who report smoking and residents who had lived longer at the apartment complex).
ContributorsFrey, S.E. (Author) / Destaillats, H. (Author) / Cohn, S. (Author) / Ahrentzen, S. (Author) / Fraser, M.P. (Author)
Created2015
Description
Quantifying halogen presence and speciation in particulate matter is crucial given the role atmospheric particulates play in transport and cycling. While some halogens (fluorine and chlorine) are often included in aerosol studies, iodine and bromine have rarely been examined, especially outside of a marine environment. Focus on this environment is, in part, due to the existence of biogenic marine sources for both halogens. However, examining iodine and bromine in an urban environment has the potential to provide key insights into the transport and processing of these species in the atmosphere. As Tempe is set within a desert environment, bromine concentration is expected to be relatively high due to its presence in Earth’s crust, while iodine is expected to exist in higher concentrations near the coast. To detect presence and concentration, ICP-MS analysis was performed on samples taken in Tempe, AZ as well as sites in Bakersfield, CA and Davis, CA, which yielded preliminary results in line with these expectations. A secondary set of samples were taken in Tempe, AZ during dust storms, haboobs, and winter holidays. CIC was used to determine the organic fraction. In doing so, this study aims to identify species present in an urban environment as well as potential transportation pathways.
ContributorsLoera, Lourdes (Author) / Herckes, Pierre (Thesis director) / Richert, Ranko (Committee member) / Fraser, Matthew (Committee member) / Barrett, The Honors College (Contributor) / School of Molecular Sciences (Contributor) / School of Human Evolution & Social Change (Contributor)
Created2023-05
Description
Atmospheric particulate matter (PM) has a pronounced effect on our climate, and exposure to PM causes negative health outcomes and elevated mortality rates in urban populations. Reactions that occur in fog can form new secondary organic aerosol material from gas-phase species or primary organic aerosols. It is important to understand these reactions, as well as how organic material is scavenged and deposited, so that climate and health effects can be fully assessed. Stable carbon isotopes have been used widely in studying gas- and particle-phase atmospheric chemistry. However, the processing of organic matter by fog has not yet been studied, even though stable isotopes can be used to track all aspects of atmospheric processing, from particle formation, particle scavenging, reactions that form secondary organic aerosol material, and particle deposition. Here, carbon isotope analysis is used for the first time to assess the processing of carbonaceous particles by fog.
This work first compares carbon isotope measurements (δ13C) of particulate matter and fog from locations across the globe to assess how different primary aerosol sources are reflected in the atmosphere. Three field campaigns are then discussed that highlight different aspects of PM formation, composition, and processing. In Tempe, AZ, seasonal and size-dependent differences in the δ13C of total carbon and n-alkanes in PM were studied. δ13C was influenced by seasonal trends, including inversion, transport, population density, and photochemical activity. Variations in δ13C among particle size fractions were caused by sources that generate particles in different size modes.
An analysis of PM from urban and suburban sites in northeastern France shows how both fog and rain can cause measurable changes in the δ13C of PM. The δ13C of PM was consistent over time when no weather events occurred, but particles were isotopically depleted by up to 1.1‰ in the presence of fog due to preferential scavenging of larger isotopically enriched particles. Finally, the δ13C of the dissolved organic carbon in fog collected on the coast of Southern California is discussed. Here, temporal depletion of the δ13C of fog by up to 1.2‰ demonstrates its use in observing the scavenging and deposition of organic PM.
This work first compares carbon isotope measurements (δ13C) of particulate matter and fog from locations across the globe to assess how different primary aerosol sources are reflected in the atmosphere. Three field campaigns are then discussed that highlight different aspects of PM formation, composition, and processing. In Tempe, AZ, seasonal and size-dependent differences in the δ13C of total carbon and n-alkanes in PM were studied. δ13C was influenced by seasonal trends, including inversion, transport, population density, and photochemical activity. Variations in δ13C among particle size fractions were caused by sources that generate particles in different size modes.
An analysis of PM from urban and suburban sites in northeastern France shows how both fog and rain can cause measurable changes in the δ13C of PM. The δ13C of PM was consistent over time when no weather events occurred, but particles were isotopically depleted by up to 1.1‰ in the presence of fog due to preferential scavenging of larger isotopically enriched particles. Finally, the δ13C of the dissolved organic carbon in fog collected on the coast of Southern California is discussed. Here, temporal depletion of the δ13C of fog by up to 1.2‰ demonstrates its use in observing the scavenging and deposition of organic PM.
ContributorsNapolitano, Denise (Author) / Herckes, Pierre (Thesis advisor) / Fraser, Matthew (Committee member) / Shock, Everett (Committee member) / Arizona State University (Publisher)
Created2018
Description
Chemical and physical interactions of flowing ice and rock have inexorably shaped planetary surfaces. Weathering in glacial environments is a significant link in biogeochemical cycles – carbon and strontium – on Earth, and may have once played an important role in altering Mars’ surface. Despite growing recognition of the importance of low-temperature chemical weathering, these processes are still not well understood. Debris-coated glaciers are also present on Mars, emphasizing the need to study ice-related processes in the evolution of planetary surfaces. During Earth’s history, subglacial environments are thought to have sheltered communities of microorganisms from extreme climate variations. On Amazonian Mars, glaciers such as lobate debris aprons (LDA) could have hosted chemolithotrophic communities, making Mars’ present glaciers candidates for life preservation. This study characterizes glacial processes on both Earth and Mars.
Chemical weathering at Robertson Glacier, a small alpine glacier in the Canadian Rocky Mountains, is examined with a multidisciplinary approach. The relative proportions of differing dissolution reactions at various stages in the glacial system are empirically determined using aqueous geochemistry. Synthesis of laboratory and orbital thermal infrared spectroscopy allows identification of dissolution rinds on hand samples and characterization of carbonate dissolution signals at orbital scales, while chemical and morphological evidence for thin, discontinuous weathering rinds at microscales are evident from electron microscopy. Subglacial dissolution rates are found to outpace those of the proglacial till plain; biologically-mediated pyrite oxidation drives the bulk of this acidic weathering.
Second, the area-elevation relationship, or hypsometry, of LDA in the midlatitudes of Mars is characterized. These glaciers are believed to have formed ~500 Ma during a climate excursion. Hypsometric measurements of these debris-covered glaciers enable insight into past flow regimes and drive predictions about past climate scenarios. The LDA in this study fall into three major groups, strongly dependent on basal elevation, implying regional and climatic controls on ice formation and flow.
I show that biologically-mediated mineral reactions drive high subglacial dissolution rates, such that variations within the valley can be detected with remote sensing techniques. In future work, these insights can be applied to examining Mars’ glacial regions for signs of chemical alteration and biosignatures.
Chemical weathering at Robertson Glacier, a small alpine glacier in the Canadian Rocky Mountains, is examined with a multidisciplinary approach. The relative proportions of differing dissolution reactions at various stages in the glacial system are empirically determined using aqueous geochemistry. Synthesis of laboratory and orbital thermal infrared spectroscopy allows identification of dissolution rinds on hand samples and characterization of carbonate dissolution signals at orbital scales, while chemical and morphological evidence for thin, discontinuous weathering rinds at microscales are evident from electron microscopy. Subglacial dissolution rates are found to outpace those of the proglacial till plain; biologically-mediated pyrite oxidation drives the bulk of this acidic weathering.
Second, the area-elevation relationship, or hypsometry, of LDA in the midlatitudes of Mars is characterized. These glaciers are believed to have formed ~500 Ma during a climate excursion. Hypsometric measurements of these debris-covered glaciers enable insight into past flow regimes and drive predictions about past climate scenarios. The LDA in this study fall into three major groups, strongly dependent on basal elevation, implying regional and climatic controls on ice formation and flow.
I show that biologically-mediated mineral reactions drive high subglacial dissolution rates, such that variations within the valley can be detected with remote sensing techniques. In future work, these insights can be applied to examining Mars’ glacial regions for signs of chemical alteration and biosignatures.
ContributorsRutledge, Alicia Marie (Author) / Christensen, Philip R. (Thesis advisor) / Shock, Everett (Committee member) / Clarke, Amanda (Committee member) / Sharp, Thomas (Committee member) / Whipple, Kelin (Committee member) / Arizona State University (Publisher)
Created2015
Description
Both volcanism and impact cratering produce ejecta and associated deposits incorporating a molten rock component. While the heat sources are different (exogenous vs. endogenous), the end results are landforms with similar morphologies including ponds and flows of impact melt and lava around the central crater. Ejecta from both impact and volcanic craters can also include a high percentage of melted rock. Using Lunar Reconnaissance Orbiter Camera Narrow Angle Camera (LROC NAC) images, crucial details of these landforms are finally revealed, suggesting a much more dynamic Moon than is generally appreciated. Impact melt ponds and flows at craters as small as several hundred meters in diameter provide empirical evidence of abundant melting during the impact cratering process (much more than was previously thought), and this melt is mobile on the lunar surface for a significant time before solidifying. Enhanced melt deposit occurrences in the lunar highlands (compared to the mare) suggest that porosity, target composition, and pre-existing topography influence melt production and distribution. Comparatively deep impact craters formed in young melt deposits connote a relatively rapid evolution of materials on the lunar surface. On the other end of the spectrum, volcanic eruptions have produced the vast, plains-style mare basalts. However, little was previously known about the details of small-area eruptions and proximal volcanic deposits due to a lack of resolution. High-resolution images reveal key insights into small volcanic cones (0.5-3 km in diameter) that resemble terrestrial cinder cones. The cones comprise inter-layered materials, spatter deposits, and lava flow breaches. The widespread occurrence of the cones in most nearside mare suggests that basaltic eruptions occur from multiple sources in each basin and/or that rootless eruptions are relatively common. Morphologies of small-area volcanic deposits indicate diversity in eruption behavior of lunar basaltic eruptions driven by magmatic volatiles. Finally, models of polar volatile behavior during impact-heating suggest that chemical alteration of minerals in the presence of liquid water is one possible outcome that was previously not thought possible on the Moon.
ContributorsStopar, Julie D (Author) / Robinson, Mark S. (Thesis advisor) / Bell, James (Committee member) / Christensen, Philip R. (Philip Russel) (Committee member) / Clarke, Amanda (Committee member) / Scowen, Paul (Committee member) / Arizona State University (Publisher)
Created2016