A novel concept for integration of flame-assisted fuel cells (FFC) with a gas turbine is analyzed in this paper. Six different fuels (CH4, C3H8, JP-4, JP-5, JP-10(L), and H2) are investigated for the analytical model of the FFC integrated gas turbine hybrid system. As equivalence ratio increases, the efficiency of the hybrid system increases initially then decreases because the decreasing flow rate of air begins to outweigh the increasing hydrogen concentration. This occurs at an equivalence ratio of 2 for CH4. The thermodynamic cycle is analyzed using a temperature entropy diagram and a pressure volume diagram. These thermodynamic diagrams show as equivalence ratio increases, the power generated by the turbine in the hybrid setup decreases. Thermodynamic analysis was performed to verify that energy is conserved and the total chemical energy going into the system was equal to the heat rejected by the system plus the power generated by the system. Of the six fuels, the hybrid system performs best with H2 as the fuel. The electrical efficiency with H2 is predicted to be 27%, CH4 is 24%, C3H8 is 22%, JP-4 is 21%, JP-5 is 20%, and JP-10(L) is 20%. When H2 fuel is used, the overall integrated system is predicted to be 24.5% more efficient than the standard gas turbine system. The integrated system is predicted to be 23.0% more efficient with CH4, 21.9% more efficient with C3H8, 22.7% more efficient with JP-4, 21.3% more efficient with JP-5, and 20.8% more efficient with JP-10(L). The sensitivity of the model is investigated using various fuel utilizations. When CH4 fuel is used, the integrated system is predicted to be 22.7% more efficient with a fuel utilization efficiency of 90% compared to that of 30%.

Lithium ion batteries are quintessential components of modern life. They are used to power smart devices — phones, tablets, laptops, and are rapidly becoming major elements in the automotive industry. Demand projections for lithium are skyrocketing with production struggling to keep up pace. This drive is due mostly to the rapid adoption of electric vehicles; sales of electric vehicles in 2020 are more than double what they were only a year prior. With such staggering growth it is important to understand how lithium is sourced and what that means for the environment. Will production even be capable of meeting the demand as more industries make use of this valuable element? How will the environmental impact of lithium affect growth? This thesis attempts to answer these questions as the world looks to a decade of rapid growth for lithium ion batteries.

The objective of this report is to discover a skyhook’s ability to change the plane of another spacecraft’s orbit while ensuring that each vehicle’s orbital energy remains constant. Skyhooks are a proposed momentum exchange device in which a tether is attached to a counterweight at one end and at the other, a capturing device intended to intercept rendezvousing spacecraft. Trigonometric velocity vector relations, along with objective comparisons to traditionally proposed uses for skyhooks and gravity-assist maneuvers were responsible for the ultimate parameterization of the proposed energy neutral maneuver. From this methodology, it was determined that a spacecraft’s initial relative velocity vector must be perpendicular to, and rotated about the skyhook’s total velocity vector if it is to benefit from an energy neutral plane change maneuver. A quaternion was used to model the rotation of the incoming spacecraft’s relative velocity vector. The potential post-maneuver spacecraft orbits vary in their inclinations depending on the ratio between the skyhook and spacecraft’s total velocities at the point of rendezvous as defined by the parameter called the alpha criterion. For many cases, the proposed maneuver will serve as a desirable alternative to currently practiced propulsive plane change methods because it does not costly require a substantial amount of propellant. The proposed maneuver is also more accessible than alternative methods that involve gravity-assist and aerodynamic forces. Additionally, by avoiding orbital degradation through the achievement of unchanging total orbital energy, the skyhook will be able to continually and self-sustainably provide plane changes to any spacecraft that belong to orbits that abide by the identified parameters.

Dr. Ivan Ermanoski has been working towards creating a thermochemical reactor for the purposes of hydrogen production for several years. After testing the initial design, there were found to be several areas in which possible improvements could be made. It is the purpose of this thesis project to look over the shortcomings of the previous reactor design and make improvements. The primary focus of these improvements centers around increasing the heat retention of the reactor, with a secondary focus on improving the workability and ease of construction for the reactor.