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The objective of this report is to discover a skyhook’s ability to change the plane of another spacecraft’s orbit while ensuring that each vehicle’s orbital energy remains constant. Skyhooks are a proposed momentum exchange device in which a tether is attached to a counterweight at one end and at the

The objective of this report is to discover a skyhook’s ability to change the plane of another spacecraft’s orbit while ensuring that each vehicle’s orbital energy remains constant. Skyhooks are a proposed momentum exchange device in which a tether is attached to a counterweight at one end and at the other, a capturing device intended to intercept rendezvousing spacecraft. Trigonometric velocity vector relations, along with objective comparisons to traditionally proposed uses for skyhooks and gravity-assist maneuvers were responsible for the ultimate parameterization of the proposed energy neutral maneuver. From this methodology, it was determined that a spacecraft’s initial relative velocity vector must be perpendicular to, and rotated about the skyhook’s total velocity vector if it is to benefit from an energy neutral plane change maneuver. A quaternion was used to model the rotation of the incoming spacecraft’s relative velocity vector. The potential post-maneuver spacecraft orbits vary in their inclinations depending on the ratio between the skyhook and spacecraft’s total velocities at the point of rendezvous as defined by the parameter called the alpha criterion. For many cases, the proposed maneuver will serve as a desirable alternative to currently practiced propulsive plane change methods because it does not costly require a substantial amount of propellant. The proposed maneuver is also more accessible than alternative methods that involve gravity-assist and aerodynamic forces. Additionally, by avoiding orbital degradation through the achievement of unchanging total orbital energy, the skyhook will be able to continually and self-sustainably provide plane changes to any spacecraft that belong to orbits that abide by the identified parameters.

ContributorsSeale, Ryan (Author) / Peet, Matthew (Thesis director) / Dahm, Werner (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2023-05
Description

Dr. Ivan Ermanoski has been working towards creating a thermochemical reactor for the purposes of hydrogen production for several years. After testing the initial design, there were found to be several areas in which possible improvements could be made. It is the purpose of this thesis project to look over

Dr. Ivan Ermanoski has been working towards creating a thermochemical reactor for the purposes of hydrogen production for several years. After testing the initial design, there were found to be several areas in which possible improvements could be made. It is the purpose of this thesis project to look over the shortcomings of the previous reactor design and make improvements. The primary focus of these improvements centers around increasing the heat retention of the reactor, with a secondary focus on improving the workability and ease of construction for the reactor.

ContributorsWehe, Alexander (Author) / Ermanoski, Ivan (Thesis director) / Miller, James (Committee member) / Stechel, Ellen (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2023-05
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Sulfur oxidation is a process that is seen a wide variety of places. One particular place is Yellowstone national park where an abundance of hot springs are present. These acidic and hot places are prime locations for sulfur oxidation to occur. At a very basic level this is thought of

Sulfur oxidation is a process that is seen a wide variety of places. One particular place is Yellowstone national park where an abundance of hot springs are present. These acidic and hot places are prime locations for sulfur oxidation to occur. At a very basic level this is thought of as Sulfur, oxygen, and water forming sulfate and hydrogen. Many other reactions occur when an organism performs these processes, and many enzymes are used for this. This paper aimed to create, balance, and analyze the reactions involved in the paper Sulfur Oxidation in the Acidophilic Autotrophic Acidithiobacillus spp. (Wang et al., 2019) Once these reactions were balanced thermodynamic properties were found to evaluate the Gibbs Free Energy of these reactions. This allowed for a unique energy-based view of how this web of reactions relate to each other.

ContributorsMolina, Johnathan (Author) / Shock, Everett (Thesis director) / Weeks, Katelyn (Committee member) / Barrett, The Honors College (Contributor) / School of Molecular Sciences (Contributor)
Created2021-12
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Fossil fuels are currently the main source of energy in the world’s transportation sector. They are also the primary contributor to carbon emissions in the atmosphere, leading to adverse climate effects. The objective of the following research is to increase the yield and efficiency of algal biofuel in order to

Fossil fuels are currently the main source of energy in the world’s transportation sector. They are also the primary contributor to carbon emissions in the atmosphere, leading to adverse climate effects. The objective of the following research is to increase the yield and efficiency of algal biofuel in order to establish algal-derived fuel as a competitive alternative to predominantly used fossil fuels. Using biofuel commercially will reduce the cost of production and ultimately decrease additional carbon emissions. Experiments were performed using hydrothermal liquefaction (HTL) to determine which catalyst would enhance the algal biocrude oil and result in the highest quality biofuel product, as well as to find the optimal combination of processing temperature and manure co-liquefaction of biomass ratio. For the catalytic upgrading experiments, Micractenium Immerum algae was used in conjunction with pure H2, Pt/C, MO2C, and HZSM-5 catalysts at 350℃ and 400℃, 430 psi, and a 30-minute residence time to investigate the effects of catalyst choice and temperature on the crude oil yield. While all catalysts increased the carbon content of the crude oil, it was found that using HZSM-5 at 350℃ resulted in the greatest overall yield of about 75%. However, the Pt/C catalyst increased the HHV from 34.26 MJ/kg to 43.26 MJ/kg. Cyanidioschyzon merolae (CM) algae and swine manure were utilized in the co-liquefaction experiments, in ratios (algae to swine) of 80:20, 50:50, and 20:80 at temperatures of 300℃ and 330℃. It was found that a ratio of 80:20 at 330℃ produced the highest biocrude oil yield of 29.3%. Although the 80:20 experiments had the greatest biomass conversion and best supported the deacidification of the oil product, the biocrude oil had a HHV of 33.58 MJ/kg, the lowest between the three different ratios. However, all calorific values were relatively close to each other, suggesting that both catalytic upgrading and co-liquefaction can increase the efficiency and economic viability of algal biofuel.
ContributorsMurdock, Tessa A (Author) / Deng, Shuguang (Thesis director) / Varman, Arul (Committee member) / Chemical Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
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Description
Membrane-based technology for gas separations is currently at an emerging stage of advancement and adoption for environmental and industrial applications due to its substantial advantages like lower energy and operating costs over the conventional gas separation technologies. Unfortunately, the available polymeric (or organic) membranes suffer a trade-off between permeance and

Membrane-based technology for gas separations is currently at an emerging stage of advancement and adoption for environmental and industrial applications due to its substantial advantages like lower energy and operating costs over the conventional gas separation technologies. Unfortunately, the available polymeric (or organic) membranes suffer a trade-off between permeance and selectivity. Mixed matrix membranes (MMMs) containing two-dimensional (2D) metal-organic frameworks (MOFs) as fillers are a highly sought approach to redress this trade-off given their enhanced gas permeabilities and selectivities compared to the pure polymeric membrane. These MMMs are increasingly gaining attention by researchers due to their unique properties and wide small- and large-scale gas separation applications. However, straightforward and scalable methods for the synthesis of MOFs nanosheets have thus far been persistently elusive. This study reports the single-phase preparation, and characterization of MMMs with 2D MOFs nanosheets as fillers. The prepared MOF and the polymer matrix form the ‘dense’ MMMs which exhibit increased gas diffusion resistance, and thus improved separation abilities. The single-phase approach was more successful than the bi-phase at synthesizing the MOFs. The influence of sonication power and time on the characteristics and performance of the membranes are examined and discussed. Increasing the sonication power from 50% to 100% reduces the pore size. Additionally, the ultimate effect on the selectivity and permeance of the MMMs with different single gases is reported. Analysis of results with various gas mixers indicates further performance improvements in these MMMs could be achieved by increasing sonication time and tuning suitable membrane thicknesses. Reported results reveal that MMMs are excellent candidates for next-generation gas mixture separations, with potential applications in CO2 capture and storage, hydrogen recovery, alkene recovery from alkanes, and natural gas purification.
ContributorsNkuutu, John (Author) / Mu, Bin (Thesis director) / Shan, Bohan (Committee member) / Chemical Engineering Program (Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
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Description
Ionic liquids are salts with low melting temperatures that maintain their liquid form below 100 °C, or even at ambient temperature. Ionic liquids are conductive, electrochemically stable, non-volatile, and have a low vapor pressure, making them a class of excellent candidate materials for electrolytes in energy storage, electrodeposition, batteries,

Ionic liquids are salts with low melting temperatures that maintain their liquid form below 100 °C, or even at ambient temperature. Ionic liquids are conductive, electrochemically stable, non-volatile, and have a low vapor pressure, making them a class of excellent candidate materials for electrolytes in energy storage, electrodeposition, batteries, fuel cells, and supercapacitors. Due to their multiple advantages, the use of ionic liquids on Earth has been widely studied; however, further research must be done before their implementation in space. The extreme temperatures encountered during space travel and extra-terrestrial deployment have the potential to greatly affect the liquid electrolyte system. Examples of low temperature planetary bodies are the permanently shadowed sections of the moon or icy surfaces of Jupiter’s moons. Recent studies have explored the limits of glass transition temperatures for ionic liquid systems. The project is centered around the development of an ionic liquid system for a molecular electronic transducer seismometer that would be deployed on the low temperature system of Europa. For this project, molecular dynamics simulations used input intermolecular and intramolecular parameters that then simulated molecular interactions. Molecular dynamics simulations are based around the statistical mechanics of chemistry and help calculate equilibrium properties that are not easily calculated by hand. These simulations will give insight into what interactions are significant inside a ionic liquid solution. The simulations aim to create an understanding how ionic liquid electrolyte systems function at a molecular level. With this knowledge one can tune their system and its contents to adapt the systems properties to fit all environments the seismometers will experience.
ContributorsDavis, Vincent Champneys (Author) / Dai, Lenore (Thesis director) / Gliege, Marisa (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
Each year, the average vehicle contributes 4.6 metric tons of carbon dioxide into the atmosphere [1]. These gases contribute to around 30,000 premature deaths each year [2] and are linked to in the increase in cases of Asthma. Human health is further impacted by the increase of greenhouse gasses in

Each year, the average vehicle contributes 4.6 metric tons of carbon dioxide into the atmosphere [1]. These gases contribute to around 30,000 premature deaths each year [2] and are linked to in the increase in cases of Asthma. Human health is further impacted by the increase of greenhouse gasses in the atmosphere. Rays from the sun travel to the Earth where they are absorbed. Absorbing the sun’s rays heats up the Earth which is then radiated into space. Greenhouse gasses inhibit this process much like the glass walls in a greenhouse. As a result, the temperature of the Earth steadily increases. The greenhouse effect is dangerous because it can be linked to natural disasters, rising ocean levels, and extinction of species. One of the biggest contributors to the greenhouse effect is burning fossil fuels. Powerplants, agriculture, and transportation are some of the largest contributors to the increase of atmospheric carbon dioxide. To mitigate the effects of transportation, car companies have invested into production of alternative and renewable fuels for their products. One of the sources which has gained popularity recently, is the use of electricity to power our vehicles. Tesla has spearheaded the electric car movement and is largely responsible for this beneficial shift. One issue with this approach is that a majority, around 76.3%, of Americans drive alone on their commute [13]. The market in its current state encourages inefficient transportation due to the lack of alternatives. While motorcycles may offer a more eco-friendly and economical approach to cars, many are afraid of potential hazards of using this mode of transportation. The introduction of electric bikes offers an interesting approach to improving this efficiency and safety issue. The wide availability to customers offers an alternative which pushes the traditional distance limits for commuting on a bicycle. Since the market is relatively new, several issues pose challenges to consumers. This research aims to clarify and analyze the electric bike market in order to supply a potential customer with the tools needed to acquire a high quality and reasonably price bike.
ContributorsFriedrich, Collin Anthony (Author) / Lee, Hyunglae (Thesis director) / Lacy, Gerald (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
With renewable energy on the rise, researchers have turned their funding and their focus towards new solar cell technologies, and perovskites are a major source of interest. This class of materials is particularly interesting due to their quick, simple synthesis as well as their physical and electrical superiority when compared

With renewable energy on the rise, researchers have turned their funding and their focus towards new solar cell technologies, and perovskites are a major source of interest. This class of materials is particularly interesting due to their quick, simple synthesis as well as their physical and electrical superiority when compared to current silicon-based solar cells. Through this thesis, we will explore the synthesis of various types of perovskites and their subsequent characterization, which includes optical microscopy, photoluminescence spectroscopy, Raman microscopy, and X-ray diffraction. Analyzing two different perovskites both before and after a two-week period of storage revealed that while synthesis is indeed experiment-friendly, these materials have a concerning lack of stability even in ideal conditions.
ContributorsBuzas, Benjamin Joseph (Author) / Tongay, Sefaattin (Thesis director) / Muhich, Christopher (Committee member) / Materials Science and Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
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This project seeks to provide a general picture of the economic dependence on fossil fuels per County in the United States. The purpose for this study is creating a foundation for conversations about the future of fossil fuel workers and counties that depend heavily on fossil fuels. The main indicators

This project seeks to provide a general picture of the economic dependence on fossil fuels per County in the United States. The purpose for this study is creating a foundation for conversations about the future of fossil fuel workers and counties that depend heavily on fossil fuels. The main indicators utilized for this were employment and payroll data extracted from United States Census Bureau’s County Business Patterns dataset. A section on similarities between fossil fuel workers and other occupations was included, which shows possible alternative industries for fossil fuel workers. The main goal of the project is to provide possible solutions for mitigating job losses in the future. Some proposed solutions include retraining, expanding higher education, and investing in new industries. It is most important for future work to include input from most vulnerable counties and understand the social and cultural complexities that are tied to this problem.
ContributorsRamirez Torres, Jairo Adriel (Author) / Miller, Claek (Thesis director) / Shutters, Shade (Committee member) / Watts College of Public Service & Community Solut (Contributor) / Electrical Engineering Program (Contributor) / Economics Program in CLAS (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
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This paper analyzes Burkina Faso’s Souro Sanou University Hospital Center’s energy needs and discusses whether or not solar panels are a good investment. This paper also discusses a way to limit the damage caused by power outages. The hospital has a history of problems with power outages; in the summer

This paper analyzes Burkina Faso’s Souro Sanou University Hospital Center’s energy needs and discusses whether or not solar panels are a good investment. This paper also discusses a way to limit the damage caused by power outages. The hospital has a history of problems with power outages; in the summer they have power outages every other day lasting between one to four hours, and in the rainy season they have outages once every other week lasting the same amount of time.
The first step in this analysis was collecting relevant data which includes: location, electricity rates, energy consumption, and existing assets. The data was entered into a program called HOMER. HOMER is a program which analyzes an electrical system and determines the best configuration and usage of assets to get the lowest levelized cost of energy (LCOE). In HOMER, five different analyses were performed. They reviewed the hospital’s energy usage over 25 years: the current situation, one of the current situation with added solar panels, and another where the solar panels have single axis tracking. The other two analyses created incentives to have more solar panels, one situation with net metering, and one with a sellback rate of 0.03 $/kWh. The result of the analysis concluded that the ideal situation would have solar panels with a capacity of 300 kW, and the LCOE in this situation will be 0.153 $/kWh. The analysis shows that investing in solar panels will save the hospital approximately $65,500 per year, but the initial investment of $910,000 only allows for a total savings of $61,253 over the life of the project. The analysis also shows that if the electricity company, Sonabel, eventually buys back electricity then net metering would be more profitable than reselling electricity for the hospital.
Solar panels will help the hospital save money over time, but they will not stop power outages from happening at the hospital. For the outages to stop affecting the hospital’s operations they will have to invest in an uninterrupted power supply (UPS). The UPS will power the hospital for the time between when the power goes out and when their generators are turning on which makes it an essential investment. This will stop outages from affecting the hospital, and if the power goes out during the day then the solar panels can help supplement the energy production which will take some of the strain from their generators.
The results of this study will be sent to officials at the hospital and they can decide if the large initial investment justifies the savings. If the solar panels and UPS can save one life, then maybe the large initial investment is worth it.
ContributorsSchmidt, Evin Khalil (Author) / Johnson, Nathan (Thesis director) / Miner, Mark (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05