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- All Subjects: energy
- Creators: Vittal, Vijay
- Creators: Alford, Terry
- Creators: Chemical Engineering Program
Description
Emission of CO2 into the atmosphere has become an increasingly concerning issue as we progress into the 21st century Flue gas from coal-burning power plants accounts for 40% of all carbon dioxide emissions. The key to successful separation and sequestration is to separate CO2 directly from flue gas (10-15% CO2, 70% N2), which can range from a few hundred to as high as 1000°C. Conventional microporous membranes (carbons/silicas/zeolites) are capable of separating CO2 from N2 at low temperatures, but cannot achieve separation above 200°C. To overcome the limitations of microporous membranes, a novel ceramic-carbonate dual-phase membrane for high temperature CO2 separation was proposed. The membrane was synthesized from porous La0.6Sr0.4Co0.8Fe0.2O3-d (LSCF) supports and infiltrated with molten carbonate (Li2CO3/Na2CO3/K2CO3). The CO2 permeation mechanism involves a reaction between CO2 (gas phase) and O= (solid phase) to form CO3=, which is then transported through the molten carbonate (liquid phase) to achieve separation. The effects of membrane thickness, temperature and CO2 partial pressure were studied. Decreasing thickness from 3.0 to 0.375 mm led to higher fluxes at 900°C, ranging from 0.186 to 0.322 mL.min-1.cm-2 respectively. CO2 flux increased with temperature from 700 to 900°C. Activation energy for permeation was similar to that for oxygen ion conduction in LSCF. For partial pressures above 0.05 atm, the membrane exhibited a nearly constant flux. From these observations, it was determined that oxygen ion conductivity limits CO2 permeation and that the equilibrium oxygen vacancy concentration in LSCF is dependent on the partial pressure of CO2 in the gas phase. Finally, the dual-phase membrane was used as a membrane reactor. Separation at high temperatures can produce warm, highly concentrated streams of CO2 that could be used as a chemical feedstock for the synthesis of syngas (H2 + CO). Towards this, three different membrane reactor configurations were examined: 1) blank system, 2) LSCF catalyst and 3) 10% Ni/y-alumina catalyst. Performance increased in the order of blank system < LSCF catalyst < Ni/y-alumina catalyst. Favorable conditions for syngas production were high temperature (850°C), low sweep gas flow rate (10 mL.min-1) and high methane concentration (50%) using the Ni/y-alumina catalyst.
ContributorsAnderson, Matthew Brandon (Author) / Lin, Jerry (Thesis advisor) / Alford, Terry (Committee member) / Rege, Kaushal (Committee member) / Anderson, James (Committee member) / Rivera, Daniel (Committee member) / Arizona State University (Publisher)
Created2011
Description
Transmission expansion planning (TEP) is a complex decision making process that requires comprehensive analysis to determine the time, location, and number of electric power transmission facilities that are needed in the future power grid. This dissertation investigates the topic of solving TEP problems for large power systems. The dissertation can be divided into two parts. The first part of this dissertation focuses on developing a more accurate network model for TEP study. First, a mixed-integer linear programming (MILP) based TEP model is proposed for solving multi-stage TEP problems. Compared with previous work, the proposed approach reduces the number of variables and constraints needed and improves the computational efficiency significantly. Second, the AC power flow model is applied to TEP models. Relaxations and reformulations are proposed to make the AC model based TEP problem solvable. Third, a convexified AC network model is proposed for TEP studies with reactive power and off-nominal bus voltage magnitudes included in the model. A MILP-based loss model and its relaxations are also investigated. The second part of this dissertation investigates the uncertainty modeling issues in the TEP problem. A two-stage stochastic TEP model is proposed and decomposition algorithms based on the L-shaped method and progressive hedging (PH) are developed to solve the stochastic model. Results indicate that the stochastic TEP model can give a more accurate estimation of the annual operating cost as compared to the deterministic TEP model which focuses only on the peak load.
ContributorsZhang, Hui (Author) / Vittal, Vijay (Thesis advisor) / Heydt, Gerald T (Thesis advisor) / Mittelmann, Hans D (Committee member) / Hedman, Kory W (Committee member) / Arizona State University (Publisher)
Created2013
Description
At present, almost 70% of the electric energy in the United States is produced utilizing fossil fuels. Combustion of fossil fuels contributes CO2 to the atmosphere, potentially exacerbating the impact on global warming. To make the electric power system (EPS) more sustainable for the future, there has been an emphasis on scaling up generation of electric energy from wind and solar resources. These resources are renewable in nature and have pollution free operation. Various states in the US have set up different goals for achieving certain amount of electrical energy to be produced from renewable resources. The Southwestern region of the United States receives significant solar radiation throughout the year. High solar radiation makes concentrated solar power and solar PV the most suitable means of renewable energy production in this region. However, the majority of the projects that are presently being developed are either residential or utility owned solar PV plants. This research explores the impact of significant PV penetration on the steady state voltage profile of the electric power transmission system. This study also identifies the impact of PV penetration on the dynamic response of the transmission system such as rotor angle stability, frequency response and voltage response after a contingency. The light load case of spring 2010 and the peak load case of summer 2018 have been considered for analyzing the impact of PV. If the impact is found to be detrimental to the normal operation of the EPS, mitigation measures have been devised and presented in the thesis. Commercially available software tools/packages such as PSLF, PSS/E, DSA Tools have been used to analyze the power network and validate the results.
ContributorsPrakash, Nitin (Author) / Heydt, Gerald T. (Thesis advisor) / Vittal, Vijay (Thesis advisor) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2013
Description
The past few decades have seen a consistent growth of distributed PV sources. Distributed PV, like other DG sources, can be located at or near load centers and provide benefits which traditional generation may lack. However, distribution systems were not designed to accommodate such power generation sources as these sources might lead to operational as well as power quality issues. A high penetration of distributed PV resources may lead to bi-directional power flow resulting in voltage swells, increased losses and overloading of conductors. Voltage unbalance is a concern in distribution systems and the effect of single-phase residential PV systems on voltage unbalance needs to be explored. Furthermore, the islanding of DGs presents a technical hurdle towards the seamless integration of DG sources with the electricity grid. The work done in this thesis explores two important aspects of grid inte-gration of distributed PV generation, namely, the impact on power quality and anti-islanding. A test distribution system, representing a realistic distribution feeder in Arizona is modeled to study both the aforementioned aspects. The im-pact of distributed PV on voltage profile, voltage unbalance and distribution sys-tem primary losses are studied using CYMDIST. Furthermore, a PSCAD model of the inverter with anti-island controls is developed and the efficacy of the anti-islanding techniques is studied. Based on the simulations, generalized conclusions are drawn and the problems/benefits are elucidated.
ContributorsMitra, Parag (Author) / Heydt, Gerald T (Thesis advisor) / Vittal, Vijay (Thesis advisor) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2013
Description
Due to economic and environmental reasons, several states in the United States of America have a mandated renewable portfolio standard which requires that a certain percentage of the load served has to be met by renewable resources of energy such as solar, wind and biomass. Renewable resources provide energy at a low variable cost and produce less greenhouse gases as compared to conventional generators. However, some of the complex issues with renewable resource integration are due to their intermittent and non-dispatchable characteristics. Furthermore, most renewable resources are location constrained and are usually located in regions with insufficient transmission facilities. In order to deal with the challenges presented by renewable resources as compared to conventional resources, the transmission network expansion planning procedures need to be modified. New high voltage lines need to be constructed to connect the remote renewable resources to the existing transmission network to serve the load centers. Moreover, the existing transmission facilities may need to be reinforced to accommodate the large scale penetration of renewable resource. This thesis proposes a methodology for transmission expansion planning with large-scale integration of renewable resources, mainly solar and wind generation. An optimization model is used to determine the lines to be constructed or upgraded for several scenarios of varying levels of renewable resource penetration. The various scenarios to be considered are obtained from a production cost model that analyses the effects that renewable resources have on the transmission network over the planning horizon. A realistic test bed was created using the data for solar and wind resource penetration in the state of Arizona. The results of the production cost model and the optimization model were subjected to tests to ensure that the North American Electric Reliability Corporation (NERC) mandated N-1 contingency criterion is satisfied. Furthermore, a cost versus benefit analysis was performed to ensure that the proposed transmission plan is economically beneficial.
ContributorsHariharan, Sruthi (Author) / Vittal, Vijay (Thesis advisor) / Heydt, Gerald (Committee member) / Hedman, Kory (Committee member) / Arizona State University (Publisher)
Created2012
Description
In the deregulated power system, locational marginal prices are used in transmission engineering predominantly as near real-time pricing signals. This work extends this concept to distribution engineering so that a distribution class locational marginal price might be used for real-time pricing and control of advanced control systems in distribution circuits. A formulation for the distribution locational marginal price signal is presented that is based on power flow sensitivities in a distribution system. A Jacobian-based sensitivity analysis has been developed for application in the distribution pricing method. Increasing deployment of distributed energy sources is being seen at the distribution level and this trend is expected to continue. To facilitate an optimal use of the distributed infrastructure, the control of the energy demand on a feeder node in the distribution system has been formulated as a multiobjective optimization problem and a solution algorithm has been developed. In multiobjective problems the Pareto optimality criterion is generally applied, and commonly used solution algorithms are decision-based and heuristic. In contrast, a mathematically-robust technique called normal boundary intersection has been modeled for use in this work, and the control variable is solved via separable programming. The Roy Billinton Test System (RBTS) has predominantly been used to demonstrate the application of the formulation in distribution system control. A parallel processing environment has been used to replicate the distributed nature of controls at many points in the distribution system. Interactions between the real-time prices in a distribution feeder and the nodal prices at the aggregated load bus have been investigated. The application of the formulations in an islanded operating condition has also been demonstrated. The DLMP formulation has been validated using the test bed systems and a practical framework for its application in distribution engineering has been presented. The multiobjective optimization yields excellent results and is found to be robust for finer time resolutions. The work shown in this report is applicable to, and has been researched under the aegis of the Future Renewable Electric Energy Delivery and Management (FREEDM) center, which is a generation III National Science Foundation engineering research center headquartered at North Carolina State University.
ContributorsRanganathan Sathyanarayana, Bharadwaj (Author) / Heydt, Gerald T (Thesis advisor) / Vittal, Vijay (Committee member) / Ayyanar, Raja (Committee member) / Zhang, Junshan (Committee member) / Arizona State University (Publisher)
Created2012
Description
Electric power systems are facing great challenges from environmental regulations, changes in demand due to new technologies like electric vehicle, as well as the integration of various renewable energy sources. These factors taken together require the development of new tools to help make policy and investment decisions for the future power grid. The requirements of a network equivalent to be used in such planning tools are very different from those assumed in the development of traditional equivalencing procedures. This dissertation is focused on the development, implementation and verification of two network equivalencing approaches on large power systems, such as the Eastern Interconnection. Traditional Ward-type equivalences are a class of equivalencing approaches but this class has some significant drawbacks. It is well known that Ward-type equivalents "smear" the injections of external generators over a large number of boundary buses. For newer long-term investment applications that take into account such things as greenhouse gas (GHG) regulations and generator availability, it is computationally impractical to model fractions of generators located at many buses. A modified-Ward equivalent is proposed to address this limitation such that the external generators are moved wholesale to some internal buses based on electrical distance. This proposed equivalencing procedure is designed so that the retained-line power flows in the equivalent match those in the unreduced (full) model exactly. During the reduction process, accommodations for special system elements are addressed, including static VAr compensators (SVCs), high voltage dc (HVDC) transmission lines, and phase angle regulators. Another network equivalencing approach based on the dc power flow assumptions and the power transfer distribution factors (PTDFs) is proposed. This method, rather than eliminate buses via Gauss-reduction, aggregates buses on a zonal basis. The bus aggregation approach proposed here is superior to the existing bus aggregation methods in that a) under the base case, the equivalent-system inter-zonal power flows exactly match those calculated using the full-network-model b) as the operating conditions change, errors in line flows are reduced using the proposed bus clustering algorithm c) this method is computationally more efficient than other bus aggregation methods proposed heretofore. A critical step in achieving accuracy with a bus aggregation approach is selecting which buses to cluster together and how many clusters are needed. Clustering in this context refers to the process of partitioning a network into subsets of buses. An efficient network clustering method is proposed based on the PTDFs and the data mining techniques. This method is applied to the EI topology using the "Saguaro" supercomputer at ASU, a resource with sufficient memory and computational capability for handling this 60,000-bus and 80,000-branch system. The network equivalents generated by the proposed approaches are verified and tested for different operating conditions and promising results have been observed.
ContributorsShi, Di (Author) / Tylavsky, Daniel J (Thesis advisor) / Vittal, Vijay (Committee member) / Hedman, Kory (Committee member) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2012
Description
This thesis presents a new technique to develop an air-conditioner (A/C) compressor single phase induction motor model for use in an electro-magnetic transient program (EMTP) simulation tool. The method developed also has the capability to represent multiple units of the component in a specific three-phase distribution feeder and investigate the phenomenon of fault-induced delayed voltage recovery (FIDVR) and the cause of motor stalling. The system of differential equations representing the single phase induction motor model is developed and formulated. Implicit backward Euler method is applied to numerically integrate the stator currents that are to be drawn from the electric network. The angular position dependency of the rotor shaft is retained in the inductance matrix associated with the model to accurately capture the dynamics of the motor loads. The equivalent circuit of the new model is interfaced with the electric network in the EMTP. The dynamic response of the motor when subjected to faults at different points on voltage waveform has been studied using the EMTP simulator. The mechanism and the impacts of motor stalling need to be explored with multiple units of the detailed model connected to a realistic three-phase distribution system. The model developed can be utilized to assess and improve the product design of compressor motors by air-conditioner manufacturers. Another critical application of the model would be to examine the impacts of asymmetric transmission faults on distribution systems to investigate and develop mitigation measures for the FIDVR problem.
ContributorsLiu, Yuan (Author) / Vittal, Vijay (Thesis advisor) / Undrill, John (Committee member) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2012
Description
The two central goals of this project were 1) to develop a testing method utilizing coatings on ultra-thin stainless steel to measure the thermal conductivity (k) of battery electrode materials and composites, and 2) to measure and compare the thermal conductivities of lithium iron phosphate (LiFePO4, "LFP") in industry-standard graphite/LFP mixtures as well as graphene/LFP mixtures and a synthesized graphene/LFP nanocomposite. Graphene synthesis was attempted before purchasing graphene materials, and further exploration of graphene synthesis is recommended due to limitations in purchased product quality. While it was determined after extensive experimentation that the graphene/LFP nanocomposite could not be successfully synthesized according to current literature information, a mixed composite of graphene/LFP was successfully tested and found to have k = 0.23 W/m*K. This result provides a starting point for further thermal testing method development and k optimization in Li-ion battery electrode nanocomposites.
ContributorsStehlik, Daniel Wesley (Author) / Chan, Candace K. (Thesis director) / Dai, Lenore (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2014-05
Description
Currently, approximately 40% of the world’s electricity is generated from coal and coal power plants are one of the major sources of greenhouse gases accounting for a third of all CO2 emissions. The Integrated Gasification Combined Cycle (IGCC) has been shown to provide an increase in plant efficiency compared to traditional coal-based power generation processes resulting in a reduction of greenhouse gas emissions. The goal of this project was to analyze the performance of a new SNDC ceramic-carbonate dual-phase membrane for CO2 separation. The chemical formula for the SNDC-carbonate membrane was Sm0.075Nd0.075Ce0.85O1.925. This project also focused on the use of this membrane for pre-combustion CO2 capture coupled with a water gas shift (WGS) reaction for a 1000 MW power plant. The addition of this membrane to the traditional IGCC process provides a purer H2 stream for combustion in the gas turbine and results in lower operating costs and increased efficiencies for the plant. At 900 °C the CO2 flux and permeance of the SNDC-carbonate membrane were 0.65 mL/cm2•min and 1.0×10-7 mol/m2•s•Pa, respectively. Detailed in this report are the following: background regarding CO2 separation membranes and IGCC power plants, SNDC tubular membrane preparation and characterization, IGCC with membrane reactor plant design, process heat and mass balance, and plant cost estimations.
ContributorsDunteman, Nicholas Powell (Author) / Lin, Jerry (Thesis director) / Dong, Xueliang (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor) / School of Sustainability (Contributor)
Created2014-05