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- Creators: Huang, Huei-Ping
Description
With a ground-based Doppler lidar on the upwind side of a wind farm in the Tehachapi Pass of California, radial wind velocity measurements were collected for repeating sector sweeps, scanning up to 10 kilometers away. This region consisted of complex terrain, with the scans made between mountains. The dataset was utilized for techniques being studied for short-term forecasting of wind power by correlating changes in energy content and of turbulence intensity by tracking spatial variance, in the wind ahead of a wind farm. A ramp event was also captured and its propagation was tracked.
Orthogonal horizontal wind vectors were retrieved from the radial velocity using a sector Velocity Azimuth Display method. Streamlines were plotted to determine the potential sites for a correlation of upstream wind speed with wind speed at downstream locations near the wind farm. A "virtual wind turbine" was "placed" in locations along the streamline by using the time-series velocity data at the location as the input to a modeled wind turbine, to determine the extractable energy content at that location. The relationship between this time-dependent energy content upstream and near the wind farm was studied. By correlating the energy content with each upstream location based on a time shift estimated according to advection at the mean wind speed, several fits were evaluated. A prediction of the downstream energy content was produced by shifting the power output in time and applying the best-fit function. This method made predictions of the power near the wind farm several minutes in advance. Predictions were also made up to an hour in advance for a large ramp event. The Magnitude Absolute Error and Standard Deviation are presented for the predictions based on each selected upstream location.
Orthogonal horizontal wind vectors were retrieved from the radial velocity using a sector Velocity Azimuth Display method. Streamlines were plotted to determine the potential sites for a correlation of upstream wind speed with wind speed at downstream locations near the wind farm. A "virtual wind turbine" was "placed" in locations along the streamline by using the time-series velocity data at the location as the input to a modeled wind turbine, to determine the extractable energy content at that location. The relationship between this time-dependent energy content upstream and near the wind farm was studied. By correlating the energy content with each upstream location based on a time shift estimated according to advection at the mean wind speed, several fits were evaluated. A prediction of the downstream energy content was produced by shifting the power output in time and applying the best-fit function. This method made predictions of the power near the wind farm several minutes in advance. Predictions were also made up to an hour in advance for a large ramp event. The Magnitude Absolute Error and Standard Deviation are presented for the predictions based on each selected upstream location.
ContributorsMagerman, Beth (Author) / Calhoun, Ronald (Thesis advisor) / Peet, Yulia (Committee member) / Huang, Huei-Ping (Committee member) / Krishnamurthy, Raghavendra (Committee member) / Arizona State University (Publisher)
Created2014
Description
The residential building sector accounts for more than 26% of the global energy consumption and 17% of global CO2 emissions. Due to the low cost of electricity in Kuwait and increase of population, Kuwaiti electricity consumption tripled during the past 30 years and is expected to increase by 20% by 2027. In this dissertation, a framework is developed to assess energy savings techniques to help policy-makers make educated decisions. The Kuwait residential energy outlook is studied by modeling the baseline energy consumption and the diffusion of energy conservation measures (ECMs) to identify the impacts on household energy consumption and CO2 emissions.
The energy resources and power generation in Kuwait were studied. The characteristics of the residential buildings along with energy codes of practice were investigated and four building archetypes were developed. Moreover, a baseline of end-use electricity consumption and demand was developed. Furthermore, the baseline energy consumption and demand were projected till 2040. It was found that by 2040, energy consumption would double with most of the usage being from AC. While with lighting, there is a negligible increase in consumption due to a projected shift towards more efficient lighting. Peak demand loads are expected to increase by an average growth rate of 2.9% per year. Moreover, the diffusion of different ECMs in the residential sector was modeled through four diffusion scenarios to estimate ECM adoption rates. ECMs’ impact on CO2 emissions and energy consumption of residential buildings in Kuwait was evaluated and the cost of conserved energy (CCE) and annual energy savings for each measure was calculated. AC ECMs exhibited the highest cumulative savings, whereas lighting ECMs showed an immediate energy impact. None of the ECMs in the study were cost effective due to the high subsidy rate (95%), therefore, the impact of ECMs at different subsidy and rebate rates was studied. At 75% subsidized utility price and 40% rebate only on appliances, most of ECMs will be cost effective with high energy savings. Moreover, by imposing charges of $35/ton of CO2, most ECMs will be cost effective.
The energy resources and power generation in Kuwait were studied. The characteristics of the residential buildings along with energy codes of practice were investigated and four building archetypes were developed. Moreover, a baseline of end-use electricity consumption and demand was developed. Furthermore, the baseline energy consumption and demand were projected till 2040. It was found that by 2040, energy consumption would double with most of the usage being from AC. While with lighting, there is a negligible increase in consumption due to a projected shift towards more efficient lighting. Peak demand loads are expected to increase by an average growth rate of 2.9% per year. Moreover, the diffusion of different ECMs in the residential sector was modeled through four diffusion scenarios to estimate ECM adoption rates. ECMs’ impact on CO2 emissions and energy consumption of residential buildings in Kuwait was evaluated and the cost of conserved energy (CCE) and annual energy savings for each measure was calculated. AC ECMs exhibited the highest cumulative savings, whereas lighting ECMs showed an immediate energy impact. None of the ECMs in the study were cost effective due to the high subsidy rate (95%), therefore, the impact of ECMs at different subsidy and rebate rates was studied. At 75% subsidized utility price and 40% rebate only on appliances, most of ECMs will be cost effective with high energy savings. Moreover, by imposing charges of $35/ton of CO2, most ECMs will be cost effective.
ContributorsAlajmi, Turki (Author) / Phelan, Patrick E (Thesis advisor) / Kaloush, Kamil (Committee member) / Huang, Huei-Ping (Committee member) / Wang, Liping (Committee member) / Hajiah, Ali (Committee member) / Arizona State University (Publisher)
Created2019
Description
Understanding and predicting climate changes at the urban scale have been an important yet challenging problem in environmental engineering. The lack of reliable long-term observations at the urban scale makes it difficult to even assess past climate changes. Numerical modeling plays an important role in filling the gap of observation and predicting future changes. Numerical studies on the climatic effect of desert urbanization have focused on basic meteorological fields such as temperature and wind. For desert cities, urban expansion can lead to substantial changes in the local production of wind-blown dust, which have implications for air quality and public health. This study expands the existing framework of numerical simulation for desert urbanization to include the computation of dust generation related to urban land-use changes. This is accomplished by connecting a suite of numerical models, including a meso-scale meteorological model, a land-surface model, an urban canopy model, and a turbulence model, to produce the key parameters that control the surface fluxes of wind-blown dust. Those models generate the near-surface turbulence intensity, soil moisture, and land-surface properties, which are used to determine the dust fluxes from a set of laboratory-based empirical formulas. This framework is applied to a series of simulations for the desert city of Erbil across a period of rapid urbanization. The changes in surface dust fluxes associated with urbanization are quantified. An analysis of the model output further reveals the dependence of surface dust fluxes on local meteorological conditions. Future applications of the models to environmental prediction are discussed.
ContributorsTahir, Sherzad Tahseen (Author) / Huang, Huei-Ping (Thesis advisor) / Phelan, Patrick (Committee member) / Herrmann, Marcus (Committee member) / Chen, Kangping (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2019
Description
Rapid expansion of dense beds of fine, spherical particles subjected to rapid depressurization is studied in a vertical shock tube. As the particle bed is unloaded, a high-speed video camera captures the dramatic evolution of the particle bed structure. Pressure transducers are used to measure the dynamic pressure changes during the particle bed expansion process. Image processing, signal processing, and Particle Image Velocimetry techniques, are used to examine the relationships between particle size, initial bed height, bed expansion rate, and gas velocities.
The gas-particle interface and the particle bed as a whole expand and evolve in stages. First, the bed swells nearly homogeneously for a very brief period of time (< 2ms). Shortly afterward, the interface begins to develop instabilities as it continues to rise, with particles nearest the wall rising more quickly. Meanwhile, the bed fractures into layers and then breaks down further into cellular-like structures. The rate at which the structural evolution occurs is shown to be dependent on particle size. Additionally, the rate of the overall bed expansion is shown to be dependent on particle size and initial bed height.
Taller particle beds and beds composed of smaller-diameter particles are found to be associated with faster bed-expansion rates, as measured by the velocity of the gas-particle interface. However, the expansion wave travels more slowly through these same beds. It was also found that higher gas velocities above the the gas-particle interface measured \textit{via} Particle Image Velocimetry or PIV, were associated with particle beds composed of larger-diameter particles. The gas dilation between the shocktube diaphragm and the particle bed interface is more dramatic when the distance between the gas-particle interface and the diaphragm is decreased-as is the case for taller beds.
To further elucidate the complexities of this multiphase compressible flow, simple OpenFOAM (Weller, 1998) simulations of the shocktube experiment were performed and compared to bed expansion rates, pressure fluctuations, and gas velocities. In all cases, the trends and relationships between bed height, particle diameter, with expansion rates, pressure fluctuations and gas velocities matched well between experiments and simulations. In most cases, the experimentally-measured bed rise rates and the simulated bed rise rates matched reasonably well in early times. The trends and overall values of the pressure fluctuations and gas velocities matched well between the experiments and simulations; shedding light on the effects each parameter has on the overall flow.
The gas-particle interface and the particle bed as a whole expand and evolve in stages. First, the bed swells nearly homogeneously for a very brief period of time (< 2ms). Shortly afterward, the interface begins to develop instabilities as it continues to rise, with particles nearest the wall rising more quickly. Meanwhile, the bed fractures into layers and then breaks down further into cellular-like structures. The rate at which the structural evolution occurs is shown to be dependent on particle size. Additionally, the rate of the overall bed expansion is shown to be dependent on particle size and initial bed height.
Taller particle beds and beds composed of smaller-diameter particles are found to be associated with faster bed-expansion rates, as measured by the velocity of the gas-particle interface. However, the expansion wave travels more slowly through these same beds. It was also found that higher gas velocities above the the gas-particle interface measured \textit{via} Particle Image Velocimetry or PIV, were associated with particle beds composed of larger-diameter particles. The gas dilation between the shocktube diaphragm and the particle bed interface is more dramatic when the distance between the gas-particle interface and the diaphragm is decreased-as is the case for taller beds.
To further elucidate the complexities of this multiphase compressible flow, simple OpenFOAM (Weller, 1998) simulations of the shocktube experiment were performed and compared to bed expansion rates, pressure fluctuations, and gas velocities. In all cases, the trends and relationships between bed height, particle diameter, with expansion rates, pressure fluctuations and gas velocities matched well between experiments and simulations. In most cases, the experimentally-measured bed rise rates and the simulated bed rise rates matched reasonably well in early times. The trends and overall values of the pressure fluctuations and gas velocities matched well between the experiments and simulations; shedding light on the effects each parameter has on the overall flow.
ContributorsZunino, Heather (Author) / Adrian, Ronald J (Thesis advisor) / Clarke, Amanda (Committee member) / Chen, Kangping (Committee member) / Herrmann, Marcus (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2019
Description
The global energy demand is expected to grow significantly in the next several decades and support for energy generation with high carbon emissions is continuing to decline. Alternative methods have gained interest, and wind energy has established itself as a viable source. Standard wind farms have limited room for growth and improvement, so wind energy has started to explore different directions. The urban environment is a potential direction for wind energy due to its proximity to the bulk of energy demand. CFD analysis has demonstrated that the presence of buildings can accelerate wind speeds between buildings and on rooftops. However, buildings generate areas of increased turbulence at their surface. The turbulence thickness and intensity vary with roof shape, building height, and building orientation. The analysis has concluded that good wind resource is possible in the urban environment in specific locations. With that, turbine selection becomes very important. A comparison has concluded that vertical axis wind turbines are more useful in the urban environment than horizontal axis wind turbines. Furthermore, building-augmented wind turbines are recommended because they are architecturally integrated into a building for the specific purpose of generating more energy. The research has concluded that large-scale generation in the urban environment is unlikely to be successful, but small-scale generation is quite viable. Continued research and investigation on urban wind energy is recommended.
ContributorsKlumpers, Ryan Scott (Author) / Calhoun, Ronald (Thesis director) / Huang, Huei-Ping (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2014-05
Description
ABSTRACT
The Sentinel-Arlington Volcanic Field (SAVF) is the Sentinel Plains lava field and associated volcanic edifices of late Cenozoic alkali olivine basaltic lava flows and minor tephra deposits near the Gila Bend and Painted Rock Mountains, 65 km-100km southwest of Phoenix, Arizona. The SAVF covers ~600 km2 and consists of 21+ volcanic centers, primarily low shield volcanoes ranging from 4-6 km in diameter and 30-200 m in height. The SAVF represents plains-style volcanism, an emplacement style and effusion rate intermediate between flood volcanism and large shield-building volcanism. Because of these characteristics, SAVF is a good analogue to small-volume effusive volcanic centers on Mars, such as those seen the southern flank of Pavonis Mons and in the Tempe Terra region of Mars. The eruptive history of the volcanic field is established through detailed geologic map supplemented by geochemical, paleomagnetic, and geochronological analysis.
Paleomagnetic analyses were completed on 473 oriented core samples from 58 sites. Mean inclination and declination directions were calculated from 8-12 samples at each site. Fifty sites revealed well-grouped natural remanent magnetization vectors after applying alternating field demagnetization. Thirty-nine sites had reversed polarity, eleven had normal polarity. Fifteen unique paleosecular variation inclination and declination directions were identified, six were represented by more than one site with resultant vectors that correlated within a 95% confidence interval. Four reversed sites were radiometrically dated to the Matuyama Chron with ages ranging from 1.08 ± 0.15 Ma to 2.37 ± 0.02 Ma; and one normal polarity site was dated to the Olduvai normal excursion at 1.91 ± 0.59 Ma. Paleomagnetic correlations within a 95% confidence interval were used to extrapolate radiogenic dates. Results reveal 3-5 eruptive stages over ~1.5 Ma in the early Pleistocene and that the SAVF dammed and possibly diverted the lower Gila River multiple times. Preliminary modeling of the median clast size of the terrace deposits suggests a maximum discharge of ~11300 cms (~400,000 cfs) was necessary to transport observed sediment load, which is larger than the historically recorded discharge of the modern Gila River.
The Sentinel-Arlington Volcanic Field (SAVF) is the Sentinel Plains lava field and associated volcanic edifices of late Cenozoic alkali olivine basaltic lava flows and minor tephra deposits near the Gila Bend and Painted Rock Mountains, 65 km-100km southwest of Phoenix, Arizona. The SAVF covers ~600 km2 and consists of 21+ volcanic centers, primarily low shield volcanoes ranging from 4-6 km in diameter and 30-200 m in height. The SAVF represents plains-style volcanism, an emplacement style and effusion rate intermediate between flood volcanism and large shield-building volcanism. Because of these characteristics, SAVF is a good analogue to small-volume effusive volcanic centers on Mars, such as those seen the southern flank of Pavonis Mons and in the Tempe Terra region of Mars. The eruptive history of the volcanic field is established through detailed geologic map supplemented by geochemical, paleomagnetic, and geochronological analysis.
Paleomagnetic analyses were completed on 473 oriented core samples from 58 sites. Mean inclination and declination directions were calculated from 8-12 samples at each site. Fifty sites revealed well-grouped natural remanent magnetization vectors after applying alternating field demagnetization. Thirty-nine sites had reversed polarity, eleven had normal polarity. Fifteen unique paleosecular variation inclination and declination directions were identified, six were represented by more than one site with resultant vectors that correlated within a 95% confidence interval. Four reversed sites were radiometrically dated to the Matuyama Chron with ages ranging from 1.08 ± 0.15 Ma to 2.37 ± 0.02 Ma; and one normal polarity site was dated to the Olduvai normal excursion at 1.91 ± 0.59 Ma. Paleomagnetic correlations within a 95% confidence interval were used to extrapolate radiogenic dates. Results reveal 3-5 eruptive stages over ~1.5 Ma in the early Pleistocene and that the SAVF dammed and possibly diverted the lower Gila River multiple times. Preliminary modeling of the median clast size of the terrace deposits suggests a maximum discharge of ~11300 cms (~400,000 cfs) was necessary to transport observed sediment load, which is larger than the historically recorded discharge of the modern Gila River.
ContributorsCave, Shelby Renee (Author) / Clarke, Amanda (Thesis advisor) / Burt, Donald (Committee member) / Reynolds, Stephen (Committee member) / Semken, Steven (Committee member) / Schmeeckle, Mark (Committee member) / Arizona State University (Publisher)
Created2015
Description
Among volcanic gases, sulfur dioxide (SO2) is by far the most commonly measured. More than a monitoring proxy for volcanic degassing, SO2 has the potential to alter climate patterns. Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day, spanning years to decades. SO2 emissions at those volcanoes are poorly constrained, in large part because the current satellite monitoring techniques are unable to detect or quantify plumes of low concentration in the troposphere. Eruption plumes also often show high concentrations of ash and/or aerosols, which further inhibit the detection methods. In this work I focus on quantifying volcanic gas emissions at persistently active explosive volcanoes and their variations over short timescales (minutes to hours), in order to document their contribution to natural SO2 flux as well as investigate the physical processes that control their behavior.
In order to make these measurements, I first develop and assemble a UV ground-based instrument, and validate it against an independently measured source of SO2 at a coal-burning power plant in Arizona. I establish a measurement protocol and demonstrate that the instrument measures SO2 fluxes with < 20 % error. Using the same protocol, I establish a record of the degassing patterns at Semeru volcano (Indonesia), a volcano that has been producing cycles of repeated explosions with periods of minutes to hours for the past several decades. Semeru produces an average of 21-71 tons of SO2 per day, amounting to a yearly output of 8-26 Mt.
Using the Semeru data, along with a 1-D transient numerical model of magma ascent, I test the validity of a model in which a viscous plug at the top of the conduit produces cycles of eruption and gas release. I find that it can be a valid hypothesis to explain the observed patterns of degassing at Semeru. Periodic behavior in such a system occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it.
In order to make these measurements, I first develop and assemble a UV ground-based instrument, and validate it against an independently measured source of SO2 at a coal-burning power plant in Arizona. I establish a measurement protocol and demonstrate that the instrument measures SO2 fluxes with < 20 % error. Using the same protocol, I establish a record of the degassing patterns at Semeru volcano (Indonesia), a volcano that has been producing cycles of repeated explosions with periods of minutes to hours for the past several decades. Semeru produces an average of 21-71 tons of SO2 per day, amounting to a yearly output of 8-26 Mt.
Using the Semeru data, along with a 1-D transient numerical model of magma ascent, I test the validity of a model in which a viscous plug at the top of the conduit produces cycles of eruption and gas release. I find that it can be a valid hypothesis to explain the observed patterns of degassing at Semeru. Periodic behavior in such a system occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it.
ContributorsSmekens, Jean-François (Author) / Clarke, Amanda (Thesis advisor) / Christensen, Philip R. (Philip Russel) (Committee member) / Williams, Stanley (Committee member) / Burton, Michael (Committee member) / Fink, Jonathan (Committee member) / Moore, Gordon (Committee member) / Arizona State University (Publisher)
Created2015
Description
This study uses Computational Fluid Dynamics (CFD) modeling to analyze the
dependence of wind power potential and turbulence intensity on aerodynamic design of a
special type of building with a nuzzle-like gap at its rooftop. Numerical simulations using
ANSYS Fluent are carried out to quantify the above-mentioned dependency due to three
major geometric parameters of the building: (i) the height of the building, (ii) the depth of
the roof-top gap, and (iii) the width of the roof-top gap. The height of the building is varied
from 8 m to 24 m. Likewise, the gap depth is varied from 3 m to 5 m and the gap width
from 2 m to 4 m. The aim of this entire research is to relate these geometric parameters of
the building to the maximum value and the spatial pattern of wind power potential across
the roof-top gap. These outcomes help guide the design of the roof-top geometry for wind
power applications and determine the ideal position for mounting a micro wind turbine.
From these outcomes, it is suggested that the wind power potential is greatly affected by
the increasing gap width or gap depth. It, however, remains insensitive to the increasing
building height, unlike turbulence intensity which increases with increasing building
height. After performing a set of simulations with varying building geometry to quantify
the wind power potential before the installation of a turbine, another set of simulations is
conducted by installing a static turbine within the roof-top gap. The results from the latter
are used to further adjust the estimate of wind power potential. Recommendations are made
for future applications based on the findings from the numerical simulations.
dependence of wind power potential and turbulence intensity on aerodynamic design of a
special type of building with a nuzzle-like gap at its rooftop. Numerical simulations using
ANSYS Fluent are carried out to quantify the above-mentioned dependency due to three
major geometric parameters of the building: (i) the height of the building, (ii) the depth of
the roof-top gap, and (iii) the width of the roof-top gap. The height of the building is varied
from 8 m to 24 m. Likewise, the gap depth is varied from 3 m to 5 m and the gap width
from 2 m to 4 m. The aim of this entire research is to relate these geometric parameters of
the building to the maximum value and the spatial pattern of wind power potential across
the roof-top gap. These outcomes help guide the design of the roof-top geometry for wind
power applications and determine the ideal position for mounting a micro wind turbine.
From these outcomes, it is suggested that the wind power potential is greatly affected by
the increasing gap width or gap depth. It, however, remains insensitive to the increasing
building height, unlike turbulence intensity which increases with increasing building
height. After performing a set of simulations with varying building geometry to quantify
the wind power potential before the installation of a turbine, another set of simulations is
conducted by installing a static turbine within the roof-top gap. The results from the latter
are used to further adjust the estimate of wind power potential. Recommendations are made
for future applications based on the findings from the numerical simulations.
ContributorsKailkhura, Gargi (Author) / Huang, Huei-Ping (Thesis advisor) / Rajagopalan, Jagannathan (Committee member) / Forzani, Erica (Committee member) / Arizona State University (Publisher)
Created2017
Description
One the major problems of this modern industrialized world is its dependence on fossil fuels for its energy needs. Burning of fossils fuels generates green-house gases which have adverse effects on global climate contributing to global warming. According to Environmental Protection Agency (EPA), carbon dioxide makes up 80 percent of green-house gases emitted in USA. Electrochemical reduction of carbon dioxide is an approach which uses CO2 emissions to produce other useful hydrocarbons which can be used in many ways.
In this study, primary focus was on optimizing the operating conditions, determining the better catalyst material, and analyzing the reaction products for the process of electrochemical reduction of carbon dioxide (ERC). Membrane electrode assemblies (MEA’s) are developed by air bushing the metal particles with a spray gun on to Nafion-212 which is a solid polymer based electrolyte (SPE), to support the electrodes in the electrochemical reactor gas diffusion layers (GDL) are developed using porous carbon paper. Anode was always made using the same material which is platinum but cathode material was changed as it is the working electrode.
The membrane electrode assembly (MEA) is then placed into the electrochemical reactor along with gas diffusion layer (GDL) to assess the performance of the catalyst material by techniques like linear sweep voltammetry and chronoamperometry. Performance of MEA was analyzed at 4 different potentials, 2 different temperatures and for 2 different cathode catalyst materials. The reaction products of the process are analyzed using gas chromatography (GC) which has thermal conductivity detector (TCD) used for detecting hydrogen (H2), carbon monoxide (CO) and flame ionization detector (FID) used for detecting hydrocarbons. The experiments performed at 40o C gave the better results when compared with the experiments performed at ambient temperature. Also results suggested that copper oxide cathode catalyst has better durability than platinum-carbon. Maximum faradaic efficiency for methane was 5.3% it was obtained at 2.25V using copper oxide catalyst. Furthermore, experiments must be carried out to make the electrochemical reactor more robust to withstand all the operating conditions like higher potentials and to make it a solar powered reactor.
In this study, primary focus was on optimizing the operating conditions, determining the better catalyst material, and analyzing the reaction products for the process of electrochemical reduction of carbon dioxide (ERC). Membrane electrode assemblies (MEA’s) are developed by air bushing the metal particles with a spray gun on to Nafion-212 which is a solid polymer based electrolyte (SPE), to support the electrodes in the electrochemical reactor gas diffusion layers (GDL) are developed using porous carbon paper. Anode was always made using the same material which is platinum but cathode material was changed as it is the working electrode.
The membrane electrode assembly (MEA) is then placed into the electrochemical reactor along with gas diffusion layer (GDL) to assess the performance of the catalyst material by techniques like linear sweep voltammetry and chronoamperometry. Performance of MEA was analyzed at 4 different potentials, 2 different temperatures and for 2 different cathode catalyst materials. The reaction products of the process are analyzed using gas chromatography (GC) which has thermal conductivity detector (TCD) used for detecting hydrogen (H2), carbon monoxide (CO) and flame ionization detector (FID) used for detecting hydrocarbons. The experiments performed at 40o C gave the better results when compared with the experiments performed at ambient temperature. Also results suggested that copper oxide cathode catalyst has better durability than platinum-carbon. Maximum faradaic efficiency for methane was 5.3% it was obtained at 2.25V using copper oxide catalyst. Furthermore, experiments must be carried out to make the electrochemical reactor more robust to withstand all the operating conditions like higher potentials and to make it a solar powered reactor.
ContributorsMudunur, Santosh shekar (Author) / Kannan, Arunachala (Thesis advisor) / Phelan, Patrick (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2017
Description
Ascraeus Mons (AM) is the northeastern most large shield volcano residing in the Tharsis province on Mars. AM has a diameter of ~350 km and reaches a height of 16 km above Mars datum, making AM the third largest volcano on Mars. Previous mapping of a limited area of these volcanoes using HRSC images (13-25 m/pixel) revealed a diverse distribution of volcanic landforms within the calderas, along the flanks, rift aprons, and surrounding plains. The general scientific objective for which mapping was based was to show the different lava flow morphologies across AM to better understand the evolution and geologic history.
A 1: 1,000,000 scale geologic map of Ascraeus Mons was produced using ArcGIS and will be submitted to the USGS for review and publication. Mapping revealed 26 units total, broken into three separate categories: Flank units, Apron and Scarp units, and Plains units. Units were defined by geomorphological characteristics such as: surface texture, albedo, size, location, and source. Defining units in this manner allowed for contact relationships to be observed, creating a relative age date for each unit to understand the evolution and history of this large shield volcano.
Ascraeus Mons began with effusive, less viscous style of eruptions and transitioned to less effusive, more viscous eruptions building up the main shield. This was followed by eruptions onto the plains from the two main rift aprons on AM. Apron eruptions continued, while flank eruptions ceased, surrounding and embaying the flanks of AM. Eruptions from the rifts wane and build up the large aprons and low shield fields. Glaciers modified the base of the west flank and deposited the Aureole material. Followed by localized recent eruptions on the flanks, in the calderas, and small vent fields. Currently AM is modified by aeolian and tectonic processes. While the overall story of Ascraeus Mons does not change significantly, higher resolution imagery allowed for a better understanding of magma evolution and lava characteristics across the main shield. This study helps identify martian magma production rates and how not only Ascraeus Mons evolved, but also the Tharsis province and other volcanic regions of Mars.
A 1: 1,000,000 scale geologic map of Ascraeus Mons was produced using ArcGIS and will be submitted to the USGS for review and publication. Mapping revealed 26 units total, broken into three separate categories: Flank units, Apron and Scarp units, and Plains units. Units were defined by geomorphological characteristics such as: surface texture, albedo, size, location, and source. Defining units in this manner allowed for contact relationships to be observed, creating a relative age date for each unit to understand the evolution and history of this large shield volcano.
Ascraeus Mons began with effusive, less viscous style of eruptions and transitioned to less effusive, more viscous eruptions building up the main shield. This was followed by eruptions onto the plains from the two main rift aprons on AM. Apron eruptions continued, while flank eruptions ceased, surrounding and embaying the flanks of AM. Eruptions from the rifts wane and build up the large aprons and low shield fields. Glaciers modified the base of the west flank and deposited the Aureole material. Followed by localized recent eruptions on the flanks, in the calderas, and small vent fields. Currently AM is modified by aeolian and tectonic processes. While the overall story of Ascraeus Mons does not change significantly, higher resolution imagery allowed for a better understanding of magma evolution and lava characteristics across the main shield. This study helps identify martian magma production rates and how not only Ascraeus Mons evolved, but also the Tharsis province and other volcanic regions of Mars.
ContributorsMohr, Kyle James (Author) / Williams, David A. (Thesis advisor) / Christensen, Phil R (Thesis advisor) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2017