Matching Items (25)
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- All Subjects: energy
- All Subjects: electrochemistry
- Creators: Chemical Engineering Program
- Creators: Addison, Marlin
Description
Through manipulation of adaptable opportunities available within a given environment, individuals become active participants in managing personal comfort requirements, by exercising control over their comfort without the assistance of mechanical heating and cooling systems. Similarly, continuous manipulation of a building skin's form, insulation, porosity, and transmissivity qualities exerts control over the energy exchanged between indoor and outdoor environments. This research uses four adaptive response variables in a modified software algorithm to explore an adaptive building skin's potential in reacting to environmental stimuli with the purpose of minimizing energy use without sacrificing occupant comfort. Results illustrate that significant energy savings can be realized with adaptive envelopes over static building envelopes even under extreme summer and winter climate conditions; that the magnitude of these savings are dependent on climate and orientation; and that occupant thermal comfort can be improved consistently over comfort levels achieved by optimized static building envelopes. The resulting adaptive envelope's unique climate-specific behavior could inform designers in creating an intelligent kinetic aesthetic that helps facilitate adaptability and resiliency in architecture.
ContributorsErickson, James (Author) / Bryan, Harvey (Thesis advisor) / Addison, Marlin (Committee member) / Kroelinger, Michael D. (Committee member) / Reddy, T. Agami (Committee member) / Arizona State University (Publisher)
Created2013
Description
The objective of this thesis is to investigate the various types of energy end-uses to be expected in future high efficiency single family residences. For this purpose, this study has analyzed monitored data from 14 houses in the 2013 Solar Decathlon competition, and segregates the energy consumption patterns in various residential end-uses (such as lights, refrigerators, washing machines, ...). The analysis was not straight-forward since these homes were operated according to schedules previously determined by the contest rules. The analysis approach allowed the isolation of the comfort energy use by the Heating, Venting and Cooling (HVAC) systems. HVAC are the biggest contributors to energy consumption during operation of a building, and therefore are a prime concern for energy performance during the building design and the operation. Both steady state and dynamic models of comfort energy use which take into account variations in indoor and outdoor temperatures, solar radiation and thermal mass of the building were explicitly considered. Steady State Inverse Models are frequently used for thermal analysis to evaluate HVAC energy performance. These are fast, accurate, offer great flexibility for mathematical modifications and can be applied to a variety of buildings. The results are presented as a horizontal study that compares energy consumption across homes to arrive at a generic rather than unique model - to be used in future discussions in the context of ultra efficient homes. It is suggested that similar analyses of the energy-use data that compare the performance of variety of ultra efficient technologies be conducted to provide more accurate indications of the consumption by end use for future single family residences. These can be used alongside the Residential Energy Consumption Survey (RECS) and the Leading Indicator for Remodeling Activity (LIRA) indices to assist in planning and policy making related to residential energy sector.
ContributorsGarkhail, Rahul (Author) / Reddy, T Agami (Thesis advisor) / Bryan, Harvey (Committee member) / Addison, Marlin (Committee member) / Arizona State University (Publisher)
Created2014
Description
Passive cooling designs & technologies offer great promise to lower energy use in buildings. Though the working principles of these designs and technologies are well understood, simplified tools to quantitatively evaluate their performance are lacking. Cooling by night ventilation, which is the topic of this research, is one of the well known passive cooling technologies. The building's thermal mass can be cooled at night by ventilating the inside of the space with the relatively lower outdoor air temperatures, thereby maintaining lower indoor temperatures during the warmer daytime period. Numerous studies, both experimental and theoretical, have been performed and have shown the effectiveness of the method to significantly reduce air conditioning loads or improve comfort levels in those climates where the night time ambient air temperature drops below that of the indoor air. The impact of widespread adoption of night ventilation cooling can be substantial, given the large fraction of energy consumed by air conditioning of buildings (about 12-13% of the total electricity use in U.S. buildings). Night ventilation is relatively easy to implement with minimal design changes to existing buildings. Contemporary mathematical models to evaluate the performance of night ventilation are embedded in detailed whole building simulation tools which require a certain amount of expertise and is a time consuming approach. This research proposes a methodology incorporating two models, Heat Transfer model and Thermal Network model, to evaluate the effectiveness of night ventilation. This methodology is easier to use and the run time to evaluate the results is faster. Both these models are approximations of thermal coupling between thermal mass and night ventilation in buildings. These models are modifications of existing approaches meant to model dynamic thermal response in buildings subject to natural ventilation. Effectiveness of night ventilation was quantified by a parameter called the Discomfort Reduction Factor (DRF) which is the index of reduction of occupant discomfort levels during the day time from night ventilation. Daily and Monthly DRFs are calculated for two climate zones and three building heat capacities. It is verified that night ventilation is effective in seasons and regions when day temperatures are between 30 oC and 36 oC and night temperatures are below 20 oC. The accuracy of these models may be lower than using a detailed simulation program but the loss in accuracy in using these tools more than compensates for the insights provided and better transparency in the analysis approach and results obtained.
ContributorsEndurthy, Akhilesh Reddy (Author) / Reddy, T Agami (Thesis advisor) / Phelan, Patrick (Committee member) / Addison, Marlin (Committee member) / Arizona State University (Publisher)
Created2011
Description
A major problem faced by electric utilities is the need to meet electric loads during certain times of peak demand. One of the widely adopted and promising programs is demand response (DR) where building owners are encouraged, by way of financial incentives, to reduce their electric loads during a few hours of the day when the electric utility is likely to encounter peak loads. In this thesis, we investigate the effect of various DR measures and their resulting indoor occupant comfort implications, on two prototype commercial buildings in the hot and dry climate of Phoenix, AZ. The focus of this study is commercial buildings during peak hours and peak days. Two types of office buildings are modeled using a detailed building energy simulation program (EnergyPlus V6.0.0): medium size office building (53,600 sq. ft.) and large size office building (498,600 sq. ft.). The two prototype buildings selected are those advocated by the Department of Energy and adopted by ASHRAE in the framework of ongoing work on ASHRAE standard 90.1 which reflect 80% of the commercial buildings in the US. After due diligence, the peak time window is selected to be 12:00-18:00 PM (6 hour window). The days when utility companies require demand reduction mostly fall during hot summer days. Therefore, two days, the summer high-peak (15th July) and the mid-peak (29th June) days are selected to perform our investigations. The impact of building thermal mass as well as several other measures such as reducing lighting levels, increasing thermostat set points, adjusting supply air temperature, resetting chilled water temperature are studied using the EnergyPlus building energy simulation program. Subsequently the simulation results are summarized in tabular form so as to provide practical guidance and recommendations of which DR measures are appropriate for different levels of DR reductions and the associated percentage values of people dissatisfied (PPD). This type of tabular recommendations is of direct usefulness to the building owners and operators contemplating DR response. The methodology can be extended to other building types and climates as needed.
ContributorsKhanolkar, Amruta (Author) / Reddy, T Agami (Thesis advisor) / Addison, Marlin (Committee member) / Bryan, Harvey (Committee member) / Arizona State University (Publisher)
Created2012
Description
Building Envelope includes walls, roofs and openings, which react to the outdoor environmental condition. Today, with the increasing use of glass in building envelope, the energy usage of the buildings is increasing, especially in the offices and commercial buildings. Use of right glass type and control triggers helps to optimize the energy use, by tradeoff between optical and thermal properties. The part of the research looks at the different control triggers and its range that governs the use of electrochromic glass to regulate the energy usage in building. All different control trigger that can be possibly used for regulating the clear and tint state of glass were analyzed with most appropriate range. Its range was triggered such that 80% time of the glass is trigger between the ranges. The other building parameters like window wall ratio and orientations were also investigated. The other half of the research study looks into the feasibility of using the Electrochromic windows, as it is ought to be the main factor governing the market usage of Electrochromic windows and to investigate the possible ways to make it feasible. Different LCC parameters were studied to make it market feasible product. This study shows that installing this technology with most appropriate trigger range can reduce annual building energy consumption from 6-8% but still cost of the technology is 3 times the ASHRAE glass, which results in 70-90 years of payback. This study concludes that south orientation saves up to 3-5% of energy and 4-6% of cooling tons while north orientation gives negligible saving using EC glass. LCC parameters show that there is relative change in increasing the net saving for different parameters but none except 50% of the present glass cost is the possible option where significant change is observed.
ContributorsMunshi, Kavish Prakash (Author) / Bryan, Harvey (Thesis advisor) / Reddy, Agami (Committee member) / Addison, Marlin (Committee member) / Arizona State University (Publisher)
Created2012
Description
The Urban Heat Island (UHI) has been known to have been around from as long as people have been urbanizing. The growth and conglomeration of cities in the past century has caused an increase in the intensity and impact of Urban Heat Island, causing significant changes to the micro-climate and causing imbalances in the temperature patterns of cities. The urban heat island (UHI) is a well established phenomenon and it has been attributed to the reduced heating loads and increased cooling loads, impacting the total energy consumption of affected buildings in all climatic regions. This thesis endeavors to understand the impact of the urban heat island on the typical buildings in the Phoenix Metropolitan region through an annual energy simulation process spanning through the years 1950 to 2005. Phoenix, as a representative city for the hot-arid cooling-dominated region, would be an interesting example to see how the reduction in heating energy consumption offsets the increased demand for cooling energy in the building. The commercial reference building models from the Department of Energy have been used to simulate commercial building stock, while for the residential stock a representative residential model prescribing to IECC 2006 standards will be used. The multiyear simulation process will bring forth the energy consumptions of various building typologies, thus highlighting differing impacts on the various building typologies. A vigorous analysis is performed to see the impact on the cooling loads annually, specifically during summer and summer nights, when the impact of the 'atmospheric canopy layer' - urban heat island (UHI) causes an increase in the summer night time minimum and night time average temperatures. This study also shows the disparity in results of annual simulations run utilizing a typical meteorological year (TMY) weather file, to that of the current recorded weather data. The under prediction due to the use of TMY would translate to higher or lower predicted energy savings in the future years, for changes made to the efficiencies of the cooling or heating systems and thermal performance of the built-forms. The change in energy usage patterns caused by higher cooling energy and lesser heating energy consumptions could influence future policies and energy conservation standards. This study could also be utilized to understand the impacts of the equipment sizing protocols currently adopted, equipment use and longevity and fuel swapping as heating cooling ratios change.
ContributorsDoddaballapur, Sandeep (Author) / Bryan, Harvey (Thesis advisor) / Reddy, Agami T (Committee member) / Addison, Marlin (Committee member) / Arizona State University (Publisher)
Created2011
Description
Solid oxide fuel cells have become a promising candidate in the development of high-density clean energy sources for the rapidly increasing demands in energy and global sustainability. In order to understand more about solid oxide fuel cells, the important step is to understand how to model heterogeneous materials. Heterogeneous materials are abundant in nature and also created in various processes. The diverse properties exhibited by these materials result from their complex microstructures, which also make it hard to model the material. Microstructure modeling and reconstruction on a meso-scale level is needed in order to produce heterogeneous models without having to shave and image every slice of the physical material, which is a destructive and irreversible process. Yeong and Torquato [1] introduced a stochastic optimization technique that enables the generation of a model of the material with the use of correlation functions. Spatial correlation functions of each of the various phases within the heterogeneous structure are collected from a two-dimensional micrograph representing a slice of a solid oxide fuel cell through computational means. The assumption is that two-dimensional images contain key structural information representative of the associated full three-dimensional microstructure. The collected spatial correlation functions, a combination of one-point and two-point correlation functions are then outputted and are representative of the material. In the reconstruction process, the characteristic two-point correlation functions is then inputted through a series of computational modeling codes and software to generate a three-dimensional visual model that is statistically similar to that of the original two-dimensional micrograph. Furthermore, parameters of temperature cooling stages and number of pixel exchanges per temperature stage are utilized and altered accordingly to observe which parameters has a higher impact on the reconstruction results. Stochastic optimization techniques to produce three-dimensional visual models from two-dimensional micrographs are therefore a statistically reliable method to understanding heterogeneous materials.
ContributorsPhan, Richard Dylan (Author) / Jiao, Yang (Thesis director) / Ren, Yi (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
Microbial fuel cells (MFCs) promote the sustainable conversion of organic matter in black water to electrical current, enabling the production of hydrogen peroxide (H2O2) while making waste water treatment energy neutral or positive. H2O2 is useful in remote locations such as U.S. military forward operating bases (FOBs) for on-site tertiary water treatment or as a medical disinfectant, among many other uses. Various carbon-based catalysts and binders for use at the cathode of a an MFC for H2O2 production are explored using linear sweep voltammetry (LSV) and rotating ring-disk electrode (RRDE) techniques. The oxygen reduction reaction (ORR) at the cathode has slow kinetics at conditions present in the MFC, making it important to find a catalyst type and loading which promote a 2e- (rather than 4e-) reaction to maximize H2O2 formation. Using LSV methods, I compared the cathodic overpotentials associated with graphite and Vulcan carbon catalysts as well as Nafion and AS-4 binders. Vulcan carbon catalyst with Nafion binder produced the lowest overpotentials of any binder/catalyst combinations. Additionally, I determined that pH control may be required at the cathode due to large potential losses caused by hydroxide (OH-) concentration gradients. Furthermore, RRDE tests indicate that Vulcan carbon catalyst with a Nafion binder has a higher H2O2 production efficiency at lower catalyst loadings, but the trade-off is a greater potential loss due to higher activation energy. Therefore, an intermediate catalyst loading of 0.5 mg/cm2 Vulcan carbon with Nafion binder is recommended for the final MFC design. The chosen catalyst, binder, and loading will maximize H2O2 production, optimize MFC performance, and minimize the need for additional energy input into the system.
ContributorsStadie, Mikaela Johanna (Author) / Torres, Cesar (Thesis director) / Popat, Sudeep (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2015-05
Description
Iodide-based ionic liquids have been widely employed as sources of iodide in electrolytes for applications utilizing the triiodide/iodide redox couple. While adding a low-viscosity solvent such as water to ionic liquids can greatly enhance their usefulness, mixtures of highly viscous iodide-containing ILs with water have never been studied. Thus, this paper investigates, for the first time, mixtures of water and the ionic liquid 1-butyl-3-methylimidazolium iodide ([BMIM][I]) through a combined experimental and molecular dynamics study. The density, melting point, viscosity and conductivity of these mixtures were measured experimentally. The composition region below 50% water by mole was found to be dramatically different from the region above 50% water, with trends in density and melting point differing before and after that point. Water was found to have a profound effect on viscosity and conductivity of the IL, and the effect of hydrogen bonding was discussed. Molecular dynamics simulations representing the same mixture compositions were performed. Molecular ordering was observed, as were changes in this ordering corresponding to water content. Molecular ordering was related to the experimentally measured mixture properties, providing a possible explanation for the two distinct composition regions identified by experiment.
ContributorsNgan, Miranda L (Author) / Dai, Lenore (Thesis director) / Nofen, Elizabeth (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2015-05
Description
The recovery of biofuels permits renewable alternatives to present day fossil fuels that cause devastating effects on the planet. Pervaporation is a separation process that shows promise for the separation of ethanol from biologically fermentation broths. The performance of thin film composite membranes of polydimethylsiloxane (PDMS) and zeolite imidazolate frameworks (ZIF-71) dip coated onto a porous substrate are analyzed. Pervaporation performance factors of flux, separation factor and selectivity are measured for varying ZIF-71 loadings of pure PDMS, 5 wt%, 12.5 wt% and 25 wt% at 60 oC with a 2 wt% ethanol/water feed. The increase in ZIF-71 loadings increased the performance of PDMS to produce higher flux, higher separation factor and high selectivity than pure polymeric films.
ContributorsLau, Ching Yan (Author) / Lind, Mary Laura (Thesis director) / Durgun, Pinar Cay (Committee member) / Lively, Ryan (Committee member) / Barrett, The Honors College (Contributor) / School of International Letters and Cultures (Contributor) / Chemical Engineering Program (Contributor)
Created2014-05