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This paper explores women and bicycling, with the focus of looking at how to get more women onto the bicycle in Tempe, Arizona. The main areas of interest for this study are improvements to bicycling infrastructure and an increase in the safety and the perception of safety of women cyclists

This paper explores women and bicycling, with the focus of looking at how to get more women onto the bicycle in Tempe, Arizona. The main areas of interest for this study are improvements to bicycling infrastructure and an increase in the safety and the perception of safety of women cyclists in the Tempe area. In order to explore this topic, an online survey of 75 Arizona State students was conducted. From the results women were primarily concerned with their safety due to the condition of the overall infrastructure and the lack of bicycle related improvements. Research such as this that examines women and cycling is significant due to the current underrepresentation of women in the cycling community and has the potential to improve safety and increase bicycle ridership.
ContributorsStarr, Nicole (Author) / Kelley, Jason (Thesis director) / Golub, Aaron (Committee member) / Barrett, The Honors College (Contributor) / Herberger Institute for Design and the Arts (Contributor) / School of Sustainability (Contributor)
Created2014-12
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Defines the concept of the arcology as conceived by architect Paolo Soleri. Arcology combines "architecture" and "ecology" and explores a visionary notion of a self-contained urban community that has agricultural, commercial, and residential facilities under one roof. Two real-world examples of these projects are explored: Arcosanti, AZ and Masdar City,

Defines the concept of the arcology as conceived by architect Paolo Soleri. Arcology combines "architecture" and "ecology" and explores a visionary notion of a self-contained urban community that has agricultural, commercial, and residential facilities under one roof. Two real-world examples of these projects are explored: Arcosanti, AZ and Masdar City, Abu Dhabi, UAE. Key aspects of the arcology that could be applied to an existing urban fabric are identified, such as urban design fostering social interaction, reduction of automobile dependency, and a development pattern that combats sprawl. Through interviews with local representatives, a holistic approach to applying arcology concepts to the Phoenix Metro Area is devised.
ContributorsSpencer, Sarah Anne (Author) / Manuel-Navarrete, David (Thesis director) / Salon, Deborah (Committee member) / Barrett, The Honors College (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / School of Sustainability (Contributor)
Created2015-05
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Description
Locusts are a major crop pest in many parts of the world and different species are endemic to different countries. In Latin America, the South American Locust (Schistocerca cancellata) is the predominant species found mostly in Argentina, Chile, Bolivia, Paraguay, and southern Brazil with Argentina being the most affected. Several

Locusts are a major crop pest in many parts of the world and different species are endemic to different countries. In Latin America, the South American Locust (Schistocerca cancellata) is the predominant species found mostly in Argentina, Chile, Bolivia, Paraguay, and southern Brazil with Argentina being the most affected. Several control and management practices, including biological control, have been implemented in these countries in the past to control the locusts and reduce their impact on crop and vegetation, however, effective long-term control and management practices will require a detail understanding of how the predominant locust species in this region responds to resource variation. Research has shown that there is strong evidence that locusts, and many other organisms, will actively balance dietary macronutrients (protein, carbohydrates, and lipids) to optimize growth, survival, and/or reproduction. A study by Cease et. al, 2017, on the dietary preferences of the Mongolian locust (Oedaleus asiaticus) showed that it prefers diets that are high in carbohydrates over diets that are high in protein, in this case locusts self-selected a 1:2 ratio of protein:carbohydrate. This and many other studies provide vital insight into the nutritional and feeding preferences of these locust species but the effects that this difference in protein: carbohydrate preferences has on growth, egg production, flight potential, and survival has yet to be fully explored, hence, this study investigates the effects that nitrogen fertilization of wheatgrass will have on the growth, egg production, survival, and flight muscle mass of the South American locust in a controlled, laboratory environment.
ContributorsManneh, Balanding (Author) / Cease, Arianne (Thesis director) / Overson, Rick (Committee member) / School of Sustainability (Contributor) / School of Life Sciences (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
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City planners often use bicycle friendly rating schemes as tools to guide them in their efforts to establish a bicycle community. However, the criteria and methodologies used vary from program to program and often do not encapsulate all of the necessary elements that comprise true bicycle friendliness. This report documents

City planners often use bicycle friendly rating schemes as tools to guide them in their efforts to establish a bicycle community. However, the criteria and methodologies used vary from program to program and often do not encapsulate all of the necessary elements that comprise true bicycle friendliness. This report documents the important elements, strategies, and best practices that well-established Dutch, Danish, and German bike friendly cities exhibit to create a baseline standard for bicycle friendliness. Not all rating programs' criteria and methodologies align perfectly within this understanding of bicycle friendliness. City planners should use these programs as tools while keeping their limitations in consideration. The City of Tempe currently uses the League of American Bicyclists Bicycle Friendly Community program and BikeScore.com. By understanding the limitations associated with these programs, Tempe should move forward in their pursuit of bicycle friendliness by using multiple rating programs simultaneously and by looking at top-rated cities' strategies to enhance their infrastructure, network, urban form, and biking culture.
ContributorsTrombino, Frank Michael (Author) / Golub, Aaron (Thesis director) / Kelley, Jason (Committee member) / Barrett, The Honors College (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / School of Sustainability (Contributor)
Created2014-05
Description
This honors thesis is focused on two separate catalysis projects conducted under the mentorship of Dr. Javier Pérez-Ramírez at ETH Zürich. The first project explored ethylene oxychlorination over supported europium oxychloride catalysts. The second project investigated alkyne semihydrogenation over nickel phosphide catalysts. This work is the subject of a publication

This honors thesis is focused on two separate catalysis projects conducted under the mentorship of Dr. Javier Pérez-Ramírez at ETH Zürich. The first project explored ethylene oxychlorination over supported europium oxychloride catalysts. The second project investigated alkyne semihydrogenation over nickel phosphide catalysts. This work is the subject of a publication of which I am a co-author, as cited below.

Project 1 Abstract: Ethylene Oxychlorination
The current two-step process for the industrial process of vinyl chloride production involves CuCl2 catalyzed ethylene oxychlorination to ethylene dichloride followed by thermal cracking of the latter to vinyl chloride. To date, no industrial application of a one-step process is available. To close this gap, this work evaluates a wide range of self-prepared supported CeO2 and EuOCl catalysts for one-step production of vinyl chloride from ethylene in a fixed-bed reactor at 623 773 K and 1 bar using feed ratios of C2H4:HCl:O2:Ar:He = 3:3 6:1.5 6:3:82 89.5. Among all studied systems, CeO2/ZrO2 and CeO2/Zeolite MS show the highest activity but suffer from severe combustion of ethylene, forming COx, while 20 wt.% EuOCl/γ-Al2O3 leads to the best vinyl chloride selectivity of 87% at 15.6% C2H4 conversion with complete suppression of CO2 formation and only 4% selectivity to CO conversion for over 100 h on stream. Characterization by XRD and EDX mapping reveals that much of the Eu is present in non-active phases such as Al2Eu or EuAl4, indicating that alternative synthesis methods could be employed to better utilize the metal. A linear relationship between conversion and metal loading is found for this catalyst, indicating that always part of the used Eu is available as EuOCl, while the rest forms inactive europium aluminate species. Zeolite-supported EuOCl slightly outperforms EuOCl/γ Al2O3 in terms of total yield, but is prone to significant coking and is unstable. Even though a lot of Eu seems locked in inactive species on EuOCl/γ Al2O3, these results indicate possible savings of nearly 16,000 USD per kg of catalyst compared to a bulk EuOCl catalyst. These very promising findings constitute a crucial step for process intensification of polyvinyl chloride production and exploring the potential of supported EuOCl catalysts in industrially-relevant reactions.

Project 2 Abstract: Alkyne Semihydrogenation
Despite strongly suffering from poor noble metal utilization and a highly toxic selectivity modifier (Pb), the archetypal catalyst applied for the three-phase alkyne semihydrogenation, the Pb-doped Pd/CaCO3 (Lindlar catalyst), is still being utilized at industrial level. Inspired by the very recent strategies involving the modification of Pd with p-block elements (i.e., S), this work extrapolates the concept by preparing crystalline metal phosphides with controlled stoichiometry. To develop an affordable and environmentally-friendly alternative to traditional hydrogenation catalysts, nickel, a metal belonging to the same group as Pd and capable of splitting molecular hydrogen has been selected. Herein, a simple two-step synthesis procedure involving nontoxic precursors was used to synthesize bulk nickel phosphides with different stoichiometries (Ni2P, Ni5P4, and Ni12P5) by controlling the P:Ni ratios. To uncover structural and surface features, this catalyst family is characterized with an array of methods including X-ray diffraction (XRD), 31P magic-angle nuclear magnetic resonance (MAS-NMR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). Bulk-sensitive techniques prove the successful preparation of pure phases while XPS analysis unravels the facile passivation occurring at the NixPy surface that persists even after reductive treatment. To assess the characteristic surface fingerprints of these materials, Ar sputtering was carried out at different penetration depths, reveling the presence of Ni+ and P-species. Continuous-flow three-phase hydrogenations of short-chain acetylenic compounds display that the oxidized layer covering the surface is reduced under reaction conditions, as evidenced by the induction period before reaching the steady state performance. To assess the impact of the phosphidation treatment on catalytic performance, the catalysts were benchmarked against a commercial Ni/SiO2-Al2O3 sample. While Ni/SiO2-Al2O3 presents very low selectivity to the alkene (the selectivity is about 10% at full conversion) attributed to the well-known tendency of naked nickel nanoparticles to form hydrides, the performance of nickel phosphides is highly selective and independent of P:Ni ratio. In line with previous findings on PdxS, kinetic tests indicate the occurrence of a dual-site mechanism where the alkyne and hydrogen do not compete for the same site.

This work is the subject of a publication of which I am a co-author, as cited below.

D. Albani; K. Karajovic; B. Tata; Q. Li; S. Mitchell; N. López; J. Pérez-Ramírez. Ensemble Design in Nickel Phosphide Catalysts for Alkyne Semi-Hydrogenation. ChemCatChem 2019. doi.org/10.1002/cctc.201801430
ContributorsTata, Bharath (Author) / Deng, Shuguang (Thesis director) / Muhich, Christopher (Committee member) / Chemical Engineering Program (Contributor, Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
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Description
Elevated nitrate (NO3-) concentration in streams and rivers has contributed to environmental problems such as downstream eutrophication and loss of biodiversity. Sycamore Creek in Arizona is nitrogen limited, but previous studies have demonstrated high potential for denitrification, a microbial process in which biologically active NO3- is reduced to relatively inert

Elevated nitrate (NO3-) concentration in streams and rivers has contributed to environmental problems such as downstream eutrophication and loss of biodiversity. Sycamore Creek in Arizona is nitrogen limited, but previous studies have demonstrated high potential for denitrification, a microbial process in which biologically active NO3- is reduced to relatively inert dinitrogen (N2) gas. Oak Creek is similarly nitrogen limited, but NO3- concentration in reaches surrounded by agriculture can be double that of other reaches. We employed a denitrification enzyme assay (DEA) to compare potential denitrification rate between differing land uses in Oak Creek and measured whole system N2 flux using a membrane inlet mass spectrometer to compare differences in actual denitrification rates at Sycamore and Oak Creek. We anticipated that NO3- would be an important limiting factor for denitrifiers; consequentially, agricultural land use reaches within Oak Creek would have the highest potential denitrification rate. We expected in situ denitrification rate to be higher in Oak Creek than Sycamore Creek due to elevated NO3- concentration, higher discharge, and larger streambed surface area. DEA results are forthcoming, but analysis of potassium chloride (KCl) extraction data showed that there were no significant differences between sites in sediment extractable NO3- on either a dry mass or organic mass basis. Whole-reach denitrification rate was inconclusive in Oak Creek, and though a significant positive flux in N2 from upstream to downstream was measured in Sycamore Creek, the denitrification rate was not significantly different from 0 after accounting for reaeration, suggesting that denitrification does not account for a significant portion of the NO3- uptake in Sycamore Creek. Future work is needed to address the specific factors limiting denitrification in this system.
ContributorsCaulkins, Corey Robert (Author) / Grimm, Nancy (Thesis director) / Childers, Daniel (Committee member) / School of Sustainability (Contributor) / School of Life Sciences (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
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Description
City managers and policy makers are increasing looking to environmental systems to provide beneficial services for urban systems. Constructed wetland systems (CWS), highly managed and designed wetland ecosystems, are being utilized to remove pollution, particularly excess nitrogen (N), from treated wastewater. Various wetland process remove N from effluent, such as

City managers and policy makers are increasing looking to environmental systems to provide beneficial services for urban systems. Constructed wetland systems (CWS), highly managed and designed wetland ecosystems, are being utilized to remove pollution, particularly excess nitrogen (N), from treated wastewater. Various wetland process remove N from effluent, such as denitrification, direct plant uptake, and soil accumulation. Emergent macrophytes provide direct uptake of N and improve conditions for microbially-mediated N processing. The role of different macrophytes species, however, is less understood and has primarily been examined in mesocosm and microcosm experiments and in mesic environments. I examined the effects of community composition on N removal and processing at the whole ecosystem scale in an aridland, constructed wetland (42 ha) through: 1) quantifying above- and belowground biomass and community composition from July 2011 \u2014 November 2012 using a non-destructive allometric technique, and; 2) quantifying macrophyte N content and direct macrophyte N uptake over the 2012 growing season. Average peak biomass in July 2011 & 2012 was 2,930 g dw/m2 and 2,340 g dw/m2, respectively. Typha spp. (Typha domingensis and Typha latifolia) comprised the majority (approximately 2/3) of live aboveground biomass throughout the sampling period. No statistically significant differences were observed in macrophyte N content among the six species present, with an overall average of 1.68% N in aboveground tissues and 1.29% N in belowground tissues. Per unit area of wetland, Typha spp. retained the most N (22 g/m2); total N retained by all species was 34 g/m2. System-wide direct plant N uptake was markedly lower than N input to the system and thus represented a small portion of system N processing. Soil accumulation of N also played a minor role, leaving denitrification as the likely process responsible for the majority of system N processing. Based on a literature review, macrophyte species composition likely influences denitrification through oxygen diffusion into soils and through the quality and quantity of carbon in leaf litter. While this study and the literature indicates Typha spp. may be the best species to promote wetland N processing, other considerations (e.g., bird habitat) and conditions (e.g., type of wastewater being treated) likely make mixed stands of macrophytes preferable in many applications. Additionally, this study demonstrated the importance of urban wetlands as scientific laboratories for scientists of all ages and as excellent stepping-off points for experiments of science-policy discourse.
ContributorsWeller, Nicholas Anton (Author) / Daniel L., Childers (Thesis director) / Grimm, Nancy (Committee member) / Turnbull, Laura (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of Public Affairs (Contributor) / Graduate College (Contributor)
Created2013-05
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Description
Duckponics is an unconventional form of aquaponics that has recently been implemented by a small community in Washington State as an experiment in sustainable methods of food production. The community created the Duckponics system to test the possibility of using the waste of ducks present on the farm to fertilize

Duckponics is an unconventional form of aquaponics that has recently been implemented by a small community in Washington State as an experiment in sustainable methods of food production. The community created the Duckponics system to test the possibility of using the waste of ducks present on the farm to fertilize crop plants. This research paper examines aspects of the nitrogen cycle within this system to determine the efficacy of nitrogen removal by plants and microbes. More specifically, the research examines (1) the microbial activity occurring in selected beds of the system, (2) the ability of hydroponic grow beds to retain inorganic nitrogen, and (3) how periodic flushing of the system affects nitrogen retention. Water data was collected in all system tanks using aquarium test strips, but water samples were collected for flow injection analysis in (1) one of the grow beds, (2) the duck pond, and (3) a control bed with no plants but filled with gravel and inoculated with the same bacteria from the grow bed. Samples were then analyzed for ammonia (NH4+-N) and combined nitrite and nitrate (NOx-N) concentrations. The results show that the treatment type (control, duck pond, or grow bed) was a significant (p<0.05) predictor of NH4+-N, NOx-N, and total inorganic nitrogen (TIN) in the porewater of the treatment beds. The grow bed was found to have 100% removal of TIN, whereas the control had 0% TIN removal (195% increase). Timing of the sample in relation to the flushing events was a moderately significant predictor of TIN, NH4+-N and NOx-N in the duck pond (p = 0.07 for TIN, p = 0.12 for NH4+-N, p = 0.11 for NOx-N), with an overall decrease in TIN after flood pulses. NH4+-N concentrations at the inlet and outlet were found to be significantly different in the grow bed (p=0.037), but not the control, and moderately significantly different (p<0.15) for NOx-N and TIN in the grow bed (p=0.072 for NOx-N, p=0.075 for TIN), but significant for the control (p=0.043). These findings show evidence of nitrification in the grow bed and control, plant presence significantly contributing to nitrogen removal in the grow bed, and some hydrologic flushing of NOx-N out of the duck pond during pump cycles.
ContributorsPanfil, Daniela Kristiina (Author) / Doucette, Sonya (Thesis director) / Palta, Monica (Committee member) / Moody, Jack (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / School of Sustainability (Contributor) / W. P. Carey School of Business (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description

This project was inspired by Dr. Kelli L. Larson’s research which disproved three common landscaping misconceptions in the Phoenix Valley. The first misconception states that newcomers, not long-time Phoenicians more often have and prefer grassy lawns instead of xeric, desert-adapted landscapes when actually the opposite is true. Secondly, the rise

This project was inspired by Dr. Kelli L. Larson’s research which disproved three common landscaping misconceptions in the Phoenix Valley. The first misconception states that newcomers, not long-time Phoenicians more often have and prefer grassy lawns instead of xeric, desert-adapted landscapes when actually the opposite is true. Secondly, the rise in xeric landscapes is not due to personal choice but rather a variety of other factors such as developer decisions. Finally, Dr. Larson’s research also disproves the assumption that people who possess pro-environmental attitudes correspondingly demonstrate sustainable landscaping behavior, and finds that people with those attitudes actually tend to irrigate more frequently in the winter months. Debunking these misconceptions is important because the long-term impacts of global climate change could have effects on water use in the desert southwest, and promoting water conservation in urban residential landscaping is an important step in the creation of sustainable water use policy. <br/><br/>The goal of my project was to make this information more accessible to broader public audiences who may not have access to it outside of research circles. I decided to create a zine, a small batch, hand-made mini-magazine, centered around disproving these myths so that the information could be distributed to broader audiences. I conducted informal stakeholder interviews to inform my design in order to appeal to those audiences, and constructed a 16-page booklet which debunked the myths and encouraged critical thinking about individual water use and urban landscaping habits. The zine included hand-painted illustrations and was constructed as a physical copy with the intention of eventually copying and distributing both a physical and digital version. The purpose of this project is to create a way of accessing reliable information about urban landscaping for residents of the Phoenix Valley, where the climate and geography necessitate water conservation.

ContributorsThompson, Camryn Elizabeth (Author) / Larson, Kelli L. (Thesis director) / Foushée, Danielle (Committee member) / School of Sustainability (Contributor) / The Design School (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
Description

There are unfortunately very few curricular guides that focus on community engagement within the higher education of landscape architecture. A Beginner’s Guide to Community Engagement in the Curriculum of Landscape Architecture and Urban Planning to Improve Social Justice and Sustainability helps resolve this issue and serves as a resource to

There are unfortunately very few curricular guides that focus on community engagement within the higher education of landscape architecture. A Beginner’s Guide to Community Engagement in the Curriculum of Landscape Architecture and Urban Planning to Improve Social Justice and Sustainability helps resolve this issue and serves as a resource to students, educators, designers, and more. The guide centralizes a diverse collection of resources, guides students through learning materials, shares insight, and proposes potential community engagement methods. The booklet aims to help readers understand the importance of community engagement in design and shares different curricular approaches to introduce the work to students.

ContributorsNeeson, Margaret (Author) / Cheng, Chingwen (Thesis director) / Coseo, Paul (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / The Design School (Contributor)
Created2023-05