Matching Items (5)
Filtering by
- Creators: School of Sustainability
- Creators: Cook, Edward
- Status: Published
Description
Increasing concentrations of carbon dioxide in the atmosphere will inevitably lead to long-term changes in climate that can have serious consequences. Controlling anthropogenic emission of carbon dioxide into the atmosphere, however, represents a significant technological challenge. Various chemical approaches have been suggested, perhaps the most promising of these is based on electrochemical trapping of carbon dioxide using pyridine and derivatives. Optimization of this process requires a detailed understanding of the mechanisms of the reactions of reduced pyridines with carbon dioxide, which are not currently well known. This thesis describes a detailed mechanistic study of the nucleophilic and Bronsted basic properties of the radical anion of bipyridine as a model pyridine derivative, formed by one-electron reduction, with particular emphasis on the reactions with carbon dioxide. A time-resolved spectroscopic method was used to characterize the key intermediates and determine the kinetics of the reactions of the radical anion and its protonated radical form. Using a pulsed nanosecond laser, the bipyridine radical anion could be generated in-situ in less than 100 ns, which allows fast reactions to be monitored in real time. The bipyridine radical anion was found to be a very powerful one-electron donor, Bronsted base and nucleophile. It reacts by addition to the C=O bonds of ketones with a bimolecular rate constant around 1* 107 M-1 s-1. These are among the fastest nucleophilic additions that have been reported in literature. Temperature dependence studies demonstrate very low activation energies and large Arrhenius pre-exponential parameters, consistent with very high reactivity. The kinetics of E2 elimination, where the radical anion acts as a base, and SN2 substitution, where the radical anion acts as a nucleophile, are also characterized by large bimolecular rate constants in the range ca. 106 - 107 M-1 s-1. The pKa of the bipyridine radical anion was measured using a kinetic method and analysis of the data using a Marcus theory model for proton transfer. The bipyridine radical anion is found to have a pKa of 40±5 in DMSO. The reorganization energy for the proton transfer reaction was found to be 70±5 kJ/mol. The bipyridine radical anion was found to react very rapidly with carbon dioxide, with a bimolecular rate constant of 1* 108 M-1 s-1 and a small activation energy, whereas the protonated radical reacted with carbon dioxide with a rate constant that was too small to measure. The kinetic and thermodynamic data obtained in this work can be used to understand the mechanisms of the reactions of pyridines with carbon dioxide under reducing conditions.
ContributorsRanjan, Rajeev (Author) / Gould, Ian R (Thesis advisor) / Buttry, Daniel A (Thesis advisor) / Yarger, Jeff (Committee member) / Seo, Dong-Kyun (Committee member) / Arizona State University (Publisher)
Created2015
ContributorsKealoha, Alisia (Author) / Adamson, Joni (Thesis director) / Arcusa, Stéphanie (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor)
Created2024-05
ContributorsKealoha, Alisia (Author) / Adamson, Joni (Thesis director) / Arcusa, Stéphanie (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor)
Created2024-05
Description
Currently, many countries are working towards transitioning into cleaner energy to meet the Sustainable Development Goals set forth by the United Nations to be met by 2050. Moving to cleaner energy resources, enforcing carbon taxes, and cap and trade programs are all examples of carbon avoidance. Carbon removal is used to describe something that removes the carbon already existing in the atmosphere. While most countries are making decisions that would support carbon avoidance, many scientists claim it will take more than making the transition to clean energy and that something needs to be done about the carbon in the air currently. This project will look towards researching the two methods and working to inform people about carbon removal since many people do not even know what this term means, let alone have heard of it before. To this end, I interviewed one of the lead scientists and engineers on the Mechanical Tree, ASU’s Center for Negative Carbon Emissions prototype that will hopefully champion the carbon removal movement. I created podcasts, conducted student surveys, and made an informative video on this subject to raise more awareness of the difference between carbon removal and carbon avoidance. I also researched carbon avoidance to see for myself whether or not carbon removal is necessary. I concluded by the end of this project that carbon removal and carbon avoidance are both necessary components in order to reach net zero by the mid century.
ContributorsKealoha, Alisia (Author) / Adamson, Joni (Thesis director) / Arcusa, Stéphanie (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor)
Created2024-05
Description
Despite public demand for climate change mitigation and natural open space conservancy, existing political and design efforts are only beginning to address the declining efficacy of the biotic carbon pool (C-pool) to sequester carbon. Advances in understanding of biogeochemical processes have provided methods for estimating carbon embodied in natural open spaces and enhancing carbon sequestration efficacy. In this study, the benefits of carbon embodied in dryland open spaces are determined by estimating carbon flux and analyzing ecological, social, and economic benefits provided by sequestered carbon. Understanding the ecological processes and derived benefits of carbon exchange in dryland open spaces will provide insight into enhancing carbon sequestration efficacy. Open space carbon is estimated by calculating the amount of carbon sequestration (estimated in Mg C / ha / y) in dryland open space C-pools. Carbon sequestration in dryland open spaces can be summarized in five open space typologies: hydric, mesic, aridic, biomass for energy agriculture, and traditional agriculture. Hydric (wetland) systems receive a significant amount of moisture; mesic (riparian) systems receive a moderate amount of moisture; and aridic (dry) systems receive low amounts of moisture. Biomass for energy production (perennial biomass) and traditional agriculture (annual / traditional biomass) can be more effective carbon sinks if managed appropriately. Impacts of design interventions to the carbon capacity of dryland open space systems are calculated by estimating carbon exchange in existing open space (base case) compared to projections of carbon sequestered in a modified system (prototype design). A demonstration project at the Lower San Pedro River Watershed highlights the potential for enhancing carbon sequestration. The site-scale demonstration project takes into account a number of limiting factors and opportunities including: availability of water and ability to manipulate its course, existing and potential vegetation, soil types and use of carbon additives, and land-use (particularly agriculture). Specific design challenges to overcome included: restoring perennial water to the Lower San Pedro River, reestablishing hydric and mesic systems, linking fragmented vegetation, and establishing agricultural systems that provide economic opportunities and act as carbon sinks. The prototype design showed enhancing carbon sequestration efficacy by 128-133% is possible with conservative design interventions.
ContributorsHuck, Erick (Author) / Cook, Edward (Thesis advisor) / Green, Douglas (Committee member) / Brooks, Kenneth (Committee member) / Montemayor, Gabriel (Committee member) / Arizona State University (Publisher)
Created2012