Urea is an added value chemical with wide applications in the industry and agriculture. The release of urea waste to the environment affects ecosystem health despite its low toxicity. Online monitoring of urea for industrial applications and environmental health is an unaddressed challenge. Electroanalytical techniques can be a smart integrated solution for online monitoring if sensors can overcome the major barrier associated with long-term stability. Mixed metal oxides have shown excellent stability in environmental conditions with long lasting operational lives. However, these materials have been barely explored for sensing applications. This work presents a proof of concept that demonstrates the applicability of an indirect electroanalytical quantification method of urea. The use of Ti/RuO2-TiO2-SnO2 dimensional stable anode (DSA®) can provide accurate and sensitive quantification of urea in aqueous samples exploiting the excellent catalytic properties of DSA® on the electrogeneration of active chlorine species. The cathodic reduction of accumulated HClO/ClO− from anodic electrogeneration presented a direct relationship with urea concentration. This novel method can allow urea quantification with a competitive LOD of 1.83 × 10−6 mol L−1 within a linear range of 6.66 × 10−6 to 3.33 × 10−4 mol L−1 of urea concentration.

In the Southwestern United States, climate change poses challenges to reliable water access due to droughts, wildfires, and urban development. Arizonan farmers are faced with unpredictable precipitation, muddled legal water rights, and outdated equipment to irrigate their land. Located in Northern Arizona, Verde Valley residents and stakeholders are challenging the way the Verde River water is managed through collaboration, partnerships, and technical changes to water infrastructure. Through interviews conducted with various stakeholders involved in the Verde River ditch irrigation system, ranging from water users to nonprofit organizations, this paper identifies sociotechnical tinkering as an important aspect of maintaining agricultural operations along the river amid political tensions, social relations, and climate change. Through interviews and analysis, this paper further contributes to the relatively new discourse on the concept of sociotechnical tinkering by proving its existence and its subsequent effectiveness in the Verde Valley. Using statements made by respondents, the paper argues that sociotechnical tinkering helps manage resources through political and social relations.