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Population growth within drylands is occurring faster than growth in any other ecologic zone, putting pressure on already stressed water resources. Because the availability of surface water supplies in drylands tends to be highly variable, many of these populations rely on groundwater. A critical process contributing to groundwater recharge is

Population growth within drylands is occurring faster than growth in any other ecologic zone, putting pressure on already stressed water resources. Because the availability of surface water supplies in drylands tends to be highly variable, many of these populations rely on groundwater. A critical process contributing to groundwater recharge is the interaction between ephemeral channels and groundwater aquifers. Generally, it has been found that ephemeral channels contribute to groundwater recharge when streamflow infiltrates into the sandy bottoms of channels. This process has traditionally been studied in channels that drain large areas (10s to 100s km2). In this dissertation, I study the interactions between surface water and groundwater via ephemeral channels in a first-order watershed located on an arid piedmont slope within the Jornada Experimental Range (JER) in the Chihuahuan Desert. To achieve this, I utilize a combination of high-resolution observations and computer simulations using a modified hydrologic model to quantify groundwater recharge and shed light on the geomorphic and ecologic processes that affect the rate of recharge. Observational results indicate that runoff generated within the piedmont slope contributes significantly to deep percolation. During the short-term (6 yr) study period, we estimated 385 mm of total percolation, 62 mm/year, or a ratio of percolation to rainfall of 0.25. Based on the instrument network, we identified that percolation occurs inside channel areas when these receive overland sheetflow from hillslopes. By utilizing a modified version of the hydrologic model, TIN-based Real-time Integrated Basin Simulator (tRIBS), that was calibrated and validated using the observational dataset, I quantified the effects of changing watershed properties on groundwater recharge. Distributed model simulations quantify how deep percolation is produced during the streamflow generation process, and indicate that it plays a significant role in moderating the production of streamflow. Sensitivity analyses reveal that hillslope properties control the amount of rainfall necessary to initiate percolation while channel properties control the partitioning of hillslope runoff into streamflow and deep percolation. Synthetic vegetation experiments show that woody plant encroachment leads to increases in both deep percolation and streamflow. Further woody plant encroachment may result in the unexpected enhancement of dryland aquifer sustainability.
ContributorsSchreiner-McGraw, Adam P (Author) / Vivoni, Enrique R. (Thesis advisor) / Whipple, Kelin X. (Committee member) / Mascaro, Giuseppe (Committee member) / Throop, Heather L. (Committee member) / Sala, Osvaldo E. (Committee member) / Arizona State University (Publisher)
Created2017
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Description
The Colorado River Basin (CRB) is the primary source of water in the

southwestern United States. A key step to reduce the uncertainty of future streamflow

projections in the CRB is to evaluate the performance of historical simulations of General

Circulation Models (GCMs). In this study, this challenge is addressed by evaluating the

ability

The Colorado River Basin (CRB) is the primary source of water in the

southwestern United States. A key step to reduce the uncertainty of future streamflow

projections in the CRB is to evaluate the performance of historical simulations of General

Circulation Models (GCMs). In this study, this challenge is addressed by evaluating the

ability of nineteen GCMs from the Coupled Model Intercomparison Project Phase Five

(CMIP5) and four nested Regional Climate Models (RCMs) in reproducing the statistical

properties of the hydrologic cycle and temperature in the CRB. To capture the transition

from snow-dominated to semiarid regions, analyses are conducted by spatially averaging

the climate variables in four nested sub-basins. Most models overestimate the mean

annual precipitation (P) and underestimate the mean annual temperature (T) at all

locations. While a group of models capture the mean annual runoff at all sub-basins with

different strengths of the hydrological cycle, another set of models overestimate the mean

annual runoff, due to a weak cycle in the evaporation channel. An abrupt increase in the

mean annual T in observed and most of the simulated time series (~0.8 °C) is detected at

all locations despite the lack of any statistically significant monotonic trends for both P

and T. While all models simulate the seasonality of T quite well, the phasing of the

seasonal cycle of P is fairly reproduced in just the upper, snow-dominated sub-basin.

Model performances degrade in the larger sub-basins that include semiarid areas, because

several GCMs are not able to capture the effect of the North American monsoon. Finally,

the relative performances of the climate models in reproducing the climatologies of P and

T are quantified to support future impact studies in the basin.
ContributorsGautam, Jenita (Author) / Mascaro, Giuseppe (Thesis advisor) / Vivoni, Enrique (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2018
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Description
This dissertation focuses on the application of urban metabolism metrology (UMM) to process streams of the natural and built water environment to gauge public health concerning exposure to carcinogenic N-nitrosamines and abuse of narcotics. A survey of sources of exposure to N-nitrosamines in the U.S. population identified contaminated food products

This dissertation focuses on the application of urban metabolism metrology (UMM) to process streams of the natural and built water environment to gauge public health concerning exposure to carcinogenic N-nitrosamines and abuse of narcotics. A survey of sources of exposure to N-nitrosamines in the U.S. population identified contaminated food products (1,900 ± 380 ng/day) as important drivers of attributable cancer risk (Chapter 2). Freshwater sediments in the proximity of U.S. municipal wastewater treatment plants were shown for the first time to harbor carcinogenic N-nitrosamine congeners, including N-nitrosodibutylamine (0.2-3.3 ng/g dw), N-nitrosodiphenylamine (0.2-4.7 ng/g dw), and N-nitrosopyrrolidine (3.4-19.6 ng/g dw) were, with treated wastewater discharge representing one potential factor contributing to the observed contamination (p=0.42) (Chapter 3). Opioid abuse rates in two small midwestern communities were estimated through the application of wastewater-based epidemiology (WBE). Average concentrations of opioids (City 1; City 2) were highest for morphine (713 ± 38, 306 ± 29 ng/L) and varied by for the remainder of the screened analytes. Furthermore, concentrations of the powerful opioid fentanyl (1.7 ± 0.2, 1.0 ± 0.5 ng/L) in wastewater were reported for the first time in the literature for the U.S. (Chapter 4). To gauge narcotic consumption within college-aged adults the WBE process used in Chapter 4 was applied to wastewater collected from a large university in the Southwestern U.S. Estimated narcotics consumption, in units of mg/day/1,000 persons showed the following rank order: cocaine (470 ± 42), heroin (474 ± 32), amphetamine (302 ± 14) and methylphenidate (236 ± 28). Most parental drugs and their respective metabolites showed detection frequencies in campus wastewater of 80% or more, with the notable exception of fentanyl, norfentanyl, buprenorphine, and norbuprenorphine. Estimated consumption of all narcotics, aside from attention-deficit/hyperactivity disorder medication, were higher than values reported in previous U.S. WBE studies for U.S. campuses (Chapter 5). The analyses presented here have identified variation in narcotic consumption habits across different U.S. communities, which can be gauged through UMM. Application of these techniques should be implemented throughout U.S. communities to provide insight into ongoing substance abuse and health issues within a community.
ContributorsGushgari, Adam Jon (Author) / Halden, Rolf U. (Thesis advisor) / Kavazanjian, Edward (Committee member) / Fraser, Matthew (Committee member) / Venkatesan, Arjun (Committee member) / Mascaro, Giuseppe (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Soil moisture (θ) is a fundamental variable controlling the exchange of water and energy at the land surface. As a result, the characterization of the statistical properties of θ across multiple scales is essential for many applications including flood prediction, drought monitoring, and weather forecasting. Empirical evidences have demonstrated the

Soil moisture (θ) is a fundamental variable controlling the exchange of water and energy at the land surface. As a result, the characterization of the statistical properties of θ across multiple scales is essential for many applications including flood prediction, drought monitoring, and weather forecasting. Empirical evidences have demonstrated the existence of emergent relationships and scale invariance properties in θ fields collected from the ground and airborne sensors during intensive field campaigns, mostly in natural landscapes. This dissertation advances the characterization of these relations and statistical properties of θ by (1) analyzing the role of irrigation, and (2) investigating how these properties change in time and across different landscape conditions through θ outputs of a distributed hydrologic model. First, θ observations from two field campaigns in Australia are used to explore how the presence of irrigated fields modifies the spatial distribution of θ and the associated scale invariance properties. Results reveal that the impact of irrigation is larger in drier regions or conditions, where irrigation creates a drastic contrast with the surrounding areas. Second, a physically-based distributed hydrologic model is applied in a regional basin in northern Mexico to generate hyperresolution θ fields, which are useful to conduct analyses in regions and times where θ has not been monitored. For this aim, strategies are proposed to address data, model validation, and computational challenges associated with hyperresolution hydrologic simulations. Third, analyses are carried out to investigate whether the hyperresolution simulated θ fields reproduce the statistical and scaling properties observed from the ground or remote sensors. Results confirm that (i) the relations between spatial mean and standard deviation of θ derived from the model outputs are very similar to those observed in other areas, and (ii) simulated θ fields exhibit the scale invariance properties that are consistent with those analyzed from aircraft-derived estimates. The simulated θ fields are then used to explore the influence of physical controls on the statistical properties, finding that soil properties significantly affect spatial variability and multifractality. The knowledge acquired through this dissertation provides insights on θ statistical properties in regions and landscape conditions that were never investigated before; supports the refinement of the calibration of multifractal downscaling models; and contributes to the improvement of hyperresolution hydrologic modeling.
ContributorsKo, Ara (Author) / Mascaro, Giuseppe (Thesis advisor) / Vivoni, Enrique R. (Thesis advisor) / Myint, Soe (Committee member) / Wang, Zhihua (Committee member) / Muenich, Rebecca (Committee member) / Arizona State University (Publisher)
Created2018
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Description
This dissertation critically evaluated methodologies and devices for assessing and protecting the health of human populations, with particular emphasis on groundwater remediation and the use of wastewater-based epidemiology (WBE) to inform population health. A meta-analysis and assessment of laboratory-scale treatability studies for removing chlorinated solvents from groundwater found that sediment

This dissertation critically evaluated methodologies and devices for assessing and protecting the health of human populations, with particular emphasis on groundwater remediation and the use of wastewater-based epidemiology (WBE) to inform population health. A meta-analysis and assessment of laboratory-scale treatability studies for removing chlorinated solvents from groundwater found that sediment microcosms operated as continuous-flow columns are preferable to batch bottles when seeking to emulate with high fidelity the complex conditions prevailing in the subsurface in contaminated aquifers (Chapter 2). Compared to monitoring at the field-scale, use of column microcosms also showed (i) improved chemical speciation, and (ii) qualitative predictability of field parameters (Chapter 3). Monitoring of glucocorticoid hormones in wastewater of a university campus showed (i) elevated stress levels particularly at the start of the semester, (ii) on weekdays relative to weekend days (p = 0.05) (161 ± 42 μg d-1 per person, 122 ± 54 μg d-1 per person; p ≤ 0.05), and (iii) a positive association between levels of stress hormones and nicotine (rs: 0.49) and caffeine (0.63) consumption in this student population (Chapter 4). Also, (i) alcohol consumption determined by WBE was in line with literature estimates for this young sub-population (11.3 ± 7.5 g d-1 per person vs. 10.1 ± 0.8 g d-1 per person), whereas caffeine and nicotine uses were below (114 ± 49 g d-1 per person, 178 ± 19 g d-1 per person; 627 ± 219 g d-1 per person, 927 ± 243 g d-1 per person). The introduction of a novel continuous in situ sampler to WBE brought noted benefits relative to traditional time-integrated sampling, including (i) a higher sample coverage (93% vs. 3%), (ii) an ability to captured short-term analyte pulses (e.g., heroin, fentanyl, norbuprenorphine, and methadone), and (iii) an overall higher mass capture for drugs of abuse like morphine, fentanyl, methamphetamine, amphetamine, and the opioid antagonist metabolite norbuprenorphine (p ≤ 0.01). Methods and devices developed in this work are poised to find applications in the remediation sector and in human health assessments.
ContributorsDriver, Erin Michelle (Author) / Halden, Rolf (Thesis advisor) / Conroy-Ben, Otakuye (Committee member) / Kavazanjian, Edward (Committee member) / Krajmalnik-Brown, Rosa (Committee member) / Arizona State University (Publisher)
Created2018
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Description
This dissertation details an attempt to experimentally evaluate the Giroud et al. (1995) concentration factors for geomembranes loaded in tension perpendicular to a seam by laboratory measurement. Field observations of the performance of geomembrane liner systems indicates that tears occur at average strains well below the yield criteria. These observations

This dissertation details an attempt to experimentally evaluate the Giroud et al. (1995) concentration factors for geomembranes loaded in tension perpendicular to a seam by laboratory measurement. Field observations of the performance of geomembrane liner systems indicates that tears occur at average strains well below the yield criteria. These observations have been attributed, in part, to localized strain concentrations in the geomembrane loaded in tension in a direction perpendicular to the seam. Giroud et al. (1995) has presented theoretical strain concentration factors for geomembrane seams loaded in tension when the seam is perpendicular to the applied tensile strain. However, these factors have never been verified. This dissertation was prepared in fulfillment of the requirements for graduation from Barrett, the Honors College at Arizona State University. The work described herein was sponsored by the National Science Foundation as a part of a larger research project entitled "NEESR: Performance Based Design of Geomembrane Liner Systems Subject to Extreme Loading." The work is motivated by geomembrane tears observed at the Chiquita Canyon landfill following the 1994 Northridge earthquake. Numerical analysis of the strains in the Chiquita Canyon landfill liner induced by the earthquake indicated that the tensile strains, were well below the yield strain of the geomembrane material. In order to explain why the membrane did fail, strain concentration factors due to bending at seams perpendicular to the load in the model proposed by Giroud et al. (1995) had to be applied to the geomembrane (Arab, 2011). Due to the localized nature of seam strain concentrations, digital image correlation (DIC) was used. The high resolution attained with DIC had a sufficient resolution to capture the localized strain concentrations. High density polyethylene (HDPE) geomembrane samples prepared by a leading geomembrane manufacturer were used in the testing described herein. The samples included both extrusion fillet and dual hot wedge fusion seams. The samples were loaded in tension in a standard triaxial test apparatus. to the seams in the samples including both extrusion fillet and dual hot wedge seams. DIC was used to capture the deformation field and strain fields were subsequently created by computer analysis.
ContributorsAndresen, Jake Austin (Author) / Kavazanjian, Edward (Thesis director) / Gutierrez, Angel (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
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Description
Land surface fluxes of energy and mass developed over heterogeneous mountain landscapes are fundamental to atmospheric processes. However, due to their high complexity and the lack of spatial observations, land surface processes and land-atmosphere interactions are not fully understood in mountain regions. This thesis investigates land surface processes and their

Land surface fluxes of energy and mass developed over heterogeneous mountain landscapes are fundamental to atmospheric processes. However, due to their high complexity and the lack of spatial observations, land surface processes and land-atmosphere interactions are not fully understood in mountain regions. This thesis investigates land surface processes and their impact on convective precipitation by conducting numerical modeling experiments at multiple scales over the North American Monsoon (NAM) region. Specifically, the following scientific questions are addressed: (1) how do land surface conditions evolve during the monsoon season, and what are their main controls?, (2) how do the diurnal cycles of surface energy fluxes vary during the monsoon season for the major ecosystems?, and (3) what are the impacts of surface soil moisture and vegetation condition on convective precipitation?

Hydrologic simulation using the TIN-based Real-time Integrated Basin Simulator (tRIBS) is firstly carried out to examine the seasonal evolution of land surface conditions. Results reveal that the spatial heterogeneity of land surface temperature and soil moisture increases dramatically with the onset of monsoon, which is related to seasonal changes in topographic and vegetation controls. Similar results are found at regional basin scale using the uncoupled WRF-Hydro model. Meanwhile, the diurnal cycles of surface energy fluxes show large variation between the major ecosystems. Differences in both the peak magnitude and peak timing of plant transpiration induce mesoscale heterogeneity in land surface conditions. Lastly, this dissertation examines the upscale effect of land surface heterogeneity on atmospheric condition through fully-coupled WRF-Hydro simulations. A series of process-based experiments were conducted to identify the pathways of soil moisture-rainfall feedback mechanism over the NAM region. While modeling experiments confirm the existence of positive soil moisture/vegetation-rainfall feedback, their exact pathways are slightly different. Interactions between soil moisture, vegetation cover, and rainfall through a series of land surface and atmospheric boundary layer processes highlight the strong land-atmosphere coupling in the NAM region, and have important implications on convective rainfall prediction. Overall, this dissertation advances the study of complex land surface processes over the NAM region, and made important contributions in linking complex hydrologic, ecologic and atmospheric processes through numerical modeling.
ContributorsXiang, Tiantian (Author) / Vivoni, Enrique R (Thesis advisor) / Gochis, David J (Committee member) / Huang, Huei-Ping (Committee member) / Mascaro, Giuseppe (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Rapid urbanization and population growth occurring in the cities of South Western

United States have led to significant modifications in its environment at local and

regional scales. Both local and regional climate changes are expected to have massive

impacts on the hydrology of Colorado River Basin (CRB), thereby accentuating the need

of study of

Rapid urbanization and population growth occurring in the cities of South Western

United States have led to significant modifications in its environment at local and

regional scales. Both local and regional climate changes are expected to have massive

impacts on the hydrology of Colorado River Basin (CRB), thereby accentuating the need

of study of hydro-climatic impacts on water resource management in this region. This

thesis is devoted to understanding the impact of land use and land cover (LULC) changes

on the local and regional hydroclimate, with the goal to address urban planning issues

and provide guidance for sustainable development.

In this study, three densely populated urban areas, viz. Phoenix, Las Vegas and

Denver in the CRB are selected to capture the various dimensions of the impacts of land

use changes on the regional hydroclimate in the entire CRB. Weather Research and

Forecast (WRF) model, incorporating the latest urban modeling system, is adopted for

regional climate modeling. Two major types of urban LULC changes are studied in this

Thesis: (1) incorporation of urban trees with their radiative cooling effect, tested in

Phoenix metropolitan, and (2) projected urban expansion in 2100 obtained from

Integrated Climate and Land Use Scenarios (ICLUS) developed by the US

Environmental Protection Agency for all three cities.

The results demonstrated prominent nocturnal cooling effect of due to radiative

shading effect of the urban trees for Phoenix reducing urban surface and air temperature

by about 2~9 °C and 1~5 °C respectively and increasing relative humidity by 10~20%

during an mean diurnal cycle. The simulations of urban growth in CRB demonstratedii

nocturnal warming of about 0.36 °C, 1.07 °C, and 0.94 °C 2m-air temperature and

comparatively insignificant change in daytime temperature, with the thermal environment

of Denver being the most sensitive the urban growth. The urban hydroclimatic study

carried out in the thesis assists in identifying both context specific and generalizable

relationships, patterns among the cities, and is expected to facilitate urban planning and

management in local (cities) and regional scales.
ContributorsUpreti, Ruby (Author) / Wang, Zhihua (Thesis advisor) / Vivoni, Enrique R. (Committee member) / Mascaro, Giuseppe (Committee member) / White, Dave (Committee member) / Arizona State University (Publisher)
Created2017
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Description
The hydrologic cycle in drylands is complex with large spatiotemporal variationsacross scales and is particularly vulnerable to changes in climate and land cover. To address the challenges posed by hydrologic changes, a synergistic approach that combines numerical models, ground and remotely sensed observations, and data analysis is crucial. This dissertation uses innovative detection

The hydrologic cycle in drylands is complex with large spatiotemporal variationsacross scales and is particularly vulnerable to changes in climate and land cover. To address the challenges posed by hydrologic changes, a synergistic approach that combines numerical models, ground and remotely sensed observations, and data analysis is crucial. This dissertation uses innovative detection and modeling techniques to assess key hydrologic variables in drylands, including irrigated water use, streamflow, and snowpack conditions, answering following research questions that also have broad societal implications: (1) What are the individual and combined effects of future climate and land use change on irrigation water use (IWU) in the Phoenix Metropolitan Area (PMA)?; (2) How can temporal changes in streamflow and the impacts of flash flooding be detected in dryland rivers?; and (3) What are the impacts of rainfall-snow partitioning on future snowpack and streamflow in the Colorado River Basin (CRB)? Firstly, I conducted a scenario modeling using the Variable Infiltration Capacity (VIC) model under future climate and land use change scenarios. Results showed that future IWU will change from -0.5% to +6.8% in the far future (2071-2100) relative to the historical period (1981-2010). Secondly, I employed CubeSat imagery to map streamflow presence in the Hassayampa River of Arizona, finding that the imaging capacity of CubeSats enabled the detection of ephemeral flow events using the surface reflectance of the near-infrared (NIR) band. Results showed that 12% of reaches were classified as intermittent, with the remaining as ephemeral. Finally, I implemented a physically-based rainfall-snow partitioning scheme in the VIC model that estimates snowfall fraction from the wet-bulb temperature using a sigmoid function. The new scheme predicts more significant declines in snowfall (-8 to -11%) and streamflow (-14 to -27%) by the end of the 21st century over the CRB, relative to historical conditions. Overall, this dissertation demonstrates how innovative technologies can enhance the understanding of dryland hydrologic changes and inform decision-making of water resources management. The findings offer important insights for policymakers, water managers, and researchers who seek to ensure water resources sustainability under the effects of climate and land use change.
ContributorsWang, Zhaocheng (Author) / Vivoni, Enrique R (Thesis advisor) / White, Dave D (Committee member) / Mascaro, Giuseppe (Committee member) / Huang, Huei-Ping (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Accelerated climate and land use land cover (LULC) changes are anticipated to significantly impact water resources in the Colorado River Basin (CRB), a major freshwater source in the southwestern U.S. The need for actionable information from hydrologic research is growing rapidly, given considerable uncertainties. For instance, it is unclear if

Accelerated climate and land use land cover (LULC) changes are anticipated to significantly impact water resources in the Colorado River Basin (CRB), a major freshwater source in the southwestern U.S. The need for actionable information from hydrologic research is growing rapidly, given considerable uncertainties. For instance, it is unclear if the predicted high degree of interannual precipitation variability across the basin could overwhelm the impacts of future warming and how this might vary in space. Climate change will also intensify forest disturbances (wildfire, mortality, thinning), which can significantly impact water resources. These impacts are not constrained, given findings of mixed post-disturbance hydrologic responses. Process-based models like the Variable Infiltration Capacity (VIC) platform can quantitatively predict hydrologic behaviors of these complex systems. However, barriers limit their effectiveness to inform decision making: (1) simulations generate enormous data volumes, (2) outputs are inaccessible to managers, and (3) modeling is not transparent. I designed a stakeholder engagement and VIC modeling process to overcome these challenges, and developed a web-based tool, VIC-Explorer, to “open the black box” of my efforts. Meteorological data was from downscaled historical (1950-2005) and future projections (2006-2099) of eight climate models that best represent climatology under low- and high- emissions. I used two modeling methods: (1) a “top-down” approach to assess an “envelope of hydrologic possibility” under the 16 climate futures; and (2) a “bottom-up” evaluation of hydrology in two climates from the ensemble representing “Hot/Dry” and “Warm/Wet” futures. For the latter assessment, I modified land cover using projections of a LULC model and applied more drastic forest disturbances. I consulted water managers to expand the legitimacy of the research. Results showed Far-Future (2066-2095) basin-wide mean annual streamflow decline (relative to 1976-2005; ensemble median trends of -5% to -25%), attributed to warming that diminished spring snowfall and melt and year-round increased soil evaporation from the Upper Basin, and overall precipitation declines in the Lower Basin. Forest disturbances partially offset warming effects (basin-wide mean annual streamflow up to 12% larger than without disturbance). Results are available via VIC-Explorer, which includes documentation and guided analyses to ensure findings are interpreted appropriately for decision-making.
ContributorsWhitney, Kristen Marie (Author) / Vivoni, Enrique R (Thesis advisor) / Mascaro, Giuseppe (Committee member) / Whipple, Kelin X (Committee member) / White, Dave D (Committee member) / Xu, Tianfang (Committee member) / Arizona State University (Publisher)
Created2022