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A study of heating and degradation of acrylonitrile-butadiene-styrene/polycarbonate polymer due to ultraviolet lasers illumination during localized pre-deposition heating for fused filament fabrication 3D printing

Description
With the growing popularity of 3d printing in recreational, research, and commercial enterprises new techniques and processes are being developed to improve the quality of parts created. Even so, the anisotropic properties is still a major hindrance of parts manufactured in this method. The goal is to produce parts that…

With the growing popularity of 3d printing in recreational, research, and commercial enterprises new techniques and processes are being developed to improve the quality of parts created. Even so, the anisotropic properties is still a major hindrance of parts manufactured in this method. The goal is to produce parts that mimic the strength characteristics of a comparable part of the same design and materials created using injection molding. In achieving this goal the production cost can be reduced by eliminating the initial investment needed for the creation of expensive tooling. This initial investment reduction will allow for a wider variant of products in smaller batch runs to be made available. This thesis implements the use of ultraviolet (UV) illumination for an in-process laser local pre-deposition heating (LLPH). By comparing samples with and without the LLPH process it is determined that applied energy that is absorbed by the polymer is converted to an increase in the interlayer temperature, and resulting in an observed increase in tensile strength over the baseline test samples. The increase in interlayer bonding thus can be considered the dominating factor over polymer degradation.
ContributorsKusel, Scott Daniel (Author) / Hsu, Keng (Thesis advisor) / Sodemann, Angela (Committee member) / Kannan, Arunachala M (Committee member) / Arizona State University (Publisher)
Created2017
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Three Essays on Implementing a Sustainable Circular Economy for Plastics

Description
Plastic is a valuable part of the consumer economy, but it creates negative environmental externalities throughout its lifecycle. To reduce these effects, a sustainable circular economy is needed, where more plastic is diverted from landfill or environmental sinks through reduction, reuse, recycling, or composting, while addressing social needs. Although many…

Plastic is a valuable part of the consumer economy, but it creates negative environmental externalities throughout its lifecycle. To reduce these effects, a sustainable circular economy is needed, where more plastic is diverted from landfill or environmental sinks through reduction, reuse, recycling, or composting, while addressing social needs. Although many different stakeholders (industry, academia, policymakers) are calling for a sustainable circular economy for plastics, globally, less than 20% of plastic is recycled with no data on reduction and reuse. In this dissertation, a mixed methods approach is used to suggest how organizations related to the plastic industry can implement a sustainable circular economy. The first chapter identifies how firms across the plastic value chain can innovate to adopt a sustainable circular flow. A systematic review reveals over 300 examples, which are used to create a material flow typology. Findings summarize five critical points of innovation and indicate that innovation adoption is low. More concerted efforts are needed to improve innovation adoption and there is a need to shift innovation focus from resource efficiency to sustainability. The second chapters studies U.S. plastic recyclers’ price signals to generate evidence for favorable recycling policies. A hedonic analysis reveals recyclers preferences for recyclability – plastic properties that enable recycling. Results suggest that adequate recycling infrastructure and absence of virgin plastic can play an important role in facilitating more recycling. In the third paper, the role of governments as consumers is studied. As the largest consumers in a market, governments can signal a large demand for circular products and services, however public administration literature has paid limited attention to it. A theoretical framework is created to fill the knowledge gap and suggest how governments can use sustainable public procurement for a circular economy. A systematic literature review of the top ten public administration journals over 32 years reveals critical knowledge gaps and the potential for important sustainable public procurement research
ContributorsHafsa, Fatima (Author) / Englin, Jeffrey (Thesis advisor) / Abbott, Joshua K (Committee member) / Darnall, Nicole (Committee member) / Dooley, Kevin J (Committee member) / Arizona State University (Publisher)
Created2022
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Depolymerization of Polypropylene Plastic Wastes under Solvothermal Liquefaction Conditions

Description
Polypropylene, a non-biodegradable plastic with a higher c-c bond disassociation energy than other conventional polymers like Polyethylene (PE), is used to manufacture these three-layered masks. The amount of plastic pollution in the environment has grown tremendously, nearing million tons in a short period of time. As a result, the purpose…

Polypropylene, a non-biodegradable plastic with a higher c-c bond disassociation energy than other conventional polymers like Polyethylene (PE), is used to manufacture these three-layered masks. The amount of plastic pollution in the environment has grown tremendously, nearing million tons in a short period of time. As a result, the purpose of this study is to reduce the environmental damage caused by facemasks. This M.S. thesis offers a concise overview of various thermochemical methods employed to depolymerize plastic waste materials. It emphasizes environmentally conscious and sustainable practices, specifically focusing on solvothermal processing. This innovative approach aims to convert discarded face masks into valuable resources, including hydrocarbons suitable for jet fuel and other useful products. The thesis provides an in-depth exploration of experimental investigations into solvothermal liquefaction techniques. Operating under specific conditions, namely, a temperature of 350°C and a reaction duration of 90 minutes, the results were notably impressive. These results included an exceptional conversion rate of 99.8%, an oil yield of 39.3%, and higher heating values (HHV) of 46.81 MJ/kg for the generated oil samples. It's worth noting that the HHV of the oil samples obtained through the solvothermal liquefaction (STL) method, at 46.82 MJ/kg, surpasses the HHV of gasoline, which stands at 43.4 MJ/kg. The significant role of the solvent in the depolymerization process involves the dissolution and dispersion of the feedstock through solvation. This reduces the required thermal cracking temperature by enhancing mass and thermal energy transfer. While solvolysis reactions between the solvent and feedstock are limited in thermal liquefaction, the primary depolymerization process follows thermal cracking. This involves the random scission of polypropylene (PP) molecules during heat treatment, with minimal polymerization, cyclization, and radical recombination reactions occurring through free radical mechanisms. Overall, this work demonstrates the feasibility of a highly promising technique for the effective chemical upcycling of polypropylene-based plastics into valuable resources, particularly in the context of jet fuel hydrocarbons, showcasing the comprehensive analytical methods employed to characterize the products of this innovative process.
ContributorsAkula, kapil Chandra (Author) / Deng, Shuguang (Thesis advisor) / Fini, Elham (Committee member) / Salifu, Emmanuel (Committee member) / Arizona State University (Publisher)
Created2023