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- All Subjects: Hydrologic sciences
- All Subjects: Environmental engineering
- Creators: Mascaro, Giuseppe
- Resource Type: Text
Description
Population growth within drylands is occurring faster than growth in any other ecologic zone, putting pressure on already stressed water resources. Because the availability of surface water supplies in drylands tends to be highly variable, many of these populations rely on groundwater. A critical process contributing to groundwater recharge is the interaction between ephemeral channels and groundwater aquifers. Generally, it has been found that ephemeral channels contribute to groundwater recharge when streamflow infiltrates into the sandy bottoms of channels. This process has traditionally been studied in channels that drain large areas (10s to 100s km2). In this dissertation, I study the interactions between surface water and groundwater via ephemeral channels in a first-order watershed located on an arid piedmont slope within the Jornada Experimental Range (JER) in the Chihuahuan Desert. To achieve this, I utilize a combination of high-resolution observations and computer simulations using a modified hydrologic model to quantify groundwater recharge and shed light on the geomorphic and ecologic processes that affect the rate of recharge. Observational results indicate that runoff generated within the piedmont slope contributes significantly to deep percolation. During the short-term (6 yr) study period, we estimated 385 mm of total percolation, 62 mm/year, or a ratio of percolation to rainfall of 0.25. Based on the instrument network, we identified that percolation occurs inside channel areas when these receive overland sheetflow from hillslopes. By utilizing a modified version of the hydrologic model, TIN-based Real-time Integrated Basin Simulator (tRIBS), that was calibrated and validated using the observational dataset, I quantified the effects of changing watershed properties on groundwater recharge. Distributed model simulations quantify how deep percolation is produced during the streamflow generation process, and indicate that it plays a significant role in moderating the production of streamflow. Sensitivity analyses reveal that hillslope properties control the amount of rainfall necessary to initiate percolation while channel properties control the partitioning of hillslope runoff into streamflow and deep percolation. Synthetic vegetation experiments show that woody plant encroachment leads to increases in both deep percolation and streamflow. Further woody plant encroachment may result in the unexpected enhancement of dryland aquifer sustainability.
ContributorsSchreiner-McGraw, Adam P (Author) / Vivoni, Enrique R. (Thesis advisor) / Whipple, Kelin X. (Committee member) / Mascaro, Giuseppe (Committee member) / Throop, Heather L. (Committee member) / Sala, Osvaldo E. (Committee member) / Arizona State University (Publisher)
Created2017
Description
The Colorado River Basin (CRB) is the primary source of water in the
southwestern United States. A key step to reduce the uncertainty of future streamflow
projections in the CRB is to evaluate the performance of historical simulations of General
Circulation Models (GCMs). In this study, this challenge is addressed by evaluating the
ability of nineteen GCMs from the Coupled Model Intercomparison Project Phase Five
(CMIP5) and four nested Regional Climate Models (RCMs) in reproducing the statistical
properties of the hydrologic cycle and temperature in the CRB. To capture the transition
from snow-dominated to semiarid regions, analyses are conducted by spatially averaging
the climate variables in four nested sub-basins. Most models overestimate the mean
annual precipitation (P) and underestimate the mean annual temperature (T) at all
locations. While a group of models capture the mean annual runoff at all sub-basins with
different strengths of the hydrological cycle, another set of models overestimate the mean
annual runoff, due to a weak cycle in the evaporation channel. An abrupt increase in the
mean annual T in observed and most of the simulated time series (~0.8 °C) is detected at
all locations despite the lack of any statistically significant monotonic trends for both P
and T. While all models simulate the seasonality of T quite well, the phasing of the
seasonal cycle of P is fairly reproduced in just the upper, snow-dominated sub-basin.
Model performances degrade in the larger sub-basins that include semiarid areas, because
several GCMs are not able to capture the effect of the North American monsoon. Finally,
the relative performances of the climate models in reproducing the climatologies of P and
T are quantified to support future impact studies in the basin.
southwestern United States. A key step to reduce the uncertainty of future streamflow
projections in the CRB is to evaluate the performance of historical simulations of General
Circulation Models (GCMs). In this study, this challenge is addressed by evaluating the
ability of nineteen GCMs from the Coupled Model Intercomparison Project Phase Five
(CMIP5) and four nested Regional Climate Models (RCMs) in reproducing the statistical
properties of the hydrologic cycle and temperature in the CRB. To capture the transition
from snow-dominated to semiarid regions, analyses are conducted by spatially averaging
the climate variables in four nested sub-basins. Most models overestimate the mean
annual precipitation (P) and underestimate the mean annual temperature (T) at all
locations. While a group of models capture the mean annual runoff at all sub-basins with
different strengths of the hydrological cycle, another set of models overestimate the mean
annual runoff, due to a weak cycle in the evaporation channel. An abrupt increase in the
mean annual T in observed and most of the simulated time series (~0.8 °C) is detected at
all locations despite the lack of any statistically significant monotonic trends for both P
and T. While all models simulate the seasonality of T quite well, the phasing of the
seasonal cycle of P is fairly reproduced in just the upper, snow-dominated sub-basin.
Model performances degrade in the larger sub-basins that include semiarid areas, because
several GCMs are not able to capture the effect of the North American monsoon. Finally,
the relative performances of the climate models in reproducing the climatologies of P and
T are quantified to support future impact studies in the basin.
ContributorsGautam, Jenita (Author) / Mascaro, Giuseppe (Thesis advisor) / Vivoni, Enrique (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2018
Description
This dissertation focuses on the application of urban metabolism metrology (UMM) to process streams of the natural and built water environment to gauge public health concerning exposure to carcinogenic N-nitrosamines and abuse of narcotics. A survey of sources of exposure to N-nitrosamines in the U.S. population identified contaminated food products (1,900 ± 380 ng/day) as important drivers of attributable cancer risk (Chapter 2). Freshwater sediments in the proximity of U.S. municipal wastewater treatment plants were shown for the first time to harbor carcinogenic N-nitrosamine congeners, including N-nitrosodibutylamine (0.2-3.3 ng/g dw), N-nitrosodiphenylamine (0.2-4.7 ng/g dw), and N-nitrosopyrrolidine (3.4-19.6 ng/g dw) were, with treated wastewater discharge representing one potential factor contributing to the observed contamination (p=0.42) (Chapter 3). Opioid abuse rates in two small midwestern communities were estimated through the application of wastewater-based epidemiology (WBE). Average concentrations of opioids (City 1; City 2) were highest for morphine (713 ± 38, 306 ± 29 ng/L) and varied by for the remainder of the screened analytes. Furthermore, concentrations of the powerful opioid fentanyl (1.7 ± 0.2, 1.0 ± 0.5 ng/L) in wastewater were reported for the first time in the literature for the U.S. (Chapter 4). To gauge narcotic consumption within college-aged adults the WBE process used in Chapter 4 was applied to wastewater collected from a large university in the Southwestern U.S. Estimated narcotics consumption, in units of mg/day/1,000 persons showed the following rank order: cocaine (470 ± 42), heroin (474 ± 32), amphetamine (302 ± 14) and methylphenidate (236 ± 28). Most parental drugs and their respective metabolites showed detection frequencies in campus wastewater of 80% or more, with the notable exception of fentanyl, norfentanyl, buprenorphine, and norbuprenorphine. Estimated consumption of all narcotics, aside from attention-deficit/hyperactivity disorder medication, were higher than values reported in previous U.S. WBE studies for U.S. campuses (Chapter 5). The analyses presented here have identified variation in narcotic consumption habits across different U.S. communities, which can be gauged through UMM. Application of these techniques should be implemented throughout U.S. communities to provide insight into ongoing substance abuse and health issues within a community.
ContributorsGushgari, Adam Jon (Author) / Halden, Rolf U. (Thesis advisor) / Kavazanjian, Edward (Committee member) / Fraser, Matthew (Committee member) / Venkatesan, Arjun (Committee member) / Mascaro, Giuseppe (Committee member) / Arizona State University (Publisher)
Created2018
Description
Soil moisture (θ) is a fundamental variable controlling the exchange of water and energy at the land surface. As a result, the characterization of the statistical properties of θ across multiple scales is essential for many applications including flood prediction, drought monitoring, and weather forecasting. Empirical evidences have demonstrated the existence of emergent relationships and scale invariance properties in θ fields collected from the ground and airborne sensors during intensive field campaigns, mostly in natural landscapes. This dissertation advances the characterization of these relations and statistical properties of θ by (1) analyzing the role of irrigation, and (2) investigating how these properties change in time and across different landscape conditions through θ outputs of a distributed hydrologic model. First, θ observations from two field campaigns in Australia are used to explore how the presence of irrigated fields modifies the spatial distribution of θ and the associated scale invariance properties. Results reveal that the impact of irrigation is larger in drier regions or conditions, where irrigation creates a drastic contrast with the surrounding areas. Second, a physically-based distributed hydrologic model is applied in a regional basin in northern Mexico to generate hyperresolution θ fields, which are useful to conduct analyses in regions and times where θ has not been monitored. For this aim, strategies are proposed to address data, model validation, and computational challenges associated with hyperresolution hydrologic simulations. Third, analyses are carried out to investigate whether the hyperresolution simulated θ fields reproduce the statistical and scaling properties observed from the ground or remote sensors. Results confirm that (i) the relations between spatial mean and standard deviation of θ derived from the model outputs are very similar to those observed in other areas, and (ii) simulated θ fields exhibit the scale invariance properties that are consistent with those analyzed from aircraft-derived estimates. The simulated θ fields are then used to explore the influence of physical controls on the statistical properties, finding that soil properties significantly affect spatial variability and multifractality. The knowledge acquired through this dissertation provides insights on θ statistical properties in regions and landscape conditions that were never investigated before; supports the refinement of the calibration of multifractal downscaling models; and contributes to the improvement of hyperresolution hydrologic modeling.
ContributorsKo, Ara (Author) / Mascaro, Giuseppe (Thesis advisor) / Vivoni, Enrique R. (Thesis advisor) / Myint, Soe (Committee member) / Wang, Zhihua (Committee member) / Muenich, Rebecca (Committee member) / Arizona State University (Publisher)
Created2018
Description
Rapid urban expansion and the associated landscape modifications have led to significant changes of surface processes in built environments. These changes further interact with the overlying atmospheric boundary layer and strongly modulate urban microclimate. To capture the impacts of urban land surface processes on urban boundary layer dynamics, a coupled urban land-atmospheric modeling framework has been developed. The urban land surface is parameterized by an advanced single-layer urban canopy model (SLUCM) with realistic representations of urban green infrastructures such as lawn, tree, and green roof, etc. The urban atmospheric boundary layer is simulated by a single column model (SCM) with both convective and stable schemes. This coupled SLUCM-SCM framework can simulate the time evolution and vertical profile of different meteorological variables such as virtual potential temperature, specific humidity and carbon dioxide concentration. The coupled framework has been calibrated and validated in the metropolitan Phoenix area, Arizona. To quantify the model sensitivity, an advanced stochastic approach based on Markov-Chain Monte Carlo procedure has been applied. It is found that the development of urban boundary layer is highly sensitive to surface characteristics of built terrains, including urban land use, geometry, roughness of momentum, and vegetation fraction. In particular, different types of urban vegetation (mesic/xeric) affect the boundary layer dynamics through different mechanisms. Furthermore, this framework can be implanted into large-scale models such as Weather Research and Forecasting model to assess the impact of urbanization on regional climate.
ContributorsSong, Jiyun (Author) / Wang, Zhihua (Thesis advisor) / Vivoni, Enrique R (Committee member) / Mascaro, Giuseppe (Committee member) / Myint, Soe W (Committee member) / Sailor, David (Committee member) / Arizona State University (Publisher)
Created2016
Description
Land surface fluxes of energy and mass developed over heterogeneous mountain landscapes are fundamental to atmospheric processes. However, due to their high complexity and the lack of spatial observations, land surface processes and land-atmosphere interactions are not fully understood in mountain regions. This thesis investigates land surface processes and their impact on convective precipitation by conducting numerical modeling experiments at multiple scales over the North American Monsoon (NAM) region. Specifically, the following scientific questions are addressed: (1) how do land surface conditions evolve during the monsoon season, and what are their main controls?, (2) how do the diurnal cycles of surface energy fluxes vary during the monsoon season for the major ecosystems?, and (3) what are the impacts of surface soil moisture and vegetation condition on convective precipitation?
Hydrologic simulation using the TIN-based Real-time Integrated Basin Simulator (tRIBS) is firstly carried out to examine the seasonal evolution of land surface conditions. Results reveal that the spatial heterogeneity of land surface temperature and soil moisture increases dramatically with the onset of monsoon, which is related to seasonal changes in topographic and vegetation controls. Similar results are found at regional basin scale using the uncoupled WRF-Hydro model. Meanwhile, the diurnal cycles of surface energy fluxes show large variation between the major ecosystems. Differences in both the peak magnitude and peak timing of plant transpiration induce mesoscale heterogeneity in land surface conditions. Lastly, this dissertation examines the upscale effect of land surface heterogeneity on atmospheric condition through fully-coupled WRF-Hydro simulations. A series of process-based experiments were conducted to identify the pathways of soil moisture-rainfall feedback mechanism over the NAM region. While modeling experiments confirm the existence of positive soil moisture/vegetation-rainfall feedback, their exact pathways are slightly different. Interactions between soil moisture, vegetation cover, and rainfall through a series of land surface and atmospheric boundary layer processes highlight the strong land-atmosphere coupling in the NAM region, and have important implications on convective rainfall prediction. Overall, this dissertation advances the study of complex land surface processes over the NAM region, and made important contributions in linking complex hydrologic, ecologic and atmospheric processes through numerical modeling.
Hydrologic simulation using the TIN-based Real-time Integrated Basin Simulator (tRIBS) is firstly carried out to examine the seasonal evolution of land surface conditions. Results reveal that the spatial heterogeneity of land surface temperature and soil moisture increases dramatically with the onset of monsoon, which is related to seasonal changes in topographic and vegetation controls. Similar results are found at regional basin scale using the uncoupled WRF-Hydro model. Meanwhile, the diurnal cycles of surface energy fluxes show large variation between the major ecosystems. Differences in both the peak magnitude and peak timing of plant transpiration induce mesoscale heterogeneity in land surface conditions. Lastly, this dissertation examines the upscale effect of land surface heterogeneity on atmospheric condition through fully-coupled WRF-Hydro simulations. A series of process-based experiments were conducted to identify the pathways of soil moisture-rainfall feedback mechanism over the NAM region. While modeling experiments confirm the existence of positive soil moisture/vegetation-rainfall feedback, their exact pathways are slightly different. Interactions between soil moisture, vegetation cover, and rainfall through a series of land surface and atmospheric boundary layer processes highlight the strong land-atmosphere coupling in the NAM region, and have important implications on convective rainfall prediction. Overall, this dissertation advances the study of complex land surface processes over the NAM region, and made important contributions in linking complex hydrologic, ecologic and atmospheric processes through numerical modeling.
ContributorsXiang, Tiantian (Author) / Vivoni, Enrique R (Thesis advisor) / Gochis, David J (Committee member) / Huang, Huei-Ping (Committee member) / Mascaro, Giuseppe (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2016
Description
Urbanization and woody plant encroachment, with subsequent brush management, are two significant land cover changes that are represented in the southwestern United States. Urban areas continue to grow, and rangelands are undergoing vegetation conversions, either purposely through various rangeland management techniques, or by accident, through inadvertent effects of climate and management. This thesis investigates how areas undergoing land cover conversions in a semiarid region, through urbanization or rangeland management, influences energy, water and carbon fluxes. Specifically, the following scientific questions are addressed: (1) what is the impact of different urban land cover types in Phoenix, AZ on energy and water fluxes?, (2) how does the land cover heterogeneity influence energy, water, and carbon fluxes in a semiarid rangeland undergoing woody plant encroachment?, and (3) what is the impact of brush management on energy, water, and carbon fluxes?
The eddy covariance technique is well established to measure energy, water, and carbon fluxes and is used to quantify and compare flux measurements over different land surfaces. Results reveal that in an urban setting, paved surfaces exhibit the largest sensible and lowest latent heat fluxes in an urban environment, while a mesic landscape exhibits the largest latent heat fluxes, due to heavy irrigation. Irrigation impacts flux sensitivity to precipitation input, where latent heat fluxes increase with precipitation in xeric and parking lot landscapes, but do not impact the mesic system. In a semiarid managed rangeland, past management strategies and disturbance histories impact vegetation distribution, particularly the distribution of mesquite trees. At the site with less mesquite coverage, evapotranspiration (ET) is greater, due to greater grass cover. Both sites are generally net sinks of CO2, which is largely dependent on moisture availability, while the site with greater mesquite coverage has more respiration and generally greater gross ecosystem production (GEP). Initial impacts of brush management reveal ET and GEP decrease, due to the absence of mesquite trees. However the impact appears to be minimal by the end of the productive season. Overall, this dissertation advances the understanding of land cover change impacts on surface energy, water, and carbon fluxes in semiarid ecosystems.
The eddy covariance technique is well established to measure energy, water, and carbon fluxes and is used to quantify and compare flux measurements over different land surfaces. Results reveal that in an urban setting, paved surfaces exhibit the largest sensible and lowest latent heat fluxes in an urban environment, while a mesic landscape exhibits the largest latent heat fluxes, due to heavy irrigation. Irrigation impacts flux sensitivity to precipitation input, where latent heat fluxes increase with precipitation in xeric and parking lot landscapes, but do not impact the mesic system. In a semiarid managed rangeland, past management strategies and disturbance histories impact vegetation distribution, particularly the distribution of mesquite trees. At the site with less mesquite coverage, evapotranspiration (ET) is greater, due to greater grass cover. Both sites are generally net sinks of CO2, which is largely dependent on moisture availability, while the site with greater mesquite coverage has more respiration and generally greater gross ecosystem production (GEP). Initial impacts of brush management reveal ET and GEP decrease, due to the absence of mesquite trees. However the impact appears to be minimal by the end of the productive season. Overall, this dissertation advances the understanding of land cover change impacts on surface energy, water, and carbon fluxes in semiarid ecosystems.
ContributorsTempleton, Nicole Pierini (Author) / Vivoni, Enrique R (Thesis advisor) / Archer, Steven R (Committee member) / Mascaro, Giuseppe (Committee member) / Scott, Russell L. (Committee member) / Wang, Zhi-Hua (Committee member) / Arizona State University (Publisher)
Created2017
Description
Rapid urbanization and population growth occurring in the cities of South Western
United States have led to significant modifications in its environment at local and
regional scales. Both local and regional climate changes are expected to have massive
impacts on the hydrology of Colorado River Basin (CRB), thereby accentuating the need
of study of hydro-climatic impacts on water resource management in this region. This
thesis is devoted to understanding the impact of land use and land cover (LULC) changes
on the local and regional hydroclimate, with the goal to address urban planning issues
and provide guidance for sustainable development.
In this study, three densely populated urban areas, viz. Phoenix, Las Vegas and
Denver in the CRB are selected to capture the various dimensions of the impacts of land
use changes on the regional hydroclimate in the entire CRB. Weather Research and
Forecast (WRF) model, incorporating the latest urban modeling system, is adopted for
regional climate modeling. Two major types of urban LULC changes are studied in this
Thesis: (1) incorporation of urban trees with their radiative cooling effect, tested in
Phoenix metropolitan, and (2) projected urban expansion in 2100 obtained from
Integrated Climate and Land Use Scenarios (ICLUS) developed by the US
Environmental Protection Agency for all three cities.
The results demonstrated prominent nocturnal cooling effect of due to radiative
shading effect of the urban trees for Phoenix reducing urban surface and air temperature
by about 2~9 °C and 1~5 °C respectively and increasing relative humidity by 10~20%
during an mean diurnal cycle. The simulations of urban growth in CRB demonstratedii
nocturnal warming of about 0.36 °C, 1.07 °C, and 0.94 °C 2m-air temperature and
comparatively insignificant change in daytime temperature, with the thermal environment
of Denver being the most sensitive the urban growth. The urban hydroclimatic study
carried out in the thesis assists in identifying both context specific and generalizable
relationships, patterns among the cities, and is expected to facilitate urban planning and
management in local (cities) and regional scales.
United States have led to significant modifications in its environment at local and
regional scales. Both local and regional climate changes are expected to have massive
impacts on the hydrology of Colorado River Basin (CRB), thereby accentuating the need
of study of hydro-climatic impacts on water resource management in this region. This
thesis is devoted to understanding the impact of land use and land cover (LULC) changes
on the local and regional hydroclimate, with the goal to address urban planning issues
and provide guidance for sustainable development.
In this study, three densely populated urban areas, viz. Phoenix, Las Vegas and
Denver in the CRB are selected to capture the various dimensions of the impacts of land
use changes on the regional hydroclimate in the entire CRB. Weather Research and
Forecast (WRF) model, incorporating the latest urban modeling system, is adopted for
regional climate modeling. Two major types of urban LULC changes are studied in this
Thesis: (1) incorporation of urban trees with their radiative cooling effect, tested in
Phoenix metropolitan, and (2) projected urban expansion in 2100 obtained from
Integrated Climate and Land Use Scenarios (ICLUS) developed by the US
Environmental Protection Agency for all three cities.
The results demonstrated prominent nocturnal cooling effect of due to radiative
shading effect of the urban trees for Phoenix reducing urban surface and air temperature
by about 2~9 °C and 1~5 °C respectively and increasing relative humidity by 10~20%
during an mean diurnal cycle. The simulations of urban growth in CRB demonstratedii
nocturnal warming of about 0.36 °C, 1.07 °C, and 0.94 °C 2m-air temperature and
comparatively insignificant change in daytime temperature, with the thermal environment
of Denver being the most sensitive the urban growth. The urban hydroclimatic study
carried out in the thesis assists in identifying both context specific and generalizable
relationships, patterns among the cities, and is expected to facilitate urban planning and
management in local (cities) and regional scales.
ContributorsUpreti, Ruby (Author) / Wang, Zhihua (Thesis advisor) / Vivoni, Enrique R. (Committee member) / Mascaro, Giuseppe (Committee member) / White, Dave (Committee member) / Arizona State University (Publisher)
Created2017
Environmental releases of neonicotinoid and fipronil insecticides via U.S. wastewater infrastructure
Description
This dissertation is focused on environmental releases from U.S. wastewater infrastructure of recently introduced, mass-produced insecticides, namely neonicotinoids as well as fipronil and its major degradates (sulfone, sulfide, amide, and desulfinyl derivatives), jointly known as fiproles. Both groups of compounds recently have caught the attention of regulatory agencies worldwide due to their toxic effects on pollinators and on aquatic invertebrates at very low, part-per-trillion levels (Chapter 1). Mass balance studies conducted for 13 U.S. wastewater treatment plants (WWTPs) showed ubiquitous occurrence (3-666 ng/L) and persistence of neonicotinoids (Chapter 2). For the years 2001 through 2016, a longitudinal nationwide study was conducted on the occurrence of fiproles, via analysis of sludge as well as raw and treated wastewater samples. Sludge analysis revealed ubiquitous fiprole occurrence since 2001 (0.2-385 µg/kg dry weight) and a significant increase (2.4±0.3-fold; p<0.005) to elevated levels found both in 2006/7 and 2015/6. This study established a marked persistence of fiproles during both wastewater and sludge treatment, while also identifying non-agricultural uses as a major source of fiprole loading to wastewater (Chapter 3). Eight WWTPs were monitored in Northern California to assess pesticide inputs into San Francisco Bay from wastewater discharge. Per-capita-contaminant-loading calculations identified flea and tick control agents for use on pets as a previously underappreciated source term dominating the mass loading of insecticides to WWTPs in sewage and to the Bay in treated wastewater (Chapter 4). A nationwide assessment of fipronil emissions revealed that pet products, while representing only 22±7% of total fipronil usage (2011-2015), accounted for 86±5% of the mass loading to U.S. surface waters (Chapter 5). In summary, the root cause for considerable annual discharges into U.S. surface waters of the neonicotinoid imidacloprid (3,700-5,500 kg/y) and of fipronil related compounds (1,600-2,400 kg/y) is domestic rather than agricultural insecticide use. Reclaimed effluent from U.S. WWTPs contained insecticide levels that exceed toxicity benchmarks for sensitive aquatic invertebrates in 83% of cases for imidacloprid and in 67% of cases for fipronil. Recommendations are provided on how to limit toxic inputs in the future.
ContributorsSadaria, Akash Mahendra (Author) / Halden, Rolf (Thesis advisor) / Fraser, Matthew (Committee member) / Perreault, Francois (Committee member) / Mascaro, Giuseppe (Committee member) / Arizona State University (Publisher)
Created2017
Description
Accidental wetlands have been created on the bed of the Salt River and are fed by storm-water outfalls discharging at various sections of the Phoenix Metropolitan Area. Water discharges from these outfalls throughout the year, during both dry conditions (base flow) and during rain events (storm flow). In this study, DOC content and composition was studied during these two flow conditions, in the outfalls and along the wetland flow path. The importance of DOC lies in its role in transporting carbon via water movement, between different parts of a landscape, and therefore between pools in the ecosystem. Urbanization has influenced content and composition of DOC entering the accidental urban wetland via outfalls as they represent watersheds from different areas in Phoenix. First, DOC load exhibited higher quantities during stormflow compared to baseflow conditions. Second, DOC load and fluorescence analysis outcomes concluded the outfalls are different from each other. The inputs of water on the north side of the channel represent City of Phoenix watersheds were similar to each other and had high DOC load. The northern outfalls are both different in load and composition from the outfall pipe on the southern bank of the wetland as it represents South Mountain watershed. Fluorescence analysis results also concluded compositional changes occurred along the wetland flow path during both stormflow and baseflow conditions. In this study, it was explored how urbanization and the associated changes in hydrology and geomorphology have affected a desert wetland's carbon content.
ContributorsBone, Stephanie Rosalia (Author) / Hartnett, Hilairy (Thesis director) / Palta, Monica (Committee member) / Mascaro, Giuseppe (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05