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- All Subjects: Environmental engineering
- Creators: Mascaro, Giuseppe
- Creators: Fraser, Matthew
- Resource Type: Text
Description
Arsenic (As) is a naturally occurring element that poses a health risk when continually consumed at levels exceeding the Environmental Protection Agencies (EPA) maximum contaminant level (MCL) of 10 ppb. With the Arizona Department of Water Resources considering reliance on other sources of water other than just solely surface water, groundwater proves a reliable, supplemental source. The Salt River Project (SRP) wants to effectively treat their noncompliance groundwater sources to meet EPA compliance. Rapid small-scale column tests (RSSCTs) of two SRP controlled groundwater wells along the Eastern Canal and Consolidated Canal were designed to assist SRP in selection and future design of full-scale packed bed adsorbent media. Main concerns for column choice is effectiveness, design space at groundwater wells, and simplicity. Two adsorbent media types were tested for effective treatment of As to below the MCL: a synthetic iron oxide, Bayoxide E33, and a strong base anion exchange resin, SBG-1. Both media have high affinity toward As and prove effective at treating As from these groundwater sources. Bayoxide E33 RSSCT performance indicated that As treatment lasted to near 60,000 bed volumes (BV) in both water sources and still showed As adsorption extending past this operation ranging from several months to a year. SBG-1 RSSCT performance indicated As, treatment lasted to 500 BV, with the added benefit of being regenerated. At 5%, 13%, and 25% brine regeneration concentrations, regeneration showed that 5% brine is effective, yet would complicate overall design and footprint. Bayoxide E33 was selected as the best adsorbent media for SRP use in full-scale columns at groundwater wells due to its simplistic design and high efficiency.
ContributorsLesan, Dylan (Author) / Westerhoff, Paul (Thesis advisor) / Hristovski, Kiril (Committee member) / Fraser, Matthew (Committee member) / Arizona State University (Publisher)
Created2015
Description
Vapor intrusion (VI), can pose health risks to building occupants. Assessment and mitigation at VI impacted sites have been guided by a site conceptual model (SCM) in which vapors originate from subsurface sources, diffuse through soil matrix and enter into a building by gas flow across foundation cracks. Alternative VI pathways and groundwater table fluctuations are not often considered.
Alternative VI pathways, involving vapor transport along sewer lines and other subsurface infrastructure, have recently been found to be significant contributors to VI impacts at some sites. This study evaluated approaches for identifying and characterizing the significance of alternative VI pathways and assessed the effectiveness of conventional mitigation at a site with an alternative VI pathway that can be manipulated to be on or off. The alternative pathway could not be identified using conventional pathway assessment procedures and can only be discovered under controlled pressure method (CPM) conditions. Measured emission rates were two orders of magnitude greater than screening model estimates and sub-foundation vertical soil gas profiles changed and were no longer consistent with the conventional VI conceptual model when the CPM test was conducted. The pipe flow VI pathway reduced the vacuum performance of the sub-slab depressurization (SSD) VI mitigation system, but the SSD system still provided sufficient protection to the house.
The relationship between groundwater table fluctuations and subsurface vapor emissions and transport is examined using multi-year data from the field site, and is studied in the laboratory. In addition, a broader range of conditions is examined through use of modeling validated with the experimental data. The results indicate that fluctuating groundwater tables will lead to amplified volatile organic chemical (VOC) emissions from groundwater to soil surface relative to steady water table elevation, however, the magnitude of this amplification is less concerned when long-term water fluctuation present. No clear correlations were found between VOC emissions and water table changes at the study site where annual water table fluctuations of about 0.3 m existed. Significant VOC emission amplifications by water table fluctuation would be expected under shallow groundwater conditions according to model analysis results.
Alternative VI pathways, involving vapor transport along sewer lines and other subsurface infrastructure, have recently been found to be significant contributors to VI impacts at some sites. This study evaluated approaches for identifying and characterizing the significance of alternative VI pathways and assessed the effectiveness of conventional mitigation at a site with an alternative VI pathway that can be manipulated to be on or off. The alternative pathway could not be identified using conventional pathway assessment procedures and can only be discovered under controlled pressure method (CPM) conditions. Measured emission rates were two orders of magnitude greater than screening model estimates and sub-foundation vertical soil gas profiles changed and were no longer consistent with the conventional VI conceptual model when the CPM test was conducted. The pipe flow VI pathway reduced the vacuum performance of the sub-slab depressurization (SSD) VI mitigation system, but the SSD system still provided sufficient protection to the house.
The relationship between groundwater table fluctuations and subsurface vapor emissions and transport is examined using multi-year data from the field site, and is studied in the laboratory. In addition, a broader range of conditions is examined through use of modeling validated with the experimental data. The results indicate that fluctuating groundwater tables will lead to amplified volatile organic chemical (VOC) emissions from groundwater to soil surface relative to steady water table elevation, however, the magnitude of this amplification is less concerned when long-term water fluctuation present. No clear correlations were found between VOC emissions and water table changes at the study site where annual water table fluctuations of about 0.3 m existed. Significant VOC emission amplifications by water table fluctuation would be expected under shallow groundwater conditions according to model analysis results.
ContributorsGuo, Yuanming (Author) / Johnson, Paul C (Thesis advisor) / Fraser, Matthew (Committee member) / Westerhoff, Paul (Committee member) / Arizona State University (Publisher)
Created2015
Description
This dissertation focuses on the application of urban metabolism metrology (UMM) to process streams of the natural and built water environment to gauge public health concerning exposure to carcinogenic N-nitrosamines and abuse of narcotics. A survey of sources of exposure to N-nitrosamines in the U.S. population identified contaminated food products (1,900 ± 380 ng/day) as important drivers of attributable cancer risk (Chapter 2). Freshwater sediments in the proximity of U.S. municipal wastewater treatment plants were shown for the first time to harbor carcinogenic N-nitrosamine congeners, including N-nitrosodibutylamine (0.2-3.3 ng/g dw), N-nitrosodiphenylamine (0.2-4.7 ng/g dw), and N-nitrosopyrrolidine (3.4-19.6 ng/g dw) were, with treated wastewater discharge representing one potential factor contributing to the observed contamination (p=0.42) (Chapter 3). Opioid abuse rates in two small midwestern communities were estimated through the application of wastewater-based epidemiology (WBE). Average concentrations of opioids (City 1; City 2) were highest for morphine (713 ± 38, 306 ± 29 ng/L) and varied by for the remainder of the screened analytes. Furthermore, concentrations of the powerful opioid fentanyl (1.7 ± 0.2, 1.0 ± 0.5 ng/L) in wastewater were reported for the first time in the literature for the U.S. (Chapter 4). To gauge narcotic consumption within college-aged adults the WBE process used in Chapter 4 was applied to wastewater collected from a large university in the Southwestern U.S. Estimated narcotics consumption, in units of mg/day/1,000 persons showed the following rank order: cocaine (470 ± 42), heroin (474 ± 32), amphetamine (302 ± 14) and methylphenidate (236 ± 28). Most parental drugs and their respective metabolites showed detection frequencies in campus wastewater of 80% or more, with the notable exception of fentanyl, norfentanyl, buprenorphine, and norbuprenorphine. Estimated consumption of all narcotics, aside from attention-deficit/hyperactivity disorder medication, were higher than values reported in previous U.S. WBE studies for U.S. campuses (Chapter 5). The analyses presented here have identified variation in narcotic consumption habits across different U.S. communities, which can be gauged through UMM. Application of these techniques should be implemented throughout U.S. communities to provide insight into ongoing substance abuse and health issues within a community.
ContributorsGushgari, Adam Jon (Author) / Halden, Rolf U. (Thesis advisor) / Kavazanjian, Edward (Committee member) / Fraser, Matthew (Committee member) / Venkatesan, Arjun (Committee member) / Mascaro, Giuseppe (Committee member) / Arizona State University (Publisher)
Created2018
Description
Vapor intrusion (VI) pathway assessment often involves the collection and analysis of groundwater, soil gas, and indoor air data. There is temporal variability in these data, but little is understood about the characteristics of that variability and how it influences pathway assessment decision-making. This research included the first-ever collection of a long-term high-frequency indoor air data set at a house with VI impacts overlying a dilute chlorinated solvent groundwater plume. It also included periodic synoptic snapshots of groundwater and soil gas data and high-frequency monitoring of building conditions and environmental factors. Indoor air trichloroethylene (TCE) concentrations varied over three orders-of-magnitude under natural conditions, with the highest daily VI activity during fall, winter, and spring months. These data were used to simulate outcomes from common sampling strategies, with the result being that there was a high probability (up to 100%) of false-negative decisions and poor characterization of long-term exposure. Temporal and spatial variability in subsurface data were shown to increase as the sampling point moves from source depth to ground surface, with variability of an order-of-magnitude or more for sub-slab soil gas. It was observed that indoor vapor sources can cause subsurface vapor clouds and that it can take days to weeks for soil gas plumes created by indoor sources to dissipate following indoor source removal. A long-term controlled pressure method (CPM) test was conducted to assess its utility as an alternate approach for VI pathway assessment. Indoor air concentrations were similar to maximum concentrations under natural conditions (9.3 μg/m3 average vs. 13 μg/m3 for 24 h TCE data) with little temporal variability. A key outcome was that there were no occurrences of false-negative results. Results suggest that CPM tests can produce worst-case exposure conditions at any time of the year. The results of these studies highlight the limitations of current VI pathway assessment approaches and demonstrate the need for robust alternate diagnostic tools, such as CPM, that lead to greater confidence in data interpretation and decision-making.
ContributorsHolton, Chase Weston (Author) / Johnson, Paul C (Thesis advisor) / Fraser, Matthew (Committee member) / Forzani, Erica (Committee member) / Arizona State University (Publisher)
Created2015
Description
N-Nitrosodimethylamine (NDMA), a probable human carcinogen, has been found in clouds and fogs at concentration up to 500 ng/L and in drinking water as disinfection by-product. NDMA exposure to the general public is not well understood because of knowledge gaps in terms of occurrence, formation and fate both in air and water. The goal of this dissertation was to contribute to closing these knowledge gaps on potential human NDMA exposure through contributions to atmospheric measurements and fate as well as aqueous formation processes.
Novel, sensitive methods of measuring NDMA in air were developed based on Solid Phase Extraction (SPE) and Solid Phase Microextraction (SPME) coupled to Gas Chromatography-Mass Spectrometry (GC-MS). The two measuring techniques were evaluated in laboratory experiments. SPE-GC-MS was applicable in ambient air sampling and NDMA in ambient air was found in the 0.1-13.0 ng/m3 range.
NDMA photolysis, the main degradation atmospheric pathway, was studied in the atmospheric aqueous phase. Water soluble organic carbon (WSOC) was found to have more impact than inorganic species on NDMA photolysis by competing with NDMA for photons and therefore could substantially increase the NDMA lifetime in the atmosphere. The optical properties of atmospheric WSOC were investigated in aerosol, fog and cloud samples and showed WSOC from atmospheric aerosols has a higher mass absorption efficiency (MAE) than organic matter in fog and cloud water, resulting from a different composition, especially in regards of volatile species, that are not very absorbing but abundant in fogs and clouds.
NDMA formation kinetics during chloramination were studied in aqueous samples including wastewater, surface water and ground water, at two monochloramine concentrations. A simple second order NDMA formation model was developed using measured NDMA and monochloramine concentrations at select reaction times. The model fitted the NDMA formation well (R2 >0.88) in all water matrices. The proposed model was then optimized and applied to fit the data of NDMA formation from natural organic matter (NOM) and model precursors in previously studies. By determining the rate constants, the model was able to describe the effect of water conditions such as DOC and pH on NDMA formation.
Novel, sensitive methods of measuring NDMA in air were developed based on Solid Phase Extraction (SPE) and Solid Phase Microextraction (SPME) coupled to Gas Chromatography-Mass Spectrometry (GC-MS). The two measuring techniques were evaluated in laboratory experiments. SPE-GC-MS was applicable in ambient air sampling and NDMA in ambient air was found in the 0.1-13.0 ng/m3 range.
NDMA photolysis, the main degradation atmospheric pathway, was studied in the atmospheric aqueous phase. Water soluble organic carbon (WSOC) was found to have more impact than inorganic species on NDMA photolysis by competing with NDMA for photons and therefore could substantially increase the NDMA lifetime in the atmosphere. The optical properties of atmospheric WSOC were investigated in aerosol, fog and cloud samples and showed WSOC from atmospheric aerosols has a higher mass absorption efficiency (MAE) than organic matter in fog and cloud water, resulting from a different composition, especially in regards of volatile species, that are not very absorbing but abundant in fogs and clouds.
NDMA formation kinetics during chloramination were studied in aqueous samples including wastewater, surface water and ground water, at two monochloramine concentrations. A simple second order NDMA formation model was developed using measured NDMA and monochloramine concentrations at select reaction times. The model fitted the NDMA formation well (R2 >0.88) in all water matrices. The proposed model was then optimized and applied to fit the data of NDMA formation from natural organic matter (NOM) and model precursors in previously studies. By determining the rate constants, the model was able to describe the effect of water conditions such as DOC and pH on NDMA formation.
ContributorsZhang, Jinwei (Author) / Herckes, Pierre (Thesis advisor) / Westerhoff, Paul (Thesis advisor) / Fraser, Matthew (Committee member) / Shock, Everett (Committee member) / Arizona State University (Publisher)
Created2016
Description
Rapid urban expansion and the associated landscape modifications have led to significant changes of surface processes in built environments. These changes further interact with the overlying atmospheric boundary layer and strongly modulate urban microclimate. To capture the impacts of urban land surface processes on urban boundary layer dynamics, a coupled urban land-atmospheric modeling framework has been developed. The urban land surface is parameterized by an advanced single-layer urban canopy model (SLUCM) with realistic representations of urban green infrastructures such as lawn, tree, and green roof, etc. The urban atmospheric boundary layer is simulated by a single column model (SCM) with both convective and stable schemes. This coupled SLUCM-SCM framework can simulate the time evolution and vertical profile of different meteorological variables such as virtual potential temperature, specific humidity and carbon dioxide concentration. The coupled framework has been calibrated and validated in the metropolitan Phoenix area, Arizona. To quantify the model sensitivity, an advanced stochastic approach based on Markov-Chain Monte Carlo procedure has been applied. It is found that the development of urban boundary layer is highly sensitive to surface characteristics of built terrains, including urban land use, geometry, roughness of momentum, and vegetation fraction. In particular, different types of urban vegetation (mesic/xeric) affect the boundary layer dynamics through different mechanisms. Furthermore, this framework can be implanted into large-scale models such as Weather Research and Forecasting model to assess the impact of urbanization on regional climate.
ContributorsSong, Jiyun (Author) / Wang, Zhihua (Thesis advisor) / Vivoni, Enrique R (Committee member) / Mascaro, Giuseppe (Committee member) / Myint, Soe W (Committee member) / Sailor, David (Committee member) / Arizona State University (Publisher)
Created2016
Description
Land surface fluxes of energy and mass developed over heterogeneous mountain landscapes are fundamental to atmospheric processes. However, due to their high complexity and the lack of spatial observations, land surface processes and land-atmosphere interactions are not fully understood in mountain regions. This thesis investigates land surface processes and their impact on convective precipitation by conducting numerical modeling experiments at multiple scales over the North American Monsoon (NAM) region. Specifically, the following scientific questions are addressed: (1) how do land surface conditions evolve during the monsoon season, and what are their main controls?, (2) how do the diurnal cycles of surface energy fluxes vary during the monsoon season for the major ecosystems?, and (3) what are the impacts of surface soil moisture and vegetation condition on convective precipitation?
Hydrologic simulation using the TIN-based Real-time Integrated Basin Simulator (tRIBS) is firstly carried out to examine the seasonal evolution of land surface conditions. Results reveal that the spatial heterogeneity of land surface temperature and soil moisture increases dramatically with the onset of monsoon, which is related to seasonal changes in topographic and vegetation controls. Similar results are found at regional basin scale using the uncoupled WRF-Hydro model. Meanwhile, the diurnal cycles of surface energy fluxes show large variation between the major ecosystems. Differences in both the peak magnitude and peak timing of plant transpiration induce mesoscale heterogeneity in land surface conditions. Lastly, this dissertation examines the upscale effect of land surface heterogeneity on atmospheric condition through fully-coupled WRF-Hydro simulations. A series of process-based experiments were conducted to identify the pathways of soil moisture-rainfall feedback mechanism over the NAM region. While modeling experiments confirm the existence of positive soil moisture/vegetation-rainfall feedback, their exact pathways are slightly different. Interactions between soil moisture, vegetation cover, and rainfall through a series of land surface and atmospheric boundary layer processes highlight the strong land-atmosphere coupling in the NAM region, and have important implications on convective rainfall prediction. Overall, this dissertation advances the study of complex land surface processes over the NAM region, and made important contributions in linking complex hydrologic, ecologic and atmospheric processes through numerical modeling.
Hydrologic simulation using the TIN-based Real-time Integrated Basin Simulator (tRIBS) is firstly carried out to examine the seasonal evolution of land surface conditions. Results reveal that the spatial heterogeneity of land surface temperature and soil moisture increases dramatically with the onset of monsoon, which is related to seasonal changes in topographic and vegetation controls. Similar results are found at regional basin scale using the uncoupled WRF-Hydro model. Meanwhile, the diurnal cycles of surface energy fluxes show large variation between the major ecosystems. Differences in both the peak magnitude and peak timing of plant transpiration induce mesoscale heterogeneity in land surface conditions. Lastly, this dissertation examines the upscale effect of land surface heterogeneity on atmospheric condition through fully-coupled WRF-Hydro simulations. A series of process-based experiments were conducted to identify the pathways of soil moisture-rainfall feedback mechanism over the NAM region. While modeling experiments confirm the existence of positive soil moisture/vegetation-rainfall feedback, their exact pathways are slightly different. Interactions between soil moisture, vegetation cover, and rainfall through a series of land surface and atmospheric boundary layer processes highlight the strong land-atmosphere coupling in the NAM region, and have important implications on convective rainfall prediction. Overall, this dissertation advances the study of complex land surface processes over the NAM region, and made important contributions in linking complex hydrologic, ecologic and atmospheric processes through numerical modeling.
ContributorsXiang, Tiantian (Author) / Vivoni, Enrique R (Thesis advisor) / Gochis, David J (Committee member) / Huang, Huei-Ping (Committee member) / Mascaro, Giuseppe (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2016
Description
Urbanization and woody plant encroachment, with subsequent brush management, are two significant land cover changes that are represented in the southwestern United States. Urban areas continue to grow, and rangelands are undergoing vegetation conversions, either purposely through various rangeland management techniques, or by accident, through inadvertent effects of climate and management. This thesis investigates how areas undergoing land cover conversions in a semiarid region, through urbanization or rangeland management, influences energy, water and carbon fluxes. Specifically, the following scientific questions are addressed: (1) what is the impact of different urban land cover types in Phoenix, AZ on energy and water fluxes?, (2) how does the land cover heterogeneity influence energy, water, and carbon fluxes in a semiarid rangeland undergoing woody plant encroachment?, and (3) what is the impact of brush management on energy, water, and carbon fluxes?
The eddy covariance technique is well established to measure energy, water, and carbon fluxes and is used to quantify and compare flux measurements over different land surfaces. Results reveal that in an urban setting, paved surfaces exhibit the largest sensible and lowest latent heat fluxes in an urban environment, while a mesic landscape exhibits the largest latent heat fluxes, due to heavy irrigation. Irrigation impacts flux sensitivity to precipitation input, where latent heat fluxes increase with precipitation in xeric and parking lot landscapes, but do not impact the mesic system. In a semiarid managed rangeland, past management strategies and disturbance histories impact vegetation distribution, particularly the distribution of mesquite trees. At the site with less mesquite coverage, evapotranspiration (ET) is greater, due to greater grass cover. Both sites are generally net sinks of CO2, which is largely dependent on moisture availability, while the site with greater mesquite coverage has more respiration and generally greater gross ecosystem production (GEP). Initial impacts of brush management reveal ET and GEP decrease, due to the absence of mesquite trees. However the impact appears to be minimal by the end of the productive season. Overall, this dissertation advances the understanding of land cover change impacts on surface energy, water, and carbon fluxes in semiarid ecosystems.
The eddy covariance technique is well established to measure energy, water, and carbon fluxes and is used to quantify and compare flux measurements over different land surfaces. Results reveal that in an urban setting, paved surfaces exhibit the largest sensible and lowest latent heat fluxes in an urban environment, while a mesic landscape exhibits the largest latent heat fluxes, due to heavy irrigation. Irrigation impacts flux sensitivity to precipitation input, where latent heat fluxes increase with precipitation in xeric and parking lot landscapes, but do not impact the mesic system. In a semiarid managed rangeland, past management strategies and disturbance histories impact vegetation distribution, particularly the distribution of mesquite trees. At the site with less mesquite coverage, evapotranspiration (ET) is greater, due to greater grass cover. Both sites are generally net sinks of CO2, which is largely dependent on moisture availability, while the site with greater mesquite coverage has more respiration and generally greater gross ecosystem production (GEP). Initial impacts of brush management reveal ET and GEP decrease, due to the absence of mesquite trees. However the impact appears to be minimal by the end of the productive season. Overall, this dissertation advances the understanding of land cover change impacts on surface energy, water, and carbon fluxes in semiarid ecosystems.
ContributorsTempleton, Nicole Pierini (Author) / Vivoni, Enrique R (Thesis advisor) / Archer, Steven R (Committee member) / Mascaro, Giuseppe (Committee member) / Scott, Russell L. (Committee member) / Wang, Zhi-Hua (Committee member) / Arizona State University (Publisher)
Created2017
Environmental releases of neonicotinoid and fipronil insecticides via U.S. wastewater infrastructure
Description
This dissertation is focused on environmental releases from U.S. wastewater infrastructure of recently introduced, mass-produced insecticides, namely neonicotinoids as well as fipronil and its major degradates (sulfone, sulfide, amide, and desulfinyl derivatives), jointly known as fiproles. Both groups of compounds recently have caught the attention of regulatory agencies worldwide due to their toxic effects on pollinators and on aquatic invertebrates at very low, part-per-trillion levels (Chapter 1). Mass balance studies conducted for 13 U.S. wastewater treatment plants (WWTPs) showed ubiquitous occurrence (3-666 ng/L) and persistence of neonicotinoids (Chapter 2). For the years 2001 through 2016, a longitudinal nationwide study was conducted on the occurrence of fiproles, via analysis of sludge as well as raw and treated wastewater samples. Sludge analysis revealed ubiquitous fiprole occurrence since 2001 (0.2-385 µg/kg dry weight) and a significant increase (2.4±0.3-fold; p<0.005) to elevated levels found both in 2006/7 and 2015/6. This study established a marked persistence of fiproles during both wastewater and sludge treatment, while also identifying non-agricultural uses as a major source of fiprole loading to wastewater (Chapter 3). Eight WWTPs were monitored in Northern California to assess pesticide inputs into San Francisco Bay from wastewater discharge. Per-capita-contaminant-loading calculations identified flea and tick control agents for use on pets as a previously underappreciated source term dominating the mass loading of insecticides to WWTPs in sewage and to the Bay in treated wastewater (Chapter 4). A nationwide assessment of fipronil emissions revealed that pet products, while representing only 22±7% of total fipronil usage (2011-2015), accounted for 86±5% of the mass loading to U.S. surface waters (Chapter 5). In summary, the root cause for considerable annual discharges into U.S. surface waters of the neonicotinoid imidacloprid (3,700-5,500 kg/y) and of fipronil related compounds (1,600-2,400 kg/y) is domestic rather than agricultural insecticide use. Reclaimed effluent from U.S. WWTPs contained insecticide levels that exceed toxicity benchmarks for sensitive aquatic invertebrates in 83% of cases for imidacloprid and in 67% of cases for fipronil. Recommendations are provided on how to limit toxic inputs in the future.
ContributorsSadaria, Akash Mahendra (Author) / Halden, Rolf (Thesis advisor) / Fraser, Matthew (Committee member) / Perreault, Francois (Committee member) / Mascaro, Giuseppe (Committee member) / Arizona State University (Publisher)
Created2017
Description
Accidental wetlands have been created on the bed of the Salt River and are fed by storm-water outfalls discharging at various sections of the Phoenix Metropolitan Area. Water discharges from these outfalls throughout the year, during both dry conditions (base flow) and during rain events (storm flow). In this study, DOC content and composition was studied during these two flow conditions, in the outfalls and along the wetland flow path. The importance of DOC lies in its role in transporting carbon via water movement, between different parts of a landscape, and therefore between pools in the ecosystem. Urbanization has influenced content and composition of DOC entering the accidental urban wetland via outfalls as they represent watersheds from different areas in Phoenix. First, DOC load exhibited higher quantities during stormflow compared to baseflow conditions. Second, DOC load and fluorescence analysis outcomes concluded the outfalls are different from each other. The inputs of water on the north side of the channel represent City of Phoenix watersheds were similar to each other and had high DOC load. The northern outfalls are both different in load and composition from the outfall pipe on the southern bank of the wetland as it represents South Mountain watershed. Fluorescence analysis results also concluded compositional changes occurred along the wetland flow path during both stormflow and baseflow conditions. In this study, it was explored how urbanization and the associated changes in hydrology and geomorphology have affected a desert wetland's carbon content.
ContributorsBone, Stephanie Rosalia (Author) / Hartnett, Hilairy (Thesis director) / Palta, Monica (Committee member) / Mascaro, Giuseppe (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05