Matching Items (19)
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- All Subjects: Environmental engineering
- All Subjects: Aerospace Engineering
- Genre: Masters Thesis
- Creators: Hristovski, Kiril
- Creators: Dahm, Werner
- Resource Type: Text
Description
The goal of the study was twofold: (i) to investigate the synthesis of hematite-impregnated granular activated carbon (Fe-GAC) by hydrolysis of Fe (III) and (ii) to assess the effectiveness of the fabricated media in removal of arsenic from water. Fe-GAC was synthesized by hydrolysis of Fe(III) salts under two Fe (III) initial dosages (0.5M and 2M) and two hydrolysis periods (24 hrs and 72 hrs). The iron content of the fabricated Fe-GAC media ranged from 0.9% to 4.4% Fe/g of the dry media. Pseudo-equilibrium batch test data at pH = 7.7±0.2 in 1mM NaHCO3 buffered ultrapure water and challenge groundwater representative of the Arizona Mexico border region were fitted to a Freundlich isotherm model. The findings suggested that the arsenic adsorption capacity of the metal (hydr)oxide modified GAC media is primarily controlled by the surface area of the media, while the metal content exhibited lesser effect. The adsorption capacity of the media in the model Mexican groundwater matrix was significantly lower for all adsorbent media. Continuous flow short bed adsorber tests (SBA) demonstrated that the adsorption capacity for arsenic in the challenge groundwater was reduced by a factor of 3 to 4 as a result of the mass transport effects. When compared on metal basis, the iron (hydr)oxide modified media performed comparably well as existing commercial media for treatment of arsenic. On dry mass basis, the fabricated media in this study removed less arsenic than their commercial counterparts because the metal content of the commercial media was significantly higher.
ContributorsJain, Arti (Author) / Hristovski, Kiril (Thesis advisor) / Olson, Larry (Committee member) / Madar, David (Committee member) / Edwards, David (Committee member) / Arizona State University (Publisher)
Created2011
Description
Local municipalities in the Phoenix Metropolitan Area have voiced an interest in purchasing alternate source water with lower DBP precursors. Along the primary source is a hydroelectric dam in which water will be diverted from. This project is an assessment of optimizing the potential blends of source water to a water treatment plant in an effort to enable them to more readily meet DBP regulations. To perform this analysis existing water treatment models were used in conjunction with historic water quality sampling data to predict chemical usage necessary to meet DBP regulations. A retrospective analysis was performed for the summer months of 2007 regarding potential for the WTP to reduce cost through optimizing the source water by an average of 30% over the four-month period, accumulating to overall treatment savings of $154 per MG ($82 per AF).
ContributorsRice, Jacelyn (Author) / Westerhoff, Paul (Thesis advisor) / Fox, Peter (Committee member) / Hristovski, Kiril (Committee member) / Arizona State University (Publisher)
Created2011
Description
Titanium dioxide (TiO2) nanomaterial use is becoming more prevalent as is the likelihood of human exposure and environmental release. The goal of this thesis is to develop analytical techniques to quantify the level of TiO2 in complex matrices to support environmental, health, and safety research of TiO2 nanomaterials. A pharmacokinetic model showed that the inhalation of TiO2 nanomaterials caused the highest amount to be absorbed and distributed throughout the body. Smaller nanomaterials (< 5nm) accumulated in the kidneys before clearance. Nanoparticles of 25 nm diameter accumulated in the liver and spleen and were cleared from the body slower than smaller nanomaterials. A digestion method using nitric acid, hydrofluoric acid, and hydrogen peroxide was found to digest organic materials and TiO2 with a recovery of >80%. The samples were measured by inductively coupled plasma-mass spectrometry (ICP-MS) and the method detection limit was 600 ng of Ti. An intratracheal instillation study of TiO2 nanomaterials in rats found anatase TiO2 nanoparticles in the caudal lung lobe of rats 1 day post instillation at a concentration of 1.2 ug/mg dry tissue, the highest deposition rate of any TiO2 nanomaterial. For all TiO2 nanomaterial morphologies the concentrations in the caudal lobes were significantly higher than those in the cranial lobes. In a study of TiO2 concentration in food products, white colored foods or foods with a hard outer shell had higher concentrations of TiO2. Hostess Powdered Donettes were found to have the highest Ti mass per serving with 200 mg Ti. As much as 3.8% of the total TiO2 mass was able to pass through a 0.45 um indicating that some of the TiO2 is likely nanosized. In a study of TiO2 concentrations in personal care products and paints, the concentration of TiO2 was as high as 117 ug/mg in Benjamin Moore white paint and 70 ug/mg in a Neutrogena sunscreen. Greater than 6% of Ti in one sunscreen was able to pass through a 0.45 um filter. The nanosized TiO2 in food products and personal care products may release as much as 16 mg of nanosized TiO2 per individual per day to wastewater.
ContributorsWeir, Alex Alan (Author) / Westerhoff, Paul K (Thesis advisor) / Hristovski, Kiril (Committee member) / Herckes, Pierre (Committee member) / Arizona State University (Publisher)
Created2011
Description
Hexavalant chromium (Cr(VI)) poses an emerging concern in drinking water treatment with stricter regulations on the horizon. Photocatalytic reduction of Cr(VI) was investigated as an engineering scale option to remove hexavalent chromium from drinking or industrial waters via a UV/titanium dioxide (TiO2) process. Using an integrated UV lamp/ceramic membrane system to recirculate TiO2, both hexavalent and total chromium levels were reduced through photocatalytic processes without additional chemicals. Cr(VI) removal increased as a function of higher energy input and TiO2 dosage, achieving above 90% removal for a 1g/L dose of TiO2. Surface analysis of effluent TiO2 confirmed the presence of chromium species.
ContributorsStancl, Heather O'Neal (Author) / Westerhoff, Paul K (Thesis advisor) / Chan, Candace (Committee member) / Hristovski, Kiril (Committee member) / Arizona State University (Publisher)
Created2013
Description
As engineered nanomaterials (NMs) become used in industry and commerce their loading to sewage will increase. However, the fate of widely used NMs in wastewater treatment plants (WWTPs) remains poorly understood. In this research, sequencing batch reactors (SBRs) were operated with hydraulic (HRT) and sludge (SRT) retention times representative of full-scale biological WWTPs for several weeks. NM loadings at the higher range of expected environmental concentrations were selected. To achieve the pseudo-equilibrium state concentration of NMs in biomass, SBR experiments needed to operate for more than three times the SRT value, approximately 18 days. Under the conditions tested, NMs had negligible effects on ability of the wastewater bacteria to biodegrade organic material, as measured by chemical oxygen demand (COD). NM mass balance closure was achieved by measuring NMs in liquid effluent and waste biosolids. All NMs were well removed at the typical biomass concentration (1~2 gSS/L). However, carboxy-terminated polymer coated silver nanoparticles (fn-Ag) were removed less effectively (88% removal) than hydroxylated fullerenes (fullerols; >90% removal), nano TiO2 (>95% removal) or aqueous fullerenes (nC60; >95% removal). Although most NMs did not settle out of the feed solution without bacteria present, approximately 65% of the titanium dioxide was removed even in the absence of biomass simply due to self-aggregation and settling. Experiments conducted over 4 months with daily loadings of nC60 showed that nC60 removal from solution depends on the biomass concentration. Under conditions representative of most suspended growth biological WWTPs (e.g., activated sludge), most of the NMs will accumulate in biosolids rather than in liquid effluent discharged to surface waters. Significant fractions of fn-Ag were associated with colloidal material which suggests that efficient particle separation processes (sedimentation or filtration) could further improve removal of NM from effluent. As most NMs appear to accumulate in biosolids, future research should examine the fate of NMs during disposal of WWTP biosolids, which may occur through composting or anaerobic digestion and/or land application, incineration, or landfill disposal.
ContributorsWang, Yifei (Author) / Westerhoff, Paul (Thesis advisor) / Krajmalnik-Brown, Rosa (Committee member) / Rittmann, Bruce (Committee member) / Hristovski, Kiril (Committee member) / Arizona State University (Publisher)
Created2012
Description
This thesis describes the extension of an aircraft-style time-step integrating mission performance simulation to address aero-spaceplane design challenges. The result is a computationally lean program compatible with current Multi-Disciplinary Optimization schemes to assist in the conceptual design of hypersonic vehicles. To do this the starting aircraft style “Mission Code” required enhancements to the typical point-mass simulation for high altitude and high Mach flight. Stability parameters and the rigid-body modes of Short-Period and Dutch-Roll are tracked to understand time-domain limits to aerodynamic control, along with monitoring the Lateral Control Departure Parameter to ensure that the aircraft is not prone to spin. Additionally, experience has shown that for high Mach Number flight designers must consider aerothermodynamic effects early in the vehicle design process, and thus, an engineering level aerothermodynamic model is included. Comparisons to North American X-15 flight test datasets demonstrate the validity of this method in that application, and trade studies conducted show the utility of this application.
ContributorsGriffin, Jack Aidan (Author) / Takahashi, Timothy (Thesis advisor) / Dahm, Werner (Committee member) / Rodi, Patrick (Committee member) / Arizona State University (Publisher)
Created2022
Description
This thesis addresses the issue of assessing longitudinal and lateral-directional trim capability during the conceptual design process. Modern high-performance aircraft are likely to feature complex flight control systems where the control system may independently command every control surface to develop necessary moments. However, to prove stability and controllability on such an aircraft requires a near-final set of control laws. This requirement is onerous at the conceptual design level, where engineering methods need to facilitate rapid, multidisciplinary design optimization trades. This work considers the differences in Attainable Moment Sets across a wide variety of airframes using a simplified “pre-mix” approach to controls as well as a model where the control systems have independent command authority over each control surface. This work indicates that the “independent-single-panel” model offers modest improvements in attainable moments over a “pre-mix” strategy. This suggests that a “pre-mix” approach used to assess basic combined trim problems will not lead to an overly conservative final design.
ContributorsHeinz, Joshua Holden (Author) / Takahashi, Timothy (Thesis advisor) / Dahm, Werner (Committee member) / Cotting, M. Christopher (Committee member) / Arizona State University (Publisher)
Created2023
Description
This thesis investigates the configurations needed to demonstrate positive lateraldirectional controllability across the flight envelope of a hypersonic vehicle. Itexamines the NASA Space Shuttle Orbiter as a baseline reference configuration, as it
was a successful hypersonic vehicle. However, the Orbiter had limited high-speed
maneuvering capability; it relied on reaction-control jets to augment controllability
due to a strong tendency for its aerodynamics to “control couple.” It was seen that
many problems associated with the control of the hypersonic Orbiter are due to its
slender configuration. This work relies upon the Evolved-Bihrle-Weissman chart as
an accurate indicator of lateral-directional stability and controllability. The also
explores variant configurations of larger wing tip verticals to explore what
configuration changes are needed to reduce dependence on reaction controls.
ContributorsHoopes, Connor Smith (Author) / Takahashi, Timothy (Thesis advisor) / Dahm, Werner (Committee member) / Perez, Ruben (Committee member) / Arizona State University (Publisher)
Created2023
Description
Generally, porous structures are nano-enabled with a high loading of nanoparticles (NPs) to enhance adsorption capacity, but pore blockage plays a determinant role in kinetics in this approach. The goal of this study is to investigate the effect of NPs loading on the adsorption kinetics and capacity of titanium dioxide (TiO2). To accomplish this, side-emitting optical fibers impregnated with different mass loadings of TiO2 (Ti-NIFs) were developed and characterized. Additionally, taking advantage of the use of optical fibers, the potential influence of ultraviolet light (UV) irradiation in arsenate adsorption over TiO2 was studied. The adsorption kinetics and capacity of Ti-NIFs were compared with slurry TiO2 nanoparticles in batch reactors. Arsenate adsorption was evaluated under both UV irradiation and dark conditions. The Ti-NIF with the lowest TiO2 loading showed comparable adsorption rate to NPs in suspension. Higher loadings resulted in high mass-transfer limitations. Interestingly, the normalized adsorption capacity of the produced Ti-NIFs maintained the adsorption capacity similar as they were freely dispersed. The experiments showed that UV has no influence in arsenate adsorption onto TiO2, contrary to previous literature indicating a positive effect, which was likely due to pH drift. Overall, this study shows that loadings of nanoparticles below 1% effectively enhance nano-enabled surfaces' performance.
ContributorsGonzalez Rodriguez, Jose Ricardo (Author) / Westerhoff, Paul (Thesis advisor) / Garcia-Segura, Sergi (Committee member) / Hristovski, Kiril (Committee member) / Arizona State University (Publisher)
Created2023
Description
This thesis aims to determine how finite wing aerodynamic loads change in proximity to the ground. In this study, the primary design tool is an inviscid panel method code, VORLAX.
The validation tool is a commercial volume grid CFD package, ANSYS FLUENT. I use VORLAX
to simulate wings with different incidences and aspect ratios to look at how ground effect
impacts spanwise loading and incipient flow separation. Then the results were compared to
widely published equations such as McCormick, Torenbeek, and Hoerner & Borst. Because I
found that these “famous” equations function best only for specific conditions, I propose a
new empirical equation to estimate ground effect lift as a function of aspect ratio and
incidence. Using Stratford’s method to predict signs of flow separation in the inviscid
solutions, I found that variations in the height above the ground were not significant enough
to change the stall angle of low aspect ratio wings. I did find early signs of flow separation
with increasing aspect ratio. I observe significant changes in spanwise loading when in
ground effect; as I narrow the gap, the transverse loading builds higher near the center of the
wing. These effects were more apparent in wings with smaller aspect ratio; higher aspect
ratio wings experience a higher loading gradient near the tips in proximity to the ground. I
found that high aspect ratio wings have a smaller stall angle compared to that of lower
aspect ratio wings; these trends are consistent between the potential flow solution and the
volume grid CFD viscous solution.
ContributorsValenzuela, Jose Vanir (Author) / Takahashi, Timothy (Thesis advisor) / Dahm, Werner (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2024