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A recent joint study by Arizona State University and the Arizona Department of Transportation (ADOT) was conducted to evaluate certain Warm Mix Asphalt (WMA) properties in the laboratory. WMA material was taken from an actual ADOT project that involved two WMA sections. The first section used a foamed-based WMA admixture,

A recent joint study by Arizona State University and the Arizona Department of Transportation (ADOT) was conducted to evaluate certain Warm Mix Asphalt (WMA) properties in the laboratory. WMA material was taken from an actual ADOT project that involved two WMA sections. The first section used a foamed-based WMA admixture, and the second section used a chemical-based WMA admixture. The rest of the project included control hot mix asphalt (HMA) mixture. The evaluation included testing of field-core specimens and laboratory compacted specimens. The laboratory specimens were compacted at two different temperatures; 270 °F (132 °C) and 310 °F (154 °C). The experimental plan included four laboratory tests: the dynamic modulus (E*), indirect tensile strength (IDT), moisture damage evaluation using AASHTO T-283 test, and the Hamburg Wheel-track Test. The dynamic modulus E* results of the field cores at 70 °F showed similar E* values for control HMA and foaming-based WMA mixtures; the E* values of the chemical-based WMA mixture were relatively higher. IDT test results of the field cores had comparable finding as the E* results. For the laboratory compacted specimens, both E* and IDT results indicated that decreasing the compaction temperatures from 310 °F to 270 °F did not have any negative effect on the material strength for both WMA mixtures; while the control HMA strength was affected to some extent. It was noticed that E* and IDT results of the chemical-based WMA field cores were high; however, the laboratory compacted specimens results didn't show the same tendency. The moisture sensitivity findings from TSR test disagreed with those of Hamburg test; while TSR results indicated relatively low values of about 60% for all three mixtures, Hamburg test results were quite excellent. In general, the results of this study indicated that both WMA mixes can be best evaluated through field compacted mixes/cores; the results of the laboratory compacted specimens were helpful to a certain extent. The dynamic moduli for the field-core specimens were higher than for those compacted in the laboratory. The moisture damage findings indicated that more investigations are needed to evaluate moisture damage susceptibility in field.

ContributorsAlossta, Abdulaziz (Author) / Kaloush, Kamil (Thesis advisor) / Witczak, Matthew W. (Committee member) / Mamlouk, Michael S. (Committee member) / Arizona State University (Publisher)
Created2011
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Bacteroides have been suggested as alternative indicators of fecal pollution since they are highly abundant in feces and are thought to have limited potential to grow in environment. However, recent literature suggests that Bacteroides can potentially survive within water distribution systems. The first objective of this study was therefore to

Bacteroides have been suggested as alternative indicators of fecal pollution since they are highly abundant in feces and are thought to have limited potential to grow in environment. However, recent literature suggests that Bacteroides can potentially survive within water distribution systems. The first objective of this study was therefore to investigate the validity of Bacteroides as a fecal indicator for drinking water through laboratory experiments and field studies. Experiments were performed using a laboratory scale PVC model water distribution system that was spiked with 109 Bacteroides. Samples were collected over the following four and analyzed by culture and molecular-based techniques. Second, field studies were performed by collecting water meters from two large chlorinated water distribution systems in central Arizona. Upon removal for repair by city personnel, meters were collected and biofilms samples were gathered within two hours. The biofilms were then analyzed using culture and molecular-based assays. The results from these studies support the hypothesis that Bacteroides DNA may be found in water distribution systems despite the difficulty of cultivating these bacterial cells. These experiments present the importance of considering biofilm interactions with fecal indicator bacteria when performing molecular assays on environmental samples, as biofilms may provide protection from high oxygen concentrations and grazing protozoa in bulk water that limit the persistence Bacteroides in the environment. Although the significance of biofilm interactions with surface or recreational waters may be small, they are likely important when considering drinking water delivered through distribution systems. The second objective of this study was to investigate alternative detection methodologies for the fecal indicator Bacteroides. In particular, this study focused on using a simplified protocol of Nucleic Acid Sequence Based Amplification (NASBA) and Thermophilic Helicase-Dependent Amplification (tHDA) to amplify the highly conserved 16s rRNA gene in the genomic DNA of fecal indicator Bacteroides. The results of this study show that the simplified NASBA procedure was not able to amplify the target, while continuous problems with tHDA exposed the methods lack of reliability. These results suggest higher reliability in the isothermal amplification methods needs to be achieved before application to environmental samples.
ContributorsDunkin, Nate (Author) / Abbaszadegan, Morteza (Thesis advisor) / Alum, Absar (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Nanotechnology is a scientific field that has recently expanded due to its applications in pharmaceutical and personal care products, industry and agriculture. As result of this unprecedented growth, nanoparticles (NPs) have become a significant environmental contaminant, with potential to impact various forms of life in environment. Metal nanoparticles (mNPs) exhibit

Nanotechnology is a scientific field that has recently expanded due to its applications in pharmaceutical and personal care products, industry and agriculture. As result of this unprecedented growth, nanoparticles (NPs) have become a significant environmental contaminant, with potential to impact various forms of life in environment. Metal nanoparticles (mNPs) exhibit unique properties such as increased chemical reactivity due to high specific surface area to volume ratios. Bacteria play a major role in many natural and engineered biogeochemical reactions in wastewater treatment plants and other environmental compartments. I have evaluated the laboratory isolates of E. coli, Bacillus, Alcaligenes, Pseudomonas; wastewater isolates of E. coli and Bacillus; and pathogenic isolate of E. coli for their response to 50 & 100 nm sized Cu nanoparticles (CuNPs). Bactericidal tests, scanning electron microscopy (SEM) analyses, and probable toxicity pathways assays were performed. The results indicate that under continuous mixing conditions, CuNPs are effective in inactivation of the selected bacterial isolates. In general, exposure to CuNPs resulted in 4 to >6 log reduction in bacterial population within 2 hours. Based on the GR, LDH and MTT assays, bacterial cells showed different toxicity elicitation pathways after exposure to CuNPs. Therefore, it can be concluded that the laboratory isolates are good candidates for predicting the behavior of environmental isolates exposed to CuNPs. Also, high inactivation values recorded in this study suggest that the presence of CuNPs in different environmental compartments may have an impact on pollutants attenuation and wastewater biological treatment processes. These results point towards the need for an in depth investigation of the impact of NPs on the biological processes; and long-term effect of high load of NPs on the stability of aquatic and terrestrial ecologies.
ContributorsAlboloushi, Ali (Author) / Abbaszadegan, Morteza (Thesis advisor) / Alum, Absar (Committee member) / Fox, Peter (Committee member) / Olson, Larry (Committee member) / Arizona State University (Publisher)
Created2012
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Description

Perpetual Pavements, if properly designed and rehabilitated, it can last longer than 50 years without major structural rehabilitation. Fatigue endurance limit is a key parameter for designing perpetual pavements to mitigate bottom-up fatigue cracking. The endurance limit has not been implemented in the Mechanistic Empirical Pavement Design Guide software, currently

Perpetual Pavements, if properly designed and rehabilitated, it can last longer than 50 years without major structural rehabilitation. Fatigue endurance limit is a key parameter for designing perpetual pavements to mitigate bottom-up fatigue cracking. The endurance limit has not been implemented in the Mechanistic Empirical Pavement Design Guide software, currently known as DARWin-ME. This study was conducted as part of the National Cooperative Highway Research Program (NCHRP) Project 9-44A to develop a framework and mathematical methodology to determine the fatigue endurance limit using the uniaxial fatigue test. In this procedure, the endurance limit is defined as the allowable tensile strains at which a balance takes place between the fatigue damage during loading, and the healing during the rest periods between loading pulses. The viscoelastic continuum damage model was used to isolate time dependent damage and healing in hot mix asphalt from that due to fatigue. This study also included the development of a uniaxial fatigue test method and the associated data acquisition computer programs to conduct the test with and without rest period. Five factors that affect the fatigue and healing behavior of asphalt mixtures were evaluated: asphalt content, air voids, temperature, rest period and tensile strain. Based on the test results, two Pseudo Stiffness Ratio (PSR) regression models were developed. In the first model, the PSR was a function of the five factors and the number of loading cycles. In the second model, air voids, asphalt content, and temperature were replaced by the initial stiffness of the mix. In both models, the endurance limit was defined when PSR is equal to 1.0 (net damage is equal to zero). The results of the first model were compared to the results of a stiffness ratio model developed based on a parallel study using beam fatigue test (part of the same NCHRP 9-44A). The endurance limit values determined from uniaxial and beam fatigue tests showed very good correlation. A methodology was described on how to incorporate the second PSR model into fatigue analysis and damage using the DARWin-ME software. This would provide an effective and efficient methodology to design perpetual flexible pavements.

ContributorsZeiada, Waleed (Author) / Kaloush, Kamil (Thesis advisor) / Witczak, Matthew W. (Thesis advisor) / Zapata, Claudia (Committee member) / Mamlouk, Michael (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Corrosion is known to have severe infrastructure integrity implications in a broad range of industries including water and wastewater treatment and reclamation. In the U.S. alone, the total losses due to corrosion in drinking water and wastewater systems can account for economic losses as high as $80 billion dollars a

Corrosion is known to have severe infrastructure integrity implications in a broad range of industries including water and wastewater treatment and reclamation. In the U.S. alone, the total losses due to corrosion in drinking water and wastewater systems can account for economic losses as high as $80 billion dollars a year. Microbially induced corrosion is a complex phenomenon which involve various phases; 1) formation of biofilms on submerged surfaces, 2) creation of micro-environmental niches associated with biofilm growth, 3) altered availability nutrients, 4) changes in the pH and oxygen concentrations. Biofilms can harbor opportunistic or pathogenic bacteria for a long time increasing the risk of pathogen exposure for the end users. The focus of this thesis research was to study the kinetics of microbially induced corrosion of various materials in water and reclaimed water systems. The specific objective was to assess the biofilms formation potential on stainless steel 304, stainless steel 316, galvanized steel, copper, cPVC, glass, carbon steel, and cast iron in water and reclaimed water systems. Experiments were conducted using bioreactor containers, each bioreactor housed four sampling boxes with eight partitions, dedicated to each material type coupon. One bioreactor was stationed at ASU, and one at Vistancia Aquifer Storage and Recovery (ASR) well; while three bioreactors were stationed at Butler facility, at pre-disinfection, post-UV and post-chlorination. From each location, one submerged sampling box was retrieved after 1, 3, 6 and 12 months. Time series of biofilm samples recovered from various types of coupons from different locations were analyzed using physical and culture-based techniques for quantification of biofilms and detection of heterotrophic plate count (HPC) bacteria, Legionella, Mycobacterium, and sulfate reducing bacteria (SRB). After one-year, galvanized steel had the highest concentration of HPC at 4.27 logs while copper had the lowest concentration of 3.08 logs of HPC. Bacterial growth data collected from the SRB tests was compiled to develop a numerical matrix using growth potential, biofilm formation potential and metal reduction potential of SRB isolates. This risk assessment matrix can be a useful tool for the water industry to evaluate the potential risk of MIC in their systems.
ContributorsNeal, Amber (Author) / Abbaszadegan, Morteza (Thesis advisor) / Fox, Peter (Committee member) / Alum, Absar (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Water quality assessment is essential for maintaining healthy ecosystems and protecting human health. Data interrogation and exploratory data analysis techniques are used to analyze the spatial and temporal variability of water quality parameters, identifying correlations, and to better understand the factors that impacts microbial and chemical quality of water. The

Water quality assessment is essential for maintaining healthy ecosystems and protecting human health. Data interrogation and exploratory data analysis techniques are used to analyze the spatial and temporal variability of water quality parameters, identifying correlations, and to better understand the factors that impacts microbial and chemical quality of water. The seasonal dynamics of microbiome in surface waters were investigated to identify the factors driving these dynamics. Initial investigation analyzed two decades of regional water quality data from 20 various locations in Central Arizona, USA. Leveraging advanced data science techniques, the study uncovered correlations between crucial parameters, including dissolved organic carbon (DOC), ultraviolet absorbance (UVA), and specific ultraviolet absorbance (SUVA). These findings provide foundational insights into the dynamic of overall water quality. A comprehensive 12-month surface water sample collection and study was conducted to investigate potential bias in bacterial detection using EPA approved Membrane Filtration (MF) technique. The results underscore that while MF excels in recovering bacteria of public health significance, it exhibits biases, particularly against small and spore-forming bacteria and Archaea, such as Bacilli, Mollicutes, Methylacidiphilae, and Parvarchaea. This emphasizes the importance of complementing standard microbiology approaches to mitigate technological biases and enhance the accuracy of microbial water quality testing, especially for emerging pathogens. Furthermore, a complementary study of microbial dynamics within a model drinking water distribution systems (DWDSs) using treated water from the same source water as the above study. The influence of pipe material and water temperature on the microbiome and trace element composition was investigated. The research unveiled a preferential link between pipe material and trace elements, with water temperature significantly impacting the microbiome to a higher degree than the chemical composition of water. Notably, Legionellaceae and Mycobacteriaceae were found to be prevalent in warmer waters, highlighting the substantial influence of water temperature on the microbiome, surpassing that of pipe material. These studies provide comprehensive insights into the spatial and temporal variability of water quality parameters. Analyzing microbial data in depth is crucial in detecting bacterial species within a monitoring program for adjusting operational conditions to reduce the presence of microbial pathogens and enhance the quality of drinking water.
ContributorsAloraini, Saleh (Author) / Abbaszadegan, Morteza (Thesis advisor) / Fox, Peter (Committee member) / Perreault, Francois (Committee member) / Alum, Absar (Committee member) / Arizona State University (Publisher)
Created2023
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In the recent years, there have been massive technological advancements which have led to increased radical industrialization resulting in a significant impact on the environment. Effluents and by-products of the production processes from industries such as pharmaceutical and personal care products (PPCPs) have increased the concerns of “emerging contaminants” (ECs)

In the recent years, there have been massive technological advancements which have led to increased radical industrialization resulting in a significant impact on the environment. Effluents and by-products of the production processes from industries such as pharmaceutical and personal care products (PPCPs) have increased the concerns of “emerging contaminants” (ECs) in surface waters and drinking water systems. This study focuses on the treatment of emerging chemical contaminants including nitrosodimethylamine (NDMA) and 1,4-dioxane. In addition, the inactivation of microbial contaminants of concern in water including E. coli, Legionella, Mycobacterium and fungal spores were studied using the same treatment technologies. The ECs chosen are not susceptible to conventional treatment process and there still remains a need for alternate processes for their removing/remediating to ensure safe drinking water. The treatment technologies utilized were Advanced Oxidation Processes (AOP) involving UV 220 /254 nm employing an excimer lamp and a low-pressure mercury lamp with ReFLeXTM technology and peracetic acid (PAA). The main objective of this study was to develop a new alternate technology for the enhanced remediation of chemical and microorganisms of concerns in water. The specific research objectives included: 1) To study the efficacy of the UV system to treat the selected contaminants. 2) To study the effect of PAA on the remediation of the contaminants. 3) To explore a new AOP technology under dynamic flow conditions with varying UV and PAA doses. 4) To determine optimized UV and PAA dosages to obtain enhanced remediation of the selected contaminant under dynamic flow conditions to better mimic the real-world applications.
ContributorsNatekar, Sunny Anand (Author) / Abbaszadegan, Morteza (Thesis advisor) / Fox, Peter (Committee member) / Alum, Absar (Committee member) / Diefenthal, George (Committee member) / Arizona State University (Publisher)
Created2021
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The ongoing COVID pandemic has opened the doors for the development of effective surface disinfection technologies. UV technology is one of the most effective technique to be used in combination with different photocatalytic agents such as Titanium Dioxide (TiO2) for microbial inactivation. There are many bacteria and viruses which have

The ongoing COVID pandemic has opened the doors for the development of effective surface disinfection technologies. UV technology is one of the most effective technique to be used in combination with different photocatalytic agents such as Titanium Dioxide (TiO2) for microbial inactivation. There are many bacteria and viruses which have the potential to infect humans via surface-oral/inhalation pathway. Thus, it is important to evaluate the effectiveness of these techniques used to inactivate microorganisms to minimize environmental transmission. UV light directly acts on bacteria and viruses by damaging their nucleic acids and protein structures. TiO2 acts as a photocatalyst, generates hydroxyl radicals under UV, leading to enhanced inactivation efficacy. This study focuses on the impact of UVC light at 254 nm wavelength in combination with spray formulations with TiO2 for the inactivation of E. coli (exposure times of 1, 5 and 10 minutes) and bacteriophages P22 (exposure times of 5 and 10 minutes) and MS2 (exposure times of 1 and 5 minutes). This study includes tests that explored the long-lasting impact of spray formulations on non-porous surface. Minimal inactivation of ~ 0.15 log inactivation of E. coli was resulted using TiO¬2 alone but when UV was added to the procedure on average 3 log inactivation was achieved. It was noted that MS2 was found to be more susceptible to UV as compared to P22 due to its higher inactivation rate. The spray formulation homogeneity is a critical factor in consistent microbial inactivation. In addition, the UV intensity of the handheld device is an important factor for total disinfection. However, the combined spray formulation and UV technology is an effective method of surface disinfection.
ContributorsBaxi, Dhatri Kamleshbhai (Author) / Abbaszadegan, Morteza (Thesis advisor) / Fox, Peter (Committee member) / Alum, Absar (Committee member) / Arizona State University (Publisher)
Created2021
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The built environment is responsible for a significant portion of global waste generation.

Construction and demolition (C&D) waste requires significant landfill areas and costs

billions of dollars. New business models that reduce this waste may prove to be financially

beneficial and generally more sustainable. One such model is referred to as the “Circular

Economy”

The built environment is responsible for a significant portion of global waste generation.

Construction and demolition (C&D) waste requires significant landfill areas and costs

billions of dollars. New business models that reduce this waste may prove to be financially

beneficial and generally more sustainable. One such model is referred to as the “Circular

Economy” (CE), which promotes the efficient use of materials to minimize waste

generation and raw material consumption. CE is achieved by maximizing the life of

materials and components and by reclaiming the typically wasted value at the end of their

life. This thesis identifies the potential opportunities for using CE in the built environment.

It first calculates the magnitude of C&D waste and its main streams, highlights the top

C&D materials based on weight and value using data from various regions, identifies the

top C&D materials’ current recycling and reuse rates, and finally estimates a potential

financial benefit of $3.7 billion from redirecting C&D waste using the CE concept in the

United States.

ContributorsAldaaja, Mohammad (Author) / El Asmar, Mounir (Thesis advisor) / Buch, Rajesh (Committee member) / Kaloush, Kamil (Committee member) / Arizona State University (Publisher)
Created2019
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One of the two objectives of this dissertation is an investigation into the possible correlation between rainfall events and increased levels of E. coli and Mycobacterium using an existing data set. The literature states that levels of microbial concentrations do increase after rainfall events, but there are no studies to

One of the two objectives of this dissertation is an investigation into the possible correlation between rainfall events and increased levels of E. coli and Mycobacterium using an existing data set. The literature states that levels of microbial concentrations do increase after rainfall events, but there are no studies to indicate this correlation applies in any Arizona water systems. The data analyzed for the bacterial concentrations project suggested the possibility of a correlation along one river but it is not conclusive to state that any correlation exists between rainfall events and the microbial concentration for many other sites included in the analysis. This is most likely due to the highly engineered water delivery systems that are not directly impacted.

The secondary objective was to determine if there are environmental variables collected from an ongoing project which would be a good candidate for making predictions about any of the project data parameters. Of the 79 possible opportunities for the model to accurately predict the dependent variable, it showed strong statistical favorability as well as experimentally favorable results towards Dissolved Organic Carbon as the best dependent variable from the data set, resulting in an accuracy of 41%. This is relevant since Dissolved Organic Carbon is one of the most important water quality parameters of concern for drinking water treatment plants where disinfection by-products are a limiting factor. The need for further analysis and additional data collection is an obvious result from both studies. The use of hydrograph data instead of rainfall would be a logical new direction for the heavily engineered water delivery systems.
ContributorsBuell, Andrew (Author) / Fox, Peter (Thesis advisor) / Abbaszadegan, Morteza (Thesis advisor) / Alum, Absar (Committee member) / Arizona State University (Publisher)
Created2018