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The free-base tetra-tolyl-porphyrin and the corresponding cobalt and iron porphyrin complexes were synthesized and characterized to show that this class of compound can be promising, tunable catalysts for carbon dioxide reduction. During cyclic voltammetry experiments, the iron porphyrin showed an on-set of ‘catalytic current’ at an earlier potential than the

The free-base tetra-tolyl-porphyrin and the corresponding cobalt and iron porphyrin complexes were synthesized and characterized to show that this class of compound can be promising, tunable catalysts for carbon dioxide reduction. During cyclic voltammetry experiments, the iron porphyrin showed an on-set of ‘catalytic current’ at an earlier potential than the cobalt porphyrin’s in organic solutions gassed with carbon dioxide. The cobalt porphyrin yielded larger catalytic currents, but at the same potential as the electrode. This difference, along with the significant changes in the porphyrin’s electronic, optical and redox properties, showed that its capabilities for carbon dioxide reduction can be controlled by metal ions, allotting it unique opportunities for applications in solar fuels catalysis and photochemical reactions.
ContributorsSkibo, Edward Kim (Author) / Moore, Gary (Thesis director) / Woodbury, Neal (Committee member) / School of Molecular Sciences (Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
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This paper offers a radical critique of consumer capitalism and consumer activism through advertisements from Industrial Food Systems. I examine advertisements from Monsanto, Industrial Beef Farmers, and Waste Management in order to critique the rhetoric that these companies use and reveal the environmental destruction they are attempting to obscure through

This paper offers a radical critique of consumer capitalism and consumer activism through advertisements from Industrial Food Systems. I examine advertisements from Monsanto, Industrial Beef Farmers, and Waste Management in order to critique the rhetoric that these companies use and reveal the environmental destruction they are attempting to obscure through the strategic use of language and symbols. I argue that a deeper anti-capitalist analysis of Industrial Food Systems is necessary to subvert consumer activism and greenwashing tactics and to curb environmental destruction.
ContributorsSnarr, Madeline M. (Author) / Sandlin, Jennifer (Thesis director) / Richter, Jennifer (Committee member) / School of Social Transformation (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
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The project follows a recent issue between the U.S. and Mexico concerning the shared use of the transborder Santa Cruz River. The situation remains unresolved and the long-term sustainability of the river is unknown. The study is based on an analysis of scholarly research and interviews pulling from three fields:

The project follows a recent issue between the U.S. and Mexico concerning the shared use of the transborder Santa Cruz River. The situation remains unresolved and the long-term sustainability of the river is unknown. The study is based on an analysis of scholarly research and interviews pulling from three fields: Law, social science, and the environment. The project explores potential solutions from multiple levels of governance, and contextualizes the issue in terms of the people affected on both sides of the border.
ContributorsSimons, Amelie Christine (Author) / Haglund, LaDawn (Thesis director) / Lara-Valencia, Francisco (Committee member) / Sass, Sherry (Committee member) / Barrett, The Honors College (Contributor) / School of Social Transformation (Contributor)
Created2013-05
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With the rise of fast fashion and its now apparent effects on climate change, there is an evident need for change in terms of how we as individuals use our clothing and footwear. Our team has created Ray Fashion Inc., a sustainable footwear company that focuses on implementing the circular

With the rise of fast fashion and its now apparent effects on climate change, there is an evident need for change in terms of how we as individuals use our clothing and footwear. Our team has created Ray Fashion Inc., a sustainable footwear company that focuses on implementing the circular economy to reduce the amount of waste generated in shoe creation. We have designed a sandal that accommodates the rapid consumption element of fast fashion with a business model that promotes sustainability through a buy-back method to upcycle and retain our materials.

ContributorsYang, Andrea (Co-author) / Suresh Kumar, Roshni (Co-author) / Liao, Yuxin (Co-author) / Byrne, Jared (Thesis director) / Marseille, Alicia (Committee member) / Jordan, Amanda (Committee member) / Department of English (Contributor) / School of International Letters and Cultures (Contributor) / School of Social Transformation (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
Description

Food insecure populations suffer from the ability to access affordable and nutritious foods as a result of financial and transportation needs. Often these populations are concentrated in areas referenced as food deserts. A food desert is an area that does not have a supermarket or large grocery store within a

Food insecure populations suffer from the ability to access affordable and nutritious foods as a result of financial and transportation needs. Often these populations are concentrated in areas referenced as food deserts. A food desert is an area that does not have a supermarket or large grocery store within a mile and often is saturated with small non-traditional food stores and fast- food establishments. In this study, 21 food deserts along Grand Avenue in Downtown Phoenix were analyzed to better understand their access to food, population statistics and barriers to being food secure. The research question analyzed is the impact food insecurity has on communities in Phoenix, Arizona. The findings are presented in the form of a research paper, as well as 15 black and white film photographs accompanied by descriptions. There is primary qualitative data presented through photographs and observations, as well as secondary quantitative data analyzed from Census data. The food deserts studied consist of communities that are low-income and majority minority with little to no access to nutritious food in their area. The economics of food insecurity and grocery stores, racial discrimination, access to transportation, impacts on health and education and the sustainability of food deserts are all aspects of food insecurity discussed in the research. Possible solutions such as community gardens and subsidized grocery stores are also presented. The study revealed that food insecurity has several negative impacts on the affected populations and communities and disproportionately impacts low-income and minority communities.

ContributorsHollinshead, Samantha Nadine (Author) / Liao, Chuan Liao (Thesis director) / Bavousett, Brigitte Bavousett (Committee member) / School of Sustainability (Contributor) / School of Social Transformation (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
Description

Plasticizers are plastic additives used to enhance the physical properties of plastic and are ubiquitous in the environment. A class of plasticizer compounds called phthalate esters that are not fully eliminated in wastewater treatment facilities are relevant to the ecological health of downstream ecosystems and urban areas due to their

Plasticizers are plastic additives used to enhance the physical properties of plastic and are ubiquitous in the environment. A class of plasticizer compounds called phthalate esters that are not fully eliminated in wastewater treatment facilities are relevant to the ecological health of downstream ecosystems and urban areas due to their ecotoxicity, tendency for soil accumulation, and the emerging concern about their effects on public health. However, plasticizer concentrations in a constructed wetland environment have rarely been studied in the United States, prompting the need for a method of plasticizer quantification in the Tres Rios Constructed Wetlands which are sustained by the effluent of the 91st Avenue Wastewater Treatment Plant in Phoenix, Arizona. The concentrations of four common plasticizer compounds (dimethyl: DMP, diethyl: DEP, di-n-butyl: DnBP, and bis(2-ethylhexyl): DEHP phthalate) at five sites across the wetland surface water were quantified using solid-phase extraction followed by gas chromatography coupled with mass spectrometry (GC/MS). The sampling period included four sample sets taken from March 2022 to September 2022, which gave temporal data in addition to spatial concentration data. Quantification and quality control were performed using internal standard calibration, replicate samples, and laboratory blanks. Higher molecular weight phthalates accumulated in the wetland surface water at significantly higher average concentrations than those of lower molecular weight at a 95% confidence level, ranging from 8 ng/L to 7349 ng/L and 4 ng/L to 27876 ng/L for DnBP and DEHP, respectively. Concentrations for dimethyl phthalate and diethyl phthalate were typically less than 50 ng/L and were often below the method detection limit. Average concentrations of DnBP and DEHP were significantly higher during periods of high temperatures and arid conditions. The spatial distribution of phthalates was analyzed. Most importantly, a method for successful ultra-trace quantification of plasticizers at Tres Rios was established. These results confirm the presence of plasticizers at Tres Rios and a significant seasonal increase in their surface water concentrations. The developed analytical procedure provides a solid foundation for the Wetlands Environmental Ecology Lab at ASU to further investigate plasticizers and contaminants of emerging concern and determine their ultimate fate through volatilization, sorption, photodegradation, hydrolysis, microbial biodegradation, and phytoremediation studies.

ContributorsStorey, Garrett (Author) / Herckes, Pierre (Thesis director) / Childers, Dan (Committee member) / Borges, Chad (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of Molecular Sciences (Contributor)
Created2023-05
Description

This paper outlines the issue of end-of-life management in small scale solar systems deployed generally in Sub-Saharan Africa, known as PAYGos (Pay-as-you-go). Research and interviews were conducted in order to determine the current state of the industry and plans in terms of waste management. Considering the current capabilities and technology

This paper outlines the issue of end-of-life management in small scale solar systems deployed generally in Sub-Saharan Africa, known as PAYGos (Pay-as-you-go). Research and interviews were conducted in order to determine the current state of the industry and plans in terms of waste management. Considering the current capabilities and technology of PV recycling, the future of the industry was analyzed. It is important to provide the highest quality of service to the customer and minimize issues with environmental hazards. Therefore, it is recommended here that PAYGo companies create contracts with recycling companies before the issue of solar waste increases drastically.

ContributorsDiehl, Phoebe (Author) / Kelman, Jonathan (Thesis director) / Moore, Thomas (Committee member) / Barrett, The Honors College (Contributor) / School of Molecular Sciences (Contributor)
Created2023-05
Description

Food waste is a crucial issue in stores, restaurants and other institutions. Specifically, there is a high amount of food waste in grocery stores, especially in the produce section. As a result, environmental damage occurs, and many individuals struggle to have food in their homes. This thesis will analyze the

Food waste is a crucial issue in stores, restaurants and other institutions. Specifically, there is a high amount of food waste in grocery stores, especially in the produce section. As a result, environmental damage occurs, and many individuals struggle to have food in their homes. This thesis will analyze the cause, quantity, and effect of this waste, and how it can be changed or mitigated. An overarching question was posed to analyze these causes and effects of waste, asking how does the amount of produce waste that occurs in Scottsdale, Arizona contribute to environmental issues and what is being done to remedy this issue? As this is a difficult question to answer on its own, the research was broken down into two more answerable questions, which are Why does produce get wasted in grocery stores? How much of this occurs? and What remedies already exist to limit/reduce this waste? These questions are important because they contribute to knowledge and understanding about food waste, consumer waste, as well as the overall environmental impact of being wasteful. It is also important for both retailers and consumers to understand that waste has an immense and negative impact on the environment and contributes to climate change, and that taking steps to reduce this waste is essential.

ContributorsPagnillo, Mary (Author) / Haglund, LaDawn (Thesis director) / Holman, Christine (Committee member) / Barrett, The Honors College (Contributor) / School of International Letters and Cultures (Contributor) / School of Social Transformation (Contributor) / School of Politics and Global Studies (Contributor)
Created2023-05
Description

This paper focuses on the impacts of climate change on the Two-Spirit, Lesbian, Gay, Bisexual, Transgender, Queer and/or Questioning, Intersex, Asexual (2SLGBTQIA+) population. The paper seeks to fill in the current gap within research in this particular area. I utilize a decolonial and intersectional framework to determine how to achieve

This paper focuses on the impacts of climate change on the Two-Spirit, Lesbian, Gay, Bisexual, Transgender, Queer and/or Questioning, Intersex, Asexual (2SLGBTQIA+) population. The paper seeks to fill in the current gap within research in this particular area. I utilize a decolonial and intersectional framework to determine how to achieve queer climate justice. In doing so, I conduct interviews with different climate activists and review current research to come up with possible responses.

ContributorsPrasad, Danielle (Author) / Silova, Iveta (Thesis director) / Barca, Lisa (Committee member) / Barrett, The Honors College (Contributor) / School of Social Transformation (Contributor) / School of Sustainability (Contributor)
Created2023-05
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Description

The cosmetic industry utilizes plastic for most of its packaging, as it is a cheap option that produces packaging that is highly durable and resistant to many chemicals. Polyethylene terephthalate (PET) is the most commonly used plastic in cosmetic packaging, and is an ideal candidate for recycling due to their

The cosmetic industry utilizes plastic for most of its packaging, as it is a cheap option that produces packaging that is highly durable and resistant to many chemicals. Polyethylene terephthalate (PET) is the most commonly used plastic in cosmetic packaging, and is an ideal candidate for recycling due to their short lifespan and low diffusion coefficient. However, cosmetic packaging is often not recycled properly due to its small size, contributing to the growing global plastic waste problem. If a sustainable closed-loop system was created where cosmetic packaging was created using purely recycled PET, then the amount of plastic produced could be reduced. By examining the mechanical properties of recycled composite PET from the cosmetic industry, conclusions can be drawn about its applicability in cosmetic packaging. The water absorption, UV-visible absorbance, and tensile strength was tested for recycled composite PET to predict how the material would perform if it was used in cosmetic packaging. It was found that the recycled composite PET did not perform as well as virgin PET in terms of water absorption and tensile strength, but performed similarly in reference to UV-visible absorbance. More research needs to be done to further characterize the mechanical properties of recycled composite PET before it can be used in cosmetic packaging, but this study analyzes three of the most prominent aspects found in cosmetic packaging.

ContributorsSoekardono, Nadya (Author) / Kuhn, Anthony (Thesis director) / Trujillo, Rhett (Committee member) / Machas, Michael (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of Molecular Sciences (Contributor)
Created2022-05