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In recent years, an increase of environmental temperature in urban areas has raised many concerns. These areas are subjected to higher temperature compared to the rural surrounding areas. Modification of land surface and the use of materials such as concrete and/or asphalt are the main factors influencing the surface energy

In recent years, an increase of environmental temperature in urban areas has raised many concerns. These areas are subjected to higher temperature compared to the rural surrounding areas. Modification of land surface and the use of materials such as concrete and/or asphalt are the main factors influencing the surface energy balance and therefore the environmental temperature in the urban areas. Engineered materials have relatively higher solar energy absorption and tend to trap a relatively higher incoming solar radiation. They also possess a higher heat storage capacity that allows them to retain heat during the day and then slowly release it back into the atmosphere as the sun goes down. This phenomenon is known as the Urban Heat Island (UHI) effect and causes an increase in the urban air temperature. Many researchers believe that albedo is the key pavement affecting the urban heat island. However, this research has shown that the problem is more complex and that solar reflectivity may not be the only important factor to evaluate the ability of a pavement to mitigate UHI. The main objective of this study was to analyze and research the influence of pavement materials on the near surface air temperature. In order to accomplish this effort, test sections consisting of Hot Mix Asphalt (HMA), Porous Hot Mix asphalt (PHMA), Portland Cement Concrete (PCC), Pervious Portland Cement Concrete (PPCC), artificial turf, and landscape gravels were constructed in the Phoenix, Arizona area. Air temperature, albedo, wind speed, solar radiation, and wind direction were recorded, analyzed and compared above each pavement material type. The results showed that there was no significant difference in the air temperature at 3-feet and above, regardless of the type of the pavement. Near surface pavement temperatures were also measured and modeled. The results indicated that for the UHI analysis, it is important to consider the interaction between pavement structure, material properties, and environmental factors. Overall, this study demonstrated the complexity of evaluating pavement structures for UHI mitigation; it provided great insight on the effects of material types and properties on surface temperatures and near surface air temperature.

ContributorsPourshams-Manzouri, Tina (Author) / Kaloush, Kamil (Thesis advisor) / Wang, Zhihua (Thesis advisor) / Zapata, Claudia E. (Committee member) / Mamlouk, Michael (Committee member) / Arizona State University (Publisher)
Created2013
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Description
The consumption of feedstocks from agriculture and forestry by current biofuel production has raised concerns about food security and land availability. In the meantime, intensive human activities have created a large amount of marginal lands that require management. This study investigated the viability of aligning land management with biofuel production

The consumption of feedstocks from agriculture and forestry by current biofuel production has raised concerns about food security and land availability. In the meantime, intensive human activities have created a large amount of marginal lands that require management. This study investigated the viability of aligning land management with biofuel production on marginal lands. Biofuel crop production on two types of marginal lands, namely urban vacant lots and abandoned mine lands (AMLs), were assessed. The investigation of biofuel production on urban marginal land was carried out in Pittsburgh between 2008 and 2011, using the sunflower gardens developed by a Pittsburgh non-profit as an example. Results showed that the crops from urban marginal lands were safe for biofuel. The crop yield was 20% of that on agricultural land while the low input agriculture was used in crop cultivation. The energy balance analysis demonstrated that the sunflower gardens could produce a net energy return even at the current low yield. Biofuel production on AML was assessed from experiments conducted in a greenhouse for sunflower, soybean, corn, canola and camelina. The research successfully created an industrial symbiosis by using bauxite as soil amendment to enable plant growth on very acidic mine refuse. Phytoremediation and soil amendments were found to be able to effectively reduce contamination in the AML and its runoff. Results from this research supported that biofuel production on marginal lands could be a unique and feasible option for cultivating biofuel feedstocks.
ContributorsZhao, Xi (Author) / Landis, Amy (Thesis advisor) / Fox, Peter (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2013
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Description
Life Cycle Assessment (LCA) quantifies environmental impacts of products in raw material extraction, processing, manufacturing, distribution, use and final disposal. The findings of an LCA can be used to improve industry practices, to aid in product development, and guide public policy. Unfortunately, existing approaches to LCA are unreliable in the

Life Cycle Assessment (LCA) quantifies environmental impacts of products in raw material extraction, processing, manufacturing, distribution, use and final disposal. The findings of an LCA can be used to improve industry practices, to aid in product development, and guide public policy. Unfortunately, existing approaches to LCA are unreliable in the cases of emerging technologies, where data is unavailable and rapid technological advances outstrip environmental knowledge. Previous studies have demonstrated several shortcomings to existing practices, including the masking of environmental impacts, the difficulty of selecting appropriate weight sets for multi-stakeholder problems, and difficulties in exploration of variability and uncertainty. In particular, there is an acute need for decision-driven interpretation methods that can guide decision makers towards making balanced, environmentally sound decisions in instances of high uncertainty. We propose the first major methodological innovation in LCA since early establishment of LCA as the analytical perspective of choice in problems of environmental management. We propose to couple stochastic multi-criteria decision analytic tools with existing approaches to inventory building and characterization to create a robust approach to comparative technology assessment in the context of high uncertainty, rapid technological change, and evolving stakeholder values. Namely, this study introduces a novel method known as Stochastic Multi-attribute Analysis for Life Cycle Impact Assessment (SMAA-LCIA) that uses internal normalization by means of outranking and exploration of feasible weight spaces.
ContributorsPrado, Valentina (Author) / Seager, Thomas P (Thesis advisor) / Landis, Amy E. (Committee member) / Chester, Mikhail (Committee member) / White, Philip (Committee member) / Arizona State University (Publisher)
Created2013
Description
Carbon capture and sequestration (CCS) is one of the important mitigation options for climate change. Numerous technologies to capture carbon dioxide (CO2) are in development but currently, capture using amines is the predominant technology. When the flue gas reacts with amines (Monoethanaloamine) the CO2 is absorbed into the solution and

Carbon capture and sequestration (CCS) is one of the important mitigation options for climate change. Numerous technologies to capture carbon dioxide (CO2) are in development but currently, capture using amines is the predominant technology. When the flue gas reacts with amines (Monoethanaloamine) the CO2 is absorbed into the solution and forms an intermediate product which then releases CO2 at higher temperature. The high temperature necessary to strip CO2 is provided by steam extracted from the powerplant thus reducing the net output of the powerplant by 25% to 35%. The reduction in electricity output for the same input of coal increases the emissions factor of Nitrogen Oxides, Mercury, Particulate matter, Ammonia, Volatile organic compounds for the same unit of electricity produced. The thesis questions if this tradeoff between CO2 and other emissions is beneficial or not. Three different methodologies, Life Cycle Assessment, Valuation models and cost benefit analysis are used to identify if there is a net benefit to the society on implementation of CCS to a Pulverized coal powerplant. These methodologies include the benefits due to reduction of CO2 and the disbenefits due to the increase of other emissions. The life cycle assessment using ecoindicator'99 methodology shows the CCS is not beneficial under Hierarchical and Egalitarian perspective. The valuation model shows that the inclusion of the other emissions reduces the benefit associated with CCS. For a lower CO2 price the valuation model shows that CCS is detrimental to the environment. The cost benefit analysis shows that a CO2 price of at least $80/tCO2 is required for the cost benefit ratio to be 1. The methodology integrates Montecarlo simulation to characterize the uncertainties associated with the valuation models.
ContributorsSekar, Ashok (Author) / Williams, Eric (Thesis advisor) / Chester, Mikhail (Thesis advisor) / Allenby, Braden (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Ecolabels are the main driving force of consumer knowledge in the realm of sustainable product purchasing. While ecolabels strive to improve consumer's purchasing decisions, they have overwhelmed the market, leaving consumers confused and distrustful of what each label means. This study attempts to validate and understand environmental concerns commonly found

Ecolabels are the main driving force of consumer knowledge in the realm of sustainable product purchasing. While ecolabels strive to improve consumer's purchasing decisions, they have overwhelmed the market, leaving consumers confused and distrustful of what each label means. This study attempts to validate and understand environmental concerns commonly found in ecolabel criteria and the implications they have within the life cycle of a product. A life cycle assessment (LCA) case study of cosmetic products is used in comparison with current ecolabel program criteria to assess whether or not ecolabels are effectively driving environmental improvements in high impact areas throughout the life cycle of a product. Focus is placed on determining the general issues addressed by ecolabelling criteria and how these issues relate to hotspots derived through a practiced scientific methodology. Through this analysis, it was determined that a majority the top performing supply chain environmental impacts are covered, in some fashion, within ecolabelling criteria, but some, such as agricultural land occupation, are covered to a lesser extent or not at all. Additional criteria are suggested to fill the gaps found in ecolabelling programs and better address the environmental impacts most pertinent to the supply chain. Ecolabels have also been found to have a broader coverage then what can currently be addressed using LCA. The results of this analysis have led to a set of recommendations for furthering the integration between ecolabels and life cycle tools.
ContributorsBernardo, Melissa (Author) / Dooley, Kevin (Thesis advisor) / Chester, Mikhail (Thesis advisor) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Pavement surface temperature is calculated using a fundamental energy balance model developed previously. It can be studied using a one-dimensional mathematical model. The input to the model is changed, to study the effect of different properties of pavement on its diurnal surface temperatures. It is observed that the pavement surface

Pavement surface temperature is calculated using a fundamental energy balance model developed previously. It can be studied using a one-dimensional mathematical model. The input to the model is changed, to study the effect of different properties of pavement on its diurnal surface temperatures. It is observed that the pavement surface temperature has a microclimatic effect on the air temperature above it. A major increase in local air temperature is caused by heating of solid surfaces in that locality. A case study was done and correlations have been established to calculate the air temperature above a paved surface. Validation with in-situ pavement surface and air temperatures were made. Experimental measurement for the city of Phoenix shows the difference between the ambient air temperature of the city and the microclimatic air temperature above the pavement is approximately 10 degrees Fahrenheit. One mitigation strategy that has been explored is increasing the albedo of the paved surface. Although it will reduce the pavement surface temperature, leading to a reduction in air temperature close to the surface, the increased pavement albedo will also result in greater reflected solar radiation directed towards the building, thus increasing the building solar load. The first effect will imply a reduction in the building energy consumption, while the second effect will imply an increase in the building energy consumption. Simulation is done using the EnergyPlus tool, to find the microclimatic effect of pavement on the building energy performance. The results indicate the cooling energy savings of an office building for different types of pavements can be variable as much as 30%.
ContributorsSengupta, Shawli (Author) / Phelan, Patrick (Thesis advisor) / Kaloush, Kamil (Committee member) / Calhoun, Ronald (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Use of Recycled Asphalt Pavement (RAP) in newly designed asphalt mixtures is becoming a common practice. Depending on the percentage of RAP, the stiffness of the hot mix asphalt (HMA) increases by incorporating RAP in mixes. In a climatic area such as the City of Phoenix, RAP properties are expected

Use of Recycled Asphalt Pavement (RAP) in newly designed asphalt mixtures is becoming a common practice. Depending on the percentage of RAP, the stiffness of the hot mix asphalt (HMA) increases by incorporating RAP in mixes. In a climatic area such as the City of Phoenix, RAP properties are expected to be more oxidized and aged compared to other regions across the US. Therefore, there are concerns about the cracking behavior and long-term performance of asphalt mixes with high percentage of RAP. The use of Organosilane (OS) in this study was hypothesized to reduce the additional cracking potential and improve resistance to moisture damage of the asphalt mixtures when using RAP. OS has also the potential to improve the bond between the aggregate and asphalt binder. The use of OS also reduces the mixing and compaction temperatures required for asphalt mixtures, making it similar to a warm mix asphalt (WMA),

Six asphalt mixes were prepared with three RAP contents, 0%, 15% and 25%, with and without Organosilane. The mixing temperature was reduced by 10°C and the compaction temperature was reduced by 30°C. Mix designs were performed, and the volumetric properties were compared. The mixture laboratory performance was evaluated for all mixtures by conducting Dynamic Modulus, Flow Number and Tensile Strength Ratio tests.

The study findings showed that mixtures achieved better compaction at a reduced temperature of 30°C. Mixtures modified with Organosilane generally exhibited softer behavior at the extreme ends of lower and higher temperatures. The lower moduli are to reduce the potential for cracking. For the Flow Number test, the RAP mixtures with OS passed the minimum required at all traffic levels. Tensile Strength Ratio results increased with the increase in RAP percentage, and further increase was observed when OS was used. The OS reduced the sticking nature of the binder to the molds and equipment, which reduced the efforts in cleaning them.

Finally, the future use of RAP by the City of Phoenix would positively contributes to their sustainability aspiration and initiatives. The use of Organosilane may even facilitates higher percentage of RAP usage; it definitely improves the moisture resistance of asphalt mixtures, especially when lower mixing and compaction temperatures are desired or used.
ContributorsKaligotla, Phani Sasank (Author) / Kaloush, Kamil (Thesis advisor) / Mamlouk, Michael (Committee member) / Stempihar, Jeffrey (Committee member) / Arizona State University (Publisher)
Created2018
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Description

The built environment is responsible for a significant portion of global waste generation.

Construction and demolition (C&D) waste requires significant landfill areas and costs

billions of dollars. New business models that reduce this waste may prove to be financially

beneficial and generally more sustainable. One such model is referred to as the “Circular

Economy”

The built environment is responsible for a significant portion of global waste generation.

Construction and demolition (C&D) waste requires significant landfill areas and costs

billions of dollars. New business models that reduce this waste may prove to be financially

beneficial and generally more sustainable. One such model is referred to as the “Circular

Economy” (CE), which promotes the efficient use of materials to minimize waste

generation and raw material consumption. CE is achieved by maximizing the life of

materials and components and by reclaiming the typically wasted value at the end of their

life. This thesis identifies the potential opportunities for using CE in the built environment.

It first calculates the magnitude of C&D waste and its main streams, highlights the top

C&D materials based on weight and value using data from various regions, identifies the

top C&D materials’ current recycling and reuse rates, and finally estimates a potential

financial benefit of $3.7 billion from redirecting C&D waste using the CE concept in the

United States.

ContributorsAldaaja, Mohammad (Author) / El Asmar, Mounir (Thesis advisor) / Buch, Rajesh (Committee member) / Kaloush, Kamil (Committee member) / Arizona State University (Publisher)
Created2019
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Description
As urban populations rapidly increase in an era of climate change and multiple social and environmental uncertainties, scientists and governments are cultivating knowledge and solutions for the sustainable growth and maintenance of cities. Although substantial literature focuses on urban water resource management related to both human and ecological sustainability, few

As urban populations rapidly increase in an era of climate change and multiple social and environmental uncertainties, scientists and governments are cultivating knowledge and solutions for the sustainable growth and maintenance of cities. Although substantial literature focuses on urban water resource management related to both human and ecological sustainability, few studies assess the unique role of waterway restorations to bridge anthropocentric and ecological concerns in urban environments. To address this gap, my study addressed if well-established sustainability principles are evoked during the nascent discourse of recently proposed urban waterway developments along over fifty miles of Arizona’s Salt River. In this study, a deductive content analysis is used to illuminate the emergence of sustainability principles, the framing of the redevelopment, and to illuminate macro-environmental discourses. Three sustainability principles dominated the discourse: civility and democratic governance; livelihood sufficiency and opportunity; and social-ecological system integrity. These three principles connected to three macro-discourses: economic rationalism; democratic pragmatism; and ecological modernity. These results hold implications for policy and theory and inform urban development processes for improvements to sustainability. As continued densification, in-fill and rapid urbanization continues in the 21st century, more cities are looking to reconstruct urban riverways. Therefore, the emergent sustainability discourse regarding potential revitalizations along Arizona’s Salt River is a manifestation of how waterways are perceived, valued, and essential to urban environments for anthropocentric and ecological needs.
ContributorsHorvath, Veronica (Author) / White, Dave D (Thesis advisor) / Mirumachi, Naho (Committee member) / Childers, Dan (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Bicyclist and pedestrian safety is a growing concern in San Francisco, CA,

especially given the increasing numbers of residents choosing to bike and walk. Sharing

the roads with automobiles, these alternative road users are particularly vulnerable to

sustain serious injuries. With this in mind, it is important to identify the factors that

influence the

Bicyclist and pedestrian safety is a growing concern in San Francisco, CA,

especially given the increasing numbers of residents choosing to bike and walk. Sharing

the roads with automobiles, these alternative road users are particularly vulnerable to

sustain serious injuries. With this in mind, it is important to identify the factors that

influence the severity of bicyclist and pedestrian injuries in automobile collisions. This

study uses traffic collision data gathered from California Highway Patrol’s Statewide

Integrated Traffic Records System (SWITRS) to predict the most important

determinants of injury severity, given that a collision has occurred. Multivariate binomial

logistic regression models were created for both pedestrian and bicyclist collisions, with

bicyclist/pedestrian/driver characteristics and built environment characteristics used as

the independent variables. Results suggest that bicycle infrastructure is not an important

predictor of bicyclist injury severity, but instead bicyclist age, race, sobriety, and speed

played significant roles. Pedestrian injuries were influenced by pedestrian and driver age

and sobriety, crosswalk use, speed limit, and the type of vehicle at fault in the collision.

Understanding these key determinants that lead to severe and fatal injuries can help

local communities implement appropriate safety measures for their most susceptible

road users.
ContributorsMcIntyre, Andrew (Author) / Salon, Deborah (Thesis advisor) / Kuby, Mike (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2016