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Description
Life Cycle Assessment (LCA) quantifies environmental impacts of products in raw material extraction, processing, manufacturing, distribution, use and final disposal. The findings of an LCA can be used to improve industry practices, to aid in product development, and guide public policy. Unfortunately, existing approaches to LCA are unreliable in the

Life Cycle Assessment (LCA) quantifies environmental impacts of products in raw material extraction, processing, manufacturing, distribution, use and final disposal. The findings of an LCA can be used to improve industry practices, to aid in product development, and guide public policy. Unfortunately, existing approaches to LCA are unreliable in the cases of emerging technologies, where data is unavailable and rapid technological advances outstrip environmental knowledge. Previous studies have demonstrated several shortcomings to existing practices, including the masking of environmental impacts, the difficulty of selecting appropriate weight sets for multi-stakeholder problems, and difficulties in exploration of variability and uncertainty. In particular, there is an acute need for decision-driven interpretation methods that can guide decision makers towards making balanced, environmentally sound decisions in instances of high uncertainty. We propose the first major methodological innovation in LCA since early establishment of LCA as the analytical perspective of choice in problems of environmental management. We propose to couple stochastic multi-criteria decision analytic tools with existing approaches to inventory building and characterization to create a robust approach to comparative technology assessment in the context of high uncertainty, rapid technological change, and evolving stakeholder values. Namely, this study introduces a novel method known as Stochastic Multi-attribute Analysis for Life Cycle Impact Assessment (SMAA-LCIA) that uses internal normalization by means of outranking and exploration of feasible weight spaces.
ContributorsPrado, Valentina (Author) / Seager, Thomas P (Thesis advisor) / Landis, Amy E. (Committee member) / Chester, Mikhail (Committee member) / White, Philip (Committee member) / Arizona State University (Publisher)
Created2013
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Description
The consumption of feedstocks from agriculture and forestry by current biofuel production has raised concerns about food security and land availability. In the meantime, intensive human activities have created a large amount of marginal lands that require management. This study investigated the viability of aligning land management with biofuel production

The consumption of feedstocks from agriculture and forestry by current biofuel production has raised concerns about food security and land availability. In the meantime, intensive human activities have created a large amount of marginal lands that require management. This study investigated the viability of aligning land management with biofuel production on marginal lands. Biofuel crop production on two types of marginal lands, namely urban vacant lots and abandoned mine lands (AMLs), were assessed. The investigation of biofuel production on urban marginal land was carried out in Pittsburgh between 2008 and 2011, using the sunflower gardens developed by a Pittsburgh non-profit as an example. Results showed that the crops from urban marginal lands were safe for biofuel. The crop yield was 20% of that on agricultural land while the low input agriculture was used in crop cultivation. The energy balance analysis demonstrated that the sunflower gardens could produce a net energy return even at the current low yield. Biofuel production on AML was assessed from experiments conducted in a greenhouse for sunflower, soybean, corn, canola and camelina. The research successfully created an industrial symbiosis by using bauxite as soil amendment to enable plant growth on very acidic mine refuse. Phytoremediation and soil amendments were found to be able to effectively reduce contamination in the AML and its runoff. Results from this research supported that biofuel production on marginal lands could be a unique and feasible option for cultivating biofuel feedstocks.
ContributorsZhao, Xi (Author) / Landis, Amy (Thesis advisor) / Fox, Peter (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2013
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Description
Ecolabels are the main driving force of consumer knowledge in the realm of sustainable product purchasing. While ecolabels strive to improve consumer's purchasing decisions, they have overwhelmed the market, leaving consumers confused and distrustful of what each label means. This study attempts to validate and understand environmental concerns commonly found

Ecolabels are the main driving force of consumer knowledge in the realm of sustainable product purchasing. While ecolabels strive to improve consumer's purchasing decisions, they have overwhelmed the market, leaving consumers confused and distrustful of what each label means. This study attempts to validate and understand environmental concerns commonly found in ecolabel criteria and the implications they have within the life cycle of a product. A life cycle assessment (LCA) case study of cosmetic products is used in comparison with current ecolabel program criteria to assess whether or not ecolabels are effectively driving environmental improvements in high impact areas throughout the life cycle of a product. Focus is placed on determining the general issues addressed by ecolabelling criteria and how these issues relate to hotspots derived through a practiced scientific methodology. Through this analysis, it was determined that a majority the top performing supply chain environmental impacts are covered, in some fashion, within ecolabelling criteria, but some, such as agricultural land occupation, are covered to a lesser extent or not at all. Additional criteria are suggested to fill the gaps found in ecolabelling programs and better address the environmental impacts most pertinent to the supply chain. Ecolabels have also been found to have a broader coverage then what can currently be addressed using LCA. The results of this analysis have led to a set of recommendations for furthering the integration between ecolabels and life cycle tools.
ContributorsBernardo, Melissa (Author) / Dooley, Kevin (Thesis advisor) / Chester, Mikhail (Thesis advisor) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Cities are facing complex problems in urban water management due to unprecedented changes in climate, natural and built environment. The shift in urban hydrology from pre-development to post-development continues to accelerate the challenges of managing excess stormwater runoff, mitigating urban flood hazards and flood damages. Physically based hydrologic-hydraulic stormwater models

Cities are facing complex problems in urban water management due to unprecedented changes in climate, natural and built environment. The shift in urban hydrology from pre-development to post-development continues to accelerate the challenges of managing excess stormwater runoff, mitigating urban flood hazards and flood damages. Physically based hydrologic-hydraulic stormwater models are a useful tool for broad subset of urban flood management including risk and hazard assessment, flood forecasting, and infrastructure adaptation decision making and planning. The existing limitations in data availability, gaps in data, and uncertainty in data preclude reliable model construction, testing, deployment, knowledge generation, effective communication of flood risks, and adaptation decision making. These challenges that affect both the science and practice motivate three chapters of this dissertation. The first study conducts diagnostic analysis of the effects of stormwater infrastructure data completeness on model’s ability to simulate flood duration, flooding flow rate; and assesses the combined effects of data gaps and model resolution to simulate flood depth, extent and volume (chapter 2). The analysis showed the significance of complete stormwater infrastructure data and high model resolution to reduce error, bias and uncertainty; this study also presented an approach for filling infrastructure data gaps using available data and design standards. The second study addresses the lack of long-term hydrological observation in urban catchment by investigating the process and benefits of leveraging novel data sources in urban flood model construction and testing (chapter 3). A proof-of-concept demonstrated the application and benefits of leveraging novel data sources for urban flood monitoring and modeling. Furthermore, it highlights the need for developing and streamlining novel data collection infrastructure. The third study applies the hydrologic-hydraulic model as an adaptation planning tool and assess the effects of uncertainty in design precipitation estimates and land use change on the optimal configuration of green infrastructure (chapter 4). Several uncertainties affect infrastructure decision making as showed by variation in optimal green infrastructure configuration under precipitation estimates and land use change. Thus, the study further highlights the need of flexible planning process in infrastructure decision making.
ContributorsShrestha, Ashish (Author) / Garcia, Margaret (Thesis advisor) / Mascaro, Giuseppe (Committee member) / Chester, Mikhail (Committee member) / Fletcher, Sarah (Committee member) / Arizona State University (Publisher)
Created2022
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Description
The Water-Energy Nexus (WEN) is a concept that recognizes the interdependence of water and energy systems. The Phoenix metropolitan region (PMA) in Arizona has significant and potentially vulnerable WEN interactions. Future projections indicate that the population will increase and, with it, energy needs, while changes in future water demand are

The Water-Energy Nexus (WEN) is a concept that recognizes the interdependence of water and energy systems. The Phoenix metropolitan region (PMA) in Arizona has significant and potentially vulnerable WEN interactions. Future projections indicate that the population will increase and, with it, energy needs, while changes in future water demand are more uncertain. Climate change will also likely cause a reduction in surface water supply sources. Under these constraints, the expansion of renewable energy technology has the potential to benefit both water and energy systems and increase environmental sustainability by meeting future energy demands while lowering water use and CO2 emissions. However, the WEN synergies generated by renewables have not yet been thoroughly quantified, nor have the related costs been studied and compared to alternative options.Quantifying WEN intercations using numerical models is key to assessing renewable energy synergy. Despite recent advances, WEN models are still in their infancy, and research is needed to improve their accuracy and identify their limitations. Here, I highlight three research needs. First, most modeling efforts have been conducted for large-scale domains (e.g., states), while smaller scales, like metropolitan regions, have received less attention. Second, impacts of adopting different temporal (e.g., monthly, annual) and spatial (network granularity) resolutions on simulation accuracy have not been quantified. Third, the importance of simulating feedbacks between water and energy components has not been analyzed. This dissertation fills these major research gaps by focusing on long-term water allocations and energy dispatch in the metropolitan region of Phoenix. An energy model is developed using the Low Emissions Analysis Platform (LEAP) platform and is subsequently coupled with a water management model based on the Water Evaluation and Planning (WEAP) platform. Analyses are conducted to quantify (1) the value of adopting coupled models instead of single models that are externally coupled, and (2) the accuracy of simulations based on different temporal resolutions of supply and demand and spatial granularity of the water and energy networks. The WEAP-LEAP integrated model is then employed under future climate scenarios to quantify the potential of renewable energy technologies to develop synergies between the PMA's water and energy systems.
ContributorsMounir, Adil (Author) / Mascaro, Giuseppe (Thesis advisor) / White, Dave (Committee member) / Garcia, Margaret (Committee member) / Xu, Tianfang (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2022
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Description

Motivated by the need for cities to prepare and be resilient to unpredictable future weather conditions, this dissertation advances a novel infrastructure development theory of “safe-to-fail” to increase the adaptive capacity of cities to climate change. Current infrastructure development is primarily reliant on identifying probable risks to engineered systems and

Motivated by the need for cities to prepare and be resilient to unpredictable future weather conditions, this dissertation advances a novel infrastructure development theory of “safe-to-fail” to increase the adaptive capacity of cities to climate change. Current infrastructure development is primarily reliant on identifying probable risks to engineered systems and making infrastructure reliable to maintain its function up to a designed system capacity. However, alterations happening in the earth system (e.g., atmosphere, oceans, land, and ice) and in human systems (e.g., greenhouse gas emission, population, land-use, technology, and natural resource use) are increasing the uncertainties in weather predictions and risk calculations and making it difficult for engineered infrastructure to maintain intended design thresholds in non-stationary future. This dissertation presents a new way to develop safe-to-fail infrastructure that departs from the current practice of risk calculation and is able to manage failure consequences when unpredicted risks overwhelm engineered systems.

This dissertation 1) defines infrastructure failure, refines existing safe-to-fail theory, and compares decision considerations for safe-to-fail vs. fail-safe infrastructure development under non-stationary climate; 2) suggests an approach to integrate the estimation of infrastructure failure impacts with extreme weather risks; 3) provides a decision tool to implement resilience strategies into safe-to-fail infrastructure development; and, 4) recognizes diverse perspectives for adopting safe-to-fail theory into practice in various decision contexts.

Overall, this dissertation advances safe-to-fail theory to help guide climate adaptation decisions that consider infrastructure failure and their consequences. The results of this dissertation demonstrate an emerging need for stakeholders, including policy makers, planners, engineers, and community members, to understand an impending “infrastructure trolley problem”, where the adaptive capacity of some regions is improved at the expense of others. Safe-to-fail further engages stakeholders to bring their knowledge into the prioritization of various failure costs based on their institutional, regional, financial, and social capacity to withstand failures. This approach connects to sustainability, where city practitioners deliberately think of and include the future cost of social, environmental and economic attributes in planning and decision-making.

ContributorsKim, Yeowon (Author) / Chester, Mikhail (Thesis advisor) / Eakin, Hallie (Committee member) / Redman, Charles (Committee member) / Miller, Thaddeus R. (Committee member) / Arizona State University (Publisher)
Created2018
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Description
As urban populations rapidly increase in an era of climate change and multiple social and environmental uncertainties, scientists and governments are cultivating knowledge and solutions for the sustainable growth and maintenance of cities. Although substantial literature focuses on urban water resource management related to both human and ecological sustainability, few

As urban populations rapidly increase in an era of climate change and multiple social and environmental uncertainties, scientists and governments are cultivating knowledge and solutions for the sustainable growth and maintenance of cities. Although substantial literature focuses on urban water resource management related to both human and ecological sustainability, few studies assess the unique role of waterway restorations to bridge anthropocentric and ecological concerns in urban environments. To address this gap, my study addressed if well-established sustainability principles are evoked during the nascent discourse of recently proposed urban waterway developments along over fifty miles of Arizona’s Salt River. In this study, a deductive content analysis is used to illuminate the emergence of sustainability principles, the framing of the redevelopment, and to illuminate macro-environmental discourses. Three sustainability principles dominated the discourse: civility and democratic governance; livelihood sufficiency and opportunity; and social-ecological system integrity. These three principles connected to three macro-discourses: economic rationalism; democratic pragmatism; and ecological modernity. These results hold implications for policy and theory and inform urban development processes for improvements to sustainability. As continued densification, in-fill and rapid urbanization continues in the 21st century, more cities are looking to reconstruct urban riverways. Therefore, the emergent sustainability discourse regarding potential revitalizations along Arizona’s Salt River is a manifestation of how waterways are perceived, valued, and essential to urban environments for anthropocentric and ecological needs.
ContributorsHorvath, Veronica (Author) / White, Dave D (Thesis advisor) / Mirumachi, Naho (Committee member) / Childers, Dan (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2019
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Sustainable food systems have been studied extensively in recent times and the Food-Energy-Water (FEW) nexus framework has been one of the most common frameworks used. The dissertation intends to examine and quantitatively model the food system interaction with the energy system and the water system. Traditional FEW nexus studies have

Sustainable food systems have been studied extensively in recent times and the Food-Energy-Water (FEW) nexus framework has been one of the most common frameworks used. The dissertation intends to examine and quantitatively model the food system interaction with the energy system and the water system. Traditional FEW nexus studies have focused on food production alone. While this approach is informative, it is insufficient since food is extensively traded. Various food miles studies have highlighted the extensive virtual energy and virtual water footprint of food. This highlights the need for transport, and storage needs to be considered as part of the FEW framework. The Life cycle assessment (LCA) framework is the best available option to estimate the net energy and water exchange between the food, energy, and water systems. Climate plays an important role in food production as well as food preservation. Crops are very sensitive to temperature changes and it directly impacts a crop’s productivity. Changing temperatures directly impact crop productivity, and water demand. It is important to explore the feasibility of mitigation measures to keep in check increasing agricultural water demands. Conservation technologies may be able to provide the necessary energy and water savings. Even under varying climates it might be possible to meet demand for food through trade. The complex trade network might have the capacity to compensate for the produce lost due to climate change, and hence needs to be established. Re-visualizing the FEW nexus from the consumption perspective would better inform policy on exchange of constrained resources as well as carbon footprints. This puts the FEW nexus research space a step towards recreating the FEW nexus as a network of networks, that is, FEW-e (FEW exchange) nexus.
ContributorsNatarajan, Mukunth (Author) / Chester, Mikhail (Thesis advisor) / Lobo, Jose (Committee member) / Ruddell, Benjamin (Committee member) / Fraser, Andrew (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Recognition of algae as a “Fit for Purpose” biomass and its potential as an energy and bio-product resource remains relatively obscure. This is due to the absence of tailored and unified production information necessary to overcome several barriers for commercial viability and environmental sustainability. The purpose of this research was

Recognition of algae as a “Fit for Purpose” biomass and its potential as an energy and bio-product resource remains relatively obscure. This is due to the absence of tailored and unified production information necessary to overcome several barriers for commercial viability and environmental sustainability. The purpose of this research was to provide experimentally verifiable estimates for direct energy and water demand for the algal cultivation stage which yields algal biomass for biofuels and other bio-products. Algal biomass productivity was evaluated using different cultivation methods in conjunction with assessment for potential reduction in energy and water consumption for production of fuel and feed. Direct water and energy demands are the major focal sustainability metrics in hot and arid climates and are influenced by environmental and operational variables connected with selected algal cultivation technologies. Evaporation is a key component of direct water demand for algal cultivation and directly related to variations in temperature and relative humidity. Temperature control strategies relative to design and operational variables were necessary to mitigate overheating of the outdoor algae culture in panel photobioreactors and sub-optimal cultivation temperature in open pond raceways. Mixing in cultivation systems was a major component in direct energy demand that was provided by aeration in panel bioreactors and paddlewheels in open pond raceways. Management of aeration time to meet required biological interactions provides opportunities for reduced direct energy demand in panel photobioreactors. However, the potential for reduction in direct energy demand in raceway ponds is limited to hydraulics and head loss. Algal cultivation systems were reviewed for potential integration into dairy facilities in order to determine direct energy demand and nutrient requirements for algal biomass production for animal feed. The direct energy assessment was also evaluated for key components of related energy and design parameters for conventional raceway ponds and a gravity fed system. The results of this research provide a platform for selecting appropriate production scenarios with respect to resource use and to ensure a cost effective product with the least environmental burden.
ContributorsBadvipour, Shahrzad (Author) / Sommerfeld, Milton (Thesis advisor) / Downes, Meghan (Committee member) / Abbott, Joshua (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Ion exchange sorbents embedded with metal oxide nanoparticles can have high affinity and high capacity to simultaneously remove multiple oxygenated anion contaminants from drinking water. This research pursued answering the question, “Can synthesis methods of nano-composite sorbents be improved to increase sustainability and feasibility to remove hexavalent chromium and arsenic

Ion exchange sorbents embedded with metal oxide nanoparticles can have high affinity and high capacity to simultaneously remove multiple oxygenated anion contaminants from drinking water. This research pursued answering the question, “Can synthesis methods of nano-composite sorbents be improved to increase sustainability and feasibility to remove hexavalent chromium and arsenic simultaneously from groundwater compared to existing sorbents?” Preliminary nano-composite sorbents outperformed existing sorbents in equilibrium tests, but struggled in packed bed applications and at low influent concentrations. The synthesis process was then tailored for weak base anion exchange (WBAX) while comparing titanium dioxide against iron hydroxide nanoparticles (Ti-WBAX and Fe-WBAX, respectively). Increasing metal precursor concentration increased the metal content of the created sorbents, but pollutant removal performance and usable surface area declined due to pore blockage and nanoparticle agglomeration. An acid-post rinse was required for Fe-WBAX to restore chromium removal capacity. Anticipatory life cycle assessment identified critical design constraints to improve environmental and human health performance like minimizing oven heating time, improving pollutant removal capacity, and efficiently reusing metal precursor solution. The life cycle environmental impact of Ti-WBAX was lower than Fe-WBAX as well as a mixed bed of WBAX and granular ferric hydroxide for all studied categories. A separate life cycle assessment found the total number of cancer and non-cancer cases prevented by drinking safer water outweighed those created by manufacture and use of water treatment materials and energy. However, treatment relocated who bore the health risk, concentrated it in a sub-population, and changed the primary manifestation from cancer to non-cancer disease. This tradeoff was partially mitigated by avoiding use of pH control chemicals. When properly synthesized, Fe-WBAX and Ti-WBAX sorbents maintained chromium removal capacity while significantly increasing arsenic removal capacity compared to the parent resin. The hybrid sorbent performance was demonstrated in packed beds using a challenging water matrix and low pollutant influent conditions. Breakthrough curves hint that the hexavalent chromium is removed by anion exchange and the arsenic is removed by metal oxide sorption. Overall, the hybrid nano-sorbent synthesis methods increased sustainability, improved sorbent characteristics, and increased simultaneous removal of chromium and arsenic for drinking water.
ContributorsGifford, James McKay (Author) / Westerhoff, Paul (Thesis advisor) / Hristovski, Kiril (Thesis advisor) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2016