Matching Items (17)
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- All Subjects: Materials Science
- Genre: Masters Thesis
- Creators: Mobasher, Barzin
- Creators: Wang, Liping
Description
Alkali-activated aluminosilicates, commonly known as "geopolymers", are being increasingly studied as a potential replacement for Portland cement. These binders use an alkaline activator, typically alkali silicates, alkali hydroxides or a combination of both along with a silica-and-alumina rich material, such as fly ash or slag, to form a final product with properties comparable to or better than those of ordinary Portland cement. The kinetics of alkali activation is highly dependent on the chemical composition of the binder material and the activator concentration. The influence of binder composition (slag, fly ash or both), different levels of alkalinity, expressed using the ratios of Na2O-to-binders (n) and activator SiO2-to-Na2O ratios (Ms), on the early age behavior in sodium silicate solution (waterglass) activated fly ash-slag blended systems is discussed in this thesis. Optimal binder composition and the n values are selected based on the setting times. Higher activator alkalinity (n value) is required when the amount of slag in the fly ash-slag blended mixtures is reduced. Isothermal calorimetry is performed to evaluate the early age hydration process and to understand the reaction kinetics of the alkali activated systems. The differences in the calorimetric signatures between waterglass activated slag and fly ash-slag blends facilitate an understanding of the impact of the binder composition on the reaction rates. Kinetic modeling is used to quantify the differences in reaction kinetics using the Exponential as well as the Knudsen method. The influence of temperature on the reaction kinetics of activated slag and fly ash-slag blends based on the hydration parameters are discussed. Very high compressive strengths can be obtained both at early ages as well as later ages (more than 70 MPa) with waterglass activated slag mortars. Compressive strength decreases with the increase in the fly ash content. A qualitative evidence of leaching is presented through the electrical conductivity changes in the saturating solution. The impact of leaching and the strength loss is found to be generally higher for the mixtures made using a higher activator Ms and a higher n value. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) is used to obtain information about the reaction products.
ContributorsChithiraputhiran, Sundara Raman (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniyam D (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2012
Description
The alkali activation of aluminosilicate materials as binder systems derived from industrial byproducts have been extensively studied due to the advantages they offer in terms enhanced material properties, while increasing sustainability by the reuse of industrial waste and byproducts and reducing the adverse impacts of OPC production. Fly ash and ground granulated blast furnace slag are commonly used for their content of soluble silica and aluminate species that can undergo dissolution, polymerization with the alkali, condensation on particle surfaces and solidification. The following topics are the focus of this thesis: (i) the use of microwave assisted thermal processing, in addition to heat-curing as a means of alkali activation and (ii) the relative effects of alkali cations (K or Na) in the activator (powder activators) on the mechanical properties and chemical structure of these systems. Unsuitable curing conditions instigate carbonation, which in turn lowers the pH of the system causing significant reductions in the rate of fly ash activation and mechanical strength development. This study explores the effects of sealing the samples during the curing process, which effectively traps the free water in the system, and allows for increased aluminosilicate activation. The use of microwave-curing in lieu of thermal-curing is also studied in order to reduce energy consumption and for its ability to provide fast volumetric heating. Potassium-based powder activators dry blended into the slag binder system is shown to be effective in obtaining very high compressive strengths under moist curing conditions (greater than 70 MPa), whereas sodium-based powder activation is much weaker (around 25 MPa). Compressive strength decreases when fly ash is introduced into the system. Isothermal calorimetry is used to evaluate the early hydration process, and to understand the reaction kinetics of the alkali powder activated systems. A qualitative evidence of the alkali-hydroxide concentration of the paste pore solution through the use of electrical conductivity measurements is also presented, with the results indicating the ion concentration of alkali is more prevalent in the pore solution of potassium-based systems. The use of advanced spectroscopic and thermal analysis techniques to distinguish the influence of studied parameters is also discussed.
ContributorsChowdhury, Ussala (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramanium D. (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2013
Description
Concrete design has recently seen a shift in focus from prescriptive specifications to performance based specifications with increasing demands for sustainable products. Fiber reinforced composites (FRC) provides unique properties to a material that is very weak under tensile loads. The addition of fibers to a concrete mix provides additional ductility and reduces the propagation of cracks in the concrete structure. It is the fibers that bridge the crack and dissipate the incurred strain energy in the form of a fiber-pullout mechanism. The addition of fibers plays an important role in tunnel lining systems and in reducing shrinkage cracking in high performance concretes. The interest in most design situations is the load where cracking first takes place. Typically the post crack response will exhibit either a load bearing increase as deflection continues, or a load bearing decrease as deflection continues. These behaviors are referred to as strain hardening and strain softening respectively. A strain softening or hardening response is used to model the behavior of different types of fiber reinforced concrete and simulate the experimental flexural response. Closed form equations for moment-curvature response of rectangular beams under four and three point loading in conjunction with crack localization rules are utilized. As a result, the stress distribution that considers a shifting neutral axis can be simulated which provides a more accurate representation of the residual strength of the fiber cement composites. The use of typical residual strength parameters by standards organizations ASTM, JCI and RILEM are examined to be incorrect in their linear elastic assumption of FRC behavior. Finite element models were implemented to study the effects and simulate the load defection response of fiber reinforced shotcrete round discrete panels (RDP's) tested in accordance with ASTM C-1550. The back-calculated material properties from the flexural tests were used as a basis for the FEM material models. Further development of FEM beams were also used to provide additional comparisons in residual strengths of early age samples. A correlation between the RDP and flexural beam test was generated based a relationship between normalized toughness with respect to the newly generated crack surfaces. A set of design equations are proposed using a residual strength correction factor generated by the model and produce the design moment based on specified concrete slab geometry.
ContributorsBarsby, Christopher (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2011
Description
Ultra-concealable multi-threat body armor used by law-enforcement is a multi-purpose armor that protects against attacks from knife, spikes, and small caliber rounds. The design of this type of armor involves fiber-resin composite materials that are flexible, light, are not unduly affected by environmental conditions, and perform as required. The National Institute of Justice (NIJ) characterizes this type of armor as low-level protection armor. NIJ also specifies the geometry of the knife and spike as well as the strike energy levels required for this level of protection. The biggest challenges are to design a thin, lightweight and ultra-concealable armor that can be worn under street clothes. In this study, several fundamental tasks involved in the design of such armor are addressed. First, the roles of design of experiments and regression analysis in experimental testing and finite element analysis are presented. Second, off-the-shelf materials available from international material manufacturers are characterized via laboratory experiments. Third, the calibration process required for a constitutive model is explained through the use of experimental data and computer software. Various material models in LS-DYNA for use in the finite element model are discussed. Numerical results are generated via finite element simulations and are compared against experimental data thus establishing the foundation for optimizing the design.
ContributorsVokshi, Erblina (Author) / Rajan, Subramaniam D. (Thesis advisor) / Neithalath, Narayanan (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2012
Description
Vanadium-dioxide-based devices show great switchability in their optical properties due to its dramatic thermochromic phase transition from insulator to metal, but generally have concerns due to its relatively high transition temperature at 68 °C. Doping the vanadium dioxide with tungsten has been shown to reduce its transition temperature at the cost lower optical property differences between its insulating and metallic phases. A recipe is developed through parametric experimentation to fabricate tungsten-doped vanadium dioxide consisting of a novel dual target co-sputtering deposition, a furnace oxidation process, and a post-oxidation annealing process. The transmittance spectra of the resulting films are measured via Fourier-transform infrared spectroscopy at different temperatures to confirm the lowered transition temperature and analyze their thermal-optical hysteresis behavior through the transition temperature range. Afterwards, the optical properties of undoped sputtered vanadium films are modeled and effective medium theory is used to explain the effect of tungsten dopants on the observed transmittance decrease of doped vanadium dioxide. The optical modeling is used to predict the performance of tungsten-doped vanadium dioxide devices, in particular a Fabry-Perot infrared emitter and a nanophotonic infrared transmission filter. Both devices show great promise in their optical properties despite a slight performance decrease from the tungsten doping. These results serve to illustrate the excellent performance of the co-sputtered tungsten-doped vanadium dioxide films.
ContributorsChao, Jeremy (Author) / Wang, Liping (Thesis advisor) / Wang, Robert (Committee member) / Tongay, Sefaattin (Committee member) / Arizona State University (Publisher)
Created2022
Description
Concrete develops strength rapidly after mixing and is highly influenced by temperature and curing process. The material characteristics and the rate of property development, along with the exposure conditions influences volume change mechanisms in concrete, and the cracking propensity of the mixtures. Furthermore, the structure geometry (due to restraint as well as the surface area-to-volume ratio) also influences shrinkage and cracking. Thus, goal of this research is to better understand and predict shrinkage cracking in concrete slab systems under different curing conditions. In this research, different concrete mixtures are evaluated on their propensity to shrink based on free shrinkage and restrained shrinkage tests.Furthermore, from the data obtained from restrained ring test, a casted slab is measured for shrinkage. Effects of different orientation of restraints are studied and compared to better understand the shrinking behavior of the concrete mixtures. The results show that the maximum shrinkage is near the edges of the slab and decreases towards the center. Shrinkage near the edges with no restraint is found out to be more than the shrinkage towards the edges with restraining effects.
ContributorsNimbalkar, Atharwa Samir (Author) / Neithalath, Narayanan (Thesis advisor) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam (Committee member) / Arizona State University (Publisher)
Created2023
Description
This research summarizes the validation testing completed for the material model MAT213, currently implemented in the LS-DYNA finite element program. Testing was carried out using a carbon fiber composite material, T800-F3900. Stacked-ply tension and compression tests were performed for open-hole and full coupons. Comparisons of experimental and simulation results showed a good agreement between the two for metrics including, stress-strain response and displacements. Strains and displacements in the direction of loading were better predicted by the simulations than for that of the transverse direction.
Double cantilever beam and end notched flexure tests were performed experimentally and through simulations to determine the delamination properties of the material at the interlaminar layers. Experimental results gave the mode I critical energy release rate as having a range of 2.18 – 3.26 psi-in and the mode II critical energy release rate as 10.50 psi-in, both for the pre-cracked condition. Simulations were performed to calibrate other cohesive zone parameters required for modeling.
Samples of tested T800/F3900 coupons were processed and examined with scanning electron microscopy to determine and understand the underlying structure of the material. Tested coupons revealed damage and failure occurring at the micro scale for the composite material.
Double cantilever beam and end notched flexure tests were performed experimentally and through simulations to determine the delamination properties of the material at the interlaminar layers. Experimental results gave the mode I critical energy release rate as having a range of 2.18 – 3.26 psi-in and the mode II critical energy release rate as 10.50 psi-in, both for the pre-cracked condition. Simulations were performed to calibrate other cohesive zone parameters required for modeling.
Samples of tested T800/F3900 coupons were processed and examined with scanning electron microscopy to determine and understand the underlying structure of the material. Tested coupons revealed damage and failure occurring at the micro scale for the composite material.
ContributorsHolt, Nathan T (Author) / Rajan, Subramaniam D. (Thesis advisor) / Mobasher, Barzin (Committee member) / Hoover, Christian (Committee member) / Arizona State University (Publisher)
Created2018
Description
This thesis explores the possibility of fabricating superconducting tunnel junctions (STJ) using double angle evaporation using an E-beam system. The traditional method of making STJs use a shadow mask to deposit two films requires the breaking of the vacuum of the main chamber. This technique has given bad results and proven to be a tedious process. To improve on this technique, the E-beam system was modified by adding a load lock and transfer line to perform the multi-angle deposition and in situ oxidation in the load lock without breaking the vacuum of the main chamber. Bilayer photolithography process was used to prepare a pattern for double angle deposition for the STJ. The overlap length could be easily controlled by varying the deposition angles. The low-temperature resistivity measurement and scanning electron microscope (SEM) characterization showed that the deposited films were good. However, I-V measurement for tunnel junction did not give expected results for the quality of the fabricated STJs. The main objective of modifying the E-beam system for multiple angle deposition was achieved. It can be used for any application that requires angular deposition. The motivation for the project was to set up a system that can fabricate a device that can be used as a phonon spectrometer for phononic crystals. Future work will include improving the quality of the STJ and fabricating an STJs on both sides of a silicon substrate using a 4-angle deposition.
ContributorsRana, Ashish (Author) / Wang, Robert Y (Thesis advisor) / Newman, Nathan (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2019
Description
A comprehensive study was performed on non-proprietary ultra-high-performance concrete (UHPC) material and several design methods were suggested based on numerous experimental results. Several sets of compression tests, direct tensile tests, and flexural tests were performed on UHPC to provide a better understanding of the mechanisms involved in the mechanical behavior of the fiber reinforced material. In addition to compressive tests, flexural tests, based on ASTM C1609 and EN 14651, were performed. The effect of the strain rate on the UHPC material was also investigated through the high-speed tensile tests at different strain rates. Alongside the usual measurement tools such as linear variable differential transformers (LVDT) and clip gages, digital image correlation (DIC) method was also used to capture the full-range deformations in the samples and localized crack propagations. Analytical approaches were suggested, based on the experimental results of the current research and other research groups, to provide design solutions for different applications and design approaches for UHPC and hybrid reinforced concrete (HRC) sections. The suggested methods can be used both in the ultimate limit state (ULS) and the serviceability limit state (SLS) design methods. Closed form relationships, based on the non-linear design of reinforced concrete, were used in the calculation of the load-deflection response of UHPC. The procedures were used in obtaining material properties from the flexural data using procedures that are based on back-calculation of material properties from the experimental results. Model simulations were compared with other results available in the literature. Performance of flexural reinforced UHPC concrete beam sections tested under different types of loading was addressed using a combination of fibers and rebars. The same analytical approach was suggested for the fiber reinforced concrete (FRC) sections strengthened (rehabilitated) by fiber reinforced polymers (FRP) and textile reinforced concrete (TRC). The objective is to validate the proper design procedures for flexural members as well as connection elements. The proposed solutions can be used to reduce total reinforcement by means of increasing the ductility of the FRC, HRC, and UHPC members in order to meet the required flexural reinforcement, which in some cases leads to total elimination of rebars.
ContributorsKianmofrad, Farrokh (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam Dharma (Committee member) / Hoover, Christian G. (Committee member) / Arizona State University (Publisher)
Created2018
Description
Demand for green energy alternatives to provide stable and reliable energy
solutions has increased over the years which has led to the rapid expansion of global
markets in renewable energy sources such as solar photovoltaic (PV) technology. Newest
amongst these technologies is the Bifacial PV modules, which harvests incident radiation
from both sides of the module. The overall power generation can be significantly increased
by using these bifacial modules. The purpose of this research is to investigate and maximize
the effect of back reflectors, designed to increase the efficiency of the module by utilizing
the intercell light passing through the module to increase the incident irradiance, on the
energy output using different profiles placed at varied distances from the plane of the array
(POA). The optimum reflector profile and displacement of the reflector from the module
are determined experimentally.
Theoretically, a 60-cell bifacial module can produce 26% additional energy in
comparison to a 48-cell bifacial module due to the 12 excess cells found in the 60-cell
module. It was determined that bifacial modules have the capacity to produce additional
energy when optimized back reflectors are utilized. The inverted U reflector produced
higher energy gain when placed at farther distances from the module, indicating direct
dependent proportionality between the placement distance of the reflector from the module
and the output energy gain. It performed the best out of all current construction geometries
with reflective coatings, generating more than half of the additional energy produced by a
densely-spaced 60-cell benchmark module compared to a sparsely-spaced 48-cell reference
module.ii
A gain of 11 and 14% was recorded on cloudy and sunny days respectively for the
inverted U reflector. This implies a reduction in the additional cells of the 60-cell module
by 50% can produce the same amount of energy of the 60-cell module by a 48-cell module
with an inverted U reflector. The use of the back reflectors does not only affect the
additional energy gain but structural and land costs. Row to row spacing for bifacial
systems(arrays) is reduced nearly by half as the ground height clearance is largely
minimized, thus almost 50% of height constraints for mounting bifacial modules, using
back reflectors resulting in reduced structural costs for mounting of bifacial modules
solutions has increased over the years which has led to the rapid expansion of global
markets in renewable energy sources such as solar photovoltaic (PV) technology. Newest
amongst these technologies is the Bifacial PV modules, which harvests incident radiation
from both sides of the module. The overall power generation can be significantly increased
by using these bifacial modules. The purpose of this research is to investigate and maximize
the effect of back reflectors, designed to increase the efficiency of the module by utilizing
the intercell light passing through the module to increase the incident irradiance, on the
energy output using different profiles placed at varied distances from the plane of the array
(POA). The optimum reflector profile and displacement of the reflector from the module
are determined experimentally.
Theoretically, a 60-cell bifacial module can produce 26% additional energy in
comparison to a 48-cell bifacial module due to the 12 excess cells found in the 60-cell
module. It was determined that bifacial modules have the capacity to produce additional
energy when optimized back reflectors are utilized. The inverted U reflector produced
higher energy gain when placed at farther distances from the module, indicating direct
dependent proportionality between the placement distance of the reflector from the module
and the output energy gain. It performed the best out of all current construction geometries
with reflective coatings, generating more than half of the additional energy produced by a
densely-spaced 60-cell benchmark module compared to a sparsely-spaced 48-cell reference
module.ii
A gain of 11 and 14% was recorded on cloudy and sunny days respectively for the
inverted U reflector. This implies a reduction in the additional cells of the 60-cell module
by 50% can produce the same amount of energy of the 60-cell module by a 48-cell module
with an inverted U reflector. The use of the back reflectors does not only affect the
additional energy gain but structural and land costs. Row to row spacing for bifacial
systems(arrays) is reduced nearly by half as the ground height clearance is largely
minimized, thus almost 50% of height constraints for mounting bifacial modules, using
back reflectors resulting in reduced structural costs for mounting of bifacial modules
ContributorsMARTIN, PEDRO JESSE (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2019