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Description
Haiti has witnessed high deforestation rates in recent decades, caused largely by the fuel needs of a growing population. The resulting soil loss is estimated to have contributed towards a decline in agricultural productivity of 0.5% -1.2% per year since 1997. Recent studies show the potential of biochar use through

Haiti has witnessed high deforestation rates in recent decades, caused largely by the fuel needs of a growing population. The resulting soil loss is estimated to have contributed towards a decline in agricultural productivity of 0.5% -1.2% per year since 1997. Recent studies show the potential of biochar use through pyrolysis technology to increase crop yields and improve soil health. However, the appropriateness of this technology in the context of Haiti remains unexplored. The three objectives of this research were to identify agricultural- and fuel-use-related needs and gaps in rural Haitian communities; determine the appropriateness of biochar pyrolyzer technology, used to convert agricultural biomass into a carbon-rich charcoal; and develop an action-oriented plan for use by development organizations, communities, and governmental institutions to increase the likelihood of adoption. Data were collected using participatory rural appraisal techniques involving 30 individual interviews and three focus-group discussions in the villages of Cinquantin and La Boule in the La Coupe region of central Haiti. Topics discussed include agricultural practices and assets, fuel use and needs, technology use and adoption, and social management practices. The Sustainable Livelihoods framework was used to examine the assets of households and the livelihood strategies being employed. Individual and focus group interviews were analyzed to identify specific needs and gaps. E.M. Rogers' Diffusion of Innovations theory was used to develop potential strategies for the introduction of pyrolysis technology. Preliminary results indicate biochar pyrolysis has potential to address agricultural and fuel needs in rural Haiti. Probable early adopters of biochar technology include households that have adopted new agricultural techniques in the past, and those with livestock. Education about biochar, and a variety of pyrolysis technology options from which villagers may select, are important factors in successful adoption of biochar use. A grain mill as an example in one of the study villages provides a model of ownership and use of pyrolysis technology that may increase its likelihood of successful adoption. Additionally, women represent a group that may be well suited to control a new local biochar enterprise, potentially benefiting the community.
ContributorsDelaney, Michael Ryan (Author) / Aggarwal, Rimjhim (Thesis advisor) / Chhetri, Nalini (Committee member) / Henderson, Mark (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Second-generation biofuel feedstocks are currently grown in land-based systems that use valuable resources like water, electricity and fertilizer. This study investigates the potential of near-shore marine (ocean) seawater filtration as a source of planktonic biomass for biofuel production. Mixed marine organisms in the size range of 20µm to 500µm were

Second-generation biofuel feedstocks are currently grown in land-based systems that use valuable resources like water, electricity and fertilizer. This study investigates the potential of near-shore marine (ocean) seawater filtration as a source of planktonic biomass for biofuel production. Mixed marine organisms in the size range of 20µm to 500µm were isolated from the University of California, Santa Barbara (UCSB) seawater filtration system during weekly backwash events between the months of April and August, 2011. The quantity of organic material produced was determined by sample combustion and calculation of ash-free dry weights. Qualitative investigation required density gradient separation with the heavy liquid sodium metatungstate followed by direct transesterification and gas chromatography with mass spectrometry (GC-MS) of the fatty acid methyl esters (FAME) produced. A maximum of 0.083g/L of dried organic material was produced in a single backwash event and a study average of 0.036g/L was calculated. This equates to an average weekly value of 7,674.75g of dried organic material produced from the filtration of approximately 24,417,792 liters of seawater. Temporal variations were limited. Organic quantities decreased over the course of the study. Bio-fouling effects from mussel overgrowth inexplicably increased production values when compared to un-fouled seawater supply lines. FAMEs (biodiesel) averaged 0.004% of the dried organic material with 0.36ml of biodiesel produced per week, on average. C16:0 and C22:6n3 fatty acids comprised the majority of the fatty acids in the samples. Saturated fatty acids made up 30.71% to 44.09% and unsaturated forms comprised 55.90% to 66.32% of the total chemical composition. Both quantities and qualities of organics and FAMEs were unrealistic for use as biodiesel but sample size limitations, system design, geographic and temporal factors may have impacted study results.
ContributorsPierre, Christophe (Author) / Olson, Larry (Thesis advisor) / Sommerfeld, Milton (Committee member) / Brown, Albert (Committee member) / Arizona State University (Publisher)
Created2011
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Description
While much effort in Stirling engine development is placed on making the high-temperature region of the Stirling engine warmer, this research explores methods to lower the temperature of the cold region by improving heat transfer in the cooler. This paper presents heat transfer coefficients obtained for a Stirling engine heat

While much effort in Stirling engine development is placed on making the high-temperature region of the Stirling engine warmer, this research explores methods to lower the temperature of the cold region by improving heat transfer in the cooler. This paper presents heat transfer coefficients obtained for a Stirling engine heat exchanger with oscillatory flow. The effects of oscillating frequency and input heat rate on the heat transfer coefficients are evaluated and details on the design and development of the heat exchanger test apparatus are also explained. Featured results include the relationship between overall heat transfer coefficients and oscillation frequency which increase from 21.5 to 46.1 Wm-2K-1 as the oscillation frequency increases from 6.0 to 19.3 Hz. A correlation for the Nusselt number on the inside of the heat exchange tubes in oscillatory flow is presented in a concise, dimensionless form in terms of the kinetic Reynolds number as a result of a statistical analysis. The test apparatus design is proven to be successful throughout its implementation due to the usefulness of data and clear trends observed. The author is not aware of any other publicly-available research on a Stirling engine cooler to the extent presented in this paper. Therefore, the present results are analyzed on a part-by-part basis and compared to segments of other research; however, strong correlations with data from other studies are not expected. The data presented in this paper are part of a continuing effort to better understand heat transfer properties in Stirling engines as well as other oscillating flow applications.
ContributorsEppard, Erin (Author) / Phelan, Patrick (Thesis advisor) / Trimble, Steve (Committee member) / Calhoun, Ronald (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Multiphase flows are an important part of many natural and technological phe- nomena such as ocean-air coupling (which is important for climate modeling) and the atomization of liquid fuel jets in combustion engines. The unique challenges of multiphase flow often make analytical solutions to the governing equations impos- sible and

Multiphase flows are an important part of many natural and technological phe- nomena such as ocean-air coupling (which is important for climate modeling) and the atomization of liquid fuel jets in combustion engines. The unique challenges of multiphase flow often make analytical solutions to the governing equations impos- sible and experimental investigations very difficult. Thus, high-fidelity numerical simulations can play a pivotal role in understanding these systems. This disserta- tion describes numerical methods developed for complex multiphase flows and the simulations performed using these methods. First, the issue of multiphase code verification is addressed. Code verification answers the question "Is this code solving the equations correctly?" The method of manufactured solutions (MMS) is a procedure for generating exact benchmark solutions which can test the most general capabilities of a code. The chief obstacle to applying MMS to multiphase flow lies in the discontinuous nature of the material properties at the interface. An extension of the MMS procedure to multiphase flow is presented, using an adaptive marching tetrahedron style algorithm to compute the source terms near the interface. Guidelines for the use of the MMS to help locate coding mistakes are also detailed. Three multiphase systems are then investigated: (1) the thermocapillary motion of three-dimensional and axisymmetric drops in a confined apparatus, (2) the flow of two immiscible fluids completely filling an enclosed cylinder and driven by the rotation of the bottom endwall, and (3) the atomization of a single drop subjected to a high shear turbulent flow. The systems are simulated numerically by solving the full multiphase Navier- Stokes equations coupled to the various equations of state and a level set interface tracking scheme based on the refined level set grid method. The codes have been parallelized using MPI in order to take advantage of today's very large parallel computational architectures. In the first system, the code's ability to handle surface tension and large tem- perature gradients is established. In the second system, the code's ability to sim- ulate simple interface geometries with strong shear is demonstrated. In the third system, the ability to handle extremely complex geometries and topology changes with strong shear is shown.
ContributorsBrady, Peter, Ph.D (Author) / Herrmann, Marcus (Thesis advisor) / Lopez, Juan (Thesis advisor) / Adrian, Ronald (Committee member) / Calhoun, Ronald (Committee member) / Chen, Kangping (Committee member) / Arizona State University (Publisher)
Created2011
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Description
A new method of adaptive mesh generation for the computation of fluid flows is investigated. The method utilizes gradients of the flow solution to adapt the size and stretching of elements or volumes in the computational mesh as is commonly done in the conventional Hessian approach. However, in

A new method of adaptive mesh generation for the computation of fluid flows is investigated. The method utilizes gradients of the flow solution to adapt the size and stretching of elements or volumes in the computational mesh as is commonly done in the conventional Hessian approach. However, in the new method, higher-order gradients are used in place of the Hessian. The method is applied to the finite element solution of the incompressible Navier-Stokes equations on model problems. Results indicate that a significant efficiency benefit is realized.
ContributorsShortridge, Randall (Author) / Chen, Kang Ping (Thesis advisor) / Herrmann, Marcus (Thesis advisor) / Wells, Valana (Committee member) / Huang, Huei-Ping (Committee member) / Mittelmann, Hans (Committee member) / Arizona State University (Publisher)
Created2011
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Description
The focus of this investigation is on the renewed assessment of nonlinear reduced order models (ROM) for the accurate prediction of the geometrically nonlinear response of a curved beam. In light of difficulties encountered in an earlier modeling effort, the various steps involved in the construction of the reduced order

The focus of this investigation is on the renewed assessment of nonlinear reduced order models (ROM) for the accurate prediction of the geometrically nonlinear response of a curved beam. In light of difficulties encountered in an earlier modeling effort, the various steps involved in the construction of the reduced order model are carefully reassessed. The selection of the basis functions is first addressed by comparison with the results of proper orthogonal decomposition (POD) analysis. The normal basis functions suggested earlier, i.e. the transverse linear modes of the corresponding flat beam, are shown in fact to be very close to the POD eigenvectors of the normal displacements and thus retained in the present effort. A strong connection is similarly established between the POD eigenvectors of the tangential displacements and the dual modes which are accordingly selected to complement the normal basis functions. The identification of the parameters of the reduced order model is revisited next and it is observed that the standard approach for their identification does not capture well the occurrence of snap-throughs. On this basis, a revised approach is proposed which is assessed first on the static, symmetric response of the beam to a uniform load. A very good to excellent matching between full finite element and ROM predicted responses validates the new identification procedure and motivates its application to the dynamic response of the beam which exhibits both symmetric and antisymmetric motions. While not quite as accurate as in the static case, the reduced order model predictions match well their full Nastran counterparts and support the reduced order model development strategy.
ContributorsZhang, Yaowen (Author) / Mignolet, Marc P (Thesis advisor) / Davidson, Joseph (Committee member) / Spottswood, Stephen M (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Processed pyro-gel contains castor oil with solid component of boehmite (Al-OOH). The pyro-gel is synthesized by heat to convert boehmite to gamma-Al2O3 and to a certain extent alpha-Al2O3 nano-particles and castor oil into carbon residue. The effect of heat on pyro-gel is analyzed in a series of experiments using two

Processed pyro-gel contains castor oil with solid component of boehmite (Al-OOH). The pyro-gel is synthesized by heat to convert boehmite to gamma-Al2O3 and to a certain extent alpha-Al2O3 nano-particles and castor oil into carbon residue. The effect of heat on pyro-gel is analyzed in a series of experiments using two burning chambers with the initial temperature as the main factor. The obtained temperature distribution profiles are studied and it is observed that the gel behaves very close to the theoretical prediction under heat. The carbon residue with Al2O3 is then processed for twelve hours and then analyzed to obtain the pore distribution of the Al2O3 nano-particles and the relation between the pore volume and the pre-heat temperature is analyzed. The obtained pore distribution shows the pore volume of Al2O3 nano-particles has direct relation to the pre-heat temperature. The experimental process involving the cylindrical reactor is simulated by using a finite rate chemistry eddy-dissipation model in a non-premixed and a porous mesh. The temperature distribution profile of the processed gel for both the meshes is obtained and a comparison is done with the data obtained in the experimental analysis. The temperature distribution obtained from the simulations show they follow a very similar profile to the temperature distribution obtained from experimental analysis, thus confirming the accuracy of both the models. The variation in numerical values between the experimental and simulation analysis is discussed. A physical model is proposed to determine the pore formation based on the temperature distribution obtained from experimental analysis and simulation.
ContributorsSagi, Varun (Author) / Lee, Taewoo (Thesis advisor) / Phelan, Patrick (Committee member) / Chen, Kangping (Committee member) / Arizona State University (Publisher)
Created2010
Description
The focus of this research is to investigate methods for material substitution for the purpose of re-engineering legacy systems that involves incomplete information about form, fit and function of replacement parts. The primary motive is to extract as much useful information about a failed legacy part as possible and use

The focus of this research is to investigate methods for material substitution for the purpose of re-engineering legacy systems that involves incomplete information about form, fit and function of replacement parts. The primary motive is to extract as much useful information about a failed legacy part as possible and use fuzzy logic rules for identifying the unknown parameter values. Machine elements can fail by any number of failure modes but the most probable failure modes based on the service condition are considered critical failure modes. Three main parameters are of key interest in identifying the critical failure mode of the part. Critical failure modes are then directly mapped to material properties. Target material property values are calculated from material property values obtained from the originally used material and from the design goals. The material database is searched for new candidate materials that satisfy the goals and constraints in manufacturing and raw stock availability. Uncertainty in the extracted data is modeled using fuzzy logic. Fuzzy member functions model the imprecise nature of data in each available parameter and rule sets characterize the imprecise dependencies between the parameters and makes decisions in identifying the unknown parameter value based on the incompleteness. A final confidence level for each material in a pool of candidate material is a direct indication of uncertainty. All the candidates satisfy the goals and constraints to varying degrees and the final selection is left to the designer's discretion. The process is automated by software that inputs incomplete data; uses fuzzy logic to extract more information and queries the material database with a constrained search for finding candidate alternatives.
ContributorsBalaji, Srinath (Author) / Shah, Jami (Thesis advisor) / Davidson, Joseph (Committee member) / Huebner, Kenneth (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Many methods of passive flow control rely on changes to surface morphology. Roughening surfaces to induce boundary layer transition to turbulence and in turn delay separation is a powerful approach to lowering drag on bluff bodies. While the influence in broad terms of how roughness and other means of passive

Many methods of passive flow control rely on changes to surface morphology. Roughening surfaces to induce boundary layer transition to turbulence and in turn delay separation is a powerful approach to lowering drag on bluff bodies. While the influence in broad terms of how roughness and other means of passive flow control to delay separation on bluff bodies is known, basic mechanisms are not well understood. Of particular interest for the current work is understanding the role of surface dimpling on boundary layers. A computational approach is employed and the study has two main goals. The first is to understand and advance the numerical methodology utilized for the computations. The second is to shed some light on the details of how surface dimples distort boundary layers and cause transition to turbulence. Simulations are performed of the flow over a simplified configuration: the flow of a boundary layer over a dimpled flat plate. The flow is modeled using an immersed boundary as a representation of the dimpled surface along with direct numerical simulation of the Navier-Stokes equations. The dimple geometry used is fixed and is that of a spherical depression in the flat plate with a depth-to-diameter ratio of 0.1. The dimples are arranged in staggered rows separated by spacing of the center of the bottom of the dimples by one diameter in both the spanwise and streamwise dimensions. The simulations are conducted for both two and three staggered rows of dimples. Flow variables are normalized at the inlet by the dimple depth and the Reynolds number is specified as 4000 (based on freestream velocity and inlet boundary layer thickness). First and second order statistics show the turbulent boundary layers correlate well to channel flow and flow of a zero pressure gradient flat plate boundary layers in the viscous sublayer and the buffer layer, but deviates further away from the wall. The forcing of transition to turbulence by the dimples is unlike the transition caused by a naturally transitioning flow, a small perturbation such as trip tape in experimental flows, or noise in the inlet condition for computational flows.
ContributorsGutierrez-Jensen, Jeremiah J (Author) / Squires, Kyle (Thesis advisor) / Hermann, Marcus (Committee member) / Gelb, Anne (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Consumer goods supply chains have gradually incorporated lean manufacturing principles to identify and reduce non-value-added activities. Companies implementing lean practices have experienced improvements in cost, quality, and demand responsiveness. However certain elements of these practices, especially those related to transportation and distribution may have detrimental impact on the environment. This

Consumer goods supply chains have gradually incorporated lean manufacturing principles to identify and reduce non-value-added activities. Companies implementing lean practices have experienced improvements in cost, quality, and demand responsiveness. However certain elements of these practices, especially those related to transportation and distribution may have detrimental impact on the environment. This study asks: What impact do current best practices in lean logistics and retailing have on environmental performance? The research hypothesis of this dissertation establishes that lean distribution of durable and consumable goods can result in an increased amount of carbon dioxide emissions, leading to climate change and natural resource depletion impacts, while lean retailing operations can reduce carbon emissions. Distribution and retailing phases of the life cycle are characterized in a two-echelon supply chain discrete-event simulation modeled after current operations from leading organizations based in the U.S. Southwest. By conducting an overview of critical sustainability issues and their relationship with consumer products, it is possible to address the environmental implications of lean logistics and retailing operations. Provided the waste reduction nature from lean manufacturing, four lean best practices are examined in detail in order to formulate specific research propositions. These propositions are integrated into an experimental design linking annual carbon dioxide equivalent emissions to: (1) shipment frequency between supply chain partners, (2) proximity between decoupling point of products and final customers, (3) inventory turns at the warehousing level, and (4) degree of supplier integration. All propositions are tested through the use of the simulation model. Results confirmed the four research propositions. Furthermore, they suggest synergy between product shipment frequency among supply chain partners and product management due to lean retailing practices. In addition, the study confirms prior research speculations about the potential carbon intensity from transportation operations subject to lean principles.
ContributorsUgarte Irizarri, Gustavo Marco Antonio (Author) / Golden, Jay S. (Thesis advisor) / Dooley, Kevin J. (Thesis advisor) / Boone, Christopher G. (Committee member) / Basile, George M. (Committee member) / Arizona State University (Publisher)
Created2011