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Description
Currently, consumers throw away products every day, turning those materials into waste. Electronic waste poses special problems when it is not recycled because it may contain toxic components that can leach into landfill surroundings and reach groundwater sources or contaminate soil, and its plastic, metal, and electronic materials do not

Currently, consumers throw away products every day, turning those materials into waste. Electronic waste poses special problems when it is not recycled because it may contain toxic components that can leach into landfill surroundings and reach groundwater sources or contaminate soil, and its plastic, metal, and electronic materials do not biodegrade and are lost rather than recycled. This study analyzes a system that attempts to solve the electronic post-consumer-waste problem by shifting the economic burden of disposal from local municipalities to producers, reducing its environmental impacts while promoting economic development. The system was created in British Columbia, Canada after the province enacted a recycling regulation based on Extended Producer Responsibility (EPR), a policy strategy that is fast growing globally. The BC recycling regulation requires all e-toy corporations in BC to comply with a government-approved product-stewardship program to recover and dispose of e-toys after they have been discarded by consumers. In response to the regulation, e-toy corporations joined a Canadian non-profit entity that recycles regulated waste. I conducted a case study using in-depth interviews with the stakeholders to identify the outcomes of this program and its potential for replication in other industries. I derived lessons from which corporations can learn to implement stewardship programs based on EPR regulations. The e-toy program demonstrated that creating exclusive programs is neither efficient nor economically feasible. Corporations should expect low recycling rates in the first phases of the program implementation because EPR regulations are long-term strategies. In order to reach any conclusions about the demand of consumers for recycling programs, we need to measure the program's return rates during at least three years. I also derived lessons that apply to the expansion of EPR regulations to a broader scope of product categories. The optimal way to expand EPR policy is to do it by gradually adding new product categories to the regulation on a long-term schedule. By doing so, new categories can take advantage of existing stewardship programs and their infrastructure to recover and recycle the post-consumer products. EPR proved to be an effective option to make corporations start thinking about the end of life of their products.
ContributorsNemer Soto, Andrea (Author) / Dooley, Kevin (Thesis advisor) / Basile, George (Committee member) / White, Philip (Committee member) / Arizona State University (Publisher)
Created2014
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Description
This thesis focused on physicochemical and electrochemical projects directed towards two electrolyte types: 1) class of ionic liquids serving as electrolytes in the catholyte for alkali-metal ion conduction in batteries and 2) gel membrane for proton conduction in fuel cells; where overall aims were encouraged by the U.S. Department of

This thesis focused on physicochemical and electrochemical projects directed towards two electrolyte types: 1) class of ionic liquids serving as electrolytes in the catholyte for alkali-metal ion conduction in batteries and 2) gel membrane for proton conduction in fuel cells; where overall aims were encouraged by the U.S. Department of Energy.

Large-scale, sodium-ion batteries are seen as global solutions to providing undisrupted electricity from sustainable, but power-fluctuating, energy production in the near future. Foreseen ideal advantages are lower cost without sacrifice of desired high-energy densities relative to present lithium-ion and lead-acid battery systems. Na/NiCl2 (ZEBRA) and Na/S battery chemistries, suffer from high operation temperature (>300ºC) and safety concerns following major fires consequent of fuel mixing after cell-separator rupturing. Initial interest was utilizing low-melting organic ionic liquid, [EMI+][AlCl4-], with well-known molten salt, NaAlCl4, to create a low-to-moderate operating temperature version of ZEBRA batteries; which have been subject of prior sodium battery research spanning decades. Isothermal conductivities of these electrolytes revealed a fundamental kinetic problem arisen from "alkali cation-trapping effect" yet relived by heat-ramping >140ºC.

Battery testing based on [EMI+][FeCl4-] with NaAlCl4 functioned exceptional (range 150-180ºC) at an impressive energy efficiency >96%. Newly prepared inorganic ionic liquid, [PBr4+][Al2Br7-]:NaAl2Br7, melted at 94ºC. NaAl2Br7 exhibited super-ionic conductivity 10-1.75 Scm-1 at 62ºC ensued by solid-state rotator phase transition. Also improved thermal stability when tested to 265ºC and less expensive chemical synthesis. [PBr4+][Al2Br7-] demonstrated remarkable, ionic decoupling in the liquid-state due to incomplete bromide-ion transfer depicted in NMR measurements.

Fuel cells are electrochemical devices generating electrical energy reacting hydrogen/oxygen gases producing water vapor. Principle advantage is high-energy efficiency of up to 70% in contrast to an internal combustion engine <40%. Nafion-based fuel cells are prone to carbon monoxide catalytic poisoning and polymer membrane degradation unless heavily hydrated under cell-pressurization. This novel "SiPOH" solid-electrolytic gel (originally liquid-state) operated in the fuel cell at 121oC yielding current and power densities high as 731mAcm-2 and 345mWcm-2, respectively. Enhanced proton conduction significantly increased H2 fuel efficiency to 89.7% utilizing only 3.1mlmin-1 under dry, unpressurized testing conditions. All these energy devices aforementioned evidently have future promise; therefore in early developmental stages.
ContributorsTucker, Telpriore G (Author) / Angell, Charles A. (Committee member) / Moore, Ana (Committee member) / Seo, Dong-Kyun (Committee member) / Arizona State University (Publisher)
Created2014
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Description
The rise of meat consumption in the United States has been dramatic over

the past half century due to demographic changes. The increase in meat is visible in Mexico as well due to expanding economic interest in cattle production plus increased population and rising incomes. The worst consequences of our modern

The rise of meat consumption in the United States has been dramatic over

the past half century due to demographic changes. The increase in meat is visible in Mexico as well due to expanding economic interest in cattle production plus increased population and rising incomes. The worst consequences of our modern food system are in factory farming of animals, which requires a greater amount of resources than for producing grains, fruits, and vegetables. The specific effects of meat consumption highlight the importance of understanding humans as actors in the food system. In order to explore the drivers of consumer food and meat choice, my research answered the two questions: What factors influence meat consumption? and How do cultural and social norms influence decisions to consume certain types and amounts of meat?

Qualitative interviews were conducted with Mexican-American respondents between age 20 and 29 as the population of interest because of their regional dominance in the study area of Tempe, AZ and because of the high prevalence of meat in their cultural diets. Looking at millennials in particular is crucial because as the first generation born with technology and Internet as constants, they have formed unique characteristics like openness to change and new perspectives. My sample population communicated motivations and constraints to their overall consumption patterns and the frequency and types of meat consumed.

This study found that cost and convenience were the driving factors behind food choice, given the hectic schedules of the sample population, who were mostly students at Arizona State University. Culture played an important role in respondents' heavy meat consumption given their exposure to meat's centrality in traditional Mexican meals. Acculturation did not play an extensive role because prominent Mexican culture in the Southwest U.S. allowed respondents' families access to traditional food while living in the US. The lack of sustainability knowledge and its connection to food choice indicates the importance of marketing that contextualizes decreased meat consumption. Rather than focusing solely on environmental outcomes, marketing tools highlighting health, financial, and economic benefits of eating less meat would encourage more consumers to decrease consumption.
ContributorsNamugayi, Deborah (Author) / Larson, Kelli L (Thesis advisor) / Klinsky, Sonja (Committee member) / Redman, Erin (Committee member) / Arizona State University (Publisher)
Created2014
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Description
The conflict conditions that afflict the livelihoods of Palestinian residents living in the West Bank are embedded within the population's ability to travel more so than any other routine activity. For Palestinian residents, domestic and international travel is a process of following paths riddled with multiple barriers that are

The conflict conditions that afflict the livelihoods of Palestinian residents living in the West Bank are embedded within the population's ability to travel more so than any other routine activity. For Palestinian residents, domestic and international travel is a process of following paths riddled with multiple barriers that are both physical and political. Past studies have done well to paint a clear picture of the harsh transportation landscape in the region. However, less attention has focused on how barriers interact to indirectly and directly affect levels of accessibility and well-being. Additionally, suggested development solutions are rarely capable of being successfully implemented given current political conditions. This dissertation uses a systems approach to understand drivers of accessibility challenges in the West Bank and uses the understanding to propose a method to identify transition strategies that may be presently initiated whilst maintaining the ability to provide adequate benefit. The research question informing the study asks, How do drivers influencing the issue of poor accessibility and well-being in the West Bank persist and interact, and how might solutions be approached? The dissertation approaches the question in four sequential actions that each produces a functional planning deliverable. First, a system map that depicts the drivers and influences to the problem of poor accessibility and well-being is constructed (Chapter 4). Second, a future vision for the transportation system in the West Bank is identified (Chapter 5). Third, the system map and vision are used to assess how conflict conditions affect transition research (Chapter 6). Finally, the previous three deliverables are used to suggest a guide for transition management for transportation development in the West Bank (Chapter 7). Combinations of four different data sets, including an extensive review of published literature, field observations, individual field expert interviews, and group commuter interviews inform the research. Additionally, the Transformational Sustainability Research framework provides a normative base for the steps taken throughout the research. Ultimately, the dissertation presents an interpretation of information that has theoretical and practical application potential in transformational sustainability research and development efforts in the region respectively.
ContributorsAhmad, Omaya Heidi (Author) / Golub, Aaron (Thesis advisor) / Aggarwal, Rimjhim (Committee member) / Saleh Sadaqa, Ahmad (Committee member) / Arizona State University (Publisher)
Created2015
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Description
This dissertation examines the nexus of three trends in electricity systems transformations underway worldwide—the scale-up of renewable energy, regionalization, and liberalization. Interdependent electricity systems are being envisioned that require partnership and integration across power disparities. This research explores how actors in the Mediterranean region envisioned a massive scale-up of renewable

This dissertation examines the nexus of three trends in electricity systems transformations underway worldwide—the scale-up of renewable energy, regionalization, and liberalization. Interdependent electricity systems are being envisioned that require partnership and integration across power disparities. This research explores how actors in the Mediterranean region envisioned a massive scale-up of renewable energy within a single electricity system and market across Europe, North Africa, and the Middle East. It asks: How are regional sociotechnical systems envisioned? What are the anticipated consequences of a system for a region with broad disparities and deep sociopolitical differences? What can be learned about energy justice by examining this vision at multiple scales? A sociotechnical systems framework is used to analyze energy transformations, interweaving the technical aspects with politics, societal effects, and political development issues. This research utilized mixed qualitative methods to analyze Mediterranean electricity transformations at multiple scales, including fieldwork in Morocco and Germany, document analysis, and event ethnography. Each scale—from a global history of concentrating solar power technologies to a small village in Morocco—provides a different lens on the sociotechnical system and its implications for justice. This study updates Thomas Hughes’ Networks of Power, the canonical history of the sociotechnical development of electricity systems, by adding new aspects to sociotechnical electricity systems theory. First, a visioning process now plays a crucial role in guiding innovation and has a lasting influence on the justice outcomes. Second, rather than simply providing people with heat and light, electrical power systems in the 21st century are called upon to address complex integrated solutions. Furthermore, building a sustainable energy system is now a retrofitting agenda, as system builders must graft new infrastructure on top of old systems. Third, the spatial and temporal aspects of sociotechnical energy systems should be amended to account for constructed geography and temporal complexity. Fourth, transnational electricity systems pose new challenges for politics and political development. Finally, this dissertation presents a normative framework for conceptualizing and evaluating energy justice. Multi-scalar, systems-level justice requires collating diverse ideas about energy justice, expanding upon them based on the empirical material, and evaluating them with this framework.
ContributorsMoore, Sharlissa (Author) / Hackett, Ed J. (Thesis advisor) / Minteer, Ben (Committee member) / Parmentier, Mary Jane (Committee member) / Wetmore, Jameson (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Targeted growth is necessary for sustainable urbanization. There is a pattern in China of rapid development due to inflated projections. This creates "ghost towns" and underutilized urban services that don't support the population.

In the case of Taiyuan, this industrial third-tier city of 4.2 million people. A majority of the newer

Targeted growth is necessary for sustainable urbanization. There is a pattern in China of rapid development due to inflated projections. This creates "ghost towns" and underutilized urban services that don't support the population.

In the case of Taiyuan, this industrial third-tier city of 4.2 million people. A majority of the newer residential services and high-end commercial areas are on the older, eastern side of the city. Since 2007, major urban investments have been made in developing the corridor that leads to the airport, including building a massive hospital, a new sports stadium, and "University City". The intention of the city officials is to encourage a new image of Taiyuan- one that is a tourist destination, one that has a high standard of living for residents. However, the consequences of these major developments might be immense, because of the required shift of community, residents and capital that would be required to sustain these new areas. Much of the new development lacks the reliable and frequent public transit of the more established downtown areas.

Do these investments in medical complexes, sports stadiums and massive shopping centers create new jobs that impact the income disparity, or do these new areas take years to fill, creating vacuums of investment that remove funding from areas with established communities? Can Taiyuan move successfully to a post-industrial economy with these government interventions, or is it too much too soon?

By examining demographic data from 2000, 2007, 2009, 2011, and 2013, research on sustainability assessments in Chinese cities (Lu Jia), and translated government publications detailing the urbanization efforts in Taiyuan, I will assess the results of the urbanization changes instituted by the new mayor, Geng Yanbo. My thesis will evaluate the success and failures of these policies and the implications for Taiyuan.
ContributorsDolins, Sarah-Laura (Author) / Webster, Douglas (Thesis advisor) / Golub, Aaron (Committee member) / Cai, Jianming (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Advancing sustainable food systems requires holistic understanding and solutions-oriented approaches that transcend disciplines, so expertise in a variety of subjects is necessary. Proposed solutions are usually technically or socially oriented, but disagreement over the best approach to the future of food dominates the dialogue. Technological optimists argue that scientific advances

Advancing sustainable food systems requires holistic understanding and solutions-oriented approaches that transcend disciplines, so expertise in a variety of subjects is necessary. Proposed solutions are usually technically or socially oriented, but disagreement over the best approach to the future of food dominates the dialogue. Technological optimists argue that scientific advances are necessary to feed the world, but environmental purists believe that reductions in consumption and waste are sufficient and less risky. Life cycle assessment (LCA) helps resolve debates through quantitative analysis of environmental impacts from products which serve the same function. LCA used to compare dietary choices reveals that simple plant-based diets are better for the environment than diets that include animal products. However, analysis of soy protein isolate (SPI) demonstrates that certain plant-based proteins may be less preferable for the environment than some unprocessed meats in several categories due to additional impacts that come from industrial processing. LCAs' focus on production risks ignoring consumers, but the food system exists to serve consumers, who can be major drivers of change. Therefore, the path to a sustainable food system requires addressing consumption issues as well. Existing methods for advancing sustainable food systems that equate more information with better behavior or performance are insufficient to create change. Addressing food system issues requires sufficient tacit knowledge to understand how arguments are framed, what the supporting content is, the findings of primary sources, and complex and controversial dialogue surrounding innovations and interventions for food system sustainability. This level of expertise is called interactional competence and it is necessary to drive and maintain holistic progress towards sustainability. Development strategies for interactional competence are informed by studying the motivations and strategies utilized by vegans. A new methodology helps advance understanding of expertise development by assessing levels of expertise and reveals insights into how vegans maintain commitment to a principle that influences their daily lives. The study of veganism and expertise reveals that while providing information to debunk fallacies is important, the development of tacit knowledge is fundamental to advance to a stage of competence.
ContributorsBerardy, Andrew (Author) / Seager, Thomas P (Thesis advisor) / Hannah, Mark (Committee member) / Costello, Christine (Committee member) / Landis, Amy (Committee member) / Wharton, Christopher (Christopher Mack), 1977- (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Social-ecological systems (SES) are replete with hard and soft human-made components (or infrastructures) that are consciously-designed to perform specific functions valued by humans. How these infrastructures mediate human-environment interactions is thus a key determinant of many sustainability problems in present-day SES. This dissertation examines the question of how some of

Social-ecological systems (SES) are replete with hard and soft human-made components (or infrastructures) that are consciously-designed to perform specific functions valued by humans. How these infrastructures mediate human-environment interactions is thus a key determinant of many sustainability problems in present-day SES. This dissertation examines the question of how some of the designed aspects of physical and social infrastructures influence the robustness of SES under global change. Due to the fragility of rural livelihood systems, locally-managed common-pool resource systems that depend on infrastructure, such as irrigated agriculture and community forestry, are of particular importance to address this sustainability question. This dissertation presents three studies that explored the robustness of communal irrigation and forestry systems to economic or environmental shocks. The first study examined how the design of irrigation infrastructure affects the robustness of system performance to an economic shock. Using a stylized dynamic model of an irrigation system as a testing ground, this study shows that changes in infrastructure design can induce fundamental changes in qualitative system behavior (i.e., regime shifts) as well as altered robustness characteristics. The second study explored how connectedness among social units (a kind of social infrastructure) influenced the post-failure transformations of large-N forest commons under economic globalization. Using inferential statistics, the second study argues that some attributes of the social connectedness that helped system robustness in the past made the system more vulnerable to undesirable transformations in the current era. The third study explored the question of how to guide adaptive management of SES for more robustness under uncertainty. This study used an existing laboratory behavioral experiment in which human-subjects tackle a decision problem on collective management of an irrigation system under environmental uncertainty. The contents of group communication and the decisions of individuals were analyzed to understand how configurations of learning-by-doing and other adaptability-related conditions may be causally linked to robustness under environmental uncertainty. The results show that robust systems are characterized by two conditions: active learning-by-doing through outer-loop processes, i.e., frequent updating of shared assumptions or goals that underlie specific group strategies, and frequent monitoring and reflection of past outcomes.
ContributorsYu, Jae Hoon David (Author) / Anderies, John M. (Thesis advisor) / Janssen, Marco A. (Committee member) / Muneepeerakul, Rachata (Committee member) / Arizona State University (Publisher)
Created2015
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Description
The need for alternative energy efficient building heating and cooling technologies has given rise to the development and widespread use of Ground Coupled Heat Pump (GCHP) systems. This dissertation looks at the feasibility of using GCHP systems as a viable economic alternative to traditional air source cooling systems (ASHP) for

The need for alternative energy efficient building heating and cooling technologies has given rise to the development and widespread use of Ground Coupled Heat Pump (GCHP) systems. This dissertation looks at the feasibility of using GCHP systems as a viable economic alternative to traditional air source cooling systems (ASHP) for conditioning buildings in the hot, semi-arid climate of Phoenix, Arizona. Despite high initial costs, GCHPs are gaining a foothold in northern climates where heating dominates, in large part due to government incentives. However, due to issues associated with low ground heat exchanger (GHE) efficiency and thermally-induced soil deformations, GCHPs are typically not considered a viable option in hot climates with deep groundwater and low permeability soil. To evaluate the energy performance and technical feasibility of GCHPs in Phoenix, the DOE 5,500 sq.ft small office, commercial building prototype was simulated in EnergyPlus to determine the cooling and heating loads. Next, a commercial software program, Ground Loop Design (GLD), was used to design and simulate the annual energy performance of both vertical (V-GCHPs) and horizontal GCHPs (H-GCHPs). Life cycle costs (LCC) were evaluated using realistic market costs both under dry, as well as fully saturated soil conditions (meant as an upper performance limit achievable by ground modification techniques). This analysis included performing several sensitivity analyses and also investigating the effect of financial rebates. The range of annual energy savings from the GCHP system for space cooling and heating was around 38-40% compared to ASHPs for dry soil. Saturated soil condition significantly affects the length of the GHE. For V-GCHPs, there was about 26% decrease in the length of GHE, thereby reducing the initial cost by 18-19% and decreasing the payback period by 24-25%. Likewise, for H-GCHPs, the length of GHE was reduced by 25% resulting in 22% and 39-42 % reduction in the initial cost and payback period respectively. With federal incentives, H-GCHPs under saturated soil conditions have the least LCC and a good payback periods of 2.3-4.7 years. V-GCHPs systems were been found to have payback periods of over 25 years, making them unfeasible for Phoenix, AZ, for the type of building investigated.
ContributorsTambe, Vaibhavi Parmanand (Author) / Reddy, T Agami (Thesis advisor) / Kavanzanjian, Edward (Thesis advisor) / Bryan, Harvey (Committee member) / Arizona State University (Publisher)
Created2014
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Description
A methodology is developed that integrates institutional analysis with Life Cycle Assessment (LCA) to identify and overcome barriers to sustainability transitions and to bridge the gap between environmental practitioners and decisionmakers. LCA results are rarely joined with analyses of the social systems that control or influence decisionmaking and policies. As

A methodology is developed that integrates institutional analysis with Life Cycle Assessment (LCA) to identify and overcome barriers to sustainability transitions and to bridge the gap between environmental practitioners and decisionmakers. LCA results are rarely joined with analyses of the social systems that control or influence decisionmaking and policies. As a result, LCA conclusions generally lack information about who or what controls different parts of the system, where and when the processes' environmental decisionmaking happens, and what aspects of the system (i.e. a policy or regulatory requirement) would have to change to enable lower environmental impact futures. The value of the combined institutional analysis and LCA (the IA-LCA) is demonstrated using a case study of passenger transportation in the Phoenix, Arizona metropolitan area. A retrospective LCA is developed to estimate how roadway investment has enabled personal vehicle travel and its associated energy, environmental, and economic effects. Using regional travel forecasts, a prospective life cycle inventory is developed. Alternative trajectories are modeled to reveal future "savings" from reduced roadway construction and vehicle travel. An institutional analysis matches the LCA results with the specific institutions, players, and policies that should be targeted to enable transitions to these alternative futures. The results show that energy, economic, and environmental benefits from changes in passenger transportation systems are possible, but vary significantly depending on the timing of the interventions. Transition strategies aimed at the most optimistic benefits should include 1) significant land-use planning initiatives at the local and regional level to incentivize transit-oriented development infill and urban densification, 2) changes to state or federal gasoline taxes, 3) enacting a price on carbon, and 4) nearly doubling vehicle fuel efficiency together with greater market penetration of alternative fuel vehicles. This aggressive trajectory could decrease the 2050 energy consumption to 1995 levels, greenhouse gas emissions to 1995, particulate emissions to 2006, and smog-forming emissions to 1972. The potential benefits and costs are both private and public, and the results vary when transition strategies are applied in different spatial and temporal patterns.
ContributorsKimball, Mindy (Author) / Chester, Mikhail (Thesis advisor) / Allenby, Braden (Committee member) / Golub, Aaron (Committee member) / Arizona State University (Publisher)
Created2014