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- All Subjects: Air Quality
- All Subjects: Sustainability
Description
The Toledo Core Based Statistical Area (CBSA) presents an interesting case study for the new sulfur dioxide (SO2) one hour standard. Since no SO2 monitor within 75 miles to estimate the attainment status of the area, American Meteorological Society/Environmental Protection Agency Regulatory Model (AERMOD) was used in this study to predict potential problems associated with the newly revised standard. The Toledo CBSA is home to two oil refineries, a glass making industry, several coal fired lime kilns, and a sulfuric acid regeneration plant, The CBSA 3 has coal fired power plants within a 30 mile radius of its center. Additionally, Toledo is a major Great Lakes shipping port visited by both lake and ocean going vessels. As a transportation hub, the area is also traversed by several rail lines which feed four rail switching yards. Impacts of older generation freighters, or "steamers", utilizing high sulfur "Bunker C" fuel oil in the area is also an issue. With the unique challenges presented by an SO2 one hour standard, this study attempted to estimate potential problem areas in advance of any monitoring data being gathered. Based on the publicly available data as inputs, it appears that a significant risk of non-attainment may exist in the Toledo CBSA. However, future on-the-books controls and currently proposed regulatory actions appear to drive the risk below significance by 2015. Any designation as non-attainment should be self-correcting and without need for controls other than those used in these models. The outcomes of this screening study are intended for use as a basis for assessments for other mid-sized, industrial areas without SO2 monitors. The results may also be utilized by industries and planning groups within the Toledo CBSA to address potential issues in advance of monitoring system deployment to lower the risk of attaining long term or perpetual non-attainment status.
ContributorsMyers, Greg Francis (Author) / Olson, Larry (Thesis advisor) / Edwards, David (Committee member) / Hristovski, Kiril (Committee member) / Arizona State University (Publisher)
Created2011
Description
Ion exchange sorbents embedded with metal oxide nanoparticles can have high affinity and high capacity to simultaneously remove multiple oxygenated anion contaminants from drinking water. This research pursued answering the question, “Can synthesis methods of nano-composite sorbents be improved to increase sustainability and feasibility to remove hexavalent chromium and arsenic simultaneously from groundwater compared to existing sorbents?” Preliminary nano-composite sorbents outperformed existing sorbents in equilibrium tests, but struggled in packed bed applications and at low influent concentrations. The synthesis process was then tailored for weak base anion exchange (WBAX) while comparing titanium dioxide against iron hydroxide nanoparticles (Ti-WBAX and Fe-WBAX, respectively). Increasing metal precursor concentration increased the metal content of the created sorbents, but pollutant removal performance and usable surface area declined due to pore blockage and nanoparticle agglomeration. An acid-post rinse was required for Fe-WBAX to restore chromium removal capacity. Anticipatory life cycle assessment identified critical design constraints to improve environmental and human health performance like minimizing oven heating time, improving pollutant removal capacity, and efficiently reusing metal precursor solution. The life cycle environmental impact of Ti-WBAX was lower than Fe-WBAX as well as a mixed bed of WBAX and granular ferric hydroxide for all studied categories. A separate life cycle assessment found the total number of cancer and non-cancer cases prevented by drinking safer water outweighed those created by manufacture and use of water treatment materials and energy. However, treatment relocated who bore the health risk, concentrated it in a sub-population, and changed the primary manifestation from cancer to non-cancer disease. This tradeoff was partially mitigated by avoiding use of pH control chemicals. When properly synthesized, Fe-WBAX and Ti-WBAX sorbents maintained chromium removal capacity while significantly increasing arsenic removal capacity compared to the parent resin. The hybrid sorbent performance was demonstrated in packed beds using a challenging water matrix and low pollutant influent conditions. Breakthrough curves hint that the hexavalent chromium is removed by anion exchange and the arsenic is removed by metal oxide sorption. Overall, the hybrid nano-sorbent synthesis methods increased sustainability, improved sorbent characteristics, and increased simultaneous removal of chromium and arsenic for drinking water.
ContributorsGifford, James McKay (Author) / Westerhoff, Paul (Thesis advisor) / Hristovski, Kiril (Thesis advisor) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2016
Description
Description
By avoiding vehicle idling for three minutes every day of the year can reduce 1.4 million metric tons annually, which is equivalent to taking 320,000 cars off the road for the entire year (Canada.ca, 2016). The Automobile Idle Reduction Program (AIRP) is an outreach initiative to prevent carbon emissions from being released into the air by automobiles idling in Maricopa County. The initiative establishes a campaign to promote behavioral changes that target high idling industries: freight and delivery, schools and drive- thru facilities.
Background
Globally, carbon emissions negatively alter the air we breathe and is a leading cause in climate change. These problems adversely affect the global environment and human health. Additionally, they have cancer causing agents in the particulate matter. Unfortunately, over the years, Maricopa County has failed to meet air quality standards for particulate matter pollution which effects the health of residents. By not meeting the air quality standards, Maricopa County can receive sanctions and the Environmental Protection Agency can reject Arizona’s State Implementation Plan. This looming threat can financially impinge the economy of Maricopa County, potentially costing taxpayers a substantial increase in taxes.
Strategy and Solution
To battle the creation of carbon emissions and particulate matter, AIRP has developed a strategy for each industry. In partnership with the Maricopa County Air Quality Department, AIRP will introduce the freight and delivery companies to the Diesel Emission Reduction Act (DERA) Grant promotion to facilitate and fiscally assist with changing older diesel engines into higher efficiency engines that burn cleaner. Provide educators a fifth to eighth grade state approved education program to teach students the importance of vehicle idling reduction at no cost. And work with community organizations to offer a discount at their stores for those patrons who choose to turn their engine off and order inside, rather than idling in the drive-thru facilities. The campaign will market the interest of AIRP to the general public through purposefully placed billboards, light rail wraps, social media pushes, handouts and vinyl stickers.
By avoiding vehicle idling for three minutes every day of the year can reduce 1.4 million metric tons annually, which is equivalent to taking 320,000 cars off the road for the entire year (Canada.ca, 2016). The Automobile Idle Reduction Program (AIRP) is an outreach initiative to prevent carbon emissions from being released into the air by automobiles idling in Maricopa County. The initiative establishes a campaign to promote behavioral changes that target high idling industries: freight and delivery, schools and drive- thru facilities.
Background
Globally, carbon emissions negatively alter the air we breathe and is a leading cause in climate change. These problems adversely affect the global environment and human health. Additionally, they have cancer causing agents in the particulate matter. Unfortunately, over the years, Maricopa County has failed to meet air quality standards for particulate matter pollution which effects the health of residents. By not meeting the air quality standards, Maricopa County can receive sanctions and the Environmental Protection Agency can reject Arizona’s State Implementation Plan. This looming threat can financially impinge the economy of Maricopa County, potentially costing taxpayers a substantial increase in taxes.
Strategy and Solution
To battle the creation of carbon emissions and particulate matter, AIRP has developed a strategy for each industry. In partnership with the Maricopa County Air Quality Department, AIRP will introduce the freight and delivery companies to the Diesel Emission Reduction Act (DERA) Grant promotion to facilitate and fiscally assist with changing older diesel engines into higher efficiency engines that burn cleaner. Provide educators a fifth to eighth grade state approved education program to teach students the importance of vehicle idling reduction at no cost. And work with community organizations to offer a discount at their stores for those patrons who choose to turn their engine off and order inside, rather than idling in the drive-thru facilities. The campaign will market the interest of AIRP to the general public through purposefully placed billboards, light rail wraps, social media pushes, handouts and vinyl stickers.
ContributorsWeston-Smith, Kristen (Writer of accompanying material)
Created2020-05-13