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- All Subjects: Environmental engineering
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- All Subjects: Leachate
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- All Subjects: Zero Valent Metals
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Description
Zero-Valent Metals (ZVM) are highly reactive materials and have been proved to be effective in contaminant reduction in soils and groundwater remediation. In fact, zero-Valent Iron (ZVI) has proven to be very effective in removing, particularly chlorinated organics, heavy metals, and odorous sulfides. Addition of ZVI has also been proved in enhancing the methane gas generation in anaerobic digestion of activated sludge. However, no studies have been conducted regarding the effect of ZVM stimulation to Municipal Solid Waste (MSW) degradation. Therefore, a collaborative study was developed to manipulate microbial activity in the landfill bioreactors to favor methane production by adding ZVMs. This study focuses on evaluating the effects of added ZVM on the leachate generated from replicated lab scale landfill bioreactors. The specific objective was to investigate the effects of ZVMs addition on the organic and inorganic pollutants in leachate. The hypothesis here evaluated was that adding ZVM including ZVI and Zero Valent Manganese (ZVMn) will enhance the removal rates of the organic pollutants present in the leachate, likely by a putative higher rate of microbial metabolism. Test with six (4.23 gallons) bioreactors assembled with MSW collected from the Salt River Landfill and Southwest Regional Landfill showed that under 5 grams /liter of ZVI and 0.625 grams/liter of ZVMn additions, no significant difference was observed in the pH and temperature data of the leachate generated from these reactors. The conductivity data suggested the steady rise across all reactors over the period of time. The removal efficiency of sCOD was highest (27.112 mg/lit/day) for the reactors added with ZVMn at the end of 150 days for bottom layer, however the removal rate was highest (16.955 mg/lit/day) for ZVI after the end of 150 days of the middle layer. Similar trends in the results was observed in TC analysis. HPLC study indicated the dominance of the concentration of heptanoate and isovalerate were leachate generated from the bottom layer across all reactors. Heptanoate continued to dominate in the ZVMn added leachate even after middle layer injection. IC analysis concluded the chloride was dominant in the leachate generated from all the reactors and there was a steady increase in the chloride content over the period of time. Along with chloride, fluoride, bromide, nitrate, nitrite, phosphate and sulfate were also detected in considerable concentrations. In the summary, the addition of the zero valent metals has proved to be efficient in removal of the organics present in the leachate.
ContributorsPandit, Gandhar Abhay (Author) / Cadillo – Quiroz, Hinsby (Thesis advisor) / Olson, Larry (Thesis advisor) / Boyer, Treavor (Committee member) / Arizona State University (Publisher)
Created2019
Description
Population growth within drylands is occurring faster than growth in any other ecologic zone, putting pressure on already stressed water resources. Because the availability of surface water supplies in drylands tends to be highly variable, many of these populations rely on groundwater. A critical process contributing to groundwater recharge is the interaction between ephemeral channels and groundwater aquifers. Generally, it has been found that ephemeral channels contribute to groundwater recharge when streamflow infiltrates into the sandy bottoms of channels. This process has traditionally been studied in channels that drain large areas (10s to 100s km2). In this dissertation, I study the interactions between surface water and groundwater via ephemeral channels in a first-order watershed located on an arid piedmont slope within the Jornada Experimental Range (JER) in the Chihuahuan Desert. To achieve this, I utilize a combination of high-resolution observations and computer simulations using a modified hydrologic model to quantify groundwater recharge and shed light on the geomorphic and ecologic processes that affect the rate of recharge. Observational results indicate that runoff generated within the piedmont slope contributes significantly to deep percolation. During the short-term (6 yr) study period, we estimated 385 mm of total percolation, 62 mm/year, or a ratio of percolation to rainfall of 0.25. Based on the instrument network, we identified that percolation occurs inside channel areas when these receive overland sheetflow from hillslopes. By utilizing a modified version of the hydrologic model, TIN-based Real-time Integrated Basin Simulator (tRIBS), that was calibrated and validated using the observational dataset, I quantified the effects of changing watershed properties on groundwater recharge. Distributed model simulations quantify how deep percolation is produced during the streamflow generation process, and indicate that it plays a significant role in moderating the production of streamflow. Sensitivity analyses reveal that hillslope properties control the amount of rainfall necessary to initiate percolation while channel properties control the partitioning of hillslope runoff into streamflow and deep percolation. Synthetic vegetation experiments show that woody plant encroachment leads to increases in both deep percolation and streamflow. Further woody plant encroachment may result in the unexpected enhancement of dryland aquifer sustainability.
ContributorsSchreiner-McGraw, Adam P (Author) / Vivoni, Enrique R. (Thesis advisor) / Whipple, Kelin X. (Committee member) / Mascaro, Giuseppe (Committee member) / Throop, Heather L. (Committee member) / Sala, Osvaldo E. (Committee member) / Arizona State University (Publisher)
Created2017