Urea is an added value chemical with wide applications in the industry and agriculture. The release of urea waste to the environment affects ecosystem health despite its low toxicity. Online monitoring of urea for industrial applications and environmental health is an unaddressed challenge. Electroanalytical techniques can be a smart integrated solution for online monitoring if sensors can overcome the major barrier associated with long-term stability. Mixed metal oxides have shown excellent stability in environmental conditions with long lasting operational lives. However, these materials have been barely explored for sensing applications. This work presents a proof of concept that demonstrates the applicability of an indirect electroanalytical quantification method of urea. The use of Ti/RuO2-TiO2-SnO2 dimensional stable anode (DSA®) can provide accurate and sensitive quantification of urea in aqueous samples exploiting the excellent catalytic properties of DSA® on the electrogeneration of active chlorine species. The cathodic reduction of accumulated HClO/ClO− from anodic electrogeneration presented a direct relationship with urea concentration. This novel method can allow urea quantification with a competitive LOD of 1.83 × 10−6 mol L−1 within a linear range of 6.66 × 10−6 to 3.33 × 10−4 mol L−1 of urea concentration.

A web-based software tool has been developed to assist urban planners and air quality management officials in assessing the potential ofurban heat island mitigation strategies to affect the urban climate, air quality, and energy consumption within their cities. The user of thetool can select from over 170 US cities for which to conduct the analysis, and can specify city-wide changes in surface reflectivity and/or veg-etative cover. The Mitigation Impact Screening Tool (MIST) then extrapolates results from a suite of simulations for 20 cities to estimate airtemperature changes associated with the specified changes in surface characteristics for the selected city. Alternatively the user can simply definea nominal air temperature reduction that they hope to achieve with an unspecified mitigation scenario. These air temperature changes are theninput to energy and ozone models to estimate the impact that the mitigation action may have on the selected city. The results presented by MISTinclude a high degree of uncertainty and are intended only as a first-order estimate that urban planners can use to assess the viability of heatisland mitigation strategies for their cities. As appropriate, MIST analyses should be supplemented by more detailed modeling.