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Air pollution is a serious problem in most urban areas around the world, which has a number of negative ecological and human health impacts. As a result, it's vitally important to detect and characterize air pollutants to protect the health of the urban environment and our citizens. An important early

Air pollution is a serious problem in most urban areas around the world, which has a number of negative ecological and human health impacts. As a result, it's vitally important to detect and characterize air pollutants to protect the health of the urban environment and our citizens. An important early step in this process is ensuring that the air pollution monitoring network is properly designed to capture the patterns of pollution and that all social demographics in the urban population are represented. An important aspect in characterizing air pollution patterns is scale in space and time which, along with pattern and process relationships, is a key subject in the field of landscape ecology. Thus, using multiple landscape ecological methods, this dissertation research begins by characterizing and quantifying the multi-scalar patterns of ozone (O3) and particulate matter (PM10) in the Phoenix, Arizona, metropolitan region. Results showed that pollution patterns are scale-dependent, O3 is a regionally-scaled pollutant at longer temporal scales, and PM10 is a locally-scaled pollutant with patterns sensitive to season. Next, this dissertation examines the monitoring network within Maricopa County. Using a novel multiscale indicator-based approach, the adequacy of the network was quantified by integrating inputs from various academic and government stakeholders. Furthermore, deficiencies were spatially defined and recommendations were made on how to strengthen the design of the network. A sustainability ranking system also provided new insight into the strengths and weaknesses of the network. Lastly, the study addresses the question of whether distinct social groups were experiencing inequitable exposure to pollutants - a key issue of distributive environmental injustice. A novel interdisciplinary method using multi-scalar ambient pollution data and hierarchical multiple regression models revealed environmental inequities between air pollutants and race, ethnicity, age, and socioeconomic classes. The results indicate that changing the scale of the analysis can change the equitable relationship between pollution and demographics. The scientific findings of the scale-dependent relationships among air pollution patterns, network design, and population demographics, brought to light through this study, can help policymakers make informed decisions for protecting the human health and the urban environment in the Phoenix metropolitan region and beyond.
ContributorsPope, Ronald L (Author) / Wu, Jianguo (Thesis advisor) / Boone, Christopher G. (Committee member) / Brazel, Anthony J. (Committee member) / Forzani, Erica S. (Committee member) / Fraser, Matthew P. (Committee member) / Arizona State University (Publisher)
Created2014
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Description
I present the results of studies from two historically separate fields of research: heat related illness and human thermal comfort adaptation. My research objectives were: (a) to analyze the relationships between climate and heat related morbidity in Phoenix, Arizona and Chicago, Illinois; (b) explore possible linkages of human thermal comfort

I present the results of studies from two historically separate fields of research: heat related illness and human thermal comfort adaptation. My research objectives were: (a) to analyze the relationships between climate and heat related morbidity in Phoenix, Arizona and Chicago, Illinois; (b) explore possible linkages of human thermal comfort adaptation to heat-related illness; and (c) show possible benefits of collaboration between the two fields of research. Previous climate and mortality studies discovered regional patterns in summertime mortality in North America: lower in hot, southern cities compared to more temperate cities. I examined heat related emergency (911) dispatches from these two geographically and climatically different cities. I analyzed with local weather conditions with 911 dispatches identified by responders as "heat" related from 2001 to 2006 in Phoenix and 2003 through 2006 in Chicago. Both cities experienced a rapid rise in heat-related dispatches with increasing temperature and heat index, but at higher thresholds in Phoenix. Overall, Phoenix had almost two and half times more heat-related dispatches than Chicago. However, Phoenix did not experience the large spikes of heat-related dispatches that occurred in Chicago. These findings suggest a resilience to heat-related illness that may be linked to acclimatization in Phoenix. I also present results from a survey based outdoor human thermal comfort field study in Phoenix to assess levels of local acclimatization. Previous research in outdoor human thermal comfort in hot humid and temperate climates used similar survey-based methodologies and found higher levels of thermal comfort (adaptation to heat) that in warmer climates than in cooler climates. The study presented in this dissertation found outdoor thermal comfort thresholds and heat tolerance levels in Phoenix were higher than previous studies from temperate climates more similar to Chicago. These differences were then compared to the differences in weather conditions associated with heat-related dispatches. The higher comfort thresholds in Phoenix were similar in scale to the climate differences associated with the upsurge in heat-related dispatches in Phoenix and Chicago. This suggests a link between heat related illness and acclimatization, and illustrates potential for collaboration in research between the two fields.
ContributorsHartz, Donna (Author) / Brazel, Anthony J. (Thesis advisor) / Heisler, Gordon (Committee member) / Cerveny, Randal (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Monsoon hazards routinely affect the community, economy, and environment of the American Southwest. A common link for hazard development during the North American Monsoon concerns the interplay between temperature, moisture, and wind in the vertical atmosphere controlled by an unstable monsoon circulation. This dissertation investigates vertical atmospheric patterns using in-situ

Monsoon hazards routinely affect the community, economy, and environment of the American Southwest. A common link for hazard development during the North American Monsoon concerns the interplay between temperature, moisture, and wind in the vertical atmosphere controlled by an unstable monsoon circulation. This dissertation investigates vertical atmospheric patterns using in-situ sounding data, specifically, 1) environments favorable for severe hail on the Colorado Plateau, 2) significant parameters distinguishing unhealthy versus healthy ozone days in Phoenix, Arizona, and 3) vertical profile alignments associated with distinct ranges in ozone concentrations observed in Phoenix having defined health impacts.

The first study (published in the Journal of the Arizona-Nevada Academy of Science) determines significant variables on Flagstaff, Arizona 12Z rawinsonde data (1996-2009) found on severe hail days on the Colorado Plateau. Severe hail is related to greater sub-300 hectopascals (hPa) moisture, a warmer atmospheric column, lighter above surface wind speeds, more southerly to southeasterly oriented winds throughout the vertical (except at the 700 hPa pressure level), and higher geopotential heights.

The second study (published in Atmospheric Environment) employs principal component, linear discriminant, and synoptic composite analyses using Phoenix, Arizona rawinsonde data (2006-2016) to identify common monsoon patterns affecting ozone accumulation in the Phoenix metropolitan area. Unhealthy ozone occurs with amplified high-pressure ridging over the Four Corners region, 500 hPa heights often exceeding 5910 meters, surface afternoon temperatures typically over 40°C, lighter wind speeds in the planetary boundary layer under four ms-1, and persistent light easterly flow between 700-500 hPa countering the daytime mountain-valley circulation.

The final study (under revision in Weather and Forecasting) assesses composite atmospheric sounding analysis to forecast Air Quality Index ozone classifications of Good, Moderate, and collectively categories exceeding the U.S. EPA 2015 standard. The analysis, using Phoenix 12Z rawinsonde data (2006-2017), identifies the existence of “pollutant dispersion windows” for ozone accumulation and dispersal in Phoenix.

Ultimately, monsoon hazards result from a complex and evolving vertical atmosphere. This dissertation demonstrates the viability using available in-situ vertical upper-air data to anticipate recurring atmospheric states contributing to specific hazards. These results will improve monsoon hazard prediction in an effort to protect public and infrastructure.
ContributorsMalloy, Jonny William (Author) / Cerveny, Randall S. (Thesis advisor) / Selover, Nancy J (Committee member) / Brazel, Anthony J. (Committee member) / Balling, Robert C. (Committee member) / Arizona State University (Publisher)
Created2019
Description

Better methods are necessary to fully account for anthropogenic impacts on ecosystems and the essential services provided by ecosystems that sustain human life. Current methods for assessing sustainability, such as life cycle assessment (LCA), typically focus on easily quantifiable indicators such as air emissions with no accounting for the essential

Better methods are necessary to fully account for anthropogenic impacts on ecosystems and the essential services provided by ecosystems that sustain human life. Current methods for assessing sustainability, such as life cycle assessment (LCA), typically focus on easily quantifiable indicators such as air emissions with no accounting for the essential ecosystem benefits that support human or industrial processes. For this reason, more comprehensive, transparent, and robust methods are necessary for holistic understanding of urban technosphere and ecosphere systems, including their interfaces. Incorporating ecosystem service indicators into LCA is an important step in spanning this knowledge gap.

For urban systems, many built environment processes have been investigated but need to be expanded with life cycle assessment for understanding ecosphere impacts. To pilot these new methods, a material inventory of the building infrastructure of Phoenix, Arizona can be coupled with LCA to gain perspective on the impacts assessment for built structures in Phoenix. This inventory will identify the origins of materials stocks, and the solid and air emissions waste associated with their raw material extraction, processing, and construction and identify key areas of future research necessary to fully account for ecosystem services in urban sustainability assessments. Based on this preliminary study, the ecosystem service impacts of metropolitan Phoenix stretch far beyond the county boundaries. A life cycle accounting of the Phoenix’s embedded building materials will inform policy and decision makers, assist with community education, and inform the urban sustainability community of consequences.